公开(公告)号：US10351422B2

公开(公告)日：2019-07-16

申请号：US14651862

申请日：2013-12-12

申请人： BASF SE ,  LINDE AG

发明人： Otto Machhammer ,  Wolfgang Alois Hormuth ,  Christian Schneider ,  Andreas Bode ,  Volker Goeke ,  Hans-Juergen Maass ,  Matthias Kern ,  Dirk Klingler ,  Rene Koenig ,  Philipp Brueggemann ,  Jens Bernnat ,  Grigorios Kolios

IPC分类号： C01B3/28 ,  B01J19/00 ,  B01J8/00

摘要： The invention relates to a method of carrying out heat-consuming processes, wherein the total energy required averaged over a year for the heat-consuming process originates from at least two different energy sources, where one of the energy sources is an electric energy source whose power varies in the range from 0 to 100% of the total power required, and three different energy modes can individually provide the total power required for the heat-consuming process: (i) exclusively electric energy, (ii) a mixture of electric energy and at least one further nonelectric energy source or (iii) exclusively nonelectric energy, where the changeover time in which the change from one energy mode to another energy mode is completed is not more than 30 minutes.

公开(公告)号：US10233078B2

公开(公告)日：2019-03-19

申请号：US14653482

申请日：2013-12-13

申请人： BASF SE ,  Linde AG ,  ThyssenKrupp Industrial Solutions AG

发明人： Christian Schneider ,  Andreas Bode ,  Dirk Klingler ,  Otto Machhammer ,  Philipp Brueggemann ,  Matthias Kern ,  Wolfgang Alois Hormuth ,  Marcus Guzmann ,  Rene Koenig ,  Jens Bernnat ,  Grigorios Kolios ,  Volker Goeke ,  Hans-Juergen Maass ,  Karsten Bueker

IPC分类号： C01B3/34

摘要： The invention relates to a process for utilizing a hydrocarbon-comprising and/or carbon dioxide-comprising coproduct gas, accompanying gas and/or biogas, wherein hydrocarbon-comprising and/or carbon dioxide-comprising coproduct gas, accompanying gas and/or biogas is introduced into a reaction space and the multicomponent mixture comprised in the coproduct gas, accompanying gas and/or biogas is converted in a high-temperature zone at temperatures of more than 1000° C. and in the presence of a carrier into a product gas mixture which comprises more than 95% by volume of CO, CO2, H2, H2O, CH4 and N2 and optionally into a carbon-comprising solid which is deposited to an extent of at least 75% by weight, based on the total mass of the carbon-comprising solid, on the carrier where the flow velocity of the gas mixture of coproduct gas, accompanying gas and/or biogas in the reaction zone is less than 20 m/s.

公开(公告)号：US20210051770A1

公开(公告)日：2021-02-18

申请号：US16964472

申请日：2019-01-22

申请人： BASF SE

发明人： Hagen APPEL ,  Jens BERNNAT ,  Friedrich GLENK ,  Grigorios KOLIOS ,  Gergard OLBERT ,  Frederik SCHEIFF ,  Berd ZOELS ,  Matthias Kern ,  Dieter FLICKde ,  Christopher Alec ANDERLOHR ,  Dirk KLINGLER ,  Achim WECSUNG

IPC分类号： H05B3/00 ,  B01J8/24 ,  C01B3/26 ,  C01B3/30 ,  H05B3/60

摘要： The present invention relates to an electrically heatable packed pressure-bearing apparatus for conducting endothermic reactions having an upper (3), middle (1) and lower (3) apparatus section, where at least one pair of electrodes (4, 5) in a vertical arrangement is installed in the middle section (1) and all electrodes are disposed in an electrically conductive solid-state packing (26), the upper and lower apparatus sections have a specific conductivity of 105 S/m to 108 S/m, and the middle apparatus section is electrically insulated against the solid-state packing, wherein the upper and lower apparatus sections are electrically insulated from the middle apparatus section, the upper electrode is connected via the upper apparatus section and the lower electrodes via the lower apparatus section or the electrodes are each connected via one or more connecting elements (10, 16) that are in electrical contact with these sections and the ratio of the cross-sectional areas of the upper and lower electrode to the cross-sectional area of the respective current-conducting connecting element or, without use of a connecting element, the ratio of the cross-sectional area of the upper and lower electrode to the cross-sectional area of the respective current-conducting apparatus section is 0.1 to 10.

