公开(公告)号：US09738758B2

公开(公告)日：2017-08-22

申请号：US15270263

申请日：2016-09-20

Applicant: Toray Fine Chemicals Co., Ltd.

Inventor： Koki Echigoya ,  Yukiko Hamada ,  Kazunori Matsumoto

IPC: C08G75/14 ,  C08G18/52 ,  C08G59/56 ,  C08G59/66 ,  C08G18/73 ,  C09K3/10 ,  C08G59/40 ,  C08L63/00 ,  C07C323/14

CPC classification number: C08G75/14 ,  C07C323/14 ,  C08G18/52 ,  C08G18/73 ,  C08G59/4028 ,  C08G59/56 ,  C08G59/66 ,  C08G2190/00 ,  C08L63/00 ,  C09K3/1012 ,  C08L81/04

Abstract: A method of producing a thiol group-containing polymer includes reacting bis(2-chloroethyl) formal with sodium hydrosulfide, wherein the thiol group-containing polymer is represented by general formula: HS—(R—Sr)n—R—SH where R is an organic group including a —C2H4—O—CH2—O—C2H4— structure, n is an integer of from 1 to 200, r is an integer of from 1 to 5, and the average value of r is 1.1 or more and lower than 1.8, and wherein the thiol group-containing polymer is a liquid polymer.

公开(公告)号：US20170226055A1

公开(公告)日：2017-08-10

申请号：US15494746

申请日：2017-04-24

Applicant: Toray Fine Chemicals Co., Ltd.

Inventor： Koki Echigoya ,  Yukiko Hamada ,  Kazunori Matsumoto

IPC: C07C323/14 ,  C09J181/02 ,  C08G18/52 ,  C08G75/14 ,  C08G18/73 ,  C08G75/12 ,  C09D181/02

CPC classification number: C07C323/14 ,  C08G18/52 ,  C08G18/73 ,  C08G59/4028 ,  C08G59/56 ,  C08G59/66 ,  C08G75/12 ,  C08G75/14 ,  C08G2190/00 ,  C08L63/00 ,  C09D181/02 ,  C09J181/02 ,  C09K3/1012 ,  C08L81/04

Abstract: A thiol group-containing polymer represented by: HS—(R—Sr)n—R—SH wherein R is an organic group including a —O—CH2—O— bond and a branched alkylene group, n is an integer of from 1 to 200, r is an integer of from 1 to 5, an average value of r is 1.1 or more and lower than 1.8, and the thiol group-containing polymer is a liquid at room temperature and has a specific gravity at 23° C. of 1.20 to 1.27.

公开(公告)号：US09663619B2

公开(公告)日：2017-05-30

申请号：US14416468

申请日：2013-07-10

Applicant: Toray Fine Chemicals Co., Ltd.

Inventor： Koki Echigoya ,  Yukiko Hamada ,  Kazunori Matsumoto

IPC: C08G75/14 ,  C08G18/52 ,  C08G59/56 ,  C08G59/66 ,  C08G18/73 ,  C09K3/10 ,  C08G59/40 ,  C08L63/00 ,  C07C323/14

CPC classification number: C08G75/14 ,  C07C323/14 ,  C08G18/52 ,  C08G18/73 ,  C08G59/4028 ,  C08G59/56 ,  C08G59/66 ,  C08G2190/00 ,  C08L63/00 ,  C09K3/1012 ,  C08L81/04

Abstract: A thiol group-containing polymer is represented by HS—(R—Sr)n—R—SH, wherein R is an organic group including a —O—CH2—O— bond and/or a branched alkylene group, n is an integer of from 1 to 200, r is an integer of from 1 to 5, and the average value of r is 1.1 or more and 1.8 or less. A curable composition using the thiol group-containing polymer can be used in sealants, adhesives, paints and the like, which require properties such as a low specific gravity, a low viscosity and a low glass transition temperature.

