Composite of organic compound and copper nanoparticles, composite of organic compound and copper(I) oxide nanoparticles, and methods for producing the composites
    2.
    发明授权
    Composite of organic compound and copper nanoparticles, composite of organic compound and copper(I) oxide nanoparticles, and methods for producing the composites 有权
    有机化合物和铜纳米颗粒的复合物,有机化合物和氧化铜(I)纳米粒子的复合材料,以及复合材料的制备方法

    公开(公告)号:US08530559B2

    公开(公告)日:2013-09-10

    申请号:US13634344

    申请日:2011-02-28

    IPC分类号: C08K3/10

    摘要: Provided is a composite including copper nanoparticles or copper(I) oxide nanoparticles and a thioether-containing organic compound represented by X(OCH2CHR1)nOCH2CH(OH)CH2SZ [X represents an alkyl group; R1 represents a hydrogen atom or a methyl group; n represents an integer of 2 to 100; R1 is independent between repeating units and may be the same or different; and Z represents an alkyl group, an allyl group, an aryl group, an arylalkyl group, —R2—OH, —R2—NHR3, or —R2—(COR4)m (where R2 represents a saturated hydrocarbon group; R3 represents a hydrogen atom, an acyl group, an alkoxycarbonyl group, or a benzyloxycarbonyl group; R4 represents a hydroxy group, an alkyl group, or an alkoxy group; and m represents 1 to 3)]. Provided is a method for producing a composite of an organic compound and copper nanoparticles or a composite of an organic compound and copper(I) oxide nanoparticles, the method including reducing a copper compound in the presence of a thioether-containing organic compound represented by the general formula (1) above.

    摘要翻译: 提供了包含铜纳米颗粒或氧化铜(I)纳米颗粒和由X(OCH 2 CHR 1)n OCH 2 CH(OH)CH 2 SZ表示的含硫醚的有机化合物[X表示烷基; R1表示氢原子或甲基; n表示2〜100的整数, R1在重复单元之间是独立的,可以相同或不同; Z表示烷基,烯丙基,芳基,芳烷基,-R 2 -OH,-R 2 -NHR 3或-R 2 - (COR 4)m(其中,R 2表示饱和烃基; R 3表示氢 原子,酰基,烷氧基羰基或苄氧基羰基; R 4表示羟基,烷基或烷氧基,m表示1〜3)]。 本发明提供一种有机化合物和铜纳米粒子的复合体的制造方法或有机化合物与氧化铜(I)纳米粒子的复合体的制造方法,其特征在于,在含有硫化物的有机化合物 上述通式(1)。

    Organic/inorganic composite coating film, structural color film using the same, and preparation methods thereof
    3.
    发明授权
    Organic/inorganic composite coating film, structural color film using the same, and preparation methods thereof 有权
    有机/无机复合涂膜,使用其的结构色膜及其制备方法

    公开(公告)号:US08486494B2

    公开(公告)日:2013-07-16

    申请号:US12530903

    申请日:2008-03-06

    IPC分类号: B32B3/26 B05D3/10

    摘要: An organic/inorganic composite coating film comprising an inorganic material as a matrix and an organic material combined therewith. The coating film has a regular hollow structure therein, and the coating film surface has a rugged pattern with semispherical protrusions. Also provided is a large-area structural color film obtained by burning the composite coating film. The organic/inorganic composite coating film is obtained by applying an aqueous coating composition comprising a metal alkoxide, an aqueous dispersion of monodisperse polymer particles, and an acid catalyst to a substrate and curing the coating composition. Burning the organic/inorganic composite coating film gives the structural color film.

    摘要翻译: 一种有机/无机复合涂膜,其包含作为基质的无机材料和与其结合的有机材料。 涂膜在其中具有规则的中空结构,并且涂膜表面具有具有半球形突起的凹凸图案。 还提供了通过燃烧复合涂膜获得的大面积结构彩色膜。 有机/无机复合涂膜通过将包含金属醇盐,单分散聚合物颗粒的水分散体和酸催化剂的水性涂料组合物涂覆到基材上并固化涂料组合物而获得。 燃烧有机/无机复合涂膜得到结构色膜。

    INFRARED ABSORBING THIN FILM CONTAINING RUTILE-TYPE TITANIUM OXIDE CRYSTAL AND METHOD FOR PRODUCING THE SAME
    4.
    发明申请
    INFRARED ABSORBING THIN FILM CONTAINING RUTILE-TYPE TITANIUM OXIDE CRYSTAL AND METHOD FOR PRODUCING THE SAME 失效
    含有类型氧化钛晶体的红外吸收薄膜及其制造方法

