Abstract:
A method for forming poly(dimethoxymethane) includes a step of separating a formaldehyde-containing blend into a first bottom stream and a first top stream. The first formaldehyde-containing blend includes methanol, formaldehyde, and water while the first bottom stream includes water. The first top stream includes dimethoxymethane that is produced from the reaction between methanol and formaldehyde. The first top stream is separated into a second bottom stream and a second top stream. The second bottom stream includes poly(dimethoxymethane) while the second top stream includes dimethoxymethane, methanol, and ethanol. The second top stream is separated into a third bottom stream and a third top stream. Third bottom stream includes methanol and ethanol while the third top stream includes dimethoxymethane. The third top steam can be recycled to form additional poly(dimethoxymethane). A system that implements the method is also provided.
Abstract:
An electricity generator includes a generator section which is a complete standalone electricity generator designed to operate on a hydrocarbon fuel and a fuel conversion section which adapts the generator section to operate on alternative fuels that are different than the designed fuel of generator section. The generator section includes a RPM control unit, an internal combustion engine which has a crankshaft, an electromagnetic conversion component which converts the rotational motion of the crankshaft into electricity and a crankshaft sensor which senses the rotational speed of the crankshaft thereby creating a RPM control signal. The control signal is provided to the RPM control unit which controls the rotational speed of the crankshaft. The fuel conversion section includes a first fuel source and a second fuel source. Characteristically, the first fuel source provides a methanol-containing fuel and the second fuel source provides LPG or flare gas.
Abstract:
A method for removing formaldehyde from a blend of partially oxygenated hydrocarbons is provided. The method including a step of reacting a hydrocarbon-containing gas with an oxygen-containing gas in a reaction vessel to form first product blend. The first product blend includes a blend of partially oxygenated compounds that include formaldehyde. The blend of partially oxygenated compounds is provided to a reactive scrubbing station where it is contacted with a reactive scrubbing liquid to form a reactive liquid-formaldehyde compound. The reactive liquid-formaldehyde compound is then removed from the first blend of partially reactive compounds.
Abstract:
A method includes a step of supplying a first heated hydrocarbon-containing gas stream to a reactor. An oxygen-containing gas stream is separately supplied to the reactor to partially oxidize the hydrocarbon-containing gas stream. The oxygen-containing gas is optionally prepared by passing air through one or more membranes to increase the oxygen content. One or more of the desired liquid oxygenated hydrocarbons are condensed and/or separated from the resulting product stream. Non-hydrocarbon gases are selectively removed from the product stream to enrich the gaseous hydrocarbon fraction using a scrubber and/or a membrane. The remaining gaseous hydrocarbon products from the product stream are mixed with a fresh hydrocarbon-containing gas stream after one cycle of the reaction. Characteristically, the process uses at least one membrane to increase oxygen content of the oxygen containing gas and/or to remove non-hydrocarbon gases from the product stream as set forth above.
Abstract:
A fire suppression apparatus and method of generating foam are provided in which a foam-forming liquid is introduced under high velocity and pressure into a mixing manifold through a plurality of jets, and a non-combustible gas is introduced under high velocity and pressure into the center of the mixing manifold, downstream of the jets and in the direction of flow of the foam-forming liquid. The foam generated in the mixing manifold is discharged through a hose and nozzle connected to the mixing manifold. The apparatus may be a self-contained unit, supported on a frame, with its own supply of foam-forming liquid and non-combustible gas.
Abstract:
A method for forming a blend of ethers from a blend of alcohols includes a step of reacting a hydrocarbon-containing gas with an oxygen-containing gas to form first product blend. The first product blend includes a blend of partially oxygenated compounds. The blend of partially oxygenated compounds is provided to a reactive distillation station where it is converted a second product blend. The second product blend typically includes a mixture of ethers. An apparatus implementing the method is also provided.
Abstract:
A method for forming poly(dimethoxymethane) includes a step of separating a formaldehyde-containing blend into a first bottom stream and a first top stream. The first formaldehyde-containing blend includes methanol, formaldehyde, and water while the first bottom stream includes water. The first top stream includes dimethoxymethane that is produced from the reaction between methanol and formaldehyde. The first top stream is separated into a second bottom stream and a second top stream. The second bottom stream includes poly(dimethoxymethane) while the second top stream includes dimethoxymethane, methanol, and ethanol. The second top stream is separated into a third bottom stream and a third top stream. Third bottom stream includes methanol and ethanol while the third top stream includes dimethoxymethane. The third top steam can be recycled to form additional poly(dimethoxymethane). A system that implements the method is also provided.
Abstract:
Catalytic CO2 hydrogenation to ethanol utilizing radio frequency is very attractive due to higher selectivity (˜99%) to ethanol and yield of 0.000718 g/h or higher. A dielectric barrier discharge (DBD) plasma reactor packed with a catalyst comprising of Cu/Zn/Al2O3 can be used for this purpose, which can be operated at approximately 100-200° C., 1-20 atm pressure and gas flow rates above 20 mL/min. The reactor can be made of a simple inert tube. The process is very attractive for a feasible industrial application. To scale up the process to industrial relevance, a multi-tubular reactor configuration is proposed.
Abstract:
A method for forming poly(dimethoxymethane) includes a step of separating a formaldehyde-containing blend into a first bottom stream and a first top stream. The first formaldehyde-containing blend includes methanol, formaldehyde, and water while the first bottom stream includes water. The first top stream includes dimethoxymethane that is produced from the reaction between methanol and formaldehyde. The first top stream is separated into a second bottom stream and a second top stream. The second bottom stream includes poly(dimethoxymethane) while the second top stream includes dimethoxymethane, methanol, and ethanol. The second top stream is separated into a third bottom stream and a third top stream. Third bottom stream includes methanol and ethanol while the third top stream includes dimethoxymethane. The third top steam can be recycled to form additional poly(dimethoxymethane). A system that implements the method is also provided.
Abstract:
A method for forming a blend of ethers from a blend of alcohols includes a step of reacting a hydrocarbon-containing gas with an oxygen-containing gas to form first product blend. The first product blend includes a blend of partially oxygenated compounds. The blend of partially oxygenated compounds is provided to a reactive distillation station where it is converted a second product blend. The second product blend typically includes a mixture of ethers. An apparatus implementing the method is also provided.