公开(公告)号：US5820665A

公开(公告)日：1998-10-13

申请号：US864427

申请日：1997-05-28

Applicant: Yoshiaki Kai

Inventor： Yoshiaki Kai

IPC: C07C51/09 ,  C07C51/353 ,  C07C53/21 ,  C07C57/52 ,  C07C323/12 ,  C07C323/25 ,  C07C323/52 ,  C07C323/60 ,  C09K3/18 ,  D06M13/02 ,  D06M13/184 ,  D06M13/213 ,  D06M13/244 ,  D06M13/248 ,  D06M13/265 ,  D06M101/00 ,  D06M101/02 ,  D06M101/06 ,  D06M101/08 ,  D21H17/14 ,  C07C323/23 ,  C07C323/03 ,  C07C323/05 ,  C07C323/14 ,  C07C323/27

CPC classification number: C07C323/25 ,  C07C323/12 ,  C07C323/52 ,  C07C323/60 ,  C07C53/21 ,  C07C57/52

Abstract: An object of the present invention is to provide a compound which imparts a sufficient water repellency and a suitable oil repellency to substrates such as a fiber, a paper, a wood material, a hide, a leather, a resin, a glass, a metal, etc. The compound of the present invention is a fluoroalkylcarboxylic acid of the general formula (I), and its derivative of the general formula (II) (e.g. fluoroalkyl alcohol, fluoroalkyl carboxylic acid chloride, fluoroalkylcarboxylic acid amide and fluoroalkylamine). ##STR1##

Abstract translation: 本发明的目的是提供一种赋予纤维，纸，木材，皮革，皮革，树脂，玻璃，金属等基材足够的防水性和合适的拒油性的化合物 本发明的化合物是通式（I）的氟烷基羧酸及其通式（II）的衍生物（例如氟烷基醇，氟代烷基羧酰氯，氟烷基羧酸酰胺和氟代烷基胺）。 （I）（II）

公开(公告)号：US5216138A

公开(公告)日：1993-06-01

申请号：US800551

申请日：1991-11-27

Applicant: Jorg Dannheim

Inventor： Jorg Dannheim

IPC: C07C317/14 ,  C07C317/18 ,  C07C317/36 ,  C07C317/44 ,  C07C323/09 ,  C07C323/12 ,  C07C323/14 ,  C07C323/36 ,  C07C323/52 ,  C09B62/507 ,  C09B62/51 ,  C09B62/513 ,  D06P3/24 ,  D06P3/66

CPC classification number: C07C323/52 ,  C07C317/14 ,  C07C317/18 ,  C07C317/36 ,  C07C317/44 ,  C07C323/09 ,  C07C323/12 ,  C09B62/507

Abstract: There are described water soluble azo compounds conforming to the formula (1)D--N.dbd.N--K (1)where D is a radical of the formula (2), (2a) or (2b) ##STR1##where Y is a substituent which is eliminable by alkali to form a vinyl group, Y.sup.2 has one of the meanings of Y or is hydroxyl, X is chlorine or bromine, and R is hydrogen, lower alkyl, phenyl or halogen, and K is a radical of a singly couplable coupling component which may additionally contain an azo group, or the radical of a doubly couplable coupling component.The compounds of the formula (1) have fiber-reactive properties and are very highly suitable for use as dyes for dyeing hydroxy- and/or carboxamido-containing material, in particular fiber material, for example cellulose-fiber materials, wool and synthetic polyamide fibers, in strong, fast shades.There are also described novel starting compounds of the formulae (7), (7a) and (7b) ##STR2##where Y.sup.2, X and R are each as defined above, x is zero or 2 and W is nitro or amino. The aniline compounds of the formula (7) obtainable from the compounds of the formula (7) where W is nitro by reduction of the nitro group can be used as diazo component for preparing the azo compounds of the formula (1).

