Stress Relief for Crosslinked Polymers
    1.
    发明申请
    Stress Relief for Crosslinked Polymers 有权
    交联聚合物的应力释放

    公开(公告)号:US20120202917A1

    公开(公告)日:2012-08-09

    申请号:US13344328

    申请日:2012-01-05

    IPC分类号: A61K6/083

    摘要: The invention provides methods for inducing reversible chain cleavage of polymer chains in a crosslinked polymeric material or during polymerization of a polymeric material. Reversible cleavage of the polymer backbone is capable of relieving stress in the polymeric material as the bonds reform in a less stressed state. The invention also provides mixtures for making crosslinked polymeric materials, methods for making polymeric materials capable of reversible chain cleavage, materials made by the methods of the invention, and linear monomers containing reversible chain cleavage groups which are useful in the materials and methods of the invention. The mixtures of the invention may be dental restorative compositions used for forming dental restorative materials.

    摘要翻译: 本发明提供用于诱导交联聚合材料中的聚合物链的可逆链断裂或在聚合物材料的聚合期间的方法。 聚合物主链的可逆切割能够缓解聚合物材料中的应力,因为键在较小应力状态下改性。 本发明还提供用于制备交联聚合材料的混合物,制备能够进行可逆链断裂的聚合物材料的方法,通过本发明方法制备的材料和可用于本发明的材料和方法的可逆链裂解基团的线性单体 。 本发明的混合物可以是用于形成牙齿修复材料的牙齿修复组合物。

    Use of Photopolymerization for Amplification and Detection of a Molecular Recognition Event
    3.
    发明申请
    Use of Photopolymerization for Amplification and Detection of a Molecular Recognition Event 有权
    使用光聚合扩增和检测分子识别事件

    公开(公告)号:US20110251092A1

    公开(公告)日:2011-10-13

    申请号:US13082814

    申请日:2011-04-08

    IPC分类号: C40B30/04 G01N21/75 B82Y15/00

    摘要: The invention provides methods to detect molecular recognition events. The invention also provides methods to detect the presence of or identify a target species based on its interaction with one or more probe species. The methods of the invention are based on amplification of the signal due to each molecular recognition event. The amplification is achieved through photopolymerization, with the polymer formed being associated with the molecular recognition event. In one aspect, a fluorescent polymer, a magnetic polymer, a radioactive polymer or an electrically conducting polymer can form the basis of detection and amplification. In another aspect, a polymer gel swollen with a fluorescent solution, a magnetic solution, a radioactive solution or an electrically conducting solution can form the basis of detection and amplification. In another aspect, detectable particles can be included in the polymer formed. In another aspect, sufficient polymer forms to be detectable by visual inspection.

    摘要翻译: 本发明提供检测分子识别事件的方法。 本发明还提供了基于其与一种或多种探针物种的相互作用来检测靶物种的存在或鉴定目的物种的方法。 本发明的方法基于由于每个分子识别事件引起的信号的放大。 通过光聚合实现扩增,形成的聚合物与分子识别事件相关联。 一方面,荧光聚合物,磁性聚合物,放射性聚合物或导电聚合物可以形成检测和扩增的基础。 另一方面,用荧光溶液,磁性溶液,放射性溶液或导电溶液溶胀的聚合物凝胶可以形成检测和扩增的基础。 在另一方面,所形成的聚合物中可以包括可检测的颗粒。 另一方面,足够的聚合物形式可通过视觉检查来检测。

    Dimer Acid-Derived Dimethacrylates and Use in Dental Restorative Compositions
    4.
    发明申请
    Dimer Acid-Derived Dimethacrylates and Use in Dental Restorative Compositions 有权
    二聚酸衍生的二甲基丙烯酸酯和用于牙齿修复组合物

    公开(公告)号:US20080318188A1

    公开(公告)日:2008-12-25

    申请号:US11568383

    申请日:2004-12-29

    CPC分类号: A61K6/083 C08L33/00

    摘要: The present invention provides polymerizable dental compositions comprising a dimer acid-derived monomer such as a dimer acid-derived di(meth)acrylate monomer. In one embodiment, the dimer acid-derived monomer is of the formula (I): wherein R1, R2, R3, R4, R5 and R6 are independently selected from H and optionally substituted C1-C25 straight-chained or branched aliphatic, optionally containing 1 or more double or triple bonds, wherein one or more carbons are optionally replaced by R* wherein R* is —C(O)—, —C(O)C(O)—, —C(O)NR7—, —C(O)NR7NR8—, —C(O)O—, —OC(O)—, —NR7CO2—, —O—, —NR7C(O)NR8—, —OC(O)NR7—, —NR7NR8—, —NR7C(O)—, —NR7C(O)O—, —S—, —SO—, —SO2—, —NR7—, —SO2NR7— or —NR7SO2—, where R7 and R8 are independently selected from H and optionally substituted aliphatic, cycloalkyl, heterocycloalkyl, aryl or heteroaryl; provided that at least two of R1, R2, R3, R4, R5 and R6 are substituted C1-25 straight-chained or branched aliphatic wherein at least one carbon is replaced by R* and at least one of the substituents is an alkenyl group.

