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    Method for continuous production of a perfluoroalkyl iodide telomer
    1.
    发明授权
    Method for continuous production of a perfluoroalkyl iodide telomer 有权
    连续生产全氟烷基碘调节剂的方法

    公开(公告)号：US06919490B2

    公开(公告)日：2005-07-19

    申请号：US10473150

    申请日：2002-04-17

    申请人： Yoshio Funakoshi ,  Jun Miki

    发明人： Yoshio Funakoshi ,  Jun Miki

    IPC分类号： B01J23/14 ,  B01J23/72 ,  B01J23/825 ,  B01J23/835 ,  B01J35/02 ,  B01J35/08 ,  C07B61/00 ,  C07C17/278 ,  C07C19/16 ,  C07C17/04 ,  C07C17/272

    CPC分类号： B01J35/023 ,  B01J23/14 ,  B01J23/72 ,  B01J23/835 ,  B01J35/02 ,  B01J35/08 ,  B01J35/1009 ,  C07C17/278 ,  C07C19/16

    摘要： The present invention relates to a process for continuously producing a perfluoroalkyl iodide represented by the general formula Rf(CF2CF2)nI, wherein Rf is a C1-6 perfluoroalkyl and n is an integer from 1 to 4, the method comprising continuously supplying a perfluoroalkyl iodide as a telogen represented by the general formula RfI, wherein Rf is as defined above, and tetrafluoroethylene as a taxogen to a tubular reactor packed with a metal catalyst comprising a powdery spherical metal or a sintered metal; and conducting telomerization at a temperature of 60 to 160° C. under a pressure of 0.1 to 5 MPa (gauge pressure).According to the present invention, medium-chain perfluoroalkyl iodides can be continuously and efficiently produced with little generation of impurities, such as hydrogen-containing organic compounds and the like.

    摘要翻译： 本发明涉及一种连续生产由通式R 2（CF 2 CH 2）2表示的全氟烷基碘的方法， n I，其中R 1是C 1-6 - 全氟烷基，n是1至4的整数，所述方法包括连续供给全氟烷基碘作为 由通式R 1 F 1表示的开环元素，其中R f定义如上，以及作为发酵剂的四氟乙烯加到装有金属催化剂的管状反应器中，所述催化剂包含粉末状 球形金属或烧结金属; 在0.1〜5MPa（表压）的压力下，在60〜160℃的温度下进行调质。 根据本发明，可以连续有效地制备中链全氟烷基碘化物，其中少量的杂质如含氢有机化合物等产生。

    Process and unit for production of perfluoroalkyl iodide telomers
    4.
    发明授权
    Process and unit for production of perfluoroalkyl iodide telomers 有权
    用于生产全氟烷基碘调聚物的方法和单元

    公开(公告)号：US07601878B2

    公开(公告)日：2009-10-13

    申请号：US11723115

    申请日：2007-03-16

    申请人： Tatsuya Hirata ,  Kouzou Noda ,  Jun Miki

    发明人： Tatsuya Hirata ,  Kouzou Noda ,  Jun Miki

    IPC分类号： C07C17/38 ,  C07C17/269 ,  C07C17/278

    CPC分类号： B01J8/0055 ,  B01J8/222 ,  B01J38/00 ,  B01J2208/00176 ,  B01J2208/00867 ,  C07C17/278 ,  C07C17/38 ,  Y02P20/582 ,  Y02P20/584 ,  C07C19/16

    摘要： A solid catalyst used in, for example, production of a perfluoroalkyl iodide telomer is effectively and continuously recovered and the recovered catalyst is continuously recycled to the reactor for reuse. A slurry containing a reaction product and the catalyst is drawn from the reaction system, and the catalyst in the drawn slurry is classified by means of a hydrocyclone, whereby a high-concentration slurry whose catalyst concentration is higher than that of the drawn slurry and a low-concentration slurry whose catalyst concentration is lower than that of the drawn slurry are obtained, and the high-concentration slurry is recycled to the reaction system.

