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1.发明授权Process for converting heavy petroleum residues to hydrogen and gaseous distillable hydrocarbons 失效将重质石油残渣转化为氢气和气态可馏分烃的方法
公开(公告)号：US4609456A
公开(公告)日：1986-09-02
申请号：US699540
申请日：1985-02-08
IPC分类号： C10G47/02 , B01J23/00 , B01J23/02 , B01J23/22 , B01J23/78 , B01J27/00 , B01J27/232 , C10G11/12 , C10G47/04 , C10G47/26 , B01J23/90 , C10J3/46
摘要： The invention concerns a process for converting heavy petroleum residues to hydrogen and to gaseous and distillable hydrocarbons, comprising the association of a step of hydropyrolysis (inside tube 3) with a step of catalytic steam-gasification of the formed coke (outside tube 3), characterized in that the hydropyrolysis step is performed in the presence of a solid supporting a carbon gasification catalyst circulating between the hydropyrolysis zone and the coke steam-gasification zone, said steam-gasification being performed in the absence of oxygen.The petroleum residue, hydrogen and steam are introduced respectively through lines 5, 6 and 7.The products are withdrawn through line 10. Heat may be supplied by the radiating tube 4.
摘要翻译： 本发明涉及将重质石油残余物转化为氢气和气态和可馏出烃的方法，其包括加氢热解步骤（管3内）与成形焦炭（外管3）的催化蒸汽气化步骤的关联， 其特征在于，所述加氢热解步骤在支持在所述加氢热解区和所述焦炭蒸汽 - 气化区之间循环的碳气化催化剂的固体存在下进行，所述蒸汽气化在不存在氧的情况下进行。 石油渣，氢气和蒸汽分别通过管线5,6和7引入。产物通过管线10排出。热量可以由辐射管4供应。
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公开(公告)号：US4310497A
公开(公告)日：1982-01-12
申请号：US230174
申请日：1981-01-30
CPC分类号： B01D53/52 , C01B17/508
摘要： A process for purifying a gas containing hydrogen sulfide, wherein said gas is admixed with oxygen and contacted with a carbon mass of specific surface higher than 50 m2/g and containing at least one oxide and/or sulfate of iron and/or copper, at a temperature from 20.degree. to 170.degree. C., the operating conditions being so selected as to avoid a substantial oxidation of said mass and said mass being periodically regenerated by heating to 200.degree.-300.degree. C. in the presence of oxygen, the regenerating conditions being such as to avoid a substantial oxidation of the carbon mass.
摘要翻译： 一种纯化含有硫化氢的气体的方法，其中所述气体与氧气混合并与特定表面积高于50m2 / g并且含有至少一种铁和/或铜的氧化物和/或硫酸盐的碳质量块接触， 温度为20℃至170℃，选择操作条件以避免所述物质的实质氧化，并且所述物质通过在氧气存在下加热至200-300℃来定期再生，再生 条件是为了避免碳质量的显着氧化。
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3.发明授权Process for removing H.sub.2 S and CO.sub.2 from gases and regenerating the adsorbing solution 失效从气体中除去H {HD 2 {B S和CO（HD 2 {B）并再生吸附溶液的方法
公开(公告)号：US4163043A
公开(公告)日：1979-07-31
申请号：US889803
申请日：1978-03-24
IPC分类号： B01D53/52 , B01D53/77 , C01B17/52 , C01C1/22 , C01D1/04 , C01D1/20 , C01G3/00 , C01G3/12 , C02F1/58 , B01D53/34
摘要： H.sub.2 S and CO.sub.2 from a waste gas are absorbed in an ammoniacal or alkali metal hydroxide solution. The resultant sodium, potassium or ammonium sulfide solution is reacted with pulverized copper oxide and the resultant copper sulfide precipitate is separated and the resultant solution of increased sodium hydroxide, potassium hydroxide or ammonia content is recycled as absorbent for hydrogen sulfide and CO.sub.2. The copper sulfide is roasted to form recyclable copper oxide and product sulfur dioxide.
