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    PROCESS FOR THE PRODUCTION OF SYNTHESIS GAS AND HYDROGEN STARTING FROM LIQUID OR GASEOUS HYDROCARBONS
    5.
    发明申请
    PROCESS FOR THE PRODUCTION OF SYNTHESIS GAS AND HYDROGEN STARTING FROM LIQUID OR GASEOUS HYDROCARBONS 审中-公开
    生产合成气和从液体或气体烃开始氢化的方法

    公开(公告)号：US20100294994A1

    公开(公告)日：2010-11-25

    申请号：US12743482

    申请日：2008-11-17

    Applicant: Luca Basini ,  Alessandra Guarinoni ,  Andrea Lainati

    Inventor： Luca Basini ,  Alessandra Guarinoni ,  Andrea Lainati

    IPC: C01B3/38 ,  B01J19/00

    CPC classification number: C01B3/386 ,  B01J4/002 ,  B01J8/0453 ,  B01J8/0492 ,  B01J8/0496 ,  B01J2208/00495 ,  B01J2219/185 ,  B01J2219/1946 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/085 ,  C01B2203/0872 ,  C01B2203/1023 ,  C01B2203/1029 ,  C01B2203/1035 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1247 ,  C01B2203/1252 ,  C01B2203/1276 ,  C01B2203/1288 ,  C01B2203/143 ,  C01B2203/82 ,  Y02P20/142

    Abstract: A process is described for producing synthesis gas and hydrogen starting from liquid hydrocarbon feedstocks, possibly also mixed with gaseous hydrocarbon streams, comprising at least the following operations: 1) nebulizing/vaporizing a stream of a liquid hydrocarbon feedstock consisting of one or more of the following hydrocarbons: naphthas, various kinds of gas oils, such as LCO, HCO and VGO, other products of refining cycles and oil up-grading, such as DAO, other heavy residues, at a N temperature ranging from 50 to 500° C. and a pressure of 2 to 50 atm, the nebulization also being effected with the help of a gaseous propellant, possibly with the addition of CO2, selected from vapour and/or a gaseous hydrocarbon and resulting in the formation of a nebulized/vaporized liquid hydrocarbon stream; 2) mixing the nebulized/vaporized liquid hydrocarbon stream coming from phase 1) with: a) an oxidizing stream, possibly mixed with vapour, b) possibly a gaseous hydrocarbon stream at a temperature ranging from 50 to 500° C. and a pressure of 2 to 50 atm, with the formation of a possibly biphasic liquid-gas reaction mixture; 3) passing the reaction mixture coming from phase 2) through at least a first structured catalytic bed with the formation of a mixture of reaction products comprising H2 and CO, said structured catalytic bed comprising a catalytic partial oxidation catalyst, arranged on one or more layers, the reaction mixture flowing through each of the layers with a contact time varying from 0.01 to 100 ms, preferably from 0.1 to 10 ms; 4) cooling the mixture of reaction products coming from phase 3). The relative equipment for effecting said process is also described.

    Abstract translation: 描述了从液态烃原料开始生产合成气和氢气的方法，其可能还与气态烃流混合，所述方法至少包括以下操作：1）将由一种或多种 以下碳氢化合物：石脑油，各种瓦斯油，如LCO，HCO和VGO，其他产品的精炼循环和油上调，如DAO，其他重残渣，N温度范围为50-500℃。 并且压力为2至50大气压，雾化还通过气体推进剂的帮助进行，可能加入选自蒸气和/或气态烃的CO 2，并导致形成雾化/蒸发的液体烃 流; 2）将来自相1）的雾化/蒸发的液体烃流与以下物质混合：a）氧化物流，可能与蒸气混合，b）可能的气态烃物流，温度范围为50-500℃， 2至50个大气压，形成可能的双相液气反应混合物; 3）使来自相2）的反应混合物通过至少第一结构化催化床，形成包含H 2和CO的反应产物的混合物，所述结构化催化床包含催化部分氧化催化剂，其被布置在一层或多层上 反应混合物以0.01至100ms，优选0.1至10ms的接触时间流过各层; 4）冷却来自相3）的反应产物的混合物。 还描述了用于实现所述过程的相关设备。

    Fluid mixing device inserted in or combined with a reactor
    6.
    发明授权
    Fluid mixing device inserted in or combined with a reactor 有权
    流体混合装置插入或与反应器组合

    公开(公告)号：US07815700B2

    公开(公告)日：2010-10-19

    申请号：US12090363

    申请日：2006-10-18

    Applicant: Andrea Bartolini ,  Luca Basini ,  Alessandra Guarinoni ,  Antonio Bennardo ,  Nicola Onorati

