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    ELASTOMERIC COMPOUND
    82.
    发明申请
    ELASTOMERIC COMPOUND 审中-公开
    弹性体

    公开(公告)号：US20100105851A1

    公开(公告)日：2010-04-29

    申请号：US12525624

    申请日：2008-02-06

    Applicant: Gerardus Henricus Josephus Van Doremaele ,  Mirko Kranenburg ,  Konraad Dullaert

    Inventor： Gerardus Henricus Josephus Van Doremaele ,  Mirko Kranenburg ,  Konraad Dullaert

    IPC: C08F10/00

    CPC classification number: C08F210/18 ,  C08L23/16 ,  C08L2205/02 ,  C08L2312/00 ,  C08L2666/06 ,  C08F210/06 ,  C08F236/20 ,  C08F2500/25 ,  C08F2500/09 ,  C08F2500/17 ,  C08F2500/21

    Abstract: The invention relates to an elastomeric compound comprising at least one olefinic elastomer comprising ethylene, an α-olefin, from 1 to 7 wt % vinyl norbornene and from 0 to 15 wt % of a second non-conjugated polyene, wherein the wt % are related to the total weight of ethylene, α-olefin, vinyl norbornene and the second non-conjugated polyene, and which elastomer has long chain branching corresponding with Δδ 30, wherein Sb is the slope in graph of ln(ac) versus Φ, in which ac is the factor along which the low frequency part (ω

    Abstract translation: 本发明涉及弹性体化合物，其包含至少一种烯烃弹性体，其包含乙烯，α-烯烃，1至7重量％的乙烯基降冰片烯和0至15重量％的第二非共轭多烯，其中wt％相关 相对于乙烯，α-烯烃，乙烯基降冰片烯和第二非共轭多烯的总重量，并且该弹性体具有对应于＆Dgr;δ<20的长链支化，其中以度计表示的＆Dgr;δ 在125℃下以0.1rad的频率和频率为100rad / s的相位角δ的动态剪切测量中的应力和应变之间的相位角δ与进一步包含固体分蘖和油的化合物之间， 使得化合物的化合物负载量在120-300phr之间，其中所述烯烃弹性体满足以下关系Sb> 30，其中Sb是ln（ac）对Φ的曲线图中的斜率，其中ac是 低频部分（ω<1 ra 在角鲨烯中的烯属弹性体的至少一个体积分数Φ在0.2和1之间测量的相位角δ对ω图的d / s必须移动以与未稀释的聚合物的δ对ω曲线一致（Φ= 1），并且其中δ对ω曲线来自在氮气气氛下使用平行板几何形状剪切下在125℃下进行的应力控制流变仪上进行的频率扫描。 本发明还涉及制备本发明化合物的方法。

    Synthesis and use of well-defined, highly-branched saturated hydrocarbon polymers
    83.
    发明授权
    Synthesis and use of well-defined, highly-branched saturated hydrocarbon polymers 有权
    明确定义的高度支化的饱和烃聚合物的合成和使用

    公开(公告)号：US07687580B2

    公开(公告)日：2010-03-30

    申请号：US11296999

    申请日：2005-12-08

    Applicant: David J. Lohse ,  César Garcia-Franco ,  Nikos Hadjichristidis

    Inventor： David J. Lohse ,  César Garcia-Franco ,  Nikos Hadjichristidis

    IPC: C08F10/00 ,  C08F36/08 ,  C08F8/42 ,  C08F36/04

    CPC classification number: C08C19/44 ,  C08C19/02 ,  C08F36/04 ,  C08F110/02 ,  C08F236/10 ,  C08F255/02 ,  C08G83/003 ,  C08L9/00 ,  C08L23/0815 ,  C08L51/06 ,  C08L101/005 ,  C08L2205/14 ,  C08L2205/16 ,  C08L2666/06 ,  C08L2666/02 ,  C08L2666/04 ,  C08F4/48 ,  C08F2500/09

    Abstract: The present invention relates to a method to produce highly branched polymers with a polyolefin backbone structure of ethylene and precise control of the nature of the branching. In particular, the distribution of branch length and number of branches can be more precisely controlled via the polymerization method of the present invention. The method comprises using anionic chemistry to make unsaturated polydienes with a well-defined, highly-branched structure, and then hydrogenating these polydienes to form highly branched or dendritic saturated hydrocarbon polymers. Highly branched or dendritic polyethylene, ethylene-propylene copolymer and atactic polypropylene are among the saturated hydrocarbon polymers that can be anionically synthesized via the proper selection of diene monomer type, coupling agent, and hydrogenation conditions. These polymers find application in injection molding and extrusion processes as a minor additive for improving processability of linear polyolefins by delaying the onset of melt fracture, and correspondingly increasing melt throughput rates.

