摘要:
An apparatus for a hydrocarbon reforming process includes a combustion chamber, a convection chamber in fluid communication with the combustion chamber, at least one burner disposed in the combustion chamber, a reaction chamber, a means for flowing a first mixed-feed through a first part of the reaction chamber, and a means for flowing a second mixed-feed through an annular portion of a second part of the reaction chamber, the second part being a tube-in-tube in fluid communication with the first part. The burner(s) generates a flow of a flue gas having a sensible heat from the combustion chamber to the convection chamber. The flow of the flue gas in the convection chamber is counter-currently with the flow of the second mixed-feed.
摘要:
A process for producing a high temperature COx-lean product gas from a high temperature COx-containing feed gas, includes: providing a sorption enhanced reactor containing a first adsorbent, a shift catalyst and a second adsorbent; feeding into the reactor a feed gas containing H2, H2O, CO and CO2; contacting the feed gas with the first adsorbent to provide a CO2 depleted feed gas; contacting the CO2 depleted feed gas with the shift catalyst to form a product mixture comprising CO2 and H2; and contacting the product mixture with a mixture of second adsorbent and shift catalyst to produce the product gas, which contains at least 50 vol. % H2, and less than 5 combined vol. % of CO2 and CO. The adsorbent is a high temperature adsorbent for a Sorption Enhanced Reaction process, such as K2CO3 promoted hydrotalcites, modified double-layered hydroxides, spinels, modified spinels, and magnesium oxides.
摘要翻译:一种由高温含CO 2原料气体制备高温CO 2 - 产物气体的方法包括:提供含有第一吸附剂的吸附增强反应器, 换挡催化剂和第二吸附剂; 向反应器中加入含有H 2,H 2 O,CO和CO 2的进料气体; 使进料气体与第一吸附剂接触以提供CO 2 CO 2贫化的进料气体; 使CO 2 2贫的进料气与转化催化剂接触以形成包含CO 2和H 2的产物混合物; 并将产物混合物与第二吸附剂和变换催化剂的混合物接触以产生产物气体,其含有至少50vol。 %H 2,和小于5的组合体积。 CO 2%和CO的吸附剂吸附剂是用于吸附增强反应方法的高温吸附剂,例如K 2 CO 3促进的水滑石 改性双层氢氧化物,尖晶石,改性尖晶石和氧化镁。
摘要:
A system for detecting fine liquid, e.g., oil, particles in a gas system having a high pressure compressor and at least two gas handling devices, e.g., a coalescer and at least one adsorber. The detection system uses plural sensors and a monitor unit to detect the presence of such fine liquid particles in various portions of the gas system and to provide alert signals in response thereto. The alert signals can be used by associated valves to control the gas system.
摘要:
A method for combusting oil from an oil-containing layer floating on water as from an oil spill or well leak. In the method, an oxygen-containing gas is passed through a conduit, the oxygen-containing gas from the conduit is introduced proximate the oil-containing layer floating on water, and oil from the oil-containing layer is combusted with the oxygen-containing gas in the presence of a flame. The oxygen-containing gas is introduced with an oxygen molar flow rate sufficient to decrease the opacity of a smoke plume from the combusting oil.
摘要:
A system for detecting fine liquid, e.g., oil, particles in a gas system having a conduit through which a gas, e.g., hydrogen, air, etc., will flow. The detection system includes a monitor including a high sensitivity photometric sensor, a data acquisition unit and flow and pressure control components to control the pressure and rate of flow of the gas to the monitor. The detection system is arranged to detect the presence of fine liquid particles the gas passing through the conduit and to provide an alert signal representative of the mass count of such particles in response thereto.
摘要:
A method for combusting oil from an oil-containing layer floating on water as from an oil spill or well leak. In the method, an oxygen-containing gas is passed through a conduit, the oxygen-containing gas from the conduit is introduced proximate the oil-containing layer floating on water, and oil from the oil-containing layer is combusted with the oxygen-containing gas in the presence of a flame. The oxygen-containing gas is introduced with an oxygen molar flow rate sufficient to decrease the opacity of a smoke plume from the combusting oil.
摘要:
A method and apparatus for the production of hydrogen-rich gas are provided. The method and apparatus prevent over-reduction of iron oxide-based shift catalyst by introducing an oxidative stream along with a carbon monoxide containing gaseous feed stream from a catalytic steam reformer to the catalyst bed region and thereby limits structural deterioration of the catalyst. Various sources may provide the oxidative stream including a shift catalyst bed region and a selective oxidation catalyst region.
摘要:
The present invention is an apparatus arranged to maximize heat utilization for a hydrocarbon steam reforming process to produce synthesis gas. The apparatus comprises a refractory lined vessel with partition walls that divide the inside of the vessel into (1) a combustion chamber(s) containing one or more burners, and (2) convection chambers used as a means to remove combustion products from the combustion chamber through one or more openings at the opposite end of the burner end. The combustion chamber contains one or more reformer tubes in which a mixed-feed of hydrocarbon and steam flow co-current with combustion products and receive direct radiant heat from the combustion flame through the tube wall. The convection chambers contain a tube-in-tube device filled with catalyst in the annuli. The mixed-feed in the annuli flows counter-current with combustion products and the hot product synthesis gas, and thereby substantially lowers the temperature of the combustion and product gases before the gases exit the furnace. High emissivity materials or walls are used inside the convection chambers to enhance the heat transfer from the flue gas to the reformer tubes.