    公开(公告)号:US20130040129A1

    公开(公告)日:2013-02-14

    申请号:US13642186

    申请日:2011-03-31

    摘要: There are provided an infrared absorbing thin film that efficiently absorbs infrared rays and has good versatility by controlling the absorption intensity of titanium oxide in an infrared region and a method for producing the infrared absorbing thin film. The infrared absorbing thin film containing a rutile-type titanium oxide crystal can be produced through a step of dispersing or dissolving a complex of an amino group-containing basic polymer and a transition metal ion in an aqueous medium; a step of obtaining a composite having a polymer/titania layered structure in which the complex of the amino group-containing basic polymer and the transition metal ion is sandwiched between layers of titania, by mixing the aqueous dispersion with a water-soluble titanium compound in the aqueous medium; a step of calcining the composite in an air atmosphere at a temperature of 650° C. or higher and pulverizing the obtained crystal into a powder; and a step of mixing the obtained powder with a sol of a metal alkoxide to prepare a fluid liquid composition, coating a surface of a substrate with the obtained fluid liquid composition, and aging the coating film.

    摘要翻译: 提供一种通过控制红外线区域中的氧化钛的吸收强度和红外线吸收薄膜的制造方法,能够有效地吸收红外线并具有良好的通用性的红外线吸收薄膜。 含有金红石型氧化钛晶体的红外吸收薄膜可以通过将含氨基的碱性聚合物和过渡金属离子的络合物分散或溶解在水性介质中的步骤来制造; 通过将水性分散体与水溶性钛化合物混合,得到具有聚氨酯层叠结构的复合体的步骤,其中含氨基的碱性聚合物和过渡金属离子的络合物夹在二氧化钛层之间 水介质; 将复合体在650℃以上的温度下在空气气氛中煅烧的步骤,将得到的结晶粉碎成粉末; 以及将得到的粉末与金属醇盐的溶胶混合以制备流体液体组合物的步骤,用所得流体液体组合物涂布基材的表面,并使涂膜老化。

    Process for producing nanostructure composite-covered structure, nanostructure composite-covered structure, and reactor using nanostructure composite-covered structure
    5.
    发明授权
    Process for producing nanostructure composite-covered structure, nanostructure composite-covered structure, and reactor using nanostructure composite-covered structure 失效
    使用纳米结构复合覆盖结构生产纳米结构复合覆盖结构,纳米结构复合覆盖结构和反应器的方法

    公开(公告)号:US08257662B2

    公开(公告)日:2012-09-04

    申请号:US12675959

    申请日:2008-09-01

    IPC分类号: B01J8/02 B01J35/02 G11B5/64

    摘要: The present invention provides a structure in which the surface of a solid substrate of any shape is covered with metal oxide, in particular, a nanostructure composite in which polyethyleneimine, which is an organic substance, and metal oxide, which is an inorganic substance, are combined in nano-meter scale, spreads at the entire surface of a substrate, and the nanostructure composite forms a nano-boundary of complex shapes so as to thoroughly cover the entire surface of the substrate; a structure in which metal ions, metal nano-particles, organic pigment molecules are contained in the nanostructure composite; a process for producing these structures which can produce these structures with ease and efficiently; and an application method for the structures as an immobilized catalyst type reactor.

    摘要翻译: 本发明提供一种结构,其中任何形状的固体基材的表面被金属氧化物覆盖,特别是其中作为有机物质的聚乙烯亚胺和作为无机物质的金属氧化物的纳米结构复合物是 以纳米尺度结合,在基底的整个表面上扩散,纳米结构复合物形成复杂形状的纳米边界,以彻底覆盖基底的整个表面; 在纳米结构复合体中含有金属离子,金属纳米粒子,有机颜料分子的结构; 制造能够容易且高效地生产这些结构的这些结构的方法; 以及作为固定化催化剂型反应器的结构的涂布方法。

    THE 1-BUTYL-2-HYDROXYARALKYL PIPERAZINE DERIVATIVES AND THE USES AS ANTI-DEPRESSION MEDICINE THEREOF
    6.
    发明申请
    THE 1-BUTYL-2-HYDROXYARALKYL PIPERAZINE DERIVATIVES AND THE USES AS ANTI-DEPRESSION MEDICINE THEREOF 有权
    1-丁基-2-羟基甲基哌嗪衍生物及其作为抗抑郁药物的用途

