公开(公告)号：US07488837B2

公开(公告)日：2009-02-10

申请号：US11632171

申请日：2005-06-28

申请人： Keiichi Tsuto ,  Tetsuya Koshikawa

发明人： Keiichi Tsuto ,  Tetsuya Koshikawa

IPC分类号： C11C3/02 ,  C11B3/02 ,  C07C29/06

CPC分类号： C11C3/003 ,  B01D15/00 ,  B01J20/26 ,  B01J20/28045 ,  B01J23/02 ,  B01J31/10 ,  B01J35/04 ,  B01J37/0215 ,  Y02E50/13

摘要： The present invention relates to a process for preparing an alkyl ester of a fatty acid, including the steps of carrying out an esterification reaction between a free fatty acid contained in a fat or oil and an alcohol; carrying out a transesterification reaction between a fat or oil and an alcohol; and refining an alkyl ester of a fatty acid, wherein at least any one of three steps is carried out in a corresponding step selected from the steps of (a) contacting a fat or oil and an alcohol with a resin foamed article to which a catalyst containing fine strongly acidic particles is supported or a resin foamed article modified to be strongly acidic, and carrying out an esterification reaction between a free fatty acid in the fat or oil and the alcohol; (b) contacting a fat or oil and an alcohol with a resin foamed article to which a catalyst containing fine alkali particles is supported, and carrying out a transesterification reaction between the fat or oil and the alcohol; and (c) contacting a reaction mixture obtained by the transesterification reaction with a resin foamed article to remove impurities via adsorption, and refining an alkyl ester of a fatty acid.

摘要翻译： 本发明涉及一种脂肪酸烷基酯的制备方法，包括在脂肪或油中含有的游离脂肪酸与醇之间进行酯化反应的步骤; 在脂肪或油与醇之间进行酯交换反应; 和精制脂肪酸的烷基酯，其中三个步骤中的至少任一步骤以相应的步骤进行，所述步骤选自以下步骤：（a）使脂肪或油和醇与树脂发泡制品接触，其中催化剂 负载含有细的强酸性颗粒的树脂发泡制品或被改性为强酸性的树脂发泡制品，并且在脂肪或油中的游离脂肪酸与醇之间进行酯化反应; （b）使脂肪或油和醇与负载有细碱性粒子的催化剂的树脂发泡体接触，并进行脂肪或油与醇之间的酯交换反应; 和（c）通过酯交换反应获得的反应混合物与树脂发泡制品接触以通过吸附除去杂质，并精制脂肪酸的烷基酯。

公开(公告)号：US4086256A

公开(公告)日：1978-04-25

申请号：US704613

申请日：1976-07-12

申请人： Keiichi Tsuto ,  Kanji Majima ,  Shigeyasu Imamura

发明人： Keiichi Tsuto ,  Kanji Majima ,  Shigeyasu Imamura

IPC分类号： B01J10/02 ,  C07B31/00 ,  C07B45/02 ,  C07C67/00 ,  C07C301/00 ,  C07C303/00 ,  C07C303/02 ,  C07C303/06 ,  C07C305/00 ,  C07C309/01 ,  C08H3/00 ,  C07C143/24

CPC分类号： B01J19/247 ,  B01J10/02 ,  B01J19/2425 ,  C07B45/02 ,  C07C303/00 ,  C07C303/24

摘要： Sulfonation of a sulfonatable organic compound is effected by means of a two-stage reaction with an SO.sub.3 -containing gas, in which the first-stage reaction is carried out by flowing, in parallel flow relation, said organic compound and said SO.sub.3 -containing gas upwardly into the lower ends of a plurality of vertically positioned cylinders or double-cylinders, and the second-stage reaction is carried out by the steps of collecting the reaction product of the first-stage reaction, adding fresh SO.sub.3 -containing gas to the reaction product thus collected and flowing in parallel flow arrangement the reaction mixture downwardly into the upper end of a vertically positioned cylinder or double-cylinder.

