公开(公告)号：US08444946B2

公开(公告)日：2013-05-21

申请号：US12373893

申请日：2007-07-13

申请人： Francois Martin ,  Jocelyne Ferret ,  Cedric Lebre ,  Sabine Petit ,  Olivier Grauby ,  Jean-Pierre Bonino ,  Didier Arseguel ,  Alain Decarreau ,  Eric Ferrage

发明人： Francois Martin ,  Jocelyne Ferret ,  Cedric Lebre ,  Sabine Petit ,  Olivier Grauby ,  Jean-Pierre Bonino ,  Didier Arseguel ,  Alain Decarreau ,  Eric Ferrage

IPC分类号： C01B33/00 ,  C01B33/24 ,  C01B33/26

CPC分类号： C09C1/28 ,  C01B33/20 ,  C01B33/22 ,  C01B33/28 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2004/03 ,  C01P2004/04

摘要： The invention relates to a method for preparing a composition, that is a talcose composition, comprising synthetic mineral particles which contain silicon, germanium and metal, have a crystalline and lamellar structure, and are of formula (SixGe1−x)4M3O10(OH)2, wherein M is at least one divalent metal and is of formula Mgy(1)COy(2)Zny(3)Cuy(4)Mny(5)Fey(6)Niy(7)Cry(8), and x is a real number of the interval [0; 1]. According to said method, a gel containing silicon, germanium and metal, of formula —(SixGe1−x)4M3O11, n′H2O—, in the liquid state, is subjected to a hydrothermal treatment over a defined period of time and at a temperature of between 300° C. and 600° C., said time and temperature being selected according to the desired particle size and structural stability for the mineral particles containing silicon, germanium and metal, to be prepared.

摘要翻译： 本发明涉及一种制备组合物的方法，即一种滑石组合物，其包含含有硅，锗和金属的合成矿物颗粒，具有结晶和层状结构，并具有式（SixGe1-x）4M3O10（OH）2 其中M是至少一种二价金属，并且具有式Mgy（1）COy（2）Zny（3）Cuy（4）Mny（5）Fey（6）Niy（7）Cry（8），x是 实际间隔数[0; 1]。 根据所述方法，将液态的含有式 - （SixGe1-x）4M3O11，n'H2O-的硅，锗和金属的凝胶在规定的时间和温度下进行水热处理 在300℃和600℃之间，所述时间和温度根据所要制备的含有硅，锗和金属的矿物颗粒的粒度和结构稳定性来选择。

公开(公告)号：US07659008B2

公开(公告)日：2010-02-09

申请号：US10537827

申请日：2003-12-08

申请人： François Martin ,  Jean-Pierre Bonino ,  Patrice Bacchin ,  Stéphane Vaillant ,  Eric Ferrage ,  William Vautrin ,  Philippe Barthes

发明人： François Martin ,  Jean-Pierre Bonino ,  Patrice Bacchin ,  Stéphane Vaillant ,  Eric Ferrage ,  William Vautrin ,  Philippe Barthes

IPC分类号： B32B5/16 ,  B32B15/00 ,  B32B15/16 ,  C25D15/00

CPC分类号： C25D15/02 ,  Y10T428/12486 ,  Y10T428/12493 ,  Y10T428/12944 ,  Y10T428/31703

摘要： The invention relates to a lubricating metal coating and to a process for its preparation. The material constituting the coating in a composite material comprising a metal matrix within which talc particles are distributed as lamellae, the metal matrix being composed of a metal chosen from Fe, Co, Ni, Mn, Cr, Cu, W, Mo, Zn, Au, Ag, Pb or Sn or of an alloy of these metals or of a metal/semimetal alloy. The coating is obtained by a process consisting in carrying out an electrolytic deposition using a solution of precursors of the metal matrix of the coating which additionally comprises talc particles in suspension, which particles are modified at the surface by irreversible adsorption of a cellulose-derived compound by replacement of all or part of the hydroxyl groups.