    公开(公告)号:US20110183996A1

    公开(公告)日:2011-07-28

    申请号:US13122691

    申请日:2009-09-29

    摘要: The invention discloses 1-butyl-2-hydroxyl aralkyl piperazine derivatives and their use as antidepressants. The derivatives of the present invention have triple inhibition effect on the reuptake of 5-HT, NA and DA, and can be administrated to the patients in need thereof in form of composition by route of oral administration, injection and the like. Compared with clinically currently used dual targets antidepressants (such as venlafaxine), said derivatives may have stronger antidepression effect, broader indications, faster onset and lower neurotoxicity and side reaction; and said derivatives have stronger antidepression activity, lower toxicity, higher bioavailability, longer half life and better druggablity, compared with aryl alkanol piperazine derivatives and optical isomers thereof disclosed in prior art. The 1-butyl-2-hydroxyl aralkyl piperazine derivative is the free alkali or its salt of a compound of formula below:

    摘要翻译: 本发明公开了1-丁基-2-羟基芳烷基哌嗪衍生物及其作为抗抑郁药的用途。 本发明的衍生物对5-HT,NA和DA的再摄取具有三重抑制作用,并且可以通过口服给药,注射等途径以组合物的形式施用于有需要的患者。 与临床目前使用的双抗抑郁药(如文拉法辛)相比,所述衍生物可能具有更强的抗抑郁作用,适应症广,发病更快,神经毒性和副反应降低; 与现有技术中公开的芳基链烷醇哌嗪衍生物及其旋光异构体相比,所述衍生物具有更强的抗抑郁活性,更低的毒性,更高的生物利用度,更长的半衰期和更好的药物可用性。 1-丁基-2-羟基芳烷基哌嗪衍生物是下式化合物的游离碱或其盐:

    STRUCTUAL OBJECT COATED WITH SUPERHYDROPHBIC NANOSTRUCTURE COMPOSITE AND PROCESS FOR PRODUCING THE SAME
    7.
    发明申请
    STRUCTUAL OBJECT COATED WITH SUPERHYDROPHBIC NANOSTRUCTURE COMPOSITE AND PROCESS FOR PRODUCING THE SAME 有权
    用超级纳米结构复合材料涂覆的结构物体及其制造方法

    公开(公告)号:US20110160374A1

    公开(公告)日:2011-06-30

    申请号:US12737128

    申请日:2009-05-25

    摘要: The present invention relates to a structural object coated with a superhydrophobic nanostructure composite, the structural object being obtained by densely coating a surface of a solid substrate having a desired shape with a nanostructure obtained by combining a polymer having a polyethyleneimine skeleton with silica on the nanometer order, and bonding a hydrophobic group to the surface of the nanostructure, and a process for producing the structural object. The present invention also relates to a structural object coated with a superhydrophobic nanostructure composite, the structural object being obtained by removing the polymer having the polyethyleneimine skeleton from the nanostructure and bonding a hydrophobic group to the surface of the residual nanostructure containing silica as a main constituent component, and a process for producing the structural object. Furthermore, the present invention provides a method of using the structural object as a container for transferring an aqueous solution.

    摘要翻译: 本发明涉及涂覆有超疏水纳米结构复合材料的结构物体,该结构物体通过将具有聚乙烯亚胺骨架的聚合物与二氧化硅在纳米上组合而获得的具有所需形状的固体基底的表面密集地涂覆而获得 将疏水性基团键合到纳米结构体的表面,以及制造该结构体的工序。 本发明还涉及一种涂覆有超疏水性纳米结构复合材料的结构物体,该结构物体是通过从纳米结构中除去具有聚乙烯亚胺骨架的聚合物而获得的,并将疏水基团结合到含有二氧化硅作为主要成分的残余纳米结构物的表面上 组件,以及用于生产结构对象的过程。 此外,本发明提供一种使用结构物作为水溶液转移容器的方法。

    Method of producing polymer using iron complex as catalyst
    8.
    发明授权
    Method of producing polymer using iron complex as catalyst 失效
    使用铁络合物作为催化剂生产聚合物的方法

    公开(公告)号:US07674866B2

    公开(公告)日:2010-03-09

    申请号:US12066706

    申请日:2006-09-12

    IPC分类号: C07F4/06 C08F4/80

    摘要: The object of the present invention is to provide a method of producing a polymer wherein radical-polymerizable monomers can be polymerized in a quantitative manner in a relatively short time, and a polymer or a block copolymer having at its termini a functional group that can be chemically converted while the polymer or the block copolymer has a high molecular weight can be produced. Furthermore, the object of the present invention is to provide a method of producing a polymer wherein the polymer is re-precipitated in a general solvent by an easy method, and the used iron complexes are recovered in the solvent, thereby recycling the iron complexes.