公开(公告)号：US20220387954A1

公开(公告)日：2022-12-08

申请号：US17755333

申请日：2020-10-20

申请人： BASF SE ,  thyssenkrupp AG ,  thyssenkrupp Industrial Solutions AG

发明人： Grigorios Kolios ,  Frederik Scheiff ,  Christopher Alec Anderlohr ,  Hagen Appel ,  Gerhard Olbert ,  Bernd Zoels ,  Dieter Flick ,  Achim Wechsung ,  Matthias Kern ,  Karsten Bueker ,  Nicolai Antweiler

IPC分类号： B01J8/12 ,  B01J8/00 ,  C01B3/30

摘要： A method can be used for operating a descending moving bed reactor with flowable granular material. The method involves: (i) filling an upper lock-hopper with granular material and/or emptying a lower lock-hopper, (ii) purging the lock-hoppers with purging gas, and (iii) filling the reaction chamber containing a descending moving bed from the upper lock-hopper and/or emptying the reaction chamber into the lower lock-hopper. The pressure equalization between the reaction chamber and lock-hopper is achieved with product gas. The method then involves: (iv) optionally, relieving the lock-hoppers and conveying the product gas flow into the product line, and (v) purging the lock-hoppers with purging gas.

公开(公告)号：US09802875B2

公开(公告)日：2017-10-31

申请号：US14915035

申请日：2014-08-28

申请人： BASF SE

发明人： Matthias Kern ,  Michael Russ ,  Peter Renze ,  Maximilian Vicari

IPC分类号： C09K3/00 ,  B01J19/00 ,  C07C2/78 ,  B01J4/00 ,  B01J19/24 ,  C01B3/36

CPC分类号： C07C2/78 ,  B01J4/002 ,  B01J19/2415 ,  B01J2219/00157 ,  B01J2219/00247 ,  B01J2219/1941 ,  B01J2219/24 ,  C01B3/36 ,  C01B2203/0255 ,  C01B2203/062 ,  C01B2203/1235 ,  C07C11/24

摘要： An apparatus (10) for preparation of acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen is proposed, comprising a reactor (12). The reactor (12) has a burner block (14) with a firing space for acetylene preparation, a secondary space (18) formed within the burner block (14), and an annular space (20) surrounding the secondary space (18). The burner block (14) has holes (22) for supply of a stream of a mixture of hydrocarbons and oxygen to the firing space and holes (24) for supply of a stream of auxiliary oxygen to the firing space. The holes (24) for supply of a stream of auxiliary oxygen to the firing space are connected to the secondary space (18). The secondary space (18) is connected to the annular space (20).There is a further proposal of a process for preparing acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen.

公开(公告)号：US20220152584A1

公开(公告)日：2022-05-19

申请号：US17439540

申请日：2020-03-06

申请人： BASF SE

发明人： Grigorios Kolios ,  Heinrich Laib ,  Frederik Scheiff ,  Bernd Zoels ,  Matthias Kern

IPC分类号： B01J21/04 ,  B32B1/08 ,  B32B18/00 ,  B32B3/30 ,  B01D69/02 ,  B01D69/04 ,  B01D69/12 ,  B01D71/02 ,  B01J27/224 ,  B01J21/18 ,  B01J21/12 ,  B01J35/06 ,  B01J35/00 ,  C01B3/16 ,  C01B3/26 ,  C01B32/05 ,  C01C3/02 ,  C10G9/36 ,  C07C2/82 ,  C10G9/20 ,  F16L9/14 ,  F16L9/10