摘要翻译： 可磺化有机化合物的磺化是通过与含SO 3的气体进行两阶段反应进行的，其中第一阶段反应是以平行流动关系流过所述有机化合物和所述含SO 3的气体 向上进入多个垂直定位的圆柱体或双圆柱体的下端，第二阶段反应通过收集第一阶段反应的反应产物，向反应中加入新鲜的含SO 3气体的步骤来进行 如此收集并平行流动的产物将反应混合物向下排列到垂直定位的气缸或双气缸的上端。

公开(公告)号：US07857869B2

公开(公告)日：2010-12-28

申请号：US10580340

申请日：2004-11-19

申请人： Keiichi Tsuto ,  Tetsuya Koshikawa

发明人： Keiichi Tsuto ,  Tetsuya Koshikawa

IPC分类号： C10L1/08 ,  C10L1/19

CPC分类号： C11C3/003 ,  C10L1/026 ,  Y02E50/13

摘要： A process for producing diesel fuel oil from fat and oil comprises producing fatty acid methyl ester for diesel fuel in accordance with transesterification of the fat and oil with methanol, wherein the process further comprises a step of converting glycerol formed as a by-product into methanol, and the obtained methanol is used as a material for the transesterification. In the step of converting glycerol formed as a by-product into methanol, water in an equimolar amount or more to the amount of glycerol is added to glycerol, the obtained mixture is gasified under a pressure of 2 MPa or greater at a temperature of 700° C. or higher to convert the mixture into a gas comprising carbon monoxide and hydrogen, and carbon monoxide and hydrogen are then converted into methanol in accordance with a methanol synthesis process.

摘要翻译： 从油脂生产柴油燃料油的方法包括根据脂肪和油与甲醇的酯交换反应制备用于柴油的脂肪酸甲酯，其中该方法还包括将副产物形成的甘油转化成甲醇的步骤 ，将所得甲醇用作酯交换反应的原料。 在将作为副产物形成的甘油转化为甲醇的步骤中，将等摩尔量以上的水加入到甘油中，将得到的混合物在2MPa或更大的压力下在700℃的温度下气化 ℃以上以将混合物转化为包含一氧化碳和氢气的气体，然后根据甲醇合成方法将一氧化碳和氢气转化成甲醇。

公开(公告)号：US06197282B1

公开(公告)日：2001-03-06

申请号：US09194199

申请日：1998-11-20

申请人： Kentaro Oshima ,  Shunji Kozaki ,  Yoshinobu Imaizumi ,  Toshio Miyake ,  Keiichi Tsuto ,  Kazuhiro Yamaki ,  Satoshi Sugawara

发明人： Kentaro Oshima ,  Shunji Kozaki ,  Yoshinobu Imaizumi ,  Toshio Miyake ,  Keiichi Tsuto ,  Kazuhiro Yamaki ,  Satoshi Sugawara

IPC分类号： A61K742

CPC分类号： C01G23/047 ,  A61K8/0241 ,  A61K8/27 ,  A61K8/29 ,  A61K2800/412 ,  A61K2800/624 ,  A61Q17/04 ,  C01G9/02 ,  C01P2004/62 ,  C09C1/3684

摘要： The present invention provides a method for producing a material dispersed with ultraviolet shielding fine particles, characterized by subjecting a starting material liquid mixture comprising particles comprising one or more inorganic substances having shielding abilities against ultraviolet light, one or more silicone dispersants selected from modified silicones and reactive silicones, and a silicone oil to a mill treatment and/or a high-pressure dispersion treatment; and ultraviolet shielding fine particles or a material dispersed therewith, characterized by being produced by the above method. Also, the present invention provides a method of producing a powdery product of ultraviolet shielding fine particles, characterized by drying the material dispersed with ultraviolet shielding fine particles obtainable by the above method. Further, the present invention provides cosmetics comprising a material dispersed with ultraviolet shielding fine particles or a powdery product of the ultraviolet shielding fine particles. The material dispersed with ultraviolet shielding fine particles of the present invention is characterized in that the ultraviolet shielding fine particles comprise particles comprising one or more inorganic substances having shielding abilities against ultraviolet light, surfaces thereof being coated with one or more silicone dispersants selected from modified silicones and reactive silicones, and that at least a part of the ultraviolet shielding fine particles is dispersed in a silicone oil as aggregated particles of the particles comprising inorganic substances.