    Inventor： Andrea Bartolini ,  Luca Basini ,  Alessandra Guarinoni ,  Antonio Bennardo ,  Nicola Onorati

    IPC: C01B3/24 ,  B01J19/00 ,  B01F5/06

    CPC classification number: B01F5/0453 ,  B01F5/0456 ,  B01J8/009 ,  B01J8/0278 ,  B01J2208/00849 ,  B01J2219/00265 ,  C01B3/386 ,  C01B2203/0261 ,  C01B2203/1276 ,  Y02P20/52 ,  Y10T137/87652

    Abstract: A device, system and method of mixing two fluids are described herein. A gaseous first fluid is distributed through a distribution zone to a mixing zone by a bundle of pipes parallel to an axis inside which the first fluid is uniformly distributed. A second fluid is uniformly distributed outside the pipes in the distribution zone. The mixing zone is separated from the distribution zone by a pipe-plate supporting the pipes. The pipe-plate has slits or openings to uniformly discharge the second fluid in an axial flow direction into the mixing zone. The pipes extend beyond the pipe-plate into the mixing zone to partialize an outlet flow of the first fluid. In one aspect, the pipes have different lengths to partialize the outlet flow. In another aspect, a terminal portion of the pipes partializes the outlet flow axially, radially, transversally or a combination thereof in the mixing zone.

    Abstract translation: 本文描述了混合两种流体的装置，系统和方法。 气态第一流体通过平行于第一流体均匀分布的轴线的一束管道分布到分配区域到混合区域。 第二流体均匀地分布在分配区域中的管道外部。 通过支撑管道的管板将混合区与分配区分离。 管板具有狭缝或开口，以使第二流体在轴向流动方向上均匀地排放到混合区域中。 管道延伸超过管板进入混合区域以局部化第一流体的出口流。 在一个方面，管道具有不同的长度以使出口流动部分化。 在另一方面，管道的末端部分将出口流轴向，径向，横向或其混合部分在混合区中。

    ENHANCED PROCESS FOR THE PRODUCTION OF SYNTHESIS GAS STARTING FROM OXYGENATED COMPOUNDS DERIVING FROM BIOMASSES
    7.
    发明申请
    ENHANCED PROCESS FOR THE PRODUCTION OF SYNTHESIS GAS STARTING FROM OXYGENATED COMPOUNDS DERIVING FROM BIOMASSES 审中-公开
    从生物量衍生的氧化化合物起始合成气的生产加强方法

    公开(公告)号：US20090127512A1

    公开(公告)日：2009-05-21

    申请号：US12271371

    申请日：2008-11-14

    Applicant: Luca BASINI ,  Alessandra GUARINONI

    Inventor： Luca BASINI ,  Alessandra GUARINONI

    IPC: C01B3/38

    CPC classification number: C01B3/323 ,  C01B2203/0261 ,  C01B2203/1211 ,  C01B2203/1229 ,  Y02P20/52

    Abstract: The present invention relates to a catalytic partial oxidation process for the production of synthesis gas starting from oxygenated compounds deriving from biomasses, comprising at least the following operative phase: reacting, in a suitable reactor, a reaction mixture comprising: a) one or more oxygenated compounds selected from glycerine, ethanol, triglycerides of fatty acids, carbohydrates having the general formula Cn(H2O)nH2 and/or mixtures thereof, b) an oxidant selected from oxygen, air or air enriched with oxygen, c) optionally a hydrocarbon propellant or vapour, said reaction being carried out at a temperature ranging from 450 to 1,100° C., at a pressure ranging from 1 to 50 ATM, with a GHSV (gas hourly space velocity) ranging from 10,000 to 1,000,000 Nl/(kg·h), in the presence of a catalyst comprising one or more transition metals on a solid carrier.

    Abstract translation: 本发明涉及一种用于从源自生物质的氧化化合物起始的生产合成气的催化部分氧化方法，其包括至少以下操作阶段：在合适的反应器中使反应混合物反应，所述反应混合物包含：a）一个或多个经氧化的 选自甘油，乙醇，脂肪酸甘油三酸酯，具有通式Cn（H 2 O）n H 2的碳水化合物和/或其混合物的化合物，b）选自氧，空气或富氧的空气的氧化剂，c）任选的烃推进剂或 蒸气，所述反应在450至1100℃的温度下进行，在1至50 ATM的压力范围内，GHSV（气时空速）为10,000至1,000,000Nl /（kg·h） 在含有固体载体上的一种或多种过渡金属的催化剂存在下进行。

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