摘要翻译： 本发明涉及一种润滑金属涂层及其制备方法。 复合材料中构成涂层的材料包括滑石颗粒作为薄片分布在其中的金属基体，金属基体由选自Fe，Co，Ni，Mn，Cr，Cu，W，Mo，Zn， Au，Ag，Pb或Sn或这些金属或金属/半金属合金的合金。 该涂层是通过一种方法获得的，该方法包括使用另外包含悬浮液中的滑石颗粒的涂层金属基质的前体溶液进行电解沉积，该颗粒在表面被不可逆吸附的纤维素衍生化合物 通过置换全部或部分羟基。

公开(公告)号：US20060162655A1

公开(公告)日：2006-07-27

申请号：US10537827

申请日：2003-12-08

申请人： Francois Martin ,  Jean-Pierre Bonino ,  Patrice Bacchin ,  Stephane Vaillant ,  Eric Ferrage ,  William Vautrin ,  Philippe Barthes

发明人： Francois Martin ,  Jean-Pierre Bonino ,  Patrice Bacchin ,  Stephane Vaillant ,  Eric Ferrage ,  William Vautrin ,  Philippe Barthes

IPC分类号： B05B5/00

CPC分类号： C25D15/02 ,  Y10T428/12486 ,  Y10T428/12493 ,  Y10T428/12944 ,  Y10T428/31703

摘要： The invention relates to a lubricating metal coating and to a process for its preparation. The material constituting the coating in a composite material comprising a metal matrix within which talc particles are distributed as lamellae, the metal matrix being composed of a metal chosen from Fe, Co, Ni, Mn, Cr, Cu, W, Mo, Zn, Au, Ag, Pb or Sn or of an alloy of these metals or of a metal/semimetal alloy. The coating is obtained by a process consisting in carrying out an electrolytic deposition using a solution of precursors of the metal matrix of the coating which additionally comprises talc particles in suspension, which particles are modified at the surface by irreversible adsorption of a cellulose-derived compound by replacement of all or part of the hydroxyl groups.

摘要翻译： 本发明涉及一种润滑金属涂层及其制备方法。 复合材料中构成涂层的材料包括滑石颗粒作为薄片分布在其中的金属基体，金属基体由选自Fe，Co，Ni，Mn，Cr，Cu，W，Mo，Zn， Au，Ag，Pb或Sn或这些金属或金属/半金属合金的合金。 该涂层是通过一种方法获得的，该方法包括使用另外包含悬浮液中的滑石颗粒的涂层金属基质的前体溶液进行电解沉积，该颗粒在表面被不可逆吸附的纤维素衍生化合物 通过置换全部或部分羟基。

公开(公告)号：US20090252963A1

公开(公告)日：2009-10-08

申请号：US12374196

申请日：2008-07-13

申请人： Francois Martin ,  Jocelyne Ferret ,  Cedric Lebre ,  Sabine Petit ,  Olivier Grauby ,  Jean-Pierre Bonino ,  Didier Arseguel ,  Alain Decarreau ,  Eric Ferrage

发明人： Francois Martin ,  Jocelyne Ferret ,  Cedric Lebre ,  Sabine Petit ,  Olivier Grauby ,  Jean-Pierre Bonino ,  Didier Arseguel ,  Alain Decarreau ,  Eric Ferrage

IPC分类号： C01B33/24 ,  B32B5/16

CPC分类号： C01B33/405 ,  B82Y30/00 ,  C01B33/22 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2004/62 ,  C01P2004/64 ,  C09C1/28 ,  Y10T428/2982

摘要： The invention relates to a method for preparing a synthetic talc composition. According to said method, a kerolite composition is subjected to an anhydrous thermal treatment carried out at a pressure lower than 5 bar, from over a few hours up to over a few days, at a treatment temperature higher than 300° C. The invention also relates to a synthetic talc composition prepared in this way, the synthetic talc particles of the composition being exclusively of chemical formula —(Si4)Mg3O10(OH)2— and identifiable, during X-ray diffraction, by the presence of a characteristic diffraction peak located at a distance of between 9.40-9.68 and corresponding to a plane (001). Said synthetic talc particles also have a thermally stable crystalline structure of stacked laminae, which is very similar to that of a natural talc and has a particle size smaller than approximately ten micrometers.

