公开(公告)号：US20100275847A1

公开(公告)日：2010-11-04

申请号：US12749175

申请日：2010-03-29

申请人： Teruyuki YAMASAKI ,  Akira SHIRAKURA ,  Hideyasu ANDO

发明人： Teruyuki YAMASAKI ,  Akira SHIRAKURA ,  Hideyasu ANDO

IPC分类号： C23C16/448

CPC分类号： C23C16/26 ,  B65D1/0215 ,  B65D23/0814 ,  C23C16/045 ,  C23C16/505 ,  Y10T428/1352

摘要： The present invention provides a plastic container having a inner wall surface coated with DLC film which has same level of oxygen barrier property as prior art and can prevent a coloring of the DLC film formed on a neck portion of the container, manufacturing apparatus therefor and manufacturing method thereof.The apparatus for manufacturing the DLC film coated plastic container, comprising: a container side electrode which forms one portion of a pressure-reducing chamber which houses a container formed from plastic, a facing electrode which faces said container side electrode and is arranged inside said container or above said opening, wherein said container side electrode and said facing electrode are made to face each other via an insulating body which forms a portion of said pressure-reducing chamber, source gas supply means which includes a supply gas inlet pipe, exhaust means, and high frequency supply means; wherein said container side electrode is formed so that the average inner hole diameter of the inner wall surrounding said neck portion when the container is housed becomes smaller than the average inner hole diameter of the inner wall surrounding said body portion, and the average distance between the outer wall of said container and the inner wall of said container side electrode in a horizontal cross section with respect to the vertical direction of said container at said neck portion becomes longer than the average distance between the outer wall of said container and the inner wall of said container side electrode in a horizontal cross section with respect to the vertical direction of said container at said body portion.

摘要翻译： 本发明提供了一种塑料容器，其具有涂覆有DLC膜的内壁表面，其具有与现有技术相同的氧阻隔性能，并且可以防止形成在容器的颈部上的DLC膜着色，其制造装置和制造 方法。 用于制造DLC薄膜包衣的塑料容器的装置包括：容器侧电极，其形成容纳由塑料形成的容器的减压室的一部分，面对所述容器侧电极并设置在所述容器内的面对电极 或上述开口，其中所述容器侧电极和所述面对电极通过形成所述减压室的一部分的绝缘体彼此面对，源气体供应装置包括供气入口管，排气装置， 和高频供电装置; 其特征在于，所述容器侧电极被形成为使得当容纳容器时围绕所述颈部的内壁的平均内孔直径小于围绕所述主体部分的内壁的平均内孔直径， 所述容器的外壁和所述容器侧电极的内壁在所述颈部处相对于所述容器的垂直方向处于水平横截面，变得比所述容器的外壁和所述容器的内壁之间的平均距离 所述容器侧电极在所述主体部分处于相对于所述容器的垂直方向的水平横截面。

公开(公告)号：US20100136337A1

公开(公告)日：2010-06-03

申请号：US12529773

申请日：2008-03-05

申请人： Hideyasu Ando ,  Yasunori Kasuga

发明人： Hideyasu Ando ,  Yasunori Kasuga

IPC分类号： H01C7/112

CPC分类号： H01C7/112 ,  C04B35/453 ,  H01B1/08 ,  Y10T428/2982

摘要： A ZnO varistor powder can be obtained with high operating voltage and excellent current-voltage nonlinear resistance characteristics. In the ZnO varistor powder, the main ingredient is zinc oxide (ZnO); and at least bismuth (Bi), cobalt (Co), manganese (Mn), antimony (Sb), nickel (Ni), and aluminum (Al), calculated as Bi2O3, CO2O3, MnO, Sb2O3, NiO, and Al3+, are contained as accessory ingredients in amounts of 0.3 to 1.5 mol % Bi2O3, 0.3 to 2.0 mol % Co2O3, 0.3 to 3 mol % MnO, 0.5 to 4 mol % Sb2O3, 0.5 to 4 mol % NiO, and 0.0005 to 0.02 mol % Al3+. ZnO content is greater than or equal to 90 mol %; the bulk density is greater than or equal to 2.5 g/cc; the powder is a spherical powder in which the 50% particle diameter in the particle size distribution is 20 μm to 120 μm.

