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公开(公告)号：US08865938B2
公开(公告)日：2014-10-21
申请号：US13877595
申请日：2011-10-05
IPC分类号： C07C209/00 , C07C209/48 , C07C253/22
CPC分类号： C07C209/48 , C07C253/22 , C07C2601/14 , C07C255/46 , C07C211/18
摘要： A method for producing bis(aminomethyl)cyclohexanes includes a nuclear hydrogenation step of producing hydrogenated phthalic acids or phthalic acid derivatives by nuclear hydrogenation of phthalic acids or phthalic acid derivatives of at least one selected from the group consisting of phthalic acids, phthalic acid esters, and phthalic acid amides; a cyanation step of treating the hydrogenated phthalic acids or phthalic acid derivatives obtained in the nuclear hydrogenation step with ammonia, thereby producing dicyanocyclohexanes; and an aminomethylation step of treating the dicyanocyclohexanes obtained in the cyanation step with hydrogen, thereby producing bis(aminomethyl)cyclohexanes. In the cyanation step, metal oxide is used as a catalyst, and the obtained dicyanocyclohexanes have a metal content of 3000 ppm or less.
摘要翻译： 制备双（氨基甲基）环己烷的方法包括核氢化步骤，其通过邻苯二甲酸或邻苯二甲酸衍生物的核氢化制备氢化邻苯二甲酸或邻苯二甲酸衍生物，所述邻苯二甲酸或邻苯二甲酸衍生物选自邻苯二甲酸，邻苯二甲酸酯， 和邻苯二甲酸酰胺; 氰化步骤，用氨处理在核氢化步骤中得到的氢化邻苯二甲酸或邻苯二甲酸衍生物，从而产生二氰基环己烷; 和在氰化步骤中用氢处理二氰基环己烷的氨基甲基化步骤，从而产生双（氨基甲基）环己烷。 在氰化步骤中，使用金属氧化物作为催化剂，所得到的二氰基环己烷的金属含量为3000ppm以下。
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2.发明申请NOVEL PHOSPHAZENE-SUPPORTED CATALYST, NOVEL COMPOUND THEREOF AND USE THEREOF 审中-公开新型磷酸盐载体催化剂，其新颖化合物及其用途公开(公告)号：US20110288240A1
公开(公告)日：2011-11-24
申请号：US13198397
申请日：2011-08-04
申请人： Naritoshi YOSHIMURA , Shinji Kiyono , Kazumi Mizutani , Isao Hara , Takaomi Hayashi , Tadahito Nobori , Yoshihiro Yamamoto , Miyuki Konno , Yoshihisa Inoue , Akira Matsuura , Tuneyuki Ohkubo
发明人： Naritoshi YOSHIMURA , Shinji Kiyono , Kazumi Mizutani , Isao Hara , Takaomi Hayashi , Tadahito Nobori , Yoshihiro Yamamoto , Miyuki Konno , Yoshihisa Inoue , Akira Matsuura , Tuneyuki Ohkubo
CPC分类号： C08G63/823 , B01J31/0265 , B01J2231/12 , C07F9/065 , C07F9/224
摘要： A phosphazene-supported catalyst in which a support is bonded to a group represented by the general formula (1): wherein n, Zn−, a, b, c, d, R, R1 and D are all defined. The phosphazene-supported catalyst is highly effective to catalyze various organic reactions, and further has no reduction of activity even after recovery and reuse of the catalyst, thus it being economically advantageous. In addition, the polymerization of cyclic monomers, substitution of substituents, carbon-carbon bond forming reactions and the like can be conducted with extremely high efficiency.
