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    ADDITIVES FOR HIGH-FLOW POLYMERS
    1.
    发明申请
    ADDITIVES FOR HIGH-FLOW POLYMERS 审中-公开
    高流动聚合物的添加剂

    公开(公告)号：US20140045980A1

    公开(公告)日：2014-02-13

    申请号：US14113072

    申请日：2012-04-23

    申请人： Michele Gerster ,  Raphael Dabbous

    发明人： Michele Gerster ,  Raphael Dabbous

    IPC分类号： C08K5/527 ,  C08K5/098

    CPC分类号： C08K5/527 ,  C08F8/50 ,  C08J3/226 ,  C08J2323/02 ,  C08J2323/10 ,  C08K5/0083 ,  C08K5/098 ,  C08K5/101 ,  C08K2201/019 ,  C08L23/10 ,  C08F110/06

    摘要： A composition containing (I) a natural or synthetic organic polymer having a melt flow index of 15 to 1000 g/10 min at 230° C. and 2.16 kg and (II) an additive mixture containing components (A1) and (A2), wherein (A1) is at least one organic cyclic phosphoric acid ester of the formula (I) (I) wherein Ro is a direct bond, —S—, C3-C12cycloalkylidene or a group —C(Xi)(X2)— with X1 and X2 independently of one another being hydrogen, C1-C18salkyl or C3-C12cycloalkyl; and the radicals R1 are identical and are C1-C4alkyl or C3-C12cycloalkyl unsubstituted or substituted by one, two or three C1-C4alkyl; and (A2) is at least one alkali or alkaline earth metal salt of a saturated or unsaturated aliphatic mono or dicarboxylic acid unsubstituted or substituted by —OH; with the proviso that the composition is essentially free of an inorganic or organic pigment.

    摘要翻译： 一种组合物，其包含（I）在230℃和2.16kg下熔体流动指数为15至1000g / 10min的天然或合成的有机聚合物，和（II）含有组分（A1）和（A2）的添加剂混合物， 其中（A1）是至少一种其中Ro是直接键的式（I）（I）的有机环状磷酸酯，-S-，C 3 -C 12亚烷基或基团-C（X 1）（X 2） 和X2彼此独立地为氢，C 1 -C 18烷基或C 3 -C 12环烷基; 并且基团R 1相同并且是未被取代或被一个，两个或三个C 1 -C 4烷基取代的C 1 -C 4烷基或C 3 -C 12环烷基; 和（A2）是至少一种未被取代或被-OH取代的饱和或不饱和脂族单或二羧酸的碱金属或碱土金属盐; 条件是组合物基本上不含无机或有机颜料。

    Additive Mixture
    2.
    发明申请
    Additive Mixture 审中-公开
    添加剂混合物

    公开(公告)号：US20140005310A1

    公开(公告)日：2014-01-02

    申请号：US14004179

    申请日：2012-03-19

    申请人： Michele Gerster ,  Raphael Dabbous

    发明人： Michele Gerster ,  Raphael Dabbous

    IPC分类号： C08K5/527 ,  C08K5/057 ,  C08K5/098

    CPC分类号： C08K5/527 ,  C07F9/65744 ,  C08K5/0008 ,  C08K5/05 ,  C08K5/057 ,  C08K5/098 ,  C08K5/521 ,  C08L23/02

    摘要： An additive mixture containing (A) a binary system consisting of components (A1) and (A2), wherein (A1) is at least one organic cyclic phosphoric acid ester of the formula (I) wherein R0 is a direct bond, —S—, C3-C12cycloalkylidene or a group —C(X1)(X2)— with X1 and X2 independently of one another being hydrogen, C1-C18alkyl or C3-C12cycloalkyl; and the radicals R1 are identical and are C1-C18alkyl or C3-C12cycloalkyl unsubstituted or substituted by one, two or three C1-C4alkyl; and (A2) is at least one alkali or alkaline earth metal salt of a saturated or unsaturated aliphatic mono or dicarboxylic acid unsubstituted or substituted by —OH; and (B) a divalent metal alcoholate wherein the metal is Zn, Ca or Mg.