Abstract translation: 描述符合式（1）的水溶性偶氮化合物DN = NK（1）其中D是式（2），（2a​​）或（2b）的基团。 （2b）其中Y是可以被碱除去以形成乙烯基的取代基，Y2具有Y或羟基的含义之一，X是氯或溴，R是氢，低级烷基，苯基 或卤素，并且K是可以另外含有偶氮基团的单一可耦合偶合组分的基团，或双重可耦合组分的基团。 式（1）的化合物具有纤维反应性，并且非常适合用作用于染色含羟基和/或羧酰氨基的材料的染料，特别是纤维材料，例如纤维素纤维材料，羊毛和合成聚酰胺 纤维，强壮，快速的色调。 还描述了式（7），（7a）和（7b）的新起始化合物。其中Y2，X和R各自如上所定义。 ，x为0或2，W为硝基或氨基。 作为用于制备式（1）的偶氮化合物的重氮组分，可以使用由式（7）的化合物得到的式（7）的苯胺化合物，其中W是硝基还原硝基。

公开(公告)号：US4892962A

公开(公告)日：1990-01-09

申请号：US129198

申请日：1987-12-07

Applicant: Robert W. Lang

Inventor： Robert W. Lang

IPC: C07C51/09 ,  C07C51/347 ,  C07C67/00 ,  C07C67/34 ,  C07C69/63 ,  C07C69/65 ,  C07C253/00 ,  C07C255/34 ,  C07C313/00 ,  C07C323/14 ,  C07C323/15 ,  C07C323/54 ,  C07C323/56 ,  C07C323/62 ,  C07F7/18

CPC classification number: C07C51/09 ,  C07C51/347 ,  C07F7/1896

Abstract: The reaction of allyl bromo- or chloro-difluoroacetates with monochlorisilanes in the presence of zinc with heating gives silyl esters of .alpha.,.alpha.-difluoro-.gamma.,.delta.-pentenoic acids. The free acids, from which acid derivatives can be prepared by conventional methods, are obtained by hydrolysis. The pentenoic acids and pentenoic acid derivatives are suitable for the preparation of polymers and copolymers, from which metal-organic polymers and copolymers having catalytic properties are obtainable.

Abstract translation: 烯丙基溴或氯二氟乙酸与单氯硅烷在锌存在下加热反应得到α，α-二氟-γ，δ-戊烯酸的甲硅烷基酯。 可以通过常规方法制备酸衍生物的游离酸通过水解获得。 戊烯酸和戊烯酸衍生物适用于制备聚合物和共聚物，可获得具有催化性能的金属 - 有机聚合物和共聚物。

公开(公告)号：US4137273A

公开(公告)日：1979-01-30

申请号：US324903

申请日：1973-01-19

Applicant: John B. Siddall

Inventor： John B. Siddall

IPC: A01N49/00 ,  C07C29/143 ,  C07C29/147 ,  C07C43/14 ,  C07C43/20 ,  C07C43/23 ,  C07C45/59 ,  C07C45/68 ,  C07C69/734 ,  C07C309/63 ,  C07C309/65 ,  C07C309/66 ,  C07C313/00 ,  C07C317/14 ,  C07C317/18 ,  C07C321/28 ,  C07C323/14 ,  C07C323/20 ,  C07D317/16

CPC classification number: C07D317/16 ,  C07C29/143 ,  C07C29/147 ,  C07C309/66 ,  C07C317/18 ,  C07C321/28 ,  C07C323/00 ,  C07C323/14 ,  C07C323/20 ,  C07C45/59 ,  C07C45/68

Abstract: Novel phenyl derivatives of formula I useful for the control of insects and novel intermediates.

Abstract translation: 式I的新型苯基衍生物可用于控制昆虫和新型中间体。

公开(公告)号：US4127654A

公开(公告)日：1978-11-28

申请号：US720376

申请日：1976-09-03

Applicant: Shigeo Inoue ,  Norioki Miyamoto ,  Haruo Shimizu

Inventor： Shigeo Inoue ,  Norioki Miyamoto ,  Haruo Shimizu

IPC: A01N31/02 ,  A01N37/02 ,  A01N37/12 ,  A01N41/04 ,  A01N41/10 ,  A01N57/12 ,  A61K8/46 ,  A61K47/20 ,  A61K47/24 ,  A61Q17/00 ,  C07C67/00 ,  C07C313/00 ,  C07C317/18 ,  C07C323/14 ,  C07F9/09 ,  C07F9/113 ,  C11D3/34 ,  C11D3/36 ,  C11D9/50 ,  A01N9/36 ,  A61K31/66 ,  A61L13/00