摘要翻译： 本发明涉及一种制备合成滑石组合物的方法。 根据所述方法，在高于300℃的处理温度下，在低于5巴的压力下进行无水热处理，从超过几个小时至多数天，进行无水热处理。本发明还 涉及以这种方式制备的合成滑石组合物，该组合物的合成滑石颗粒仅在化学式（Si 4）Mg 3 O 10（OH）2）中，并且在X射线衍射过程中可通过存在特征衍射峰 位于9.40-9.68之间的距离，对应于平面（001）。 所述合成滑石颗粒也具有堆叠薄片的热稳定结晶结构，其与天然滑石非常相似，并且具有小于约十微米的粒度。

公开(公告)号：US4722770A

公开(公告)日：1988-02-02

申请号：US888855

申请日：1986-07-24

申请人： Yves Blottiere ,  Jean-Pierre Bonino ,  Abel Rousset ,  Claude Rossignol ,  Isabelle Gossart

发明人： Yves Blottiere ,  Jean-Pierre Bonino ,  Abel Rousset ,  Claude Rossignol ,  Isabelle Gossart

IPC分类号： C23C14/24 ,  C23C2/34 ,  C23C16/00 ,  C23C28/00 ,  C25D1/02 ,  C25D1/08 ,  C25D17/16

CPC分类号： C25D1/02

摘要： A method for manufacturing continuous, closed and hollow bodies which comprises (a) using cores (25) which are soluble in a solvent, (b) depositing on each core a coating (3) with a suitable mechanical strength to be self-supporting and having open pores to pass a solvent, and (c) placing the cores so coated into a solvent for dissolving the cores; the method of the invention may be implemented in bulk parts, in an economical manner, and allows making hollow bodies, in particular hollow balls, each comprising a continuous skin devoid of any macroscopic perforation and of a kind and with a thickness which are easily adjusted in relation to the desired properties.

摘要翻译： 一种用于制造连续，封闭和中空体的方法，其包括（a）使用可溶于溶剂的芯（25），（b）以合适的机械强度在每个芯上沉积具有自支撑的涂层（3） 具有开孔以通过溶剂，和（c）将如此涂覆的芯放置在用于溶解芯的溶剂中; 本发明的方法可以以经济的方式以体积部分实现，并且允许制造中空体，特别是空心球，每个包括没有任何宏观穿孔的连续皮肤，并且具有容易调节的种类和厚度 关于期望的性质。

公开(公告)号：US20130130052A1

公开(公告)日：2013-05-23

申请号：US13634420

申请日：2011-03-11

申请人： Justine Menuey ,  Florence Ansart ,  Jean-Pierre Bonino ,  Justine Fenech ,  Celine Viazzi

发明人： Justine Menuey ,  Florence Ansart ,  Jean-Pierre Bonino ,  Justine Fenech ,  Celine Viazzi

IPC分类号： F01D5/28

CPC分类号： F01D5/288 ,  C23C18/1216 ,  C23C18/1245 ,  C23C18/1254 ,  Y10T428/12479 ,  Y10T428/12549

摘要： The invention relates to a method for manufacturing a thermal barrier protection covering a superalloy metal substrate and comprising at least one metal sublayer (13) and a ceramic layer (14) based on zirconia stabilized with yttrium having a column structure defining pores.The following steps are applied: impregnation of a portion of the pores of the ceramic layer (14) with a sol based on zirconia is achieved via a sol-gel route and this in order to form an anchoring sublayer (22), on said ceramic layer topped with said anchoring sub-layer (22), a continuous protective layer (20) based on oxide, is formed via a sol-gel route, and a heat treatment is carried out, whereby an outer protection layer is formed against the attack of the thermal barrier (11) by CMASes. Application to the protection of aeronautical protection parts.