摘要翻译： 本发明提供一种分散有紫外线屏蔽微粒的材料的制造方法，其特征在于，将包含一种或多种具有屏蔽能力的无机物质的紫外线的原料液体混合物，一种或多种选自改性硅酮的有机硅分散剂和 反应性硅氧烷和硅油进行研磨处理和/或高压分散处理; 和紫外线屏蔽微粒或其分散的材料，其特征在于通过上述方法制备。 另外，本发明提供一种紫外线屏蔽微粒的粉末状制品的制造方法，其特征在于，使用通过上述方法得到的紫外线屏蔽微粒分散的材料进行干燥。 此外，本发明提供了包含分散有紫外线屏蔽微粒的材料或紫外线屏蔽微粒的粉末状产品的化妆品。 用本发明的紫外线屏蔽微粒分散的材料的特征在于，紫外线屏蔽微粒包括包含一种或多种具有对紫外线的屏蔽能力的无机物质的颗粒，其表面涂覆有一种或多种选自改性有机硅的硅氧烷分散剂 和反应性硅氧烷，并且至少一部分紫外线屏蔽细颗粒作为包含无机物质的颗粒的凝集颗粒分散在硅油中。

公开(公告)号：US07626047B2

公开(公告)日：2009-12-01

申请号：US10504093

申请日：2003-02-18

申请人： Masahide Nakayama ,  Keiichi Tsuto

发明人： Masahide Nakayama ,  Keiichi Tsuto

IPC分类号： C11B3/10 ,  C11C1/08

CPC分类号： C10L1/026 ,  C11C3/003 ,  Y02E50/13

摘要： A method for producing a fatty acid alkyl ester for diesel fuel oil starting with a fat/oil material such as an edible oil whereby the qualities required of diesel fuel oil can be satisfied and the wastes from the production process can be minimized. The method is characterized by including subjecting a fat/oil material to transesterification with an alcohol, washing with water the oily phase of the reaction mixture, eliminating water after washing via absorption by a high-water-absorptive resin, and then separating the high-water-absorptive resin gel to thereby provide a fatty acid alkyl ester suitable for diesel fuel oil.

摘要翻译： 从油脂等食品油开始的柴油机油脂肪酸烷基酯的制造方法，能够满足柴油燃料油所需要的品质，能够使生产过程中的废物最小化。 该方法的特征在于包括使脂肪/油物质与醇进行酯交换，用水洗涤反应混合物的油相，通过高吸水性树脂的吸收洗涤后除去水分， 吸水树脂凝胶，从而提供适用于柴油的脂肪酸烷基酯。

公开(公告)号：US20080045732A1

公开(公告)日：2008-02-21

申请号：US11632171

申请日：2005-06-28

申请人： Keiichi Tsuto ,  Tetsuya Koshikawa

发明人： Keiichi Tsuto ,  Tetsuya Koshikawa

IPC分类号： C11C3/08

CPC分类号： C11C3/003 ,  B01D15/00 ,  B01J20/26 ,  B01J20/28045 ,  B01J23/02 ,  B01J31/10 ,  B01J35/04 ,  B01J37/0215 ,  Y02E50/13

摘要： The present invention relates to a process for preparing an alkyl ester of a fatty acid, including the steps of carrying out an esterification reaction between a free fatty acid contained in a fat or oil and an alcohol; carrying out a transesterification reaction between a fat or oil and an alcohol; and refining an alkyl ester of a fatty acid, wherein at least any one of three steps is carried out in a corresponding step selected from the steps of (a) contacting a fat or oil and an alcohol with a resin foamed article to which a catalyst containing fine strongly acidic particles is supported or a resin foamed article modified to be strongly acidic, and carrying out an esterification reaction between a free fatty acid in the fat or oil and the alcohol; (b) contacting a fat or oil and an alcohol with a resin foamed article to which a catalyst containing fine alkali particles is supported, and carrying out a transesterification reaction between the fat or oil and the alcohol; and (c) contacting a reaction mixture obtained by the transesterification reaction with a resin foamed article to remove impurities via adsorption, and refining an alkyl ester of a fatty acid.

摘要翻译： 本发明涉及一种脂肪酸烷基酯的制备方法，包括在脂肪或油中含有的游离脂肪酸与醇之间进行酯化反应的步骤; 在脂肪或油与醇之间进行酯交换反应; 和精制脂肪酸的烷基酯，其中三个步骤中的至少任一步骤以相应的步骤进行，所述步骤选自以下步骤：（a）使脂肪或油和醇与树脂发泡制品接触，其中催化剂 负载含有细的强酸性颗粒的树脂发泡制品或被改性为强酸性的树脂发泡制品，并且在脂肪或油中的游离脂肪酸与醇之间进行酯化反应; （b）使脂肪或油和醇与负载有细碱性粒子的催化剂的树脂发泡体接触，并进行脂肪或油与醇之间的酯交换反应; 和（c）通过酯交换反应获得的反应混合物与树脂发泡制品接触以通过吸附除去杂质，并精制脂肪酸的烷基酯。