CPC classification number: C11D3/3427 ,  A01N37/12 ,  A01N41/04 ,  A01N41/10 ,  A01N57/12 ,  A61K47/20 ,  A61K47/24 ,  A61K8/46 ,  A61K9/0014 ,  A61Q17/005 ,  C07F9/113 ,  C11D3/3445 ,  C11D3/3454 ,  C11D3/361 ,  C10M2201/02 ,  C10M2207/125 ,  C10M2207/129 ,  C10M2219/04 ,  C10M2219/044 ,  C10M2219/084 ,  C10M2223/04 ,  C10M2223/042 ,  C10N2210/01 ,  C10N2240/40 ,  C10N2240/401

Abstract: Compounds having the formulaR--X--CH.dbd.CH.sub.2 --CH.sub.2 O--Y (I)wherein R is alkyl or alkenyl containing one to 20 carbon atoms, X is S, SO or SO.sub.2 and Y is hydrogen, alkanoyl containing 2 to 20 carbon atoms or alkenoyl containing 3 to 20 carbon atoms, SO.sub.3 M or PO.sub.3 M.sub.2, wherein M is hydrogen, an alkali metal or an alkaline earth metal, or an oxyalkylene group having 1-20 ethylene oxide units or propylene oxide units, are incorporated as a preservative or anti-microbial agent, in compositions that are subject to deterioration by the action of micro-organisms, excluding food and medicines.

Abstract translation: 具有式RX-CH = CH 2 -CH 2 O-Y（I）的化合物，其中R是含有1-20个碳原子的烷基或烯基，X是S，SO或SO 2，Y是氢，含有2至20个碳原子的链烷酰基或烯酰基 含有3〜20个碳原子的SO 3 M或PO 3 M 2，其中M为氢，碱金属或碱土金属或具有1-20个环氧乙烷单元或环氧丙烷单元的氧化烯基团作为防腐剂或抗微生物剂 代理人，在由微生物行动恶化的组合物中排除食物和药物。

公开(公告)号：US3856814A

公开(公告)日：1974-12-24

申请号：US33634473

申请日：1973-02-27

Applicant: NIHON NOHYAKU CO LTD

Inventor： TANINAKA K ,  SHIOYAMA O ,  MURATA K

IPC: A01N37/36 ,  A01N43/24 ,  A01N43/28 ,  A01N43/32 ,  C07C67/00 ,  C07C313/00 ,  C07C319/14 ,  C07C323/14 ,  C07D339/00 ,  C07D339/06 ,  C07D339/08 ,  C07D71/00

CPC classification number: C07D339/08 ,  C07C323/00 ,  C07D339/00 ,  C07D339/06

Abstract: WHEREIN R1 is a lower alkyl of 3 or 4 carbon atoms or allyl useful in a fungicidal composition for agricultural and horticultural use containing said compound as an active ingredient.

A compound of the formula,

Abstract translation: 下式的化合物，其中R 1是3或4个碳原子的低级烷基或可用于农业和园艺用途的杀真菌组合物中的烯丙基，其含有所述化合物作为活性成分。

公开(公告)号：US3639487A

公开(公告)日：1972-02-01

申请号：US3639487D

申请日：1968-05-03

Applicant: HOOKER CHEMICAL CORP

Inventor： WEIL EDWARD D ,  SCHLICHTING HANS L

IPC: A01N31/08 ,  C07C323/14 ,  C08K5/13 ,  C08K5/136 ,  C08K5/375 ,  C09K15/00 ,  C09K15/08 ,  C09K15/14 ,  C10L1/14 ,  C07C43/20

CPC classification number: C07C323/00 ,  C07C323/14 ,  C08K5/13 ,  C08K5/136 ,  C08K5/375 ,  C09K15/08 ,  C09K15/14 ,  C10L1/14

Abstract: COMPOUNDS OF THE GENERAL FORMULA

2-((R4-Z-(CH2)N-)M-C(-H(3-M))-),3-R3,4-R2,5-R1,6-R5-PHENOL

WHICH ARE USEFUL AS OXIDATION INHIBITORS, FUNGICIDES, ANTIMICROBIAL AGENTS AN CHEMICAL INTERMEDIATES AND PROCESS FOR PREPARING SAID COMPOUNDS.