摘要翻译： 本发明涉及一种用于制造覆盖超合金金属基底的热障保护的方法，该方法包括至少一个金属子层（13）和陶瓷层（14），所述金属子层（13）和陶瓷层（14）基于用具有限定孔的柱结构的用钇稳定的氧化锆。 应用以下步骤：通过溶胶 - 凝胶途径实现用基于氧化锆的溶胶浸渍陶瓷层（14）的一部分孔隙，以便在所述陶瓷上形成锚定子层（22） 通过溶胶 - 凝胶途径形成基于氧化物的连续保护层（20），并且进行热处理，从而形成抵抗攻击的外部保护层 的热障（11）。 适用于航空保护部件的保护。

公开(公告)号：US08466095B2

公开(公告)日：2013-06-18

申请号：US12809672

申请日：2008-12-18

申请人： François Martin ,  Jean-Pierre Bonino ,  Pierre Micoud ,  Jocelyne Ferret ,  Cédric Lebre ,  Vincent Baylac

发明人： François Martin ,  Jean-Pierre Bonino ,  Pierre Micoud ,  Jocelyne Ferret ,  Cédric Lebre ,  Vincent Baylac

IPC分类号： C10M103/04 ,  C10M103/06

CPC分类号： C25D15/00 ,  B82Y30/00 ,  C23C30/00 ,  C25D15/02

摘要： The invention relates to a composite material including a metal matrix in which synthetic lamellar phyllosilicated mineral particles are distributed, characterized in that the lamellar phyllosilicated mineral particles are particles also called synthetic phyllosilicated nanoparticles (6) that are mineral, silico/germano-metal, lamellar, synthetic and hydrophilic, and have an average size of between 10 nm and 1 nm. The invention also relates to a substrate that comprises a lubricating coating consisting of such a material, and to an electrolytic deposition preparation method.

摘要翻译： 本发明涉及一种复合材料，其包括其中分布有合成层状薄层矿物颗粒的金属基质，其特征在于，层状薄层状矿物颗粒是称为合成的页卷状纳米粒子（6）的颗粒，其为矿物，硅/锗 - 金属，层状 ，合成和亲水的，并且具有在10nm和1nm之间的平均尺寸。 本发明还涉及一种基材，其包含由这种材料组成的润滑涂层和电解沉积制备方法。

公开(公告)号：US08202501B2

公开(公告)日：2012-06-19

申请号：US12374196

申请日：2007-07-13

申请人： Francois Martin ,  Jocelyne Ferret ,  Cedric Lebre ,  Sabine Petit ,  Olivier Grauby ,  Jean-Pierre Bonino ,  Didier Arseguel ,  Alain Decarreau ,  Eric Ferrage

发明人： Francois Martin ,  Jocelyne Ferret ,  Cedric Lebre ,  Sabine Petit ,  Olivier Grauby ,  Jean-Pierre Bonino ,  Didier Arseguel ,  Alain Decarreau ,  Eric Ferrage

IPC分类号： C01B33/00

CPC分类号： C01B33/405 ,  B82Y30/00 ,  C01B33/22 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2004/62 ,  C01P2004/64 ,  C09C1/28 ,  Y10T428/2982

摘要： The invention relates to a method for preparing a synthetic talc composition. According to said method, a kerolite composition is subjected to an anhydrous thermal treatment carried out at a pressure lower than 5 bar, from over a few hours up to over a few days, at a treatment temperature higher than 300° C. The invention also relates to a synthetic talc composition prepared in this way, the synthetic talc particles of the composition being exclusively of chemical formula —(Si4)Mg3O10(OH)2— and identifiable, during X-ray diffraction, by the presence of a characteristic diffraction peak located at a distance of between 9.40-9.68 and corresponding to a plane (001). Said synthetic talc particles also have a thermally stable crystalline structure of stacked laminae, which is very similar to that of a natural talc and has a particle size smaller than approximately ten micrometers.

