Solid elastomeric block copolymers

    公开(公告)号:US5552492A

    公开(公告)日:1996-09-03

    申请号:US443742

    申请日:1995-05-18

    摘要: There are disclosed novel, solid, elastomeric block copolymers having excellent oxidative and thermal stability, wherein the terminal blocks are each a polymer (D polymer) of at least one conjugated diene D, which is a hydrocarbon containing a 1,3-conjugated diene structure wherein the 2 and 3 carbon atoms are each additionally bonded to a hydrocarbyl side group, e.g., 2,3-dimethyl-1,3-butadiene, with a preponderance of polymerized D units being 1,4 units; and at least one interior block is a hydrogenated polymer (I polymer) of at least one conjugated diene I which is a hydrocarbon containing a 1,3-conjugated diene structure wherein one of the 2- and 3-carbon atoms is additionally bonded to a hydrocarbyl side group and the other is additionally bonded to a hydrogen atom, e.g. isoprene. The block copolymers may be prepared by selectively hydrogenating substantially all the I polymer units of a precursor block copolymer with a sufficient number of D units in the D polymer blocks retaining their unsaturation on selective hydrogenation to enable the vulcanization of the block copolymer.

    Elastomer - Modified thermoplastic olefin polymer compositions
    4.
    发明授权
    Elastomer - Modified thermoplastic olefin polymer compositions 失效
    弹性体 - 改性的热塑性烯烃聚合物组合物

    公开(公告)号:US5585441A

    公开(公告)日:1996-12-17

    申请号:US446163

    申请日:1995-05-22

    摘要: A thermoplastic composition comprising a crystalline propylene polymer and as a modifying elastomer, a hydrogenated butadiene polymer which is either an essentially linear hydrogenated butadiene homopolymer or a star-branched polymer, the arms of which are an essentially linear hydrogenated butadiene homopolymer, such hydrogenated butadiene polymer containing from about 20 to about 90% of polymerized butadiene units with the 1,2-microstructure and having a polydispersity index (P.I.) of about 1.01 to 1.50. The compositions have a superior combination of processing and mechanical properties such as flexural strength, impact resistance, and melt flow.

    摘要翻译: 包含结晶丙烯聚合物和改性弹性体的热塑性组合物,氢化丁二烯聚合物,其是基本上为线性的氢化丁二烯均聚物或星形支化聚合物,其臂是基本上线性的氢化丁二烯均聚物,这种氢化丁二烯聚合物 含有约20至约90%的具有1,2-微结构并且多分散指数(PI)为约1.01至1.50的聚合丁二烯单元。 组合物具有优良的加工和机械性能的组合,例如弯曲强度,抗冲击性和熔体流动性。

    Solid elastomeric block copolymers
    8.
    发明授权
    Solid elastomeric block copolymers 失效
    固体弹性体嵌段共聚物

    公开(公告)号:US5438102A

    公开(公告)日:1995-08-01

    申请号:US80638

    申请日:1993-06-24

    摘要: There are disclosed novel, solid, elastomeric block copolymers having excellent oxidative and thermal stability, wherein the terminal blocks are each a polymer (D polymer) of at least one conjugated diene D, which is a hydrocarbon containing a 1,3-conjugated diene structure wherein the 2 and 3 carbon atoms are each additionally bonded to a hydrocarbyl side group, e.g., 2,3-dimethyl-1,3-butadiene, with a preponderance of polymerized D units being 1,4 units; and at least one interior block is a hydrogenated polymer (I polymer) of at least one conjugated diene I which is a hydrocarbon containing a 1,3-conjugated diene structure wherein one of the 2- and 3-carbon atoms is additionally bonded to a hydrocarbyl side group and the other is additionally bonded to a hydrogen atom, e.g. isoprene. The block copolymers may be prepared by selectively hydrogenating substantially all the I polymer units of a precursor block copolymer with a sufficient number of D units in the D polymer blocks retaining their unsaturation on selective hydrogenation to enable the vulcanization of the block copolymer.

    摘要翻译: 公开了具有优异的氧化和热稳定性的新型,固体,弹性体嵌段共聚物,其中端嵌段各自是至少一种共轭二烯D的聚合物(D聚合物),其是含有1,3-共轭二烯结构的烃 其中2和3个碳原子另外与烃基侧基键合,例如2,3-二甲基-1,3-丁二烯,聚合的D单元的优势为1,4单元; 并且至少一个内部嵌段是至少一种共轭二烯I的氢化聚合物(I聚合物),其是含有1,3-共轭二烯结构的烃,其中2-和3-碳原子中的一个另外键合到 烃基侧基和另一个另外键合到氢原子,例如 异戊二烯 嵌段共聚物可以通过选择性氢化前体嵌段共聚物的基本上所有的I聚合物单元来制备,所述前体嵌段共聚物在D聚合物嵌段中具有足够数量的D单元,其在选择性氢化时保持其不饱和键以使嵌段共聚物硫化。