Thiocarbonylthio compound and free radical polymerization employing the same
    2.
    发明授权
    Thiocarbonylthio compound and free radical polymerization employing the same 有权
    硫羰硫基化合物和使用其的自由基聚合

    公开(公告)号:US07968743B2

    公开(公告)日:2011-06-28

    申请号:US12612067

    申请日:2009-11-04

    IPC分类号: C07C327/02 C08F2/00

    CPC分类号: C08F2/38 C07C327/36

    摘要: A thiocarbonylthio compound and free radical polymerization employing the same. The thiocarbonylthio compound is represented by formula (I) or (II): wherein Z can be independently perfluoroalkyl, alkyl, haloalkyl, aryl, alkylaryl, haloalkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy, alkoxyaryl, alkylsulfonyl, alkylsulfonylaryl, dialkylphosphinyl, or dialkylphosphinothioyl; R1 and R2 can be each independently hydrogen, alkyl, aryl, alkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy or alkoxyaryl; R3 is alkyl, aryl, aminoalkyl, alkylamino, alkoxy or alkoxyaryl. Furthermore, R3 can also be alkyl, aryl, alkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy, haloalkylaryl, alkylsilyl, alkylthio, alkylthioaryl, or substituent containing CN, CO, COOH, COOCH3 or heterocyclic moieties; and R4 is perfluoroalkyl. The thiocarbonylthio compound can be used as a reversible chain transfer agent in a free radical polymerization to obtain a polymer with a controlled molecular weight and narrow polydispersity.

    摘要翻译: 硫代羰基硫代化合物和使用其的自由基聚合。 硫代羰基硫代化合物由式(I)或(II)表示:其中Z可以独立地为全氟烷基,烷基,卤代烷基,芳基,烷基芳基,卤代烷基芳基,芳基烷基,氨基烷基,烷基氨基,烷氧基,烷氧基芳基,烷基磺酰基,烷基磺酰基芳基,二烷基氧膦基或二烷基膦硫基 ; R 1和R 2可各自独立地为氢,烷基,芳基,烷基芳基,芳基烷基,氨基烷基,烷基氨基,烷氧基或烷氧基芳基; R3是烷基,芳基,氨基烷基,烷基氨基,烷氧基或烷氧基芳基。 此外,R 3还可以是烷基,芳基,烷基芳基,芳基烷基,氨基烷基,烷基氨基,烷氧基,卤代烷基芳基,烷基甲硅烷基,烷硫基,烷硫基芳基或含有CN,CO,COOH,COOCH 3或杂环部分的取代基; R4是全氟烷基。 硫羰基硫代化合物可以在自由基聚合中用作可逆链转移剂,以获得具有受控分子量和窄分散性的聚合物。

    Chain transfer reagent, free radical polymerization employing the same and resulting polymers
    3.
    发明授权
    Chain transfer reagent, free radical polymerization employing the same and resulting polymers 有权
    链转移试剂,使用其的自由基聚合和得到的聚合物

    公开(公告)号:US07132491B2

    公开(公告)日:2006-11-07

    申请号:US10842141

    申请日:2004-05-10

    IPC分类号: C08F20/54 C08F2/38

    CPC分类号: C08F2/38 C08F4/00

    摘要: Organometallic reversible addition-fragmentation chain transfer reagents (RAFT reagents), processes of free radical polymerization employing the same and polymers with low polydispersity index obtained thereby. The process includes polymerizing at least one monomer with at least one initiator and at least one organometallic RAFT reagent to obtain polymers having terminal organometallic functional groups with low polydispersity index. In addition, the terminal organometallic functional group may be removed by subjecting the obtained polymer to elimination to provide the corresponding organic polymers.