    摘要翻译： 一种添加剂混合物，其包含（A）由组分（A1）和（A2）组成的二元体系，其中（A1）为至少一种式（I）的有机环状磷酸酯，其中R 0为直接键，-S- ，C 3 -C 12亚烷基或基团-C（X 1）（X 2） - ，其中X 1和X 2彼此独立地为氢，C 1 -C 18烷基或C 3 -C 12环烷基; 并且基团R1相同并且是未被取代或被一个，两个或三个C 1 -C 4烷基取代的C 1 -C 18烷基或C 3 -C 12环烷基; 和（A2）是至少一种未被取代或被-OH取代的饱和或不饱和脂族单或二羧酸的碱金属或碱土金属盐; 和（B）二价金属醇化物，其中金属是Zn，Ca或Mg。

    PERFLUOROALKYL SUBSTITUTED PHENOL DERIVATIVES AS SURFACE MODIFIERS
    4.
    发明申请
    PERFLUOROALKYL SUBSTITUTED PHENOL DERIVATIVES AS SURFACE MODIFIERS 失效
    全氟烷基取代的苯酚衍生物作为表面改性剂

    公开(公告)号：US20090242822A1

    公开(公告)日：2009-10-01

    申请号：US12310259

    申请日：2007-08-29

    申请人： Michele Gerster ,  Manuel Mihalic

    发明人： Michele Gerster ,  Manuel Mihalic

    IPC分类号： D06M15/687 ,  C08K5/136 ,  C08K5/375 ,  C07C321/20 ,  C07C271/58

    CPC分类号： C07C69/82 ,  C07C43/225 ,  C07C43/23 ,  C07C43/315 ,  C07C69/63 ,  C07C69/65 ,  C07C69/712 ,  C07C235/20 ,  C07C271/44 ,  C07C271/58 ,  C07C323/16 ,  C08K5/06 ,  C08K5/10 ,  C08K5/136 ,  C08K5/205 ,  C08K5/375

    摘要： The instant invention relates to a composition comprising a) an organic material which is susceptible to oxidative, thermal or light-induced degradation, and b) at least one compound of the formula (I) wherein the general symbols are as defined in claim 1; especially wherein at least one of the radicals R2, R3 or R4 is —CH2—CH(CH3)—S(O)p—R12, —CH2—CH2—CH2—S(O)p—R12, —CH2—CH(R11)—CH2—R12 or —CH2—CH═CH—R12, R11 is hydrogen or halogen, R12 is a monovalent perfluorinated alkyl or alkenyl, linear or branched organic radical having four to twenty fully fluorinated carbon atoms; or —CH2CH2(CF2)mCF3, m is 3 to 12, and p is 0, 1 or 2. The compounds of the formula I are useful as reducers of surface energy for organic materials, for example synthetic polymer. Polymers with such a reduced surface energy possess an “easy-to-clean”, “self-cleaning” “antisoiling”, “soil-release” “antigraffiti”, “oil resistance”, “solvent resistance”, “chemical resistance”, “self lubricating”, “scratch resistance”, “low moisture absorption”, “dirt pickup resistance”, “slip properties” and “hydrophobic surface”; and anti-adhesion properties against proteins and against microorganism such as for example bacteria, fungi and algae.

    摘要翻译： 本发明涉及一种组合物，其包含a）对氧化，热或光诱导降解敏感的有机材料，和b）至少一种式（I）化合物，其中一般符号如权利要求1所定义; 特别是其中基团R 2，R 3或R 4中的至少一个为-CH 2 -CH（CH 3）-S（O）p -R 12，-CH 2 -CH 2 -CH 2 -S（O）p -R 12，-CH 2 -CH（ R11）-CH2-R12或-CH2-CH-CH-R12，R11是氢或卤素，R12是具有四至二十个完全氟化的碳原子的一价全氟化烷基或烯基，直链或支链有机基团; 或-CH 2 CH 2（CF 2）m CF 3，m为3至12，p为0,1或2.式I化合物可用作有机材料例如合成聚合物的表面能的还原剂。 具有这种表面能降低的聚合物具有“易清洁”，“自清洁”“防污”，“释放”“防刮涂”，“耐油性”，“耐溶剂性”，“耐化学性” “自润滑”，“耐划伤性”，“低吸湿性”，“抗污性”，“滑爽性”和“疏水性表面”; 和抗蛋白质和抗微生物（例如细菌，真菌和藻类）的抗粘附性。

    N-Substituted Perfluoroalkylated Pyrrolidines as Surface Modifiers
    6.
    发明申请
    N-Substituted Perfluoroalkylated Pyrrolidines as Surface Modifiers 审中-公开
    N-取代的全氟烷基化吡咯烷作为表面改性剂