    摘要翻译: 本发明提供包含二聚酸衍生的单体如二聚酸衍生的二(甲基)丙烯酸酯单体的可聚合牙科组合物。 在一个实施方案中,二聚酸衍生的单体具有式(I):其中R 1,R 2,R 3,R 4,R 5和R 6独立地选自H和任选取代的C 1 -C 25直链或支链脂族基,任选地含 1或更多个双键或三键,其中一个或多个碳任选被R *取代,其中R *是-C(O) - , - C(O)C(O) - , - C(O)NR 7 - C(O)NR 7 NR 8 - , - C(O)O-,-OC(O) - , - NR 7 CO 2 - , - O - , - NR 7 C(O)NR 8 - -NR 7 C(O) - , - NR 7 C(O)O-,-S-,-SO-,-SO 2 - , - NR 7 - , - SO 2 NR 7 - 或-NR 7 SO 2 - ,其中R 7和R 8独立地选自H 取代的脂族,环烷基,杂环烷基,芳基或杂芳基; 条件是R 1,R 2,R 3,R 4,R 5和R 6中的至少两个是取代的C 1-2直链或支链脂族基,其中至少一个碳被R *代替,并且至少一个取代基是烯基。

    Method and material for use with dental composites for improving
conversion of monomers to polymers and reducing volume shrinkage
    5.
    发明授权
    Method and material for use with dental composites for improving conversion of monomers to polymers and reducing volume shrinkage 失效
    用于牙科复合材料以改善单体向聚合物转化并减少体积收缩的方法和材料

    公开(公告)号:US5730601A

    公开(公告)日:1998-03-24

    申请号:US613348

    申请日:1996-03-11

    IPC分类号: A61K6/083 A61C5/00

    CPC分类号: A61K6/083

    摘要: A composition for use in dental treatments of damaged or diseased teeth is provided. The composition comprises a combined filler material, photoinitiator and comonomer resin mixture polymerizable upon incidence of light. The comonomer resin mixture comprises a comonomer resin blend comprising at least two monomers from the same monomer series with at least a first monomer having a first molecular weight and a second monomer having a second molecular weight with the second molecular weight being greater than the first molecular weight of the first monomer. The comonomer resin mixture further comprises a third monomer combined with the comonomer resin blend.

    摘要翻译: 提供了一种用于牙齿治疗受损或患齿的组合物。 组合物包含组合的填充材料,光引发剂和共聚单体树脂混合物在光入射时可聚合。 共聚单体树脂混合物包括共聚单体树脂混合物,其包含至少两种与至少第一分子量的第一单体相同的单体系列的单体和具有第二分子量的第二单体,第二分子量大于第一分子量 第一单体的重量。 共聚单体树脂混合物还包含与共聚单体树脂共混物组合的第三单体。

    Stress Relaxation in Crosslinked Polymers
    7.
    发明申请
    Stress Relaxation in Crosslinked Polymers 有权
    交联聚合物中的应力松弛

    公开(公告)号:US20080269460A1

    公开(公告)日:2008-10-30

    申请号:US11815914

    申请日:2006-02-10

    摘要: The invention provides methods for inducing reversible chain cleavage of polymer chains in a crosslinked polymeric material. Reversible cleavage of the polymer backbone is capable of relieving stress in the polymeric material as the bonds reform in a less stressed state. The invention also provides methods for making polymeric materials capable of reversible chain cleavage, materials made by the methods of the invention, and linear monomers containing reversible chain cleavage groups which are useful in the materials and methods of the invention.

    摘要翻译: 本发明提供诱导交联聚合物材料中聚合物链可逆链断裂的方法。 聚合物主链的可逆切割能够缓解聚合物材料中的应力,因为键在较小应力状态下改性。 本发明还提供了制备能够进行可逆链断裂的聚合物材料的方法,通过本发明的方法制备的材料和可用于本发明的材料和方法的可逆链裂解基团的线型单体。

    Diffraction unlimited photolithography
    9.
    发明授权
    Diffraction unlimited photolithography 失效
    衍射无限光刻

    公开(公告)号:US08697346B2

    公开(公告)日:2014-04-15

    申请号:US13078485

    申请日:2011-04-01

    IPC分类号: G03F7/00 G03F7/20

    摘要: Methods, devices, systems, and materials are disclosed for diffraction unlimited photofabrication. A method is provided where a photoresponsive material is illuminated with a first optical pattern at a first wavelength of light. The first wavelength of light alters a solubility of the photoresponsive organic material. The photoresponsive material is also illuminated with a second optical pattern at a second wavelength of light. The second wavelength of light hinders the ability of the first wavelength of light to alter the solubility of the photoresponsive organic material where the second optical pattern overlaps the first optical pattern. The photoresponsive organic material is then developed.

    摘要翻译: 公开了用于衍射无限制造的方法,装置,系统和材料。 提供一种方法,其中光响应材料在第一波长的光下用第一光学图案照亮。 光的第一波长改变光响应有机材料的溶解度。 光响应材料也用第二波长的光照射第二光学图案。 光的第二波长阻碍第一波长的光改变光响应有机材料在第二光学图案与第一光学图案重叠的溶解度的能力。 然后开发光响应有机材料。