    Abstract translation: 本发明涉及一种生产具有乙烯聚烯烃骨架结构的高度支化聚合物的方法，并且精确控制了支化性质。 特别地，可以通过本发明的聚合方法更精确地控制分支长度和分支数的分布。 该方法包括使用阴离子化学制备具有明确定义的高支化结构的不饱和聚二烯，然后将这些聚二烯氢化形成高度支化或树枝状饱和烃聚合物。 高分支或树枝状聚乙烯，乙烯 - 丙烯共聚物和无规立构聚丙烯是通过二烯单体类型，偶联剂和氢化条件的适当选择可阴离子合成的饱和烃聚合物之一。 这些聚合物可用作注射成型和挤出方法，作为通过延迟熔融破裂开始以及相应地提高熔体流动速率来改善线性聚烯烃的加工性的次要添加剂。

    BRANCHED POLYOLEFIN POLYMER TETHERED WITH POLYMERIZABLE METHACRYLOYL GROUPS AND PROCESS FOR PREPARING SAME
    84.
    发明申请
    BRANCHED POLYOLEFIN POLYMER TETHERED WITH POLYMERIZABLE METHACRYLOYL GROUPS AND PROCESS FOR PREPARING SAME 审中-公开
    用可聚合甲基丙烯酸组合分散的聚烯烃聚合物及其制备方法

    公开(公告)号：US20090253878A1

    公开(公告)日：2009-10-08

    申请号：US12394540

    申请日：2009-02-27

    Applicant: Zhibin Ye ,  Jianli Wang ,  Kejian Zhang

    Inventor： Zhibin Ye ,  Jianli Wang ,  Kejian Zhang

    IPC: C08F22/10 ,  C08F2/00

    CPC classification number: C08F210/02 ,  C08F110/02 ,  C08F4/80 ,  C08F2500/09 ,  C08F220/26

    Abstract: A polyolefin polymer comprising one or more terminal polymerizable methacryloyl groups (i.e. tethered to the main body of the polymer) and a novel process for preparing same are herein disclosed. A hyperbranched polyethylene polymer and a process for preparing same are also disclosed. The polymer is prepared by a novel one-pot copolymerization reaction of an olefin, such as ethylene, and a heterobifunctional comonomer comprising a methacryloyl group, catalyzed by a late transition metal α-diimine catalyst which is selectively non-reactive towards methacryloyl groups. The process allows for preparation of polymers with various chain topologies, including linear, branched, and hyperbranched topologies. The terminal methacryloyl groups within the polymer are reactive in further polymerization reactions. Thus, the polymer may be used in materials and applications which require cross-linking or further polymerization, for example, UV/thermal/radical curable crosslinkers for use in thermoset applications.

    Abstract translation: 本文公开了包含一个或多个末端可聚合甲基丙烯酰基（即与聚合物的主体连接的聚烯烃）的聚烯烃聚合物及其制备方法。 还公开了一种超支化聚乙烯聚合物及其制备方法。 聚合物通过烯烃如乙烯的新型单罐共聚反应和包含甲基丙烯酰基的异双官能共聚单体制备，由对过甲基丙烯酰基的选择性不反应的后过渡金属α-二亚胺催化剂催化。 该方法允许制备具有各种链拓扑的聚合物，包括线性，支化和超支化拓扑。 聚合物内的末端甲基丙烯酰基在进一步的聚合反应中具有反应性。 因此，聚合物可以用于需要交联或进一步聚合的材料和应用中，例如用于热固性应用的UV /热可固化交联剂。