摘要翻译： 来自废气的H 2 S和CO 2被吸收在氨或碱金属氢氧化物溶液中。 所得的硫化钠，硫化钾或硫化铵溶液与粉碎的氧化铜反应，分离得到的硫化铜沉淀物，所得到的氢氧化钠，氢氧化钾或氨含量的溶液作为硫化氢和CO 2的吸收剂再循环。 硫化铜被焙烧以形成可回收的氧化铜和产物二氧化硫。
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4.发明授权
公开(公告)号：US4164543A
公开(公告)日：1979-08-14
申请号：US865287
申请日：1977-12-28
CPC分类号： C01B17/60 , B01D53/501
摘要： Process for regenerating brines containing simultaneously sodium sulfites and sulfates so as to produce sulfur dioxide and an alkaline solution usable for absorbing sulfur dioxide, comprising contacting the brine with ammonium bisulfate, sodium bisulfate and ammonium sulfite to produce sulfur dioxide and an enriched solution of sodium sulfate and ammonium sulfate, which is reacted with CO.sub.2 and ammonia to obtain solid sodium bicarbonate which is decomposed to form CO.sub.2 and an enriched solution of ammonium sulfate, containing dissolved ammonium bicarbonate, which is heated with a reducing agent so as to decompose the ammonium sulfate to ammonia and ammonium bisulfate which is partly reduced to gaseous ammonia and sulfur dioxide, said process including several recycling steps.
摘要翻译： 再生含有亚硫酸钠和硫酸盐的盐水以制备可用于吸收二氧化硫的二氧化硫和碱性溶液的方法，包括使盐水与硫酸氢铵，硫酸氢钠和亚硫酸铵接触以产生二氧化硫和富含硫酸钠的溶液 和硫酸铵，其与CO 2和氨反应以获得固体碳酸氢钠，其分解形成CO 2和含有溶解的碳酸氢铵的富含硫酸铵的溶液，其用还原剂加热以将硫酸铵分解成 氨和硫酸氢铵，其部分还原成气态氨和二氧化硫，所述方法包括若干回收步骤。
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公开(公告)号：US4048293A
公开(公告)日：1977-09-13
申请号：US671711
申请日：1976-03-29
CPC分类号： B01D53/501 , B01D53/8612 , C01B17/05
摘要： This process for purifying a sulfur dioxide containing gas, for example stack gas, comprises the steps of washing the gas with aqueous ammonia or ammonium sulfite, vaporizing sulfur dioxide and ammonia therefrom, reacting vaporized sulfur dioxide with hydrogen sulfide and recycling an ammonia containing stream. To avoid the drawbacks resulting from the presence of hydrogen sulfide in the recycle stream, a further oxidation step is provided to convert hydrogen sulfide to sulfur dioxide.
摘要翻译： 用于纯化含二氧化硫的气体（例如烟气）的方法包括以下步骤：用氨水或亚硫酸铵洗涤气体，从其中蒸发二氧化硫和氨，使蒸发的二氧化硫与硫化氢反应并再循环含氨气流。 为了避免在循环物流中存在硫化氢导致的缺点，提供了另外的氧化步骤以将硫化氢转化为二氧化硫。
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6.发明授权Process for converting ammonium imidodisulfate, ammonium sulfamate and ammonium dithionate to sulfur dioxide and ammonia 失效将亚氨二硫酸铵，氨基磺酸铵和连二硫酸铵转化为二氧化硫和氨的方法
公开(公告)号：US4220634A
公开(公告)日：1980-09-02
申请号：US002273
申请日：1979-01-10
CPC分类号： C01B17/90 , C01B17/501 , C01C1/028 , Y02P20/52
摘要： Ammonium imidodisulfate and ammonium sulfamate may be converted to sulfur dioxide and ammonia by heating them with a reducing agent or a catalyst in a bath of molten ammonium sulfate and ammonium bisulfate. The reducing agent is sulfur or a sulfur compound and the catalyst is selected from Mo, W, Cu, Fe, Co, Cr, Mn and Ni.
摘要翻译： 亚胺二硫酸铵和氨基磺酸铵可以通过在熔融硫酸铵和硫酸氢铵浴中用还原剂或催化剂加热而转化为二氧化硫和氨。 还原剂是硫或硫化合物，催化剂选自Mo，W，Cu，Fe，Co，Cr，Mn和Ni。
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公开(公告)号：US4044114A
公开(公告)日：1977-08-23
申请号：US641223
申请日：1975-12-16
CPC分类号： C01B17/05 , B01D53/8615 , C01B17/0408 , C01B17/0456
摘要： Process for purifying a gas containing hydrogen sulfide and sulfur dioxide, comprising substantially removing sulfur dioxide, absorbing hydrogen sulfide on a solid contact mass, intermittently regenerating said mass by means of an oxygen-containing gas, so as to produce a gas containing sulfur dioxide, and reacting the latter gas with hydrogen sulfide to produce sulfur.