    公开(公告)号：US20090253838A1

    公开(公告)日：2009-10-08

    申请号：US12227547

    申请日：2007-05-14

    申请人： Michele Gerster ,  Stephan Thorand

    发明人： Michele Gerster ,  Stephan Thorand

    IPC分类号： C08K5/3415

    CPC分类号： C08K5/3415

    摘要： The invention describes a composition comprising comprising a) a natural, semi-synthetic or synthetic polymer which is susceptible to oxidative, thermal or light-induced degradation, and b) a compound of the formula (I) wherein RF, R, Q and q are as defined herein, and are prepared from diallylamine, a perfluoroalkyl iodide and an amino-reactive compound selected from the group of carboxylic acids, anhydrides, acid chlorides, oxiranes, haloalkanes, isocyanates and ureas. The compounds of the formula I are useful as reducers of surface energy for natural, semi-synthetic or synthetic polymers, for example, for increasing the oil and water repellency and stain release of natural, semi-synthetic or synthetic polymers.

    摘要翻译： 本发明描述了一种组合物，其包含a）天然的，半合成的或合成的聚合物，其易于氧化，热或光诱导的降解，和b）式（I）的化合物，其中RF，R，Q和q 由二烯丙基胺，全氟烷基碘和选自羧酸，酸酐，酰氯，环氧乙烷，卤代烷烃，异氰酸酯和脲的氨基反应性化合物制备。 式I的化合物可用作天然，半合成或合成聚合物的表面能的还原剂，例如用于增加天然的，半合成的或合成的聚合物的防油和防水性和污渍释放。

    SILANE COUPLING AGENTS FOR FILLED RUBBERS
    9.
    发明申请
    SILANE COUPLING AGENTS FOR FILLED RUBBERS 有权
    用于填充橡胶的硅烷偶联剂

    公开(公告)号：US20100261826A1

    公开(公告)日：2010-10-14

    申请号：US12678165

    申请日：2008-09-05

    申请人： Michele Gerster ,  Manuel Mihalic

    发明人： Michele Gerster ,  Manuel Mihalic

    IPC分类号： C08K3/36 ,  C08L9/00 ,  C08K3/22 ,  C07F7/18

    CPC分类号： C08K5/548 ,  C08L21/00

    摘要： The invention describes a composition comprising a) a naturally occurring or synthetic rubber susceptible to oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, b) a white reinforcing filler, and c) as coupling agent, at least one compound of the formula I wherein the general symbols are as defined in claim 1, or an oligomeric hydrolysis product of the compound of the formula I.

    摘要翻译： 本发明描述了一种组合物，其包含a）对氧化，热，动态，光诱导和/或臭氧诱导的降解敏感的天然存在或合成橡胶，b）白色增强填料，和c）作为偶联剂，至少一种 式I化合物，其中通式如权利要求1所定义，或式I化合物的低聚水解产物。

    Fluorinated Compounds
    10.
    发明申请
    Fluorinated Compounds 审中-公开
    氟化合物

    公开(公告)号：US20080149879A1

    公开(公告)日：2008-06-26

    申请号：US11884615

    申请日：2006-02-15

    申请人： Fabien Jean Brand ,  Martin Brunner ,  Michele Gerster ,  Andrew Joseph Leggio ,  Michael Tinkl

    发明人： Fabien Jean Brand ,  Martin Brunner ,  Michele Gerster ,  Andrew Joseph Leggio ,  Michael Tinkl

    IPC分类号： D06M13/08 ,  C08K5/02

    CPC分类号： C08K5/02

    摘要： The invention describes a composition comprising a) an organic material which is susceptible to oxidative, thermal or light-induced degradation, and b) at least a compound of the formula (I) wherein Q is a direct bond (II), R1 is C1-C100alkyl, C2-C100alkenyl, C3-C12cycloalkyl or C3-C12cycloalkyl substituted by 1 to 5 C1-C4alkyl; R2 is a fluorine containing group, and R3 and R4 independently of each other are hydrogen or C1-C4alkyl. The compounds of the formula (I) are useful as reducers of surface energy for organic materials, for example, for increasing the oil and water repellency of organic materials.

    摘要翻译： 本发明描述了一种组合物，其包含a）对氧化，热或光诱导降解敏感的有机材料，和b）至少一种式（I）化合物，其中Q是直接键（II），R 1是C 1 -C 12烷基，C 2 -C 20链烯基，C 由1至5个C 1取代的C 3 -C 12环烷基或C 3 -C 12 -C 12环烷基 C 4 -C 14烷基; R 2是含氟基团，R 3和R 4彼此独立地是氢或C 1 H 2 -C 4 -C 4烷基。 式（I）的化合物可用作有机材料的表面能的还原剂，例如用于增加有机材料的防油和拒水性。