    One-pot process and reagents for preparing long chain branched polymers
    85.
    发明授权
    One-pot process and reagents for preparing long chain branched polymers 失效
    一锅法和制备长支链聚合物的试剂

    公开(公告)号：US07511105B2

    公开(公告)日：2009-03-31

    申请号：US11170698

    申请日：2005-06-29

    Applicant: Tze-Chiang Chung

    Inventor： Tze-Chiang Chung

    IPC: C08F4/6192 ,  C08F210/06 ,  C08F12/06 ,  C08F12/34 ,  C08F8/18 ,  C08F8/30 ,  C08F257/00

    CPC classification number: C08F10/00 ,  C08F4/65912 ,  C08F10/06 ,  C08F210/06 ,  C08F4/65927 ,  C08F2/38 ,  C08F212/06 ,  C08F2500/09

    Abstract: A one-pot polymerization process of preparing long chain branching polymers is provided. Also described is a “T” reagent that serves as a link between main and side chains of an inventive long chain branching polymer. A “T” reagent has at least two functionalities, serving as both co-monomer and chain transfer reaction agent. Optionally, a copolymerization reaction between an alpha-olefin and “T” reagent takes place initially to incorporate some “T” molecules in the polyolefin main chain, and the incorporated “T” units then behave as chain transfer agents for reacting with the propagating polyolefin chains to form side chains. In a particular embodiment, a polymerization process for preparing long chain branching polyethylene (LCBPE) and long chain branching polypropylene (LCBPP) is detailed.

    Abstract translation: 提供了制备长链支化聚合物的一锅聚合方法。 还描述了作为本发明的长链支化聚合物的主链和侧链之间的连接的“T”试剂。 “T”试剂具有至少两种用作共聚单体和链转移反应剂的功能。 可选地，首先在α-烯烃和“T”试剂之间进行共聚反应，以在聚烯烃主链中加入一些“T”分子，然后加入的“T”单元表现为用于与传播聚烯烃反应的链转移剂 链形成侧链。 在具体实施方案中，详细描述了制备长支链聚乙烯（LCBPE）和长链支化聚丙烯（LCBPP）的聚合方法。

    Multiple catalyst system for olefin polymerization and polymers produced therefrom
    86.
    发明申请
    Multiple catalyst system for olefin polymerization and polymers produced therefrom 有权

    公开(公告)号：US20090069475A1

    公开(公告)日：2009-03-12

    申请号：US11888870

    申请日：2007-08-02

    Applicant: Peijun Jiang ,  Armenag Hagop Dekmezian ,  Jo Ann Marie Canich ,  Charles Lewis Sims ,  Ramin Abhari ,  Cesar Alberto Garcia-Franco ,  David Raymond Johnsrud

    Inventor： Peijun Jiang ,  Armenag Hagop Dekmezian ,  Jo Ann Marie Canich ,  Charles Lewis Sims ,  Ramin Abhari ,  Cesar Alberto Garcia-Franco ,  David Raymond Johnsrud

    IPC: C08F10/00 ,  C08F10/04 ,  C08F10/14 ,  C08L91/06

    CPC classification number: C09J123/12 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  C08L57/02 ,  C08L2666/02 ,  C09J5/00 ,  C09J7/20 ,  C09J123/10 ,  C09J2201/606 ,  C09J2201/622 ,  C09J2205/31 ,  C09J2401/006 ,  C09J2421/00 ,  C09J2423/006 ,  C09J2423/046 ,  C09J2423/106 ,  C09J2427/006 ,  C09J2433/00 ,  Y10S526/943 ,  C08F4/65904 ,  C08F2500/15 ,  C08F2500/05 ,  C08F2500/20 ,  C08F2500/17 ,  C08F2500/09 ,  C08F2500/12 ,  C08F236/20 ,  C08F2500/03 ,  C08F210/16 ,  C08F4/63904

