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公开(公告)号：US20100317910A1
公开(公告)日：2010-12-16
申请号：US12813244
申请日：2010-06-10
IPC分类号： B01J29/068 , B01J29/06 , C07C5/27
CPC分类号： B01J29/85 , B01J29/005 , B01J37/10 , B01J2229/18 , C01B39/54 , C07C5/2775 , C07C2529/85 , C10G45/64 , C07C9/22
摘要： Novel silicoaluminophosphate molecular sieve compositions comprising SAPO-11 and SAPO-41 with at least about 5 wt % of in situ-produced amorphous portion. Such compositions can be uncalcined or calcined and novel processes for their preparation are described. These compositions, when loaded or impregnated with a catalytically active species such as a Group VIII noble metal are novel, and are excellent hydroisomerization catalysts.
摘要翻译： 新型硅铝磷酸盐分子筛组合物，其包含SAPO-11和SAPO-41，其具有至少约5重量％的原位产生的无定形部分。 这些组合物可以是未煅烧的或煅烧的，并且描述了它们制备的新方法。 当用催化活性物质如VIII族贵金属负载或浸渍时，这些组合物是新颖的，并且是优异的加氢异构化催化剂。
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2.发明授权Alkylation process using a catalyst comprising a solid acid and a hydrogenation metal 有权使用包含固体酸和氢化金属的催化剂的烷基化方法公开(公告)号：US07750197B2
公开(公告)日：2010-07-06
申请号：US10588106
申请日：2005-01-26
CPC分类号： C07C2/58 , B01J29/126 , B01J2229/42 , C10G29/20 , C10G29/205 , C10G2400/02 , Y10S585/906
摘要： The invention relates to a process for alkylating a hydrocarbon feed which comprises contacting the hydrocarbon feed to be alkylated with an alkylation agent in the presence of a catalyst comprising a solid acid, a hydrogenation metal, and 1.5-6 wt % of water, measured as the loss on ignition at 600° C. The presence of 1.5-6 wt % of water results in a higher activity and a higher alkylate quality compared with a comparable but drier catalyst.
摘要翻译： 本发明涉及烃类进料的烷基化方法，该方法包括使待烷基化的烃进料与烷基化试剂在含有固体酸，氢化金属和1.5-6重量％水的催化剂存在下接触，测量为 在600℃下的点火损失。与可比较但干燥的催化剂相比，存在1.5-6重量％的水导致更高的活性和更高的烷基化物质量。
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公开(公告)号：US08105968B2
公开(公告)日：2012-01-31
申请号：US11906945
申请日：2007-10-04
申请人： Anne Mae Gaffney , Philip Jay Angevine , Cheun Yuan Yeh , Johannes Hendrik Koegler , Jingguang Chen , Emanuel Hermanus van Broekhoven
发明人： Anne Mae Gaffney , Philip Jay Angevine , Cheun Yuan Yeh , Johannes Hendrik Koegler , Jingguang Chen , Emanuel Hermanus van Broekhoven
IPC分类号： B01J29/06
CPC分类号： B01J29/072 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/8913 , B01J23/892 , B01J29/146 , B01J35/002 , B01J35/0053 , B01J2229/186 , C10G29/205 , C10G2300/1088 , C10G2400/02
摘要： Solid acid catalysts for use in alkylation processes are described. The solid acid catalysts include a multimetallic (e.g. bimetallic, trimetallic or tetrametallic) component that performs a hydrogenating function for the reactivation (or regeneration) of the catalyst in the presence of hydrogen. The multimetallic catalyst includes a noble metal such as platinum or palladium. The invention also relates to alkylation processes using the multimetallic solid acid catalysts having a multimetallic component for hydrogenation.