摘要翻译： 载体与由通式（1）表示的基团键合的磷腈担载催化剂：其中n，Zn-，a，b，c，d，R，R1和D全部定义。 磷腈担载的催化剂对于催化各种有机反应是非常有效的，即使在回收和再利用催化剂之后也不会降低活性，因此在经济上是有利的。 此外，可以极高效率进行环状单体的聚合，取代基的取代，碳 - 碳键形成反应等。
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3.发明申请TRANSITION METAL COMPLEX COMPOUNDS, OLEFIN OLIGOMERIZATION CATALYSTS INCLUDING THE COMPOUNDS, AND PROCESSES FOR PRODUCING OLEFIN OLIGOMERS USING THE CATALYSTS 有权过渡金属复合化合物，包括该化合物的烯烃低聚催化剂，以及使用催化剂生产烯烃低聚物的方法公开(公告)号：US20110082325A1
公开(公告)日：2011-04-07
申请号：US12452438
申请日：2008-06-27
申请人： Yasuhiko Suzuki , Shinsuke Kinoshita , Atsushi Shibahara , Naritoshi Yoshimura , Isao Hara , Tetsuya Hamada , Kazumori Kawamura , Kou Tsurugi , Yasunori Saito , Seiichi Ishii , Yasushi Nakayama , Naoto Matsukawa , Susumu Murata
发明人： Yasuhiko Suzuki , Shinsuke Kinoshita , Atsushi Shibahara , Naritoshi Yoshimura , Isao Hara , Tetsuya Hamada , Kazumori Kawamura , Kou Tsurugi , Yasunori Saito , Seiichi Ishii , Yasushi Nakayama , Naoto Matsukawa , Susumu Murata
CPC分类号： C08F10/00 , B01J31/143 , B01J31/1616 , B01J31/2243 , B01J2231/122 , B01J2231/20 , B01J2531/46 , B01J2531/62 , C07C2/32 , C07C251/24 , C07C2521/08 , C07C2521/16 , C07C2531/14 , C07C2531/22 , C07F7/003 , C08F110/02 , C07C11/107 , C08F4/64048 , C08F2500/02 , C08F4/64124 , C08F4/6931 , C08F4/64117 , C08F4/02
摘要： The invention provides transition metal complex compounds, high-activity olefin oligomerization catalysts containing the compounds, and olefin oligomerization processes using the catalysts.A transition metal complex compound [A] according to the invention is represented by Formula (I) or Formula (I′) below. An olefin oligomerization catalyst includes the transition metal complex compound [A]. In an olefin oligomerization process of the invention, an olefin is oligomerized in the presence of the catalyst.
摘要翻译： 本发明提供了过渡金属络合物，含有这些化合物的高活性烯烃低聚催化剂和使用该催化剂的烯烃低聚方法。 根据本发明的过渡金属络合物[A]由下式（I）或式（I'）表示。 烯烃低聚催化剂包括过渡金属络合物[A]。 在本发明的烯烃低聚方法中，烯烃在催化剂存在下被低聚。
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公开(公告)号：US20110040131A1
公开(公告)日：2011-02-17
申请号：US12989892
申请日：2009-04-21
申请人： Hiroshi Kouno , Shuji Ozawa , Naritoshi Yoshimura
发明人： Hiroshi Kouno , Shuji Ozawa , Naritoshi Yoshimura
IPC分类号： C07C29/60
CPC分类号： B01J37/031 , B01J23/002 , B01J23/80 , B01J35/002 , B01J37/0201 , B01J37/04 , B01J37/08 , B01J37/18 , B01J2523/00 , C07C29/60 , C07C31/205 , B01J2523/17 , B01J2523/27 , B01J2523/842 , B01J2523/41 , B01J2523/22
摘要： Propylene glycol is produced by a method of producing propylene glycol, the method including: obtaining propylene glycol by performing catalytic hydrogenation of glycerol in the presence of a catalyst, the catalyst containing zinc oxide and at least one of copper and copper oxide, and the catalyst, after being reduced at 180° C. to 230° C. in the presence of hydrogen, showing a half width of from 0.4 to 1.1 of a peak having a peak top at a position at which a diffraction angle (2θ±0.2°) is 43.1° in an X-ray diffraction pattern obtained using CuKα as a radiation source.
摘要翻译： 通过丙二醇的制造方法制造丙二醇，该方法包括：在催化剂存在下进行甘油的催化氢化，含有氧化锌和铜和氧化铜中的至少一种的催化剂和催化剂得到丙二醇 在氢的存在下在180℃下还原至230℃，显示在衍射角（2θ=±0.2°）的位置具有峰顶的峰的半宽度为0.4-1.1 ）在使用CuKα作为辐射源获得的X射线衍射图中为43.1°。
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公开(公告)号：US20110034735A1
公开(公告)日：2011-02-10
申请号：US12936269
申请日：2009-04-07
CPC分类号： C07B53/00 , C07C37/07 , C07C45/62 , C07C45/66 , C07C51/00 , C07C2601/14 , C07C2601/16 , C07C39/08 , C07C49/497 , C07C49/713
摘要： Provided is a method for producing catechol in a one-pot by reacting (4S,5R,6S)-4,5,6-trihydroxy-2-cyclohexene-1-one under hydrogen-reducing conditions while heating.
