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    Process for the production of cyanate ester resins having unique composition
    5.
    发明授权
    Process for the production of cyanate ester resins having unique composition 失效
    用于生产具有独特组成的氰酸酯树脂的方法

    公开(公告)号：US5756592A

    公开(公告)日：1998-05-26

    申请号：US751083

    申请日：1996-11-15

    申请人： William B. Bedwell ,  Raymond J. Swedo ,  Bruce T. DeBona ,  George D. Green

    发明人： William B. Bedwell ,  Raymond J. Swedo ,  Bruce T. DeBona ,  George D. Green

    IPC分类号： B01J19/24 ,  C08G8/28 ,  C08G73/06 ,  C08G85/00 ,  C08G65/48

    CPC分类号： B01J19/2415 ,  C08G8/28 ,  B01J2219/00058 ,  B01J2219/00099 ,  B01J2219/00166 ,  B01J2219/00186

    摘要： A continuous process for the production of a phenolic-based cyanate ester resin is provided and includes the steps of: feeding a phenolic organic compound, a trialkylamine and a cyanogen halide into a continuous, plug-flow type reactor; causing the reactants to flow through and react in the reactor over a period of time defined as a residence time; continuously reacting the phenolic organic compound, the triallckylamine and the cyanogen halide in the reactor; and maintaining a temperature in the reactor of between about -75.degree. C. to about 0.degree. C. The reactor has a length which is equal to or greater than ten times its internal diameter. The mol equivalent concentration of the cyanogen halide is greater than the mol equivalent concentration of the trialkylamine, and the mol equivalent of the trialkylamine is greater than the mol equivalent of the phenolic organic compound. The reactants are resident for a long enough time in the reactor to achieve at least substantial conversion of the phenol groups to cyanate ester groups, but for short enough a time to substantially suppress undesirable side reactions. The phenolic-based cyanate ester resins prepared by the continuous process may contain as much as 95 percent by weight or more cyanate ester groups.

    摘要翻译： 提供了一种生产酚基氰酸酯树脂的连续方法，包括以下步骤：将酚类有机化合物，三烷基胺和氰卤化物进料到连续的流动型反应器中; 使反应物在定义为停留时间的时间内流过并在反应器中反应; 在反应器中使酚类有机化合物，三环戊胺和氰卤化物连续反应; 并将反应器中的温度保持在约-75℃至约0℃之间。反应器的长度等于或大于其内径的十倍。 氰卤化物的摩尔当量浓度大于三烷基胺的摩尔当量浓度，三烷基胺的摩尔当量大于酚类有机化合物的摩尔当量。 反应物在反应器中驻留足够长的时间以实现酚基团至少基本上转化为氰酸酯基团，但足够短的时间以基本上抑制不期望的副反应。 通过连续方法制备的酚基氰酸酯树脂可以含有多达95重量％或更多个氰酸酯基团。

    Hydrogen stabilizers for vinyl ether-based coating systems
    6.
    发明授权
    Hydrogen stabilizers for vinyl ether-based coating systems 失效
    乙烯基醚类涂料体系用氢稳定剂

    公开(公告)号：US5491178A

    公开(公告)日：1996-02-13

    申请号：US293613

    申请日：1994-08-19

    申请人： Raymond J. Swedo ,  George D. Green ,  James R. Snyder

    发明人： Raymond J. Swedo ,  George D. Green ,  James R. Snyder

    IPC分类号： C08F2/50 ,  C08F290/14 ,  C09D4/06 ,  C08K5/134 ,  C08K5/098 ,  C08K5/36 ,  C08L67/00

    CPC分类号： C08F290/141 ,  C09D4/06

    摘要： This invention relates to vinyl ether-based coatings for which properties such as color stability, thermal stability, mechanical stability, hydrolytic stability, and resistance to embrittlement may be maintained and properties hydrogen generation and blocking are minimized. The coatings comprise a vinyl ether-containing composition polymerizable by actinic, gamma ray, or electron beam radiation comprising: (a) an oligomer or a mixture of oligomers which are monofunctional, multifunctional, or a mixture of both monofunctional and multifunctional and which have a reactive functionality chosen from the group consisting of epoxy, acrylate, vinyl ether, maleate, or mixtures thereof; (b) monomers which are monofunctional, multifunctional, or a mixture of both monofunctional and multifunctional monomers and which have a reactive functionality chosen from the group consisting of epoxy, acrylate, vinyl ether, maleate, or mixtures thereof, wherein at least one of (a) or (b) must contain a vinyl ether functionality; (c) a photoinitiator, optionally including a sensitizer, chosen from the group consisting of a cationic photoinitiator and a radical photoinitiator; and (d) a thermal oxidation stabilizer. The composition also comprises additives including as hydrogen stabilizers; mixtures of hindered phenols, organic sulfides or disulfides, and transition metal salts of organic compounds.

    摘要翻译： 本发明涉及可以保持诸如颜色稳定性，热稳定性，机械稳定性，水解稳定性和耐脆性等性能的乙烯基醚类涂料，并且氢气产生和阻塞性能最小化。 涂层包含可通过光化学，γ射线或电子束辐射聚合的含乙烯基醚的组合物，其包含：（a）低聚物或低聚物的混合物，其是单官能的，多官能的或单官能的和多功能的混合物，并且具有 选自环氧基，丙烯酸酯，乙烯基醚，马来酸酯或其混合物的反应性官能团; （b）单官能单体，多官能单体或单官能单体和多官能单体的混合物，其具有选自环氧基，丙烯酸酯，乙烯基醚，马来酸酯或其混合物的反应性官能团的单体，其中至少一种（ a）或（b）必须含有乙烯基醚官能团; （c）任选地包含敏化剂的光引发剂，其选自阳离子光引发剂和自由基光引发剂; 和（d）热氧化稳定剂。 该组合物还包括作为氢稳定剂的添加剂; 受阻酚，有机硫化物或二硫化物的混合物，以及有机化合物的过渡金属盐。