摘要翻译： 描述了用于烷基化方法的固体酸催化剂。 固体酸催化剂包括在氢存在下进行催化剂再活化（或再生）的氢化功能的多金属（例如双金属，三金属或四金属）组分。 多金属催化剂包括贵金属如铂或钯。 本发明还涉及使用具有用于氢化的多金属组分的多金属固体酸催化剂的烷基化方法。
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公开(公告)号：US20110313227A1
公开(公告)日：2011-12-22
申请号：US13148447
申请日：2010-02-09
CPC分类号： B01J29/068 , B01J23/42 , B01J29/087 , B01J29/088 , B01J29/123 , B01J29/126 , B01J29/22 , B01J29/7415 , B01J29/7476 , B01J29/90 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/1066 , B01J37/0009 , B01J37/0201 , B01J2229/16 , B01J2229/20 , B01J2229/36 , B01J2229/42 , C07C2/58 , C07C2529/08 , Y02P20/584 , C07C9/16
摘要： A solid alkylation catalyst having a hydrogenation metal and a solid acid in the form of a rare earth exchanged molecular sieve, wherein the catalyst is at least characterized by a porosity of less than 0.20 ml/g in pores below 100 nm in diameter, and a total porosity of greater than 0.30 ml/g. A process for alkylation using the catalyst is also described.
摘要翻译： 一种具有氢化金属和稀土交换分子筛形式的固体酸的固体烷基化催化剂，其中该催化剂的特征至少在于直径小于100nm的孔中孔隙率小于0.20ml / g，和 总孔隙率大于0.30ml / g。 还描述了使用催化剂的烷基化方法。
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公开(公告)号：US06855856B2
公开(公告)日：2005-02-15
申请号：US10395622
申请日：2003-03-24
CPC分类号： B01J37/0009 , B01J29/126 , B01J35/002 , B01J35/023 , B01J35/10 , B01J35/1038 , C07C2/54 , C07C2/58 , C07C2529/12
摘要： The invention pertains to a process for the alkylation of hydrocarbons wherein a hydrocarbon feedstock and an olefin are contacted with a catalyst at alkylation process conditions. The catalyst comprises a hydrogenation function and a solid acid. The ratio between (i) the volume in catalyst pores with a diameter in the range of about 40-8000 nm and (ii) the specific length of the catalyst particles is in the range of about 0.01-0.90 ml/(g*mm). The catalyst has a total pore volume of at least about 0.20 ml/g and the volume in the catalyst pores with a diameter in the range of about 40-8000 nm is below about 0.30 ml/g.
摘要翻译： 本发明涉及烃的烷基化方法，其中烃原料和烯烃在烷基化工艺条件下与催化剂接触。 该催化剂包括氢化功能和固体酸。 （i）直径在约40-8000nm范围内的催化剂孔中的体积和（ii）催化剂颗粒的特定长度之间的比例在约0.01-0.90ml /（g * mm）的范围内， 。 催化剂具有至少约0.20ml / g的总孔容积，并且直径在约40-8000nm范围内的催化剂孔中的体积低于约0.30ml / g。
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公开(公告)号：US11225614B2
公开(公告)日：2022-01-18
申请号：US16490644
申请日：2018-03-01
摘要： An improved alkylation process with improved octane number and lower final boiling point. Further, the present disclosure comprises an alkylation system that allows flexibility in the operating parameters without loss of productivity. This enhances the advantage of the solid acid alkylation process of the invention over the liquid acid processes, as the C9+ alkylate will mainly contain the desired highly branched paraffin's in the case of solid acid alkylation. By fractionation of C9+, the RON number of the gasoline alkylate after fractionation remains very high, while the final boiling point of the gasoline fraction will decrease, improving value and blending flexibility.