公开(公告)号：US20070101640A1

公开(公告)日：2007-05-10

申请号：US10580340

申请日：2004-11-19

申请人： Keiichi Tsuto ,  Tetsuya Koshikawa

发明人： Keiichi Tsuto ,  Tetsuya Koshikawa

IPC分类号： C10L1/18

CPC分类号： C11C3/003 ,  C10L1/026 ,  Y02E50/13

摘要： A process for producing diesel fuel oil from fat and oil comprises producing fatty acid methyl ester for diesel fuel in accordance with transesterification of the fat and oil with methanol, wherein the process further comprises a step of converting glycerol formed as a by-product into methanol, and the obtained methanol is used as a material for the transesterification. In the step of converting glycerol formed as a by-product into methanol, water in an equimolar amount or more to the amount of glycerol is added to glycerol, the obtained mixture is gasified under a pressure of 2 MPa or greater at a temperature of 700° C. or higher to convert the mixture into a gas comprising carbon monoxide and hydrogen, and carbon monoxide and hydrogen are then converted into methanol in accordance with a methanol synthesis process.

摘要翻译： 从油脂生产柴油燃料油的方法包括根据脂肪和油与甲醇的酯交换反应制备用于柴油的脂肪酸甲酯，其中该方法还包括将副产物形成的甘油转化成甲醇的步骤 ，将所得甲醇用作酯交换反应的原料。 在将作为副产物形成的甘油转化为甲醇的步骤中，将等摩尔量以上的水加入到甘油中，将得到的混合物在2MPa或更大的压力下在700℃的温度下气化 ℃以上以将混合物转化为包含一氧化碳和氢气的气体，然后根据甲醇合成方法将一氧化碳和氢气转化成甲醇。

公开(公告)号：US5902569A

公开(公告)日：1999-05-11

申请号：US894672

申请日：1997-08-27

申请人： Kentaro Oshima ,  Shunji Kozaki ,  Yoshinobu Imaizumi ,  Toshio Miyake ,  Toru Nishimura ,  Keiichi Tsuto ,  Satoshi Sugawara ,  Makoto Torizuka

发明人： Kentaro Oshima ,  Shunji Kozaki ,  Yoshinobu Imaizumi ,  Toshio Miyake ,  Toru Nishimura ,  Keiichi Tsuto ,  Satoshi Sugawara ,  Makoto Torizuka

IPC分类号： A61K8/04 ,  A61K8/06 ,  A61Q1/02 ,  A61Q1/06 ,  A61Q1/10 ,  A61Q17/04 ,  C09C1/00 ,  C09C1/30 ,  C09C1/64 ,  A61K7/42 ,  A61K6/00 ,  A61K7/44 ,  A61K9/00

CPC分类号： C09C1/0081 ,  A61K8/0287 ,  A61K8/06 ,  A61Q1/02 ,  A61Q1/06 ,  A61Q1/10 ,  A61Q17/04 ,  B82Y30/00 ,  B82Y5/00 ,  A61K2800/262 ,  A61K2800/413 ,  C01P2002/84 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/10 ,  C01P2004/20 ,  C01P2004/32 ,  C01P2004/50 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2004/82 ,  C01P2004/84 ,  C01P2006/60 ,  C01P2006/80 ,  C01P2006/90

摘要： The present invention is directed to ultraviolet shielding composite fine particles having transparency in a visible light region include (a) matrix particles comprising an aggregate of primary particles having an average particle diameter of from 0.001 to 0.3 .mu.m, the aggregate being formed while the primary particles retain their shapes; and (b) daughter particles having an average particle diameter of from 0.001 to 0.1 .mu.m, the daughter particles being dispersed in and supported by the matrix particles. In the composite fine particles, the daughter particles have a smaller band gap energy than the particles constituting the matrix particles and are capable of absorbing ultraviolet light, and the resulting ultraviolet shielding composite fine particles have substantially no catalytic activity.