摘要翻译： 可以获得具有高工作电压和优异的电流 - 电压非线性电阻特性的ZnO变阻器粉末。 在ZnO变阻器粉末中，主要成分是氧化锌（ZnO）; 并且以Bi 2 O 3，CO 2 O 3，MnO，Sb 2 O 3，NiO和Al 3+计算的至少铋（Bi），钴（Co），锰（Mn），锑（Sb），镍（Ni）和铝（Al） 含有0.3〜1.5摩尔％Bi 2 O 3，0.3〜2.0摩尔％Co 2 O 3，0.3〜3摩尔％MnO，0.5〜4摩尔％Sb 2 O 3，0.5〜4摩尔％NiO和0.0005〜0.02摩尔％的Al 3+作为辅助成分。 ZnO含量大于或等于90mol％; 体积密度大于或等于2.5g / cc; 粉末是粒径分布中50％粒径为20μm〜120μm的球状粉末。

公开(公告)号：US20060051539A1

公开(公告)日：2006-03-09

申请号：US10514728

申请日：2003-05-26

申请人： Teruyuki Yamasaki ,  Akira Shirakura ,  Hideyasu Ando

发明人： Teruyuki Yamasaki ,  Akira Shirakura ,  Hideyasu Ando

IPC分类号： B32B27/08

CPC分类号： C23C16/26 ,  B65D1/0215 ,  B65D23/0814 ,  C23C16/045 ,  C23C16/505 ,  Y10T428/1352

摘要： The present invention provides a plastic container having a inner wall surface coated with DLC film which has same level of oxygen barrier property as prior art and can prevent a coloring of the DLC film formed on a neck portion of the container, manufacturing apparatus therefor and manufacturign method thereof. The apparatus for manufacturing the DLC film coated plastic container, comprising: a container side electrode which forms one portion of a pressure-reducing chamber which houses a container formed from plastic, a facing electrode which faces said container side electrode and is arranged inside said container or above said opening, wherein said container side electrode and said facing electrode are made to face each other via an insulating body which forms a portion of said pressure-reducing chamber, source gas supply means which includes a supply gas inlet pipe, exhaust means, and high frequency supply means; wherein said container side electrode is formed so that the average inner hole diameter of the inner wall surrounding said neck portion when the container is housed becomes smaller than the average inner hole diameter of the inner wall surrounding said body portion, and the average distance between the outer wall of said container and the inner wall of said container side electrode in a horizontal cross section with respect to the vertical direction of said container at said neck portion becomes longer than the average distance between the outer wall of said container and the inner wall of said container side electrode in a horizontal cross section with respect to the vertical direction of said container at said body portion.

摘要翻译： 本发明提供了一种塑料容器，其具有涂覆有DLC膜的内壁表面，其具有与现有技术相同的氧阻隔性能，并且可以防止形成在容器的颈部上的DLC膜的着色，其制造装置和制造 方法。 用于制造DLC薄膜包衣的塑料容器的装置包括：容器侧电极，其形成容纳由塑料形成的容器的减压室的一部分，面对所述容器侧电极并设置在所述容器内的面对电极 或上述开口，其中所述容器侧电极和所述面对电极通过形成所述减压室的一部分的绝缘体彼此面对，源气体供应装置包括供气入口管，排气装置， 和高频供电装置; 其特征在于，所述容器侧电极被形成为使得当容纳容器时围绕所述颈部的内壁的平均内孔直径小于围绕所述主体部分的内壁的平均内孔直径， 所述容器的外壁和所述容器侧电极的内壁在所述颈部处相对于所述容器的垂直方向处于水平横截面，变得比所述容器的外壁和所述容器的内壁之间的平均距离 所述容器侧电极在所述主体部分处于相对于所述容器的垂直方向的水平横截面。