摘要： Described herein is a gaslight multilayered composite tube having a heat transfer coefficient of >500 W/m2/K which in its construction over the cross section of the wall of the composite tube includes as an inner layer a nonporous monolithic oxide ceramic surrounded by an outer layer of oxidic fiber composite ceramic, where this outer layer has an open porosity of 5%

公开(公告)号：US10059640B2

公开(公告)日：2018-08-28

申请号：US15129094

申请日：2015-03-25

申请人： BASF SE

发明人： Maximilian Vicari ,  Susanne Britzius ,  Lilian Kara-Hippen ,  Michael Russ ,  Matthias Kern ,  Christian Weichert

IPC分类号： C07C11/24 ,  C07C2/78 ,  B01D3/14 ,  C01B3/36 ,  C07D207/267 ,  C07C15/073 ,  C07C15/06 ,  C07C9/04 ,  C07C9/06 ,  C07C11/04 ,  C07C9/14 ,  C07C15/58 ,  C07C15/04 ,  C07C15/08

CPC分类号： C07C2/78 ,  B01D3/14 ,  B01J2219/00006 ,  C01B3/36 ,  C07C9/04 ,  C07C9/06 ,  C07C9/14 ,  C07C11/04 ,  C07C11/24 ,  C07C15/04 ,  C07C15/06 ,  C07C15/073 ,  C07C15/08 ,  C07C15/58 ,  C07D207/267

摘要： An apparatus (10) for the preparation of acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen is proposed. The apparatus (10) comprises a reactor (12), wherein the reactor (12) comprises a burner block (14) with a furnace chamber for the preparation of a composition C1 comprising at least acetylene and substituted acetylene, a first scrubber (22) which is constructed for adding a solvent to the composition C1 to obtain a composition C2, a second scrubber (26) which is constructed for adding the solvent to the composition C2 to obtain a composition C3, a first stripper (36) which is constructed for stripping the composition C3 to obtain a composition C4 comprising the substituted acetylene, acetylene and the solvent and for separating off the acetylene, a first column (46) which is constructed for partial degassing of the composition C4 under a pressure of from 1.0 bar to 1.5 bar to obtain a composition C5 and a first amount A1 of the solvent, a second stripper (56) to which the composition C5 can be fed for stripping a composition C9 to obtain a second amount A2 of the solvent and a composition C6, a third stripper (68) which is constructed for stripping the solvent from the first scrubber (22) to obtain a composition C9, wherein the third striper (68) is connected to the second stripper (56) for feeding the composition C9 to the second stripper (56), an apparatus (72) for adding a diluting gas to the composition C5, which is arranged between the first column (46) and the second stripper (56), a second column (76) which is constructed for adding water to the composition C6 to obtain a composition C7 comprising a third amount A3 of the solvent and water and to obtain a composition C8 comprising the substituted acetylene, and a mixing condenser (82) which is constructed for adding water to the composition C8 to obtain a composition C11 comprising the substituted acetylene.A process for the preparation of acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen is further proposed.

公开(公告)号：US09783415B2

公开(公告)日：2017-10-10

申请号：US14652346

申请日：2013-12-17

申请人： BASF SE

发明人： Matthias Kern ,  Friedrich Glenk ,  Dirk Klingler ,  Andreas Bode ,  Grigorios Kolios ,  Stephan Schunk ,  Guido Wasserschaff ,  Jens Bernnat ,  Bernd Zoels ,  Sabine Schmidt ,  Rene Koenig

IPC分类号： C01B3/24 ,  C01B31/00 ,  C01B31/18 ,  C01B3/38 ,  C10K3/02 ,  C10J3/06

摘要： The invention relates to a process for the parallel preparation of hydrogen, carbon monoxide and a carbon-comprising product, wherein one or more hydrocarbons are thermally decomposed and at least part of the pyrolysis gas formed is taken off from the reaction zone of the decomposition reactor at a temperature of from 800 to 1400° C. and reacted with carbon dioxide to form a gas mixture comprising carbon monoxide and hydrogen (synthesis gas).