摘要翻译： 本发明提供通过在加氢条件下在氢还原条件下使（4S，5R，6S）-4,5,6-三羟基-2-环己烯-1-酮反应而在一锅中生产儿茶酚的方法。
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公开(公告)号：US08865939B2
公开(公告)日：2014-10-21
申请号：US13878090
申请日：2011-10-05
IPC分类号： C07C209/00 , C07C253/34 , C07C209/48 , C07C253/22 , B01J23/44 , B01J25/00 , B01J25/02
CPC分类号： C07C209/48 , B01J23/44 , B01J25/00 , B01J25/02 , C07B2200/09 , C07C253/22 , C07C253/34 , C07C2601/14 , C07C255/46 , C07C211/18
摘要： A method for producing trans-1,4-bis(aminomethyl)cyclohexane includes a nuclear hydrogenation step of producing a hydrogenated terephthalic acid or terephthalic acid derivative by nuclear hydrogenation of a terephthalic acid or terephthalic acid derivative, the terephthalic acid or terephthalic acid derivative being at least one selected from the group consisting of terephthalic acid, terephthalic acid ester, and terephthalic acid amide; a cyanation step of treating the hydrogenated terephthalic acid or terephthalic acid derivative with ammonia, thereby producing 1,4-dicyanocyclohexane, and producing trans-1,4-dicyanocyclohexane from the obtained 1,4-dicyanocyclohexane; and an aminomethylation step of treating the trans-1,4-dicyanocyclohexane with hydrogen, thereby producing trans-1,4-bis(aminomethyl)cyclohexane. Metal oxide is used as a catalyst in the cyanation step, and the obtained trans-1,4-dicyanocyclohexane has a metal content of 3000 ppm or less.
摘要翻译： 反式-1,4-双（氨基甲基）环己烷的制造方法包括通过对苯二甲酸或对苯二甲酸衍生物的核氢化制造氢化对苯二甲酸或对苯二甲酸衍生物的核氢化工序，对苯二甲酸或对苯二甲酸衍生物为 选自对苯二甲酸，对苯二甲酸酯和对苯二甲酸酰胺中的至少一种; 用氨处理氢化对苯二甲酸或对苯二甲酸衍生物的氰化步骤，从而得到1,4-二氰基环己烷，由所得1,4-二氰基环己烷生产反式-1,4-二氰基环己烷; 和用氢处理反式-1,4-二氰基环己烷的氨基甲基化步骤，从而产生反式-1,4-双（氨基甲基）环己烷。 在氰化步骤中使用金属氧化物作为催化剂，得到的反式-1,4-二氰基环己烷的金属含量为3000ppm以下。
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公开(公告)号：US20130197269A1
公开(公告)日：2013-08-01
申请号：US13877595
申请日：2011-10-05
IPC分类号： C07C209/48
CPC分类号： C07C209/48 , C07C253/22 , C07C2601/14 , C07C255/46 , C07C211/18
摘要： A method for producing bis(aminomethyl)cyclohexanes includes a nuclear hydrogenation step of producing hydrogenated phthalic acids or phthalic acid derivatives by nuclear hydrogenation of phthalic acids or phthalic acid derivatives of at least one selected from the group consisting of phthalic acids, phthalic acid esters, and phthalic acid amides; a cyanation step of treating the hydrogenated phthalic acids or phthalic acid derivatives obtained in the nuclear hydrogenation step with ammonia, thereby producing dicyanocyclohexanes; and an aminomethylation step of treating the dicyanocyclohexanes obtained in the cyanation step with hydrogen, thereby producing bis(aminomethyl)cyclohexanes. In the cyanation step, metal oxide is used as a catalyst, and the obtained dicyanocyclohexanes have a metal content of 3000 ppm or less.