摘要翻译： 本发明涉及一种制备合成滑石组合物的方法。 根据所述方法，在高于300℃的处理温度下，在低于5巴的压力下进行无水热处理，从超过几个小时至多数天，进行无水热处理。本发明还 涉及以这种方式制备的合成滑石组合物，该组合物的合成滑石颗粒仅在化学式（Si 4）Mg 3 O 10（OH）2）中，并且在X射线衍射过程中可通过存在特征衍射峰 位于9.40-9.68之间的距离，对应于平面（001）。 所述合成滑石颗粒也具有堆叠薄片的热稳定结晶结构，其与天然滑石非常相似，并且具有小于约十微米的粒度。

公开(公告)号：US20110015102A1

公开(公告)日：2011-01-20

申请号：US12809672

申请日：2008-12-18

申请人： Francois Martin ,  Jean-Pierre Bonino ,  Pierre Micoud ,  Jocelyne Ferret ,  Cedric Lebre ,  Vincent Baylac

发明人： Francois Martin ,  Jean-Pierre Bonino ,  Pierre Micoud ,  Jocelyne Ferret ,  Cedric Lebre ,  Vincent Baylac

IPC分类号： C10M125/04 ,  C25D15/00

CPC分类号： C25D15/00 ,  B82Y30/00 ,  C23C30/00 ,  C25D15/02

摘要： A composite material includes a metal matrix in which synthetic lamellar phyllosilicated mineral particles are distributed. The lamellar phyllosilicated mineral particles are particles also called synthetic phyllosilicated nanoparticles (6) that are mineral, silico/germano-metal, lamellar, synthetic and hydrophilic, and have an average size of between 10 nm and 1 μm. A substrate that includes a lubricating coating consisting of such a material, and an electrolytic deposition preparation method are also described.

摘要翻译： 复合材料包括其中分布有合成层状层间矿物颗粒的金属基质。 层状片状矿物颗粒是称为矿物，硅/锗 - 金属，层状，合成和亲水的平均尺寸在10nm和1μm之间的颗粒，也称为合成树脂状纳米颗粒（6）。 还描述了包括由这种材料组成的润滑涂层的基板和电解沉积制备方法。

公开(公告)号：US09121295B2

公开(公告)日：2015-09-01

申请号：US13634420

申请日：2011-03-11

申请人： Justine Menuey ,  Florence Ansart ,  Jean-Pierre Bonino ,  Justine Fenech ,  Celine Viazzi

发明人： Justine Menuey ,  Florence Ansart ,  Jean-Pierre Bonino ,  Justine Fenech ,  Celine Viazzi

IPC分类号： B32B27/32 ,  B32B9/00 ,  B32B19/00 ,  F01D5/28 ,  C23C18/12

CPC分类号： F01D5/288 ,  C23C18/1216 ,  C23C18/1245 ,  C23C18/1254 ,  Y10T428/12479 ,  Y10T428/12549

摘要： The invention relates to a method for manufacturing a thermal barrier protection covering a superalloy metal substrate and comprising at least one metal sublayer (13) and a ceramic layer (14) based on zirconia stabilized with yttrium having a column structure defining pores.The following steps are applied: impregnation of a portion of the pores of the ceramic layer (14) with a sol based on zirconia is achieved via a sol-gel route and this in order to form an anchoring sublayer (22), on said ceramic layer topped with said anchoring sub-layer (22), a continuous protective layer (20) based on oxide, is formed via a sol-gel route, and a heat treatment is carried out, whereby an outer protection layer is formed against the attack of the thermal barrier (11) by CMASes. Application to the protection of aeronautical protection parts.

摘要翻译： 本发明涉及一种用于制造覆盖超合金金属基底的热障保护的方法，该方法包括至少一个金属子层（13）和陶瓷层（14），所述金属子层（13）和陶瓷层（14）基于用具有限定孔的柱结构的用钇稳定的氧化锆。 应用以下步骤：通过溶胶 - 凝胶途径实现用基于氧化锆的溶胶浸渍陶瓷层（14）的一部分孔隙，以便在所述陶瓷上形成锚定子层（22） 通过溶胶 - 凝胶途径形成基于氧化物的连续保护层（20），并且进行热处理，从而形成抵抗攻击的外部保护层 的热障（11）。 适用于航空保护部件的保护。