    摘要翻译: 有机金属可逆加成 - 断裂链转移试剂(RAFT试剂),使用该方法的自由基聚合方法和由此获得的具有低多分散指数的聚合物。 该方法包括使至少一种单体与至少一种引发剂和至少一种有机金属RAFT试剂聚合,得到具有低多分散指数的末端有机金属官能团的聚合物。 此外,可以通过使所得聚合物进行消除以提供相应的有机聚合物来除去末端有机金属官能团。

    Chain transfer reagent, free radical polymerization employing the same and resulting polymers
    4.
    发明申请
    Chain transfer reagent, free radical polymerization employing the same and resulting polymers 有权
    链转移试剂,使用其的自由基聚合和得到的聚合物

    公开(公告)号:US20050096440A1

    公开(公告)日:2005-05-05

    申请号:US10842141

    申请日:2004-05-10

    IPC分类号: C08F2/38 C08F4/00 C08F4/06

    CPC分类号: C08F2/38 C08F4/00

    摘要: Organometallic reversible addition-fragmentation chain transfer reagents (RAFT reagents), processes of free radical polymerization employing the same and polymers with low polydispersity index obtained thereby. The process includes polymerizing at least one monomer with at least one initiator and at least one organometallic RAFT reagent to obtain polymers having terminal organometallic functional groups with low polydispersity index. In addition, the terminal organometallic functional group may be removed by subjecting the obtained polymer to elimination to provide the corresponding organic polymers.

    摘要翻译: 有机金属可逆加成 - 断裂链转移试剂(RAFT试剂),使用该方法的自由基聚合方法和由此获得的具有低多分散指数的聚合物。 该方法包括使至少一种单体与至少一种引发剂和至少一种有机金属RAFT试剂聚合,得到具有低多分散指数的末端有机金属官能团的聚合物。 此外,可以通过使所得聚合物进行消除以提供相应的有机聚合物来除去末端有机金属官能团。

    CAPACITOR AND MANUFACTURING METHOD THEREOF
    6.
    发明申请
    CAPACITOR AND MANUFACTURING METHOD THEREOF 有权
    电容器及其制造方法

    公开(公告)号:US20130155578A1

    公开(公告)日:2013-06-20

    申请号:US13615650

    申请日:2012-09-14

    IPC分类号: H01G9/00 H01G9/042

    摘要: A capacitor and a manufacturing method thereof are provided. Two electrodes are disposed opposite to each other. Two electrode protection layers are respectively disposed on inner sides of the electrodes and include carbon particles each covered and bonded with a polymer shell. Active carbon layers are disposed on opposite inner sides of the electrode protection layers. The separator is disposed between the active carbon layers. The electrolyte fills between the electrode protection layers. The polymer shells of each electrode protection layer are bonded to the surface of the corresponding electrode by first and second functional groups. The first functional groups include thiol groups. The second functional groups include epoxy groups or carboxylic groups. The electrode protection layers serve as adhesion layers between the active carbon layers and the electrodes, and protect the electrodes from being corroded by the acid electrolyte solution.

    摘要翻译: 提供电容器及其制造方法。 两个电极彼此相对设置。 两个电极保护层分别设置在电极的内侧,并且包括各自覆盖并与聚合物壳结合的碳颗粒。 活性碳层设置在电极保护层的相对的内侧。 分离器设置在活性碳层之间。 电解质填充在电极保护层之间。 每个电极保护层的聚合物壳通过第一和第二官能团结合到相应电极的表面。 第一官能团包括硫醇基团。 第二官能团包括环氧基或羧基。 电极保护层用作活性碳层和电极之间的粘合层,并且保护电极免受酸性电解质溶液的腐蚀。

    THIOCARBONYLTHIO COMPOUND AND FREE RADICAL POLYMERIZATION EMPLOYING THE SAME
    8.
    发明申请
    THIOCARBONYLTHIO COMPOUND AND FREE RADICAL POLYMERIZATION EMPLOYING THE SAME 有权
    甲硫醇化合物和使用它的自由基聚合

    公开(公告)号:US20100048844A1

    公开(公告)日:2010-02-25

    申请号:US12612067

    申请日:2009-11-04

    IPC分类号: C08F2/00

    CPC分类号: C08F2/38 C07C327/36

    摘要: A thiocarbonylthio compound and free radical polymerization employing the same. The thiocarbonylthio compound is represented by formula (I) or (II): wherein Z can be independently perfluoroalkyl, alkyl, haloalkyl, aryl, alkylaryl, haloalkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy, alkoxyaryl, alkylsulfonyl, alkylsulfonylaryl, dialkylphosphinyl, or dialkylphosphinothioyl; R1 and R2 can be each independently hydrogen, alkyl, aryl, alkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy or alkoxyaryl; R3 is alkyl, aryl, aminoalkyl, alkylamino, alkoxy or alkoxyaryl. Furthermore, R can also be alkyl, aryl, alkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy, haloalkylaryl, alkylsilyl, alkylthio, alkylthioaryl, or substituent contaning CN, CO, COOH, COOCH3 or heterocyclic moieties; and R4 is perfluoroalkyl. The thiocarbonylthio compound can be used as a reversible chain transfer agent in a free radical polymerization to obtain a polymer with a controlled molecular weight and narrow polydispersity.