公开(公告)号：US08535575B2

公开(公告)日：2013-09-17

申请号：US12630138

申请日：2009-12-03

申请人： Yasunori Kasuga ,  Hideyasu Ando

发明人： Yasunori Kasuga ,  Hideyasu Ando

IPC分类号： H01B1/02

CPC分类号： H01C7/112 ,  C04B35/453 ,  C04B35/6261 ,  C04B35/62695 ,  C04B2235/3218 ,  C04B2235/3262 ,  C04B2235/3275 ,  C04B2235/3277 ,  C04B2235/3284 ,  C04B2235/3294 ,  C04B2235/3298 ,  C04B2235/5436 ,  C04B2235/5445 ,  C04B2235/5481 ,  C04B2235/656 ,  C04B2235/6562 ,  C04B2235/6565 ,  C04B2235/6567 ,  C04B2235/784 ,  C04B2235/785 ,  C04B2235/786 ,  C04B2235/80

摘要： A current-voltage non-linear resistor (10) comprises a sintered body (20) of a mixture whose chief constituent is zinc oxide and including as auxiliary constituents at least bismuth (Bi), antimony (Sb), manganese (Mn), cobalt (Co) and nickel (Ni). Also, the average grain size of the mixture is no more than 0.4 μm; and the average grain size of the zinc oxide grains in the sintered body (20) is no more than 7.5 μm and the standard deviation based on the grain size distribution of zinc oxide grains in the sintered body (20) is no more than 15% of the average grain size of the zinc oxide grains.

摘要翻译： 电流电压非线性电阻器（10）包括主要成分为氧化锌并且至少包括铋（Bi），锑（Sb），锰（Mn），钴 （Co）和镍（Ni）。 此外，混合物的平均粒径不超过0.4μm; 烧结体（20）中的氧化锌粒子的平均粒径为7.5μm以下，烧结体（20）中氧化锌粒子的粒度分布的标准偏差为15％以下， 的氧化锌颗粒的平均晶粒尺寸。

公开(公告)号：US5479028A

公开(公告)日：1995-12-26

申请号：US310761

申请日：1994-09-27

申请人： Takeshi Tomioka ,  Hideyasu Ando ,  Naoya Okamoto ,  Shinji Yamaura

发明人： Takeshi Tomioka ,  Hideyasu Ando ,  Naoya Okamoto ,  Shinji Yamaura

IPC分类号： H01L29/73 ,  H01L21/203 ,  H01L21/205 ,  H01L21/331 ,  H01L21/338 ,  H01L27/06 ,  H01L29/205 ,  H01L29/207 ,  H01L29/737 ,  H01L29/778 ,  H01L29/812 ,  H01L33/00

CPC分类号： H01L29/207 ,  H01L21/02395 ,  H01L21/02463 ,  H01L21/02505 ,  H01L21/02543 ,  H01L21/02546 ,  H01L21/02573 ,  H01L21/02579 ,  H01L21/0262 ,  H01L21/02631 ,  H01L27/0605 ,  H01L29/66318

摘要： The invention relates to a method for manufacturing a III-V system compound semiconductor device, provides such a new C dopant as alkyl halide (CH.sub.2 I.sub.2 for example) containing carbon (C), iodine (I), and hydrogen (H) for giving a highly p-type conductivity to a GaAs crystal layer, an InGaAs crystal layer or the like as an object of it, and includes a process of forming a p-type III-V system compound semiconductor layer as using a compound containing carbon (C) as a dopant material for giving a p-type conductivity and further containing iodine (I) and hydrogen (H) as impurity.

摘要翻译： 本发明涉及一种制备III-V系化合物半导体器件的方法，提供了含有碳（C），碘（I）和氢（H）的烷基卤化物（例如，CH 2 I 2）等新的C掺杂剂， 作为其目的的GaAs晶体层，InGaAs晶体层等的高p型导电性，包括使用含有碳的化合物（C）形成p型III-V系化合物半导体层的工序， 作为用于赋予p型导电性且进一步含有碘（I）和氢（H））作为杂质的掺杂剂材料。