公开(公告)号：US11882629B2

公开(公告)日：2024-01-23

申请号：US16964472

申请日：2019-01-22

申请人： BASF SE

发明人： Hagen Appel ,  Jens Bernnat ,  Friedrich Glenk ,  Grigorios Kolios ,  Gerhard Olbert ,  Frederik Scheiff ,  Bernd Zoels ,  Matthias Kern ,  Dieter Flick ,  Christopher Alec Anderlohr ,  Dirk Klingler ,  Achim Wechsung

IPC分类号： B01J8/24 ,  H05B3/00 ,  H05B3/60 ,  C01B3/26 ,  C01B3/30

CPC分类号： H05B3/0004 ,  B01J8/24 ,  C01B3/26 ,  C01B3/30 ,  H05B3/60 ,  B01J2208/00176

摘要： The present invention relates to an electrically heatable packed pressure-bearing apparatus for conducting endothermic reactions having an upper (3), middle (1) and lower (3) apparatus section, where at least one pair of electrodes (4, 5) in a vertical arrangement is installed in the middle section (1) and all electrodes are disposed in an electrically conductive solid-state packing (26), the upper and lower apparatus sections have a specific conductivity of 105 S/m to 108 S/m, and the middle apparatus section is electrically insulated against the solid-state packing, wherein the upper and lower apparatus sections are electrically insulated from the middle apparatus section, the upper electrode is connected via the upper apparatus section and the lower electrodes via the lower apparatus section or the electrodes are each connected via one or more connecting elements (10, 16) that are in electrical contact with these sections and the ratio of the cross-sectional areas of the upper and lower electrode to the cross-sectional area of the respective current-conducting connecting element or, without use of a connecting element, the ratio of the cross-sectional area of the upper and lower electrode to the cross-sectional area of the respective current-conducting apparatus section is 0.1 to 10.

公开(公告)号：US11691115B2

公开(公告)日：2023-07-04

申请号：US16346672

申请日：2017-10-26

申请人： BASF SE

发明人： Grigorios Kolios ,  Bernd Zoels ,  Matthias Kern ,  Jens Bernnat ,  Rene Koenig ,  Friedrich Glenk ,  Achim Wechsung

IPC分类号： B01J8/04 ,  B01J38/32 ,  C01B3/56 ,  C01B32/05 ,  C01B3/04 ,  C01B3/26 ,  C01B3/38 ,  C01B13/02 ,  C04B2/10 ,  C07C5/333

CPC分类号： B01J8/04 ,  B01J8/0492 ,  B01J8/0496 ,  B01J38/32 ,  C01B3/045 ,  C01B3/26 ,  C01B3/38 ,  C01B13/0207 ,  C01B32/05 ,  C04B2/108 ,  C07C5/3337 ,  B01J2208/00522 ,  B01J2219/0004 ,  C01B3/56 ,  C01B2203/043

摘要： The present invention relates to a process for conducting endothermic gas phase or gas-solid reactions, wherein the endothermic reaction is conducted in a production phase in a first reactor zone, the production zone, which is at least partly filled with solid particles, where the solid particles are in the form of a fixed bed, of a moving bed and in sections/or in the form of a fluidized bed, and the product-containing gas stream is drawn off from the production zone in the region of the highest temperature level plus/minus 200 K and the product-containing gas stream is guided through a second reactor zone, the heat recycling zone, which at least partly comprises a fixed bed, where the heat from the product-containing gas stream is stored in the fixed bed, and, in the subsequent purge step, a purge gas is guided through the production zone and the heat recycling zone in the same flow direction, and, in a heating zone disposed between the production zone and the heat recycling zone, the heat required for the endothermic reaction is introduced into the product-containing gas stream and into the purge stream or into the purge stream, and then, in a regeneration phase, a gas is passed through the two reactor zones in the reverse flow direction and the production zone is heated up; the present invention further relates to a structured reactor comprising three zones, a production zone containing solid particles, a heating zone and a heat recycling zone containing a fixed bed, wherein the solid particles and the fixed bed consist of different materials.