    摘要翻译: 本发明的目的是提供一种生产聚合物的方法,其中可自由基聚合的单体可以在相当短的时间内以定量方式聚合,并且聚合物或嵌段共聚物在其末端具有官能团,其可以是 可以在聚合物或嵌段共聚物具有高分子量的情况下进行化学转化。 此外,本发明的目的是提供一种聚合物的制造方法,其中通过简单的方法将聚合物在一般溶剂中再沉淀,并将所用的铁络合物回收到溶剂中,从而再循环铁络合物。

    Composite nanofiber, composite nanofiber association, complex structure, and production method thereof
    9.
    发明申请
    Composite nanofiber, composite nanofiber association, complex structure, and production method thereof 失效
    复合纳米纤维,复合纳米纤维关联,复合结构及其制备方法

    公开(公告)号:US20070197708A1

    公开(公告)日:2007-08-23

    申请号:US11569300

    申请日:2005-05-27

    IPC分类号: C08K3/08

    摘要: A silica nanofiber is derived from a crystalline polymer filament of a polymer including straight chain polyethyleneimine backbones, which is capable of forming a water-insoluble crystal in the presence of water molecules at room temperature, and the crystalline polymer filament in the silica concentrates metal ions, thereby realizing a composite nanofiber including metals or metal ions in the silica. Furthermore, the composite nanofiber of the present invention can be easily produced by fixing a polymer structure in the silica as the scaffold for metal ions and concentrating metal ions at the scaffold or reducing the metal ions. Furthermore, a metal-containing silica nanofiber can be easily obtained by removing a polymer component from the composite nanofiber, the composite nanofiber association, and the complex nanofiber structure. These nanofibers can be assembled and integrated, and the assembled or integrated association or structure can realize various shapes.

    摘要翻译: 二氧化硅纳米纤维来源于包含直链聚乙烯亚胺骨架的聚合物的结晶聚合物长丝,其能够在室温下在水分子存在下形成水不溶性晶体,二氧化硅中的结晶聚合物长丝浓缩金属离子 从而实现在二氧化硅中包含金属或金属离子的复合纳米纤维。 此外,本发明的复合纳米纤维可以通过将二氧化硅中的聚合物结构固定在金属离子的支架上并将金属离子浓缩在支架上或还原金属离子而容易地制备。 此外,通过从复合纳米纤维,复合纳米纤维结合体和复合纳米纤维结构中除去聚合物组分,可以容易地获得含金属的二氧化硅纳米纤维。 这些纳米纤维可以组装和集成,并且组装或整合的关联或结构可以实现各种形状。

    Comb-shaped epoxy resin and method for preparing comb-shaped epoxy resin
    10.
    发明申请
    Comb-shaped epoxy resin and method for preparing comb-shaped epoxy resin 失效
    梳状环氧树脂及梳状环氧树脂的制备方法

    公开(公告)号:US20070142611A1

    公开(公告)日:2007-06-21

    申请号:US10593244

    申请日:2005-03-23

    IPC分类号: C08G59/14

    摘要: The present invention provides a comb-shaped epoxy resin represented by the following formula (1): in the formula (1), X1 and X2 represent a divalent group having a residue selected from xanthene residue, biphenylene residue, hydrogenated bisphenol residue, alkylene residue and polyoxyalkylene residue, each may having a methyl group or a ethyl group as a substituent, and at least one of them is an aromatic residue, Y represents a polymer chain such as linear polymer chain, a number average polymerization degree being 5 to 2000, and n (number average polymerization degree) represents an integer within a range of 3 to 200, and to a method for preparing the comb-shaped epoxy resin.

    摘要翻译: 本发明提供由下式(1)表示的梳形环氧树脂:在式(1)中,X 1和X 2表示具有 选自呫吨残基,联苯残基,氢化双酚残基,亚烷基残基和聚氧化烯残基的残基各自可以具有甲基或乙基作为取代基,并且其中至少一个是芳族残基,Y表示聚合物链 例如线性聚合物链,数均聚合度为5〜2000,n(数均聚合度)为3〜200的整数,以及制备梳形环氧树脂的方法。