    Preparation of vinyl ether terminated polyesters
    7.
    发明授权
    Preparation of vinyl ether terminated polyesters 失效
    乙烯基醚封端聚酯的制备

    公开(公告)号：US5286835A

    公开(公告)日：1994-02-15

    申请号：US935078

    申请日：1992-08-24

    申请人： George D. Green ,  James R. Snyder ,  Darryl K. Barnes

    发明人： George D. Green ,  James R. Snyder ,  Darryl K. Barnes

    IPC分类号： C07C67/29 ,  C08G63/21 ,  C08G63/52 ,  C08G63/676 ,  C08G63/91 ,  H04N7/169 ,  H04N7/173 ,  C08G63/47

    CPC分类号： H04N7/1696 ,  C07C67/29 ,  C08G63/21 ,  C08G63/676 ,  H04N7/17327

    摘要： Vinyl ether terminated ester oligomers having a range of molecular weights are prepared by reacting a vinyl ether terminated polybasic ester with a polyol in the presence of a catalyst. Continual removal of a hydroxy monovinyl ether avoids formation compounds containing acetal moieties. Alternatively, a polybasic ester is chain extended with a polyol with continual removal of the alcohol by-product. Then, the terminal ester moieties are end capped with a monohydroxy vinyl ether. The oligomers have application in coatings and the like.

    摘要翻译： 通过在催化剂存在下使乙烯基醚封端的多元酯与多元醇反应来制备具有一定范围分子量的乙烯基醚封端的酯低聚物。 持续去除羟基单乙烯基醚避免含有缩醛部分的形成化合物。 或者，多元醇与多元醇链延伸，连续除去醇副产物。 然后，末端酯部分用一羟基乙烯基醚封端。 低聚物可用于涂料等。

    Method to impart coffee stain resistance to polyamide fibers
    8.
    发明授权
    Method to impart coffee stain resistance to polyamide fibers 失效
    提高咖啡对聚酰胺纤维的耐污染性的方法

    公开(公告)号：US5135774A

    公开(公告)日：1992-08-04

    申请号：US500813

    申请日：1990-03-27

    申请人： Lidia T. Calcaterra ,  Mathias P. Koljack ,  Qamardin Farishta ,  Michael G. Koehler ,  William B. Bedwell ,  Dale A. Hangey ,  George D. Green

    发明人： Lidia T. Calcaterra ,  Mathias P. Koljack ,  Qamardin Farishta ,  Michael G. Koehler ,  William B. Bedwell ,  Dale A. Hangey ,  George D. Green

    IPC分类号： D06M15/233 ,  D06M15/263 ,  D06M101/00 ,  D06M101/16 ,  D06M101/30 ,  D06M101/34 ,  D06M101/36

    CPC分类号： D06M15/263 ,  D06M15/233

    摘要： A method to impart coffee stain resistance to polyamide fibers such as those found in textile substrates (e.g., carpets). The method includes preparing an aqueous dispersion of charged microfine beads of either (i) a copolymer selected from the group consisting of a hydrolyzed aromatic-containing vinyl ether maleic anhydride copolymer, a half ester of an aromatic-containing vinyl ether maleic anhydride copolymer, and mixtures thereof, or (ii) an aromatic-containing acrylate copolymerized with an acid selected from the group consisting of acrylic acid and maleic acid, immersing the polyamide fiber in the aqueous dispersion so that the beads contact and coat the fiber via an electrostatic attraction. The aqueous dispersion is prepared by dissolving the polymer into a water-soluble solvent to form a solution, injecting the solution into water, and evaporating the solvent.

    摘要翻译： 赋予聚酰胺纤维耐咖啡污染性的方法，例如在织物基材（例如地毯）中发现的那些。 该方法包括制备带电微细珠粒的水性分散体，其选自（i）选自由水解的含芳族乙烯基醚马来酸酐共聚物，含芳族乙烯基醚马来酸酐共聚物的半酯，和 其混合物，或（ii）与选自丙烯酸和马来酸的酸共聚的含芳族酯的丙烯酸酯，将聚酰胺纤维浸渍在水性分散体中，使得珠粒通过静电吸引而接触和涂覆纤维。 通过将聚合物溶解在水溶性溶剂中以形成溶液，将溶液注入水中并蒸发溶剂来制备水分散体。

    BIPHENOL ETHER COMPOUNDS
    10.
    发明申请
    BIPHENOL ETHER COMPOUNDS 审中-公开
    BIPHENOL醚化合物

    公开(公告)号：US20140142346A1

    公开(公告)日：2014-05-22

    申请号：US14129388

    申请日：2012-06-28

    申请人： George D. Green ,  Raymond J. Swedo

    发明人： George D. Green ,  Raymond J. Swedo

    IPC分类号： C07C43/205

    CPC分类号： C07C43/2055 ,  C10L1/003

    摘要： A compound having formula (I), wherein R represents C1-C18 alkyl, C5-C18 cycloalkyl, C3-C18 alkenyl or C3-C18 alkynyl; provided that, when —OR groups are in 2,2′-positions on benzene rings in formula (I), R is not methyl, ethyl, hexyl, octyl or allyl.

    摘要翻译： 具有式（I）的化合物，其中R表示C 1 -C 18烷基，C 5 -C 18环烷基，C 3 -C 18烯基或C 3 -C 18炔基; 条件是当式（I）中的-OR基团在苯环上为2,2'-位时，R不是甲基，乙基，己基，辛基或烯丙基。