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    Hybrid process for nitrogen oxides reduction
    4.
    发明授权
    Hybrid process for nitrogen oxides reduction 失效
    氮氧化物还原的混合工艺

    公开(公告)号：US5047219A

    公开(公告)日：1991-09-10

    申请号：US395810

    申请日：1989-08-18

    Applicant: W. Robert Epperly ,  Barry N. Sprague

    Inventor： W. Robert Epperly ,  Barry N. Sprague

    IPC: B01D53/56

    CPC classification number: B01D53/56

    Abstract: The invention presented is a process for reducing the nitrogen oxides concentration in the effluent from the combustion of a carbonaceous fuel. The inventive process comprises introducing into the effluent an oxygenated treatment agent which includes an oxygenated hydrocarbon under conditions effective to oxidize nitric oxide in the effluent to nitrogen dioxide and to produce ammonia; and contacting the effluent with an aqueous absorbing solution having a component capable of causing nitrogen dioxide to be absorbed into the solution.

    Abstract translation: 本发明提供了一种降低来自碳质燃料燃烧的流出物中的氮氧化物浓度的方法。 本发明的方法包括在有效地将流出物中的一氧化氮氧化成二氧化氮并产生氨的条件下将包含含氧烃的含氧处理剂引入流出物中; 并将流出物与具有能够使二氧化氮吸收到溶液中的成分的吸收水溶液接触。

    Process for nitrogen oxides reduction and minimization of the production of other pollutants
    6.
    发明授权
    Process for nitrogen oxides reduction and minimization of the production of other pollutants 失效
    氮氧化物还原和其他污染物生产最小化的过程

    公开(公告)号：US5017347A

    公开(公告)日：1991-05-21

    申请号：US411902

    申请日：1989-05-23

    Applicant: William R. Epperly ,  James C. Sullivan ,  Barry N. Sprague ,  John H. O'Leary

    Inventor： William R. Epperly ,  James C. Sullivan ,  Barry N. Sprague ,  John H. O'Leary

    IPC: B01D53/34 ,  B01D53/56 ,  B01J19/00

    CPC classification number: B01D53/346 ,  B01D53/56 ,  B01J19/0006 ,  B01J2219/00058

    Abstract: A process for the reduction of nitrogen oxides in an effluent from the combustion of a carbonaceous fuel while minimizing the production of other pollutants is presented. The process comprises introducing (most commonly by injecting) a nitrogen oxides reducing treatment agent into an effluent according to a nitrogen oxides reducing treatment regimen under conditions such that the treatment agent is operating on the high temperature or right side of its nitrogen oxides reduction versus effluent temperature curve, especially on the high temperature or right side of the curve plateau.

    Abstract translation: PCT No.PCT / US88 / 02751 Sec。 371日期1989年5月23日 102（e）日期1989年5月23日PCT提交1988年8月12日PCT公布。 公开号WO89 / 02781 日期：1989年4月6日。一种减少来自碳质燃料燃烧的流出物中的氮氧化物同时最小化其它污染物的产生的方法。 该方法包括在氮氧化物还原处理方案下将氮氧化物还原处理剂引入（最通常地将氮氧化物还原处理剂）注入流出物中，使得处理剂在其氮氧化物还原相对于流出物的高温或右侧 温度曲线，特别是在曲线高原的高温或右侧。

    Gasoline additives and gasoline containing soluble platinum group metal compounds and use in internal combustion engines
    7.
    发明授权
    Gasoline additives and gasoline containing soluble platinum group metal compounds and use in internal combustion engines 失效
    含有可溶性铂族金属化合物的汽油添加剂和汽油，用于内燃机