    Abstract: This invention relates to a polymer comprising one or more C3 to C40 olefins, optionally one or more diolefins, and less than 15 mole % of ethylene, where the polymer has: a) a Dot T-Peel of 1 Newton or more; and b) a branching index (g′) of 0.95 or less measured at the Mz of the polymer; c) an Mw of 100,000 or less. This invention also relates a polymer comprising one or more C3 to C40 olefins where the polymer has: a) a Dot T-Peel of 1 Newton or more on Kraft paper; b) a branching index (g′) of 0.95 or less measured at the Mz of the polymer; c) a Mw of 10,000 to 100,000; and d) a heat of fusion of 1 to 70 J/g. This invention also relates a polymer comprising one or more C3 to C40 olefins where the polymer has: a) a Dot T-Peel of 1 Newton or more on Kraft paper; b) a branching index (g′) of 0.98 or less measured at the Mz of the polymer; c) a Mw of 10,000 to 60,000; d) a heat of fusion of 1 to 50 J/g. This invention also relates to a homopolypropylene or a copolymer of propylene and up to 5 mole % ethylene having: a) an isotactic run length of 1 to 30 (isotactic run length “IRL” is defined to be the percent of mmmm pentad divided by 0.5×percent of mmmr pentad) as determined by Carbon 13 NMR, preferably 3 to 25, more preferably 4 to 20, b) a percent of r dyad of greater than 20%, preferably from 20 to 70% as determined by Carbon 13 NMR, and c) a heat of fusion of 70 J/g or less, preferably 60 J/g or less, more preferably between 1 and 55 J/g, more preferably between 4 and 50 J/g. This invention further relates to a process to produce an olefin polymer comprising: 1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 5% or less at selected polymerization conditions; 2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 20% or more at the selected polymerization conditions; 3) contacting the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins, at the selected polymerization conditions in a reaction zone; 4) obtaining the polymer. This invention further relates to a continuous process to produce a branched olefin polymer comprising: 1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 5% or less under selected polymerization conditions; 2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 20% or more at the selected polymerization conditions; 3) contacting the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins, and, optionally one or more diolefins; 4) at a temperature of greater than 100° C.; 5) at a residence time of 120 minutes or less; 6) wherein the ratio of the first catalyst to the second catalyst is from 1:1 to 50:1; 7) wherein the activity of the catalyst components is at least 100 kilograms of polymer per gram of the catalyst components; and wherein at least 20% of the olefins are converted to polymer.

    Super-Solution Homogeneous Propylene Polymerization
    90.
    发明申请
    Super-Solution Homogeneous Propylene Polymerization 有权
    超溶液均相丙烯聚合

    公开(公告)号：US20080188635A1

    公开(公告)日：2008-08-07

    申请号：US12098907

    申请日：2008-04-07

    Applicant: Patrick Brant ,  Gary L. Casty ,  Gabor kiss ,  Raymond A. Cook ,  James R. Lattner

    Inventor： Patrick Brant ,  Gary L. Casty ,  Gabor kiss ,  Raymond A. Cook ,  James R. Lattner

    IPC: C08F110/06

    CPC classification number: C08F10/06 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/06 ,  C08L21/00 ,  C08F4/65908 ,  C08F2/06 ,  C08F2/14 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/20

    Abstract: Processes for polymerizing propylene. About 40 wt % to about 80 wt % propylene monomer, based on total weight of propylene monomer and diluent, and about 20 wt % to about 60 wt % diluent, based on total weight of propylene monomer and diluent, can be fed into a reactor. The propylene monomer can be polymerized in the presence of a metallocene catalyst and an activator within the reactor at a temperature of about 80° C. or more and a pressure of about 13 MPa or more to produce a polymer product in a homogenous system. About 20 wt % to about 76 wt % (preferably About 28 wt % to about 76 wt %) propylene monomer, based on total weight of the propylene monomer, diluent, and polymer product, can be present at the reactor exit at steady state conditions.

    Abstract translation: 丙烯聚合方法 基于丙烯单体和稀释剂的总重量计，约40重量％至约80重量％的丙烯单体和约20重量％至约60重量％的稀释剂（基于丙烯单体和稀释剂的总重量）可以进料到反应器 。 丙烯单体可在茂金属催化剂和活化剂存在下在约80℃以上的温度和约13MPa或更高的压力下在反应器内聚合，以在均匀体系中生产聚合物产物。 基于丙烯单体，稀释剂和聚合物产物的总重量，约20重量％至约76重量％（优选约28重量％至约76重量％）的丙烯单体可以在稳态条件下在反应器出口处存在 。

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