    摘要翻译： 用于例如生产全氟烷基碘调节剂的固体催化剂被有效且连续地回收，并将回收的催化剂连续再循环到反应器中再使用。 从反应体系中抽出含有反应产物和催化剂的浆料，并且通过水力旋流器对拉伸浆料中的催化剂进行分级，由此得到催化剂浓度高于拉制浆料的高浓度浆料和 得到催化剂浓度低于所提取的浆液的低浓度浆料，将高浓度浆液再循环至反应体系。

    Catalyst and process for producing phenol
    7.
    发明授权
    Catalyst and process for producing phenol 失效
    催化剂和生产苯酚的方法

    公开(公告)号：US5268512A

    公开(公告)日：1993-12-07

    申请号：US954794

    申请日：1992-07-10

    申请人： Jun Miki ,  Toshifumi Suzuki ,  Tsutomu Shikada ,  Kazuhiko Tate ,  Yakudo Tachibana

    发明人： Jun Miki ,  Toshifumi Suzuki ,  Tsutomu Shikada ,  Kazuhiko Tate ,  Yakudo Tachibana

    IPC分类号： B01J23/755 ,  B01J23/78 ,  C07C37/56 ,  C07C37/055 ,  C07C37/00

    CPC分类号： B01J23/755 ,  B01J23/78 ,  C07C37/56 ,  Y02P20/52

    摘要： A catalyst for producing phenol consisting essentially of a nickel compound supported on a metal oxide carrier, or a catalyst for producing phenol consisting essentially of iron oxide and nickel oxide, and processes for producing phenol using either of the above catalyst. The catalysts of the invention exercise a high conversion of benzoic acid and a high selectivity to phenol, and phenol can be produced in a high yield, particularly in a high space time yield through the processes of the invention using the above catalysts. The above conversion, selectivity and space time yield can be improved by calcining the catalyst at 600.degree. to 900.degree. C.

    摘要翻译： 用于制备基本上由负载在金属氧化物载体上的镍化合物组成的酚的催化剂，或用于生产基本上由氧化铁和氧化镍组成的酚的催化剂，以及使用上述催化剂生产苯酚的方法。 本发明的催化剂具有苯甲酸的高转化率和对苯酚的高选择性，并且可以通过使用上述催化剂的本发明的方法，以高产率，特别是在高空时收率生产苯酚。 通过在600-900℃下煅烧催化剂可以提高上述转化率，选择性和时间产率。

    Process and unit for production of perfluoroalkyl iodide telomers
    10.
    发明申请
    Process and unit for production of perfluoroalkyl iodide telomers 有权
    用于生产全氟烷基碘调聚物的方法和单元

    公开(公告)号：US20070161831A1

    公开(公告)日：2007-07-12

    申请号：US11723115

    申请日：2007-03-16

    申请人： Tatsuya Hirata ,  Kouzou Noda ,  Jun Miki

    发明人： Tatsuya Hirata ,  Kouzou Noda ,  Jun Miki

    IPC分类号： C07C17/38

    CPC分类号： B01J8/0055 ,  B01J8/222 ,  B01J38/00 ,  B01J2208/00176 ,  B01J2208/00867 ,  C07C17/278 ,  C07C17/38 ,  Y02P20/582 ,  Y02P20/584 ,  C07C19/16

    摘要： A solid catalyst used in, for example, production of a perfluoroalkyl iodide telomer is effectively and continuously recovered and the recovered catalyst is continuously recycled to the reactor for reuse. A slurry containing a reaction product and the catalyst is drawn from the reaction system, and the catalyst in the drawn slurry is classified by means of a hydrocyclone, whereby a high-concentration slurry whose catalyst concentration is higher than that of the drawn slurry and a low-concentration slurry whose catalyst concentration is lower than that of the drawn slurry are obtained, and the high-concentration slurry is recycled to the reaction system.

    摘要翻译： 用于例如生产全氟烷基碘调节剂的固体催化剂被有效且连续地回收，并将回收的催化剂连续再循环到反应器中再使用。 从反应体系中抽出含有反应产物和催化剂的浆料，并且通过水力旋流器对拉伸浆料中的催化剂进行分级，由此得到催化剂浓度高于拉制浆料的高浓度浆料和 得到催化剂浓度低于所提取的浆液的低浓度浆料，将高浓度浆液再循环至反应体系。