摘要翻译： 制备双（氨基甲基）环己烷的方法包括核氢化步骤，其通过邻苯二甲酸或邻苯二甲酸衍生物的核氢化制备氢化邻苯二甲酸或邻苯二甲酸衍生物，所述邻苯二甲酸或邻苯二甲酸衍生物选自邻苯二甲酸，邻苯二甲酸酯， 和邻苯二甲酸酰胺; 氰化步骤，用氨处理在核氢化步骤中得到的氢化邻苯二甲酸或邻苯二甲酸衍生物，从而产生二氰基环己烷; 和在氰化步骤中用氢处理二氰基环己烷的氨基甲基化步骤，从而产生双（氨基甲基）环己烷。 在氰化步骤中，使用金属氧化物作为催化剂，所得到的二氰基环己烷的金属含量为3000ppm以下。
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公开(公告)号：US08378152B2
公开(公告)日：2013-02-19
申请号：US12989892
申请日：2009-04-21
申请人： Hiroshi Kouno , Shuji Ozawa , Naritoshi Yoshimura
发明人： Hiroshi Kouno , Shuji Ozawa , Naritoshi Yoshimura
IPC分类号： C07C27/00
CPC分类号： B01J37/031 , B01J23/002 , B01J23/80 , B01J35/002 , B01J37/0201 , B01J37/04 , B01J37/08 , B01J37/18 , B01J2523/00 , C07C29/60 , C07C31/205 , B01J2523/17 , B01J2523/27 , B01J2523/842 , B01J2523/41 , B01J2523/22
摘要： Propylene glycol is produced by a method of producing propylene glycol, the method including: obtaining propylene glycol by performing catalytic hydrogenation of glycerol in the presence of a catalyst, the catalyst containing zinc oxide and at least one of copper and copper oxide, and the catalyst, after being reduced at 180° C. to 230° C. in the presence of hydrogen, showing a half width of from 0.4 to 1.1 of a peak having a peak top at a position at which a diffraction angle (2θ±0.2°) is 43.1° in an X-ray diffraction pattern obtained using CuKα as a radiation source.
摘要翻译： 通过丙二醇的制造方法制造丙二醇，该方法包括：在催化剂存在下进行甘油的催化氢化，含有氧化锌和铜和氧化铜中的至少一种的催化剂和催化剂得到丙二醇 在氢的存在下在180℃下还原至230℃，显示在衍射角（2θ=±0.2°）的位置具有峰顶的峰的半宽度为0.4-1.1 ）在使用CuKα作为辐射源获得的X射线衍射图中为43.1°。
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公开(公告)号：US08053608B2
公开(公告)日：2011-11-08
申请号：US12740197
申请日：2008-10-28
申请人： Hiroshi Kouno , Shuji Ozawa , Naritoshi Yoshimura
发明人： Hiroshi Kouno , Shuji Ozawa , Naritoshi Yoshimura
IPC分类号： C07C29/60
CPC分类号： B01J23/80 , C07C29/60 , C07C31/205
摘要： It is an object of the present invention to provide a process for producing propylene glycol from glycerol as a raw material without the necessity for a step of gasifying glycerol. The process for producing propylene glycol of the present invention comprises a step of subjecting glycerol to catalytic hydrogenation in the presence of a catalyst A containing zinc oxide, silica, and at least one of copper and copper oxide.
摘要翻译： 本发明的目的是提供一种从甘油生产丙二醇作为原料的方法，而不需要使甘油气化的步骤。 本发明的丙二醇的制造方法包括在含有氧化锌，二氧化硅和铜和氧化铜中的至少一种的催化剂A的存在下使甘油进行催化氢化的工序。
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公开(公告)号：US20100256425A1
公开(公告)日：2010-10-07
申请号：US12740197
申请日：2008-10-28
申请人： Hiroshi Kouno , Shuji Ozawa , Naritoshi Yoshimura
发明人： Hiroshi Kouno , Shuji Ozawa , Naritoshi Yoshimura
IPC分类号： C07C29/60
CPC分类号： B01J23/80 , C07C29/60 , C07C31/205
摘要： It is an object of the present invention to provide a process for producing propylene glycol from glycerol as a raw material without the necessity for a step of gasifying glycerol. The process for producing propylene glycol of the present invention comprises a step of subjecting glycerol to catalytic hydrogenation in the presence of a catalyst A containing zinc oxide, silica, and at least one of copper and copper oxide.
摘要翻译： 本发明的目的是提供一种从甘油生产丙二醇作为原料的方法，而不需要使甘油气化的步骤。 本发明的丙二醇的制造方法包括在含有氧化锌，二氧化硅和铜和氧化铜中的至少一种的催化剂A的存在下使甘油进行催化氢化的工序。
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