公开(公告)号：US20130189448A1

公开(公告)日：2013-07-25

申请号：US13557737

申请日：2012-07-25

申请人： Teruyuki YAMASAKI ,  Akira SHIRAKURA ,  Hideyasu ANDO

发明人： Teruyuki YAMASAKI ,  Akira SHIRAKURA ,  Hideyasu ANDO

IPC分类号： C23C16/26

CPC分类号： C23C16/26 ,  B65D1/0215 ,  B65D23/0814 ,  C23C16/045 ,  C23C16/505 ,  Y10T428/1352

摘要： The present invention provides method of DLC film coating a plastic container by DLC film coating the container in an apparatus, where the apparatus comprises a container side electrode which forms one portion of a pressure-reducing chamber and a facing electrode, where the container side electrode is formed so that the average inner hole diameter (R2) of the inner wall surrounding a neck portion is smaller than the average inner hole diameter (R1) of the inner wall surrounding the body portion, and the average distance (d2) between the outer wall of the container and the inner wall of the container side electrode in a horizontal cross section with respect to the vertical direction of the container at the neck portion becomes longer than the average distance (d1) between the outer wall of the container and the inner wall of the container side electrode.

摘要翻译： 本发明提供了通过在装置中涂覆容器的DLC膜将塑料容器涂覆在塑料容器上的方法，其中该装置包括形成减压室和面对电极的一部分的容器侧电极，其中容器侧电极 形成为使得围绕颈部的内壁的平均内孔直径（R2）小于围绕主体部的内壁的平均内孔径（R1），外周面的平均距离（d2） 容器侧壁和容器侧电极的内壁相对于容器在颈部的垂直方向的水平截面变得比容器的外壁和内侧的容器侧壁的平均距离（d1）长 容器侧电极的壁。

公开(公告)号：US08216544B2

公开(公告)日：2012-07-10

申请号：US12529773

申请日：2008-03-05

申请人： Hideyasu Ando ,  Yasunori Kasuga

发明人： Hideyasu Ando ,  Yasunori Kasuga

IPC分类号： B32B5/16 ,  C01G9/02 ,  H01C8/00

CPC分类号： H01C7/112 ,  C04B35/453 ,  H01B1/08 ,  Y10T428/2982

摘要： A ZnO varistor powder can be obtained with high operating voltage and excellent current-voltage nonlinear resistance characteristics. In the ZnO varistor powder, the main ingredient is zinc oxide (ZnO); and at least bismuth (Bi), cobalt (Co), manganese (Mn), antimony (Sb), nickel (Ni), and aluminum (Al), calculated as Bi2O3, CO2O3, MnO, Sb2O3, NiO, and Al3+, are contained as accessory ingredients in amounts of 0.3 to 1.5 mol % Bi2O3, 0.3 to 2.0 mol % Co2O3, 0.3 to 3 mol % MnO, 0.5 to 4 mol % Sb2O3, 0.5 to 4 mol % NiO, and 0.0005 to 0.02 mol % Al3+. ZnO content is greater than or equal to 90 mol %; the bulk density is greater than or equal to 2.5 g/cc; the powder is a spherical powder in which the 50% particle diameter in the particle size distribution is 20 μm to 120 μm.

摘要翻译： 可以获得具有高工作电压和优异的电流 - 电压非线性电阻特性的ZnO变阻器粉末。 在ZnO变阻器粉末中，主要成分是氧化锌（ZnO）; 并且以Bi 2 O 3，CO 2 O 3，MnO，Sb 2 O 3，NiO和Al 3+计算的至少铋（Bi），钴（Co），锰（Mn），锑（Sb），镍（Ni）和铝（Al） 含有0.3〜1.5摩尔％Bi 2 O 3，0.3〜2.0摩尔％Co 2 O 3，0.3〜3摩尔％MnO，0.5〜4摩尔％Sb 2 O 3，0.5〜4摩尔％NiO和0.0005〜0.02摩尔％的Al 3+作为辅助成分。 ZnO含量大于或等于90mol％; 体积密度大于或等于2.5g / cc; 粉末是粒径分布中50％粒径为20μm〜120μm的球状粉末。

