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公开(公告)号：US20230136180A1
公开(公告)日：2023-05-04
申请号：US17905233
申请日：2021-02-25
发明人： Takashi ABE
摘要： The present invention provides resin beads that can provide various types of products such as cosmetics which are unlikely to generate an odor and have superior tactile impression and spreadability on the skin and that can be substituted for resin particles composed of a synthetic material derived from petroleum, and the present invention also provides various types of products such as cosmetics using the resin beads. The resin beads are formed with a resin containing a cellulose derivative as a main component. In the resin beads, the cellulose derivative is at least one selected from the group consisting of cellulose acetate, cellulose acetate propionate, ethyl cellulose, and hydroxypropyl methyl cellulose, the volume average particle diameter is 50 μm or smaller, the degree of sphericity is 0.7 to 1.0, the degree of surface smoothness is 80 to 100%, the acetyl group content ratio is 15% by mass or less, and the propionyl group content ratio is 10% by mass or more. In addition, the present invention provides a product of any one of a cosmetic, a dermatological preparation, a paint, a shaped article, a film, a coating agent, and a resin composition, which contain the resin beads.
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公开(公告)号：US11458088B2
公开(公告)日：2022-10-04
申请号：US16755800
申请日：2018-10-24
发明人： Yasuyuki Isono , Yu Aso
摘要： The present invention provides a cosmetic shaped product: which is substantially formed with relatively low-molecular-weight hyaluronic acid or a water-soluble salt thereof having a high penetrability into the skin; which is easily soluble to water; and which has satisfactory handling properties, and a method for producing the cosmetic shaped product. There is provided a cosmetic shaped product being a sponge-like shaped body formed with at least one polyanionic polysaccharide of hyaluronic acid and a water-soluble salt thereof each having an average molecular weight of 30,000 or lower, the sponge-like shaped body having a bulk specific gravity of 5 to 500 mg/mL. This cosmetic shaped product can be produced by freeze-drying an aqueous solution having a content of the polyanionic polysaccharide of 0.5 to 30% by mass.
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公开(公告)号：US20220267573A1
公开(公告)日：2022-08-25
申请号：US17597111
申请日：2020-07-07
发明人： Takashi ABE
摘要： The present invention provides a method for producing resin beads which can provide various types of products, such as cosmetics, imparted with superior tactile impression, spreadability on the skin, transparency, and product stability, and which can be substituted for resin particles composed of a synthetic material derived from petroleum. The method is a method for producing resin beads containing a cellulose derivative as a main component. The production method includes: a suspension preparation step of mixing an oil phase containing the cellulose derivative and an organic solvent that dissolves the cellulose derivative, the organic solvent having a water-solubility of 0.1 to 50.0 g, and an aqueous phase containing a dispersion stabilizer, thereby preparing a suspension containing oil droplets containing the cellulose derivative and the organic solvent; and an oil droplet contraction step of adding water to the suspension, thereby contracting the oil droplets, wherein the water is added to the suspension in such a way as to satisfy the following expression (A) until a content of the organic solvent in the suspension becomes equal to or less than the water-solubility of the organic solvent. (W/S)/T≤1.00 (A), wherein W: an addition amount of water (parts by mass),
S: an amount of the suspension (parts by mass), and
T: a time (minutes) required for addition.-
公开(公告)号：US20220034027A1
公开(公告)日：2022-02-03
申请号：US17278488
申请日：2019-09-20
发明人： Ryo KAWAMURA , Toshiki YAMADA , Kazuya SASAKI
摘要： Provided is a porous layer structure including a base material (A) and a urethane foam layer provided on the base material (A), wherein the urethane foam layer is a foam layer formed by foaming a urethane prepolymer having an isocyanate group, the urethane foam layer has a density of 0.10 to 0.60 g/cm3, and the urethane prepolymer substantially contains no volatile component and satisfies a predetermined composition.
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公开(公告)号：US11174335B2
公开(公告)日：2021-11-16
申请号：US16091024
申请日：2017-03-31
申请人： SHIN-ETSU CHEMICAL CO., LTD. , DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD. , SHINSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION
发明人： Hatsuhiko Hattori , Masaki Tanaka , Hiromasa Sato , Shota Iino , Motoaki Umezu , Toshihisa Tanaka , Mikihisa Kondo
IPC分类号： C08G18/61 , D04H1/4358 , D04H1/728 , D01F6/70 , C08G18/65 , C08G18/18 , C08G18/32 , C08G18/40 , C08G18/48 , C08G18/66 , C08G18/75 , C08G18/76 , D01D5/00
摘要： Disclosed herein is a fiber formed from a resin including a silicone-modified polyurethane resin comprising the reaction products of a polyol (A), a chain extender (B), an active-hydrogen-group-containing organopolysiloxane (C), and a polyisocyanate (D), wherein the active-hydrogen-group-containing organopolysiloxane (C) contains an active-hydrogen-group-containing organopolysiloxane (C-1) having a carbinol group at only one terminal.