    摘要翻译: 硫代羰基硫代化合物和使用其的自由基聚合。 硫代羰基硫代化合物由式(I)或(II)表示:其中Z可以独立地为全氟烷基,烷基,卤代烷基,芳基,烷基芳基,卤代烷基芳基,芳基烷基,氨基烷基,烷基氨基,烷氧基,烷氧基芳基,烷基磺酰基,烷基磺酰基芳基,二烷基氧膦基或二烷基膦硫基 ; R 1和R 2可各自独立地为氢,烷基,芳基,烷基芳基,芳基烷基,氨基烷基,烷基氨基,烷氧基或烷氧基芳基; R3是烷基,芳基,氨基烷基,烷基氨基,烷氧基或烷氧基芳基。 此外,R还可以是烷基,芳基,烷基芳基,芳基烷基,氨基烷基,烷基氨基,烷氧基,卤代烷基芳基,烷基甲硅烷基,烷硫基,烷基硫代芳基或与CN,CO,COOH,COOCH 3或杂环部分相连的取代基; R4是全氟烷基。 硫羰基硫代化合物可以在自由基聚合中用作可逆链转移剂,以获得具有受控分子量和窄分散性的聚合物。

    Catalyst composition and process for preparing norbornene-type homopolymers or copolymers
    9.
    发明授权
    Catalyst composition and process for preparing norbornene-type homopolymers or copolymers 有权
    催化剂组合物和制备降冰片烯型均聚物或共聚物的方法

    公开(公告)号:US06774195B2

    公开(公告)日:2004-08-10

    申请号:US10186977

    申请日:2002-07-02

    IPC分类号: C08F426

    CPC分类号: C08F32/08

    摘要: A catalyst composition and process for preparing norbornene-type homopolymers or copolymers. The norbornene-type homopolymers or copolymers can be prepared using an in-situ catalyst composition including: (a) a transition metal compound of ML4, wherein M is a Group 10 metal and L is a neutral electron donor ligand; (b) a hydrocarbyl halogen containing a double bond or a triple bond; and (c) a salt of a non or weakly coordinative anion that can replace a halogen bonded to a metal. The catalyst composition is in a mixing state of components (a), (b), and (c), or in a mixing state of a reaction product of components (a) and (b) together with component (c).

    摘要翻译: 催化剂组合物和制备降冰片烯型均聚物或共聚物的方法。 降冰片烯型均聚物或共聚物可以使用原位催化剂组合物制备,包括:(a)ML4的过渡金属化合物,其中M是第10族金属,L是中性电子给体配体; (b)含有双键或三键的烃基卤素; 和(c)可以取代与金属键合的卤素的非配位或弱配位阴离子的盐。 催化剂组合物处于组分(a),(b)和(c)的混合状态,或组分(a)和(b)的反应产物与组分(c)的混合状态。

    Measuring method for equivalent circuitry
    10.
    发明授权
    Measuring method for equivalent circuitry 失效
    等效电路的测量方法

    公开(公告)号:US6137293A

    公开(公告)日:2000-10-24

    申请号:US218108

    申请日:1998-12-21

    摘要: A measuring method for equivalent circuitry is disclosed herein to characterize the interconnects using time-domain reflectometry measurement. By combining the layer peeling algorithm for transmission lines and the matrix-pencil approach for discontinuities, the technique yields a simple equivalent circuit model which consists of distributed transmission lines and networks of lumped elements. With element values being independent of frequency, the model is well suited to model nonlinear broadband circuit simulation for electrical performance of the interconnects.

    摘要翻译: 本文公开了等效电路的测量方法,以使用时域反射计测量来表征互连。 通过组合传输线的层剥离算法和不连续性的矩阵式方法,该技术产生了一个简单的等效电路模型,由分布式传输线和集总元件网络组成。 元素值与频率无关,该模型非常适合于对互连电气性能的非线性宽带电路仿真进行建模。