公开(公告)号：US07754302B2

公开(公告)日：2010-07-13

申请号：US10514728

申请日：2003-05-26

申请人： Teruyuki Yamasaki ,  Akira Shirakura ,  Hideyasu Ando

发明人： Teruyuki Yamasaki ,  Akira Shirakura ,  Hideyasu Ando

IPC分类号： B32B27/08 ,  C23C16/00

CPC分类号： C23C16/26 ,  B65D1/0215 ,  B65D23/0814 ,  C23C16/045 ,  C23C16/505 ,  Y10T428/1352

摘要： The present invention provides a plastic container or bottle having an inner wall surface coated with a DLC film which has the same level of oxygen barrier property as prior art DLC coated containers while at the same time preventing the coloration of the neck portion found in the containers of the prior art. The DLC film formed on the neck portion of the inventive bottle has a lower graphite mixing proportion than the DLC film formed on body portion, and the oxygen permeability of the container is less than or equal to 0.0050 ml/container (500 ml PET container)/day. The apparatus and the method of producing such a bottle are also described.

摘要翻译： 本发明提供了一种具有涂覆有DLC膜的内壁表面的塑料容器或瓶，其具有与现有技术的DLC涂覆的容器相同的阻氧性能，同时防止在容器中发现的颈部部分着色 的现有技术。 形成在本发明瓶颈部的DLC膜的石墨混合比例低于在本体部分上形成的DLC膜，并且容器的透氧性小于或等于0.0050ml /容器（500ml PET容器） /天。 还描述了制造这种瓶子的装置和方法。

公开(公告)号：US07095310B2

公开(公告)日：2006-08-22

申请号：US11114012

申请日：2005-04-26

申请人： Toshiya Imai ,  Hideyasu Ando ,  Susumu Nishiwaki

发明人： Toshiya Imai ,  Hideyasu Ando ,  Susumu Nishiwaki

IPC分类号： H01C7/10

CPC分类号： H01C7/102 ,  H01C7/12

摘要： A non-linear resistor comprises a sintered body having zinc oxide as a main component, a side-surface high resistance layer arranged at a side-surface of the sintered body, and an electrode arranged at upper and lower surfaces of the sintered body. The side-surface high resistance layer is formed of a specifically selected material. The end-to-end distance between an end portion of the electrode and a nonlinear resistor end portion including the side-surface high resistance layer falls within a range of 0 mm to the thickness of the side-surface high resistance layer+0.01 mm.

摘要翻译： 非线性电阻器包括以氧化锌为主要成分的烧结体，设置在烧结体的侧面的侧面高电阻层以及布置在烧结体的上表面和下表面的电极。 侧面高电阻层由特定选择的材料形成。 电极的端部与包括侧面高电阻层的非线性电阻器端部之间的端对端距离在与侧面高电阻层的厚度为0.01mm的范围内。

公开(公告)号：US20050195065A1

公开(公告)日：2005-09-08

申请号：US11114012

申请日：2005-04-26

申请人： Toshiya Imai ,  Hideyasu Ando ,  Susumu Nishiwaki

发明人： Toshiya Imai ,  Hideyasu Ando ,  Susumu Nishiwaki

IPC分类号： H01C7/10 ,  H01C7/102 ,  H01C7/12

CPC分类号： H01C7/102 ,  H01C7/12

摘要： A non-linear resistor comprises a sintered body having zinc oxide as a main component, a side-surface high resistance layer arranged at a side-surface of the sintered body, and an electrode arranged at upper and lower surfaces of the sintered body. The side-surface high resistance layer is formed of a specifically selected material. The end-to-end distance between an end portion of the electrode and a nonlinear resistor end portion including the side-surface high resistance layer falls within a range of 0 mm to the thickness of the side-surface high resistance layer+0.01 mm.

摘要翻译： 非线性电阻器包括以氧化锌为主要成分的烧结体，设置在烧结体的侧面的侧面高电阻层以及布置在烧结体的上表面和下表面的电极。 侧面高电阻层由特定选择的材料形成。 电极的端部与包括侧面高电阻层的非线性电阻器端部之间的端对端距离在与侧面高电阻层的厚度为0.01mm的范围内。