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公开(公告)号：US20210115278A1
公开(公告)日：2021-04-22
申请号：US16606591
申请日：2018-04-24
发明人： Iwao MISAIZU , Hiromasa SATO , Motoaki UMEZU , Hiroki GOTO , Tomoyuki NATSUI
IPC分类号： C09D11/102 , C08G18/68 , C08G63/553 , C08L75/06 , C09D11/037 , C08G18/75
摘要： Provided are: a polyurethane resin having a high degree of biomass, the polyurethane resin useful as a binder for a printing exhibiting excellent adhesion performance particularly to biomass plastic base materials and having excellent dispersibility of a pigment contained at a high concentration; and a printing ink using the polyurethane resin. A bio-polyurethane resin obtained by reacting a bio-polyol (A) and an isocyanate (B), wherein the (A) is a bio-polyester polyol being a polymerized product of a diol component (a) and a dicarboxylic acid component (b) each containing a plant-derived component, the (a) contains at least one selected from ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,4-butanediol, 1,10-decanediol, and dimer diols each derived from a plant, the (b) contains plant-derived succinic acid and an additional dicarboxylic acid, and plant-derived succinic acid/additional carboxylic acid=98/2 to 5/95, and a content of plant-derived components is 35% or more based on 100% by mass of the bio-polyurethane resin, and a printing ink.
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公开(公告)号：US10982020B2
公开(公告)日：2021-04-20
申请号：US15313179
申请日：2014-06-25
发明人： Hiroyuki Shimanaka , Yoichi Tagi , Yoshikazu Murakami , Shinichiro Aoyagi , Kazutaka Arai , Sachio Yoshikawa
IPC分类号： C08F8/36 , C08F293/00 , C08F8/34 , C09D17/00 , C08F8/44 , C09D11/107 , C08L71/00 , C08F2/06 , C09C3/10 , C09D11/10 , C09D11/326 , C08F8/42 , C09B69/10
摘要： There is provided a resin-treated pigment that is useful as a coloring agent for color filters or inkjet inks, that can expand a hue range and improve performances such as color density, color developability, and transparency, and that is excellent in properties such as dispersibility and dispersion stability of pigments, re-dissolvability, and alkali-solubility. An A-B block copolymer 90% by mass or more of which is constituted by a methacrylate-based monomer or methacrylate-based monomers, in which the block A has a carboxy group-containing methacrylate as a constituent, and the block B has an ionic bond moiety represented by formula (1) as a constitutional unit, the ionic bond moiety containing a methacrylate, and an organic coloring matter having one or more sulfonate ions each being bonded thereto and each being a counter ion of a nitrogen cation of a quaternary ammonium salt.
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公开(公告)号：US20210087323A1
公开(公告)日：2021-03-25
申请号：US17041922
申请日：2019-05-14
发明人： Ryo KAWAMURA , Kazuya SASAKI , Toshiki YAMADA
摘要： A polyurethane prepolymer produced by reacting a polyol and a polyisocyanate, wherein the polyol contains a polyether polyol (A) in an amount of 30% by mass or more, a polyester polyol (B) containing an isophthalic acid-derived structure and a sebacic acid-derived structure as partial structures derived from a dibasic acid in an amount of 30% by mass or more, and a polyester polyol (C) containing only a sebacic acid-derived structure as a partial structure derived from a dibasic acid in an amount of 20% by mass or less, the number-average molecular weight of the polyether polyol (A) is 1100 to 2400, and the ratio of the isocyanate equivalent of the polyisocyanate to the hydroxyl equivalent of the polyol is 2.1 or less.
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9.发明授权公开(公告)号：US10400115B2
公开(公告)日：2019-09-03
申请号：US13956667
申请日：2013-08-01
IPC分类号： H01M4/04 , H01M4/66 , H01G11/48 , H01G9/042 , C09D5/24 , C09D5/14 , C09D133/06 , H01B1/12 , H01G11/38 , H01M4/13 , C09D7/63 , C08K5/5317 , C08K7/24
摘要： An aqueous liquid composition contains a water-based medium containing water, a polymer having at least one type of groups selected from hydroxyl groups and amino groups, and phosphonobutanetricarboxylic acid. The aqueous liquid composition contains low-cost materials having low environmental load, can retain adequate viscosity even when stored over a long term, and can form a functional coating film having excellent adhesiveness to a base material and superb durability, solvent resistance and waterproofness and capable of exhibiting various functions led by electrical conductivity and hydrophilicity.
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公开(公告)号：US10081001B2
公开(公告)日：2018-09-25
申请号：US15125856
申请日：2015-03-30
发明人： Takahiro Imai , Taiyo Aoyagi , Hiroyuki Shimanaka , Yoshinobu Tsujii , Keita Sakakibara , Atsushi Goto
IPC分类号： B01F17/00 , C08J3/05 , C08L1/02 , C08F293/00 , C08G81/02
CPC分类号： B01F17/0028 , C08F293/005 , C08G81/021 , C08J3/05 , C08J2301/02 , C08J2323/06 , C08J2401/02 , C08J2453/00 , C08L1/02 , C08L53/00
摘要： An object of the present invention is to provide a high-performance polymer dispersant that can be applied to cellulose being a hydrophilic substance, and another object of the present invention is to provide a technology for practical application of obtaining a cellulose-dispersed resin composition that realizes stable dispersion of cellulose in a simpler manner and in an environmentally conscious manner that never uses a large amount of organic solvents when the polymer dispersant for cellulose is applied to cellulose and disperses the cellulose in a thermoplastic resin. These objects are achieved by providing a polymer dispersant for cellulose, being a polymer compound including a block copolymer structure having a resin-affinitive segment A and a cellulose-adsorptive segment B, the polymer compound synthesized by a reversible chain transfer catalyzed polymerization (RTCP) method not using any of a heavy metal, a nitroxide compound, and a sulfur-based compound, using an organic iodine compound as an initiation compound, and using a phosphorus compound, a nitrogen compound, an oxygen compound, or a carbon compound as a catalyst.
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