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公开(公告)号：US20130225887A1
公开(公告)日：2013-08-29
申请号：US13883089
申请日：2011-08-30
申请人： Emanuel Hermanus Van Broekhoven , Ralph Klomp , Ruben Theodoor Fronk , Leendert Arie Gerritsen , Frans Lodewijk Plantenga , Edgar Evert Steenminkel
发明人： Emanuel Hermanus Van Broekhoven , Ralph Klomp , Ruben Theodoor Fronk , Leendert Arie Gerritsen , Frans Lodewijk Plantenga , Edgar Evert Steenminkel
IPC分类号： C07C1/22
CPC分类号： C07C1/22 , B01J23/85 , B01J23/883 , B01J37/20 , C10G3/46 , C10G3/50 , C10G2300/4006 , C10G2300/4081 , C10G2300/42 , Y02P30/20
摘要： The present invention relates to the hydrodeoxygenation of pyrolysis oils in the presence of an alcohol.
摘要翻译： 本发明涉及在醇存在下热解油的加氢脱氧。
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8.发明授权Alkylation process using a catalyst comprising rare earth containing zeolites and a hydrogenation metal 有权使用包含含稀土沸石和氢化金属的催化剂的烷基化方法公开(公告)号：US08163969B2
公开(公告)日：2012-04-24
申请号：US12021096
申请日：2008-01-28
CPC分类号： B01J29/126 , B01J29/7007 , B01J29/90 , B01J35/023 , B01J38/56 , B01J38/58 , B01J2229/18 , B01J2229/40 , B01J2229/42 , C07C2/58 , C07C2521/04 , C07C2529/12 , C07C2529/74 , C10G2300/703 , C10G2300/805 , C10G2400/02 , Y02P20/584 , C07C9/16
摘要： An improved alkylation process utilizing a solid-acid catalyst comprising a rare earth containing zeolite and a hydrogenation metal is disclosed.
摘要翻译： 公开了一种利用包含含稀土沸石和氢化金属的固体酸催化剂的改进的烷基化方法。
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公开(公告)号：US07176340B2
公开(公告)日：2007-02-13
申请号：US10163108
申请日：2002-06-05
CPC分类号： C07C2/58 , C07C2523/42 , C07C2523/44 , Y02P20/584
摘要： A continuous alkylation process performed in an apparatus comprising a series of at least two zone A reactors and a series of at least two zone B reactors, in which the zone A reactors and the zone B reactors cycle between alkylation mode and mild regeneration mode, and wherein the alkylation mode comprises introducing an alkylation agent into a first reactor of the zone through which the alkylatable compound passes, reacting a portion of the alkylatable compound with a portion of the alkylation agent to produce a product stream, and performing this operation at least once more in a downstream reactor in the same zone employing, instead of alkylatable compound, a stream comprising the product stream.
摘要翻译： 在包括一系列至少两个A区反应器和一系列至少两个B区反应器的装置中进行的连续烷基化方法，其中A区反应器和B区反应器在烷基化模式和温和再生模式之间循环，以及 其中所述烷基化模式包括将烷基化试剂引入所述可烷基化合物通过的区域的第一反应器中，使可烷基化合物的一部分与部分烷基化试剂反应以产生产物流，并进行至少一次 在同一区域的下游反应器中更多地使用代替可烷化化合物的包含产物流的物流。
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公开(公告)号：US09701594B2
公开(公告)日：2017-07-11
申请号：US13883089
申请日：2011-08-30
申请人： Emanuel Hermanus Van Broekhoven , Ralph Klomp , Ruben Theodoor Pronk , Leendert Arie Gerritsen , Frans Lodewijk Plantenga , Edgar Evert Steenwinkel
发明人： Emanuel Hermanus Van Broekhoven , Ralph Klomp , Ruben Theodoor Pronk , Leendert Arie Gerritsen , Frans Lodewijk Plantenga , Edgar Evert Steenwinkel
IPC分类号： C07C1/22 , C10G3/00 , B01J37/20 , B01J23/85 , B01J23/883
CPC分类号： C07C1/22 , B01J23/85 , B01J23/883 , B01J37/20 , C10G3/46 , C10G3/50 , C10G2300/4006 , C10G2300/4081 , C10G2300/42 , Y02P30/20
摘要： The present invention relates to the hydrodeoxygenation of pyrolysis oils in the presence of an alcohol.
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