摘要翻译： 用于纯化含有硫化氢和二氧化硫的气体的方法，包括基本上除去二氧化硫，在固体接触物质上吸收硫化氢，通过含氧气体间歇地再生所述物质，以产生含有二氧化硫的气体， 并使后者的气体与硫化氢反应产生硫。
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8.发明授权Process for converting sulfitic solutions by means of ammonium bisulfate with SO.sub.2 production 失效通过具有“2”生产的三聚氰胺转换硫酸溶液的方法
公开(公告)号：US4146579A
公开(公告)日：1979-03-27
申请号：US840947
申请日：1977-10-11
摘要： This process avoids the disadvantages of admixing hot molten ammonium bisulfate with ammonium sulfites solutions. Overflowing hot molten ammonium bisulfate is admixed with a stream of aqueous ammonium bisulfate solution, said solution being preferably circulated in a closed loop. A portion of the resulting solution is then used to acidify the ammonium sulfites solution.
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9.发明授权Process for purifying a gas containing hydrogen sulfide and carbon dioxide and apparatus therefor 失效用于净化含有硫化氢和二氧化碳的气体的方法及其设备
公开(公告)号：US4421725A
公开(公告)日：1983-12-20
申请号：US281798
申请日：1981-07-09
CPC分类号： B01D53/18
摘要： Process for separating H.sub.2 S from CO.sub.2, both contained in a treated gas, wherein said gas is contacted with a solution which selectively absorbs H.sub.2 S, wherefrom H.sub.2 S is separated in a regeneration zone, CO.sub.2 being released, said contact step being effected in a contact apparatus comprising 1 to 10 stages each formed of parallel vertical tubes whose bottom portion is provided with injection means of the cyclonic type imparting to the supplied gas and liquid a swirling ascending motion.
摘要翻译： 二氧化碳的分离方法，二者都包含在处理气体中，其中所述气体与选择性吸收H 2 S的溶液接触，其中H 2 S在再生区域中被分离，CO 2被释放，所述接触步骤在接触装置中进行，包括 1至10级，每个级别由平行的垂直管形成，其底部设置有向所供应气体和液体赋予旋转上升运动的旋风式喷射装置。
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10.发明授权Process for purifying a sulfur dioxide containing gas with production of elemental sulfur 失效用生成元素硫来净化含二氧化硫的气体的方法
公开(公告)号：US4174383A
公开(公告)日：1979-11-13
申请号：US717943
申请日：1976-08-26
CPC分类号： C01B17/56 , B01D53/501 , C01B17/05
摘要： Process for purifying SO.sub.2 -containing gas comprising a first step of contacting said gas with an aqueous solution of an ammonium sulfite or an ammonium thiosulfate also containing ammonium sulfate, a second step of contacting the resulting solution with a H.sub.2 S-containing gas at 20.degree.-90.degree. C. to produce sulfur which is separated from the remaining solution, a third step of recyling 90 to 99.99% by volume of said remaining solution to the first step, and a fourth step of introducing 0.01 to 10% by volume of said remaining solution into a molten salt formed of ammonium sulfate and/or bisulfate so as to produce a gas containing SO.sub.2, ammonia, sulfur and steam, which is recycled to the first step.
摘要翻译： 包括用于纯化含SO 2的气体的方法，包括使所述气体与还含有硫酸铵的亚硫酸铵或硫代硫酸铵的水溶液接触的第一步骤，第二步是使所得溶液与含有H 2 S的气体在20℃下接触， 90℃，以产生与剩余溶液分离的硫，第三步骤，将90至99.99体积％的剩余溶液重新循环至第一步骤;第四步骤，将0.01至10体积％的所述剩余溶液 溶液形成由硫酸铵和/或硫酸氢盐形成的熔盐，以产生含有SO 2，氨，硫和蒸汽的气体，其被再循环到第一步。
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