摘要翻译： PCT No.PCT / JP96 / 00593 Sec。 371日期1997年8月27日第 102（e）日期1997年8月27日PCT PCT 1996年3月7日PCT公布。 公开号WO96 / 28137 日期1996年9月19日本发明涉及在可见光区域具有透明性的紫外线屏蔽复合微粒子，其包含（a）基质颗粒，其包含平均粒径为0.001〜0.3μm的一次粒子的聚集体， 在初级颗粒保持其形状时形成; 和（b）平均粒径为0.001〜0.1μm的子粒子，所述子粒分散在基质颗粒中并由基质颗粒支撑。 在复合微粒子中，子粒子具有比构成基体粒子的粒子更小的带隙能量，能够吸收紫外线，所得到的紫外线屏蔽复合微粒基本上没有催化活性。

公开(公告)号：US5321630A

公开(公告)日：1994-06-14

申请号：US783128

申请日：1991-10-28

申请人： Yoshifumi Torimoto ,  Junichi Nakamura ,  Keiichi Tsuto ,  Iori Hashimoto ,  Takeshi Fujiwara ,  Kenichiro Sotowa

发明人： Yoshifumi Torimoto ,  Junichi Nakamura ,  Keiichi Tsuto ,  Iori Hashimoto ,  Takeshi Fujiwara ,  Kenichiro Sotowa

IPC分类号： G01F23/00 ,  G01F23/14 ,  G01F23/22 ,  G01F23/24 ,  G06F15/18 ,  G06N3/00 ,  G06N99/00 ,  G01K13/10

CPC分类号： G01F23/14 ,  G01F23/0076 ,  G01F23/22 ,  G01F23/246

摘要： A method of detecting the condition of a liquid layer level in a case where a plurality of liquids are in a layer condition, such method of being capable of knowing each layer level condition even in a case where a system as a whole is high at temperature, pressure or dirt as well as emulsification are large in extent. In order to detect the layer condition, the measurement values of temperatures and so on in a system as a whole or the mathematically processed values of the measurement values are provided as inputs, the layer level condition at this time is outputted, processed by a neurocomputer so as to compose an input-output model. As the layer level condition at this time is adapted to be estimated with the use of the input-output model, the layer level condition may be properly detected even when a system as a whole is high at temperature, pressure or the dirt as well as the emulsification are larger in extent.

摘要翻译： 在多个液体处于层状的情况下，检测液面状态的方法，即使在整个系统的温度高的情况下，也能够了解各层次的状态的方法 ，压力或污垢以及乳化程度都很大。 为了检测层条件，将系统整体的温度等的测量值或测量值的数学处理值作为输入，此时的层级条件被输出，由神经计算机处理 以便构成输入 - 输出模型。 由于此时的层级条件适于使用输入 - 输出模型进行估计，因此即使在整个系统在温度，压力或污物以及高度的情况下，也可以适当地检测层级条件 乳化程度较大。

公开(公告)号：US5274187A

公开(公告)日：1993-12-28

申请号：US936666

申请日：1992-08-28

申请人： Hiroshi Kimura ,  Keiichi Tsuto

发明人： Hiroshi Kimura ,  Keiichi Tsuto

IPC分类号： B01J23/54 ,  B01J23/63 ,  B01J23/644 ,  C07C45/38 ,  C07C45/39 ,  C07C51/245 ,  C07C51/16

CPC分类号： C07C51/245 ,  B01J23/54 ,  B01J23/63 ,  B01J23/6447 ,  C07C45/38 ,  C07C45/39

摘要： A compound having a carbonyl group and/or a carboxyl group is produced by catalytically oxidizing a polyhydric alcohol having at least one primary hydroxyl group and at least one secondary hydroxyl group in the presence of a supported catalyst comprising at least one catalytic component selected from among the following components (I) to (IV) loaded on a support:(I) A first catalytic component chosen from at least one element selected from group A consisting of platinum, palladium, rhodium, ruthenium, rhenium, gold, silver and copper,(II) a combination of the first catalytic component with a second catalytic component chosen from at least one element selected from group B consisting of tin, lead, antimony, bismuth, selenium and tellurium,(III) a combination of the first catalytic component with a third catalytic component chosen from at least one element selected from group C consisting of rare earth elements, and(IV) a combination of the first catalytic component with the second catalytic component and the third catalytic component.

摘要翻译： 通过催化氧化具有至少一个伯羟基和至少一个仲羟基的多元醇在含有至少一种催化剂组分的载体催化剂的存在下，制备具有羰基和/或羧基的化合物，所述催化剂组分选自 负载在载体上的以下组分（I）至（IV）：（I）选自由铂，钯，铑，钌，铼，金，银和铜组成的组A中的至少一种元素的第一催化组分， （II）第一催化组分与选自由锡，铅，锑，铋，硒和碲组成的组B中的至少一种元素的第二催化组分的组合，（III）第一催化组分与 选自由选自由稀土元素组成的组C中的至少一种元素的第三催化组分，和（IV）第一催化组分与第二c的组合 萜烯组分和第三催化组分。