    公开(公告)号：US4891050A

    公开(公告)日：1990-01-02

    申请号：US897869

    申请日：1986-08-19

    Applicant: Wayne E. Bowers ,  Barry N. Sprague

    Inventor： Wayne E. Bowers ,  Barry N. Sprague

    IPC: C07F15/00 ,  C10L1/14 ,  C10L1/16 ,  C10L1/18 ,  C10L1/22 ,  C10L1/30 ,  C10L3/00 ,  C10L10/02

    CPC classification number: C10L1/14 ,  C07F15/0086 ,  C10L1/1814 ,  C10L1/301 ,  C10L1/305 ,  C10L10/02 ,  C10L3/003 ,  C10L1/1608 ,  C10L1/1824 ,  C10L1/1852 ,  C10L1/1855 ,  C10L1/1857 ,  C10L1/231

    Abstract: The invention provides gasoline additive compositions comprising solutions of at least one fuel-soluble platinum group metal compound in a solvent miscible in the gasoline, the platinum group metal complex being present in an amount sufficient to supply from 0.01 to 1.0 parts per million of the platinum group metal when added to a predetermined amount of gasoline.Preferred solvents are oxygenated hydrocarbons such as ethanol, tetrahydrofuran, and methyl tertiary butyl ether, and will preferably be employed in amounts of less than 5% of the weight of the gasoline to provide oxygen and the metal at a weight ratio of from 1,000:1 to 100,000:1. Especially preferred compounds are those of the formula:X M.sup.II R.sub.2wherein X is a cyclooctadienyl ligand; M is a platinum group metal; and R is benzyl, phenyl or nitrobenzyl.The additive compositions and fuel treated therewith improve operating efficiency of internal combustion engines in terms of increased power output per unit of fuel burned and reduce the emissions of particulates and noxious gases such as carbon monoxide and nitrogen monoxide. The additives provide beneficial results upon immediate use and over long periods of continuous use.

    Abstract translation: 本发明提供了汽油添加剂组合物，其包含至少一种可溶于燃料的铂族金属化合物在可与汽油混合的溶剂中的溶液，铂族金属络合物的存在量足以提供0.01至1.0ppm的铂 当添加到预定量的汽油时，将金属组合。 优选的溶剂是含氧烃如乙醇，四氢呋喃和甲基叔丁基醚，并且优选以低于汽油重量的5％的量使用以提供氧和重量比为1,000:1的金属 至100,000：1。 特别优选的化合物是下式的化合物：X MII R2其中X是环辛二烯基配体; M是铂族金属; R为苄基，苯基或硝基苄基。 添加剂组合物和经过处理的燃料可以提高内燃机的运行效率，从而提高每单位燃料燃料的功率输出，并减少颗粒物和有毒气体如一氧化碳和一氧化氮的排放。 这些添加剂在立即使用和长时间连续使用时提供有益的结果。

    Process for nitrogen oxides reduction with minimization of the production of other pollutants
    8.
    发明授权
    Process for nitrogen oxides reduction with minimization of the production of other pollutants 失效
    减少氮氧化物的方法，尽可能减少其他污染物的产生

    公开(公告)号：US4877590A

    公开(公告)日：1989-10-31

    申请号：US155864

    申请日：1988-02-29

    Applicant: William R. Epperly ,  John H. O'Leary ,  James C. Sullivan ,  Barry N. Sprague

    Inventor： William R. Epperly ,  John H. O'Leary ,  James C. Sullivan ,  Barry N. Sprague

    IPC: B01D53/56

    CPC classification number: B01D53/56 ,  B01J2219/00058

    Abstract: A process for the reduction of nitrogen oxides in an effluent from the combustion of a carbonaceous fuel while minimizing the production of other pollutants is presented. The process comprises introducing a nitrogen oxides reducing treatment agent comprising a hydrocarbon into an effluent at a temperature below about 1450.degree. F. according to a nitrogen oxides reducing treatment regimen under conditions such that the hydrocarbon treatment agent is operating on the high temperature or right side of its nitrogen oxides reduction versus effluent temperature curve, especially on the high temperature or right side of the curve plateau.

