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公开(公告)号：US5110563A
公开(公告)日：1992-05-05
申请号：US530309
申请日：1990-05-30
CPC分类号： B01J8/0496 , B01J8/0453 , C01B3/386 , B01J2208/0007 , B01J2208/00088 , B01J2208/0015 , B01J2208/00212 , B01J2208/00256 , B01J2208/00371 , B01J2208/00495 , B01J2208/00504 , B01J2208/0053 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/06 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/0866 , C01B2203/1023 , C01B2203/1052 , C01B2203/107 , C01B2203/1241 , C01B2203/1276 , C01B2203/142 , C01B2203/143 , C01B2203/148 , C01B2203/1604 , C01B2203/80 , C01B2203/82 , Y02P20/128
摘要： Process and apparatus for catalytic combustion in which a combustible gas stream is mixed with part of the recycled hot product stream and then fed to a combustion zone containing a combustion catalyst, and from which the hot pressurized product is obtained. The recycle is preferably effected by means of a constriction at the end of the inlet gas supply producing a region of lower pressure than the pressure of the product gas.
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公开(公告)号：US4938685A
公开(公告)日：1990-07-03
申请号：US181031
申请日：1988-04-13
CPC分类号： B01J8/0492 , B01J8/0453 , B01J8/0496 , C01B3/386 , B01J2208/0007 , B01J2208/00088 , B01J2208/0015 , B01J2208/00212 , B01J2208/00256 , B01J2208/00371 , B01J2208/00495 , B01J2208/00504 , B01J2208/0053 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/06 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/0866 , C01B2203/1023 , C01B2203/1052 , C01B2203/107 , C01B2203/1241 , C01B2203/1276 , C01B2203/142 , C01B2203/143 , C01B2203/148 , C01B2203/1604 , C01B2203/80 , C01B2203/82 , Y02P20/128
摘要： Process and apparatus for catalytic combustion in which a combustible gas stream is mixed with part of the recycled hot product stream and then fed to a combustion zone containing a combustion catalyst, and from which the hot pressurized product is obtained. The recycle is preferably effected by means of a constriction at the end of the inlet gas supply producing a region of lower pressure than the pressure of the product gas.
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公开(公告)号：US4788004A
公开(公告)日：1988-11-29
申请号：US52004
申请日：1987-05-20
CPC分类号： B01J8/0496 , B01J8/0453 , C01B3/386 , B01J2208/0007 , B01J2208/00088 , B01J2208/0015 , B01J2208/00212 , B01J2208/00256 , B01J2208/00371 , B01J2208/00495 , B01J2208/00504 , B01J2208/0053 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/06 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/0866 , C01B2203/1023 , C01B2203/1052 , C01B2203/107 , C01B2203/1241 , C01B2203/1276 , C01B2203/142 , C01B2203/143 , C01B2203/148 , C01B2203/1604 , C01B2203/80 , C01B2203/82 , Y02P20/128
摘要： A catalytic partial oxidation or secondary reforming process wherein a flame is established at a burner upstream of the catalyst is started-up by catalytic combustion of a suitable combustible material to produce a hot gas stream and directly, or indirectly, using the heat from the gas stream to heat the reactants fed to the burner to the autoignition temperature. After a flame has been established at the burner, production of the hot gas stream by combustion of the combustible material is discontinued.
摘要翻译： 催化部分氧化或二次重整过程，其中在催化剂上游的燃烧器处建立火焰，通过合适的可燃材料的催化燃烧启动产生热气流，并直接或间接地使用来自气体的热 流将加入燃烧器的反应物加热至自燃温度。 在燃烧器已经建立火焰之后，停止通过可燃材料的燃烧产生热气流。
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公开(公告)号：US4729982A
公开(公告)日：1988-03-08
申请号：US924037
申请日：1986-10-28
IPC分类号： B01D53/04 , B01D53/047 , B01D53/18 , B01J19/30 , B01J20/28 , B01J23/745 , B01J23/78 , B01J35/02 , B01J37/08 , B01J23/74 , B01J35/04
CPC分类号： B01D53/02 , B01J19/30 , B01J23/745 , B01J23/78 , B01J37/08 , B01J2219/30223 , B01J2219/30296 , B01J2219/30416 , B01J2219/30475 , B01J2219/3085 , B01J2219/312
摘要： A bed packing material, e.g. for use as a catalyst precursor, in the form of regular, preferably cylindrical, units having a multiplicity of through passages of small cross section so that the units have a low voidage, GV, a high ratio of the geometric surface area, GSA, to the volume V, of the equivalent cylindrical unit having no passages, and a high ratio of GSA to the product of GV and the surface area, A, of the equivalent cylindrical unit having no passages.
摘要翻译： 床包装材料，例如 用作催化剂前体，呈规则的，优选为圆柱形的单元形式，具有多个具有小横