    Abstract translation: 提出了一种在将碳质燃料燃烧的污水中的氮氧化物还原，同时最小化其它污染物的产生的方法。 该方法包括在低于约1450°F的温度下将含有烃的氮氧化物还原处理剂根据氮氧化物还原处理方案引入到烃处理剂在高温或右侧 的氮氧化物还原与出口温度曲线，特别是在曲线高原的高温或右侧。

    Low-emissions diesel fuel
    9.
    发明授权
    Low-emissions diesel fuel 失效
    低排放柴油

    公开(公告)号：US07063729B2

    公开(公告)日：2006-06-20

    申请号：US10290798

    申请日：2002-11-08

    Applicant: James M. Valentine ,  Barry N. Sprague ,  Jeremy D. Peter-Hoblyn

    Inventor： James M. Valentine ,  Barry N. Sprague ,  Jeremy D. Peter-Hoblyn

    IPC: C10L1/30 ,  C10L10/02 ,  C10L10/04 ,  C10L10/06

    CPC classification number: C10L10/08 ,  C10L1/14 ,  C10L1/1857 ,  C10L1/1881 ,  C10L1/1883 ,  C10L1/1886 ,  C10L1/1888 ,  C10L1/301 ,  C10L1/305 ,  C10L1/328 ,  C10L10/02 ,  F01N3/023 ,  F01N3/106 ,  F01N2430/04

    Abstract: A low-emissions diesel fuel comprises fungible aviation kerosene grade 55, 50–300 ppm detergent, 25–500 ppm lubricity additive and a bimetallic, fuel soluble platinum and cerium fuel borne catalyst (e.g., 0.1–2.0 ppm platinum COD and 5–20 ppm cerium oleate). The fuel can be used as is or in the form of an emulsion. A method of reducing the emissions of pollutants from a diesel engine, comprising running the engine on a fuel as defined. Retarding engine timing can further reduce NOx and the use of a diesel particulate filter and/or diesel oxidation catalyst can provide further reductions in carbon monoxide, unburned hydrocarbons and particulates.

    Abstract translation: 低排放柴油包括可替换航空煤油55级，50-300ppm洗涤剂，25-500ppm润滑添加剂和双金属，燃料可溶性铂和铈燃料催化剂（例如，0.1-2.0ppm铂COD和5-20 ppm油酸铈）。 燃料可以原样使用或以乳液的形式使用。 一种减少来自柴油发动机的污染物排放的方法，包括以定义的燃料运行发动机。 阻止发动机正时可以进一步减少NOx，并且使用柴油微粒过滤器和/或柴油氧化催化剂可以进一步减少一氧化碳，未燃碳氢化合物和颗粒物。

    Process for reducing nitrogen oxides without generating nitrous oxide
    10.
    发明授权
    Process for reducing nitrogen oxides without generating nitrous oxide 失效
    减少氮氧化物而不产生一氧化二氮的方法

    公开(公告)号：US4997631A

    公开(公告)日：1991-03-05

    申请号：US489919

    申请日：1990-03-07

    Applicant: John E. Hofmann ,  Barry N. Sprague ,  William H. Sun

    Inventor： John E. Hofmann ,  Barry N. Sprague ,  William H. Sun

    IPC: B01D53/56

    CPC classification number: B01D53/56 ,  Y02C20/10

    Abstract: A process is presented for the reduction of nitrogen oxides in the effluent from the combustion of a carbonaceous fuel while reducing the generation of nitrous oxide. The process comprises introducing a treatment agent comprising ammonium carbamate into the effluent in an amount effective to substantially avoid the presence of nitrous oxide.

    Abstract translation: 提出了一种减少来自碳质燃料燃烧的流出物中的氮氧化物同时减少一氧化二氮的产生的方法。 该方法包括将含有氨基甲酸铵的处理剂以有效基本避免一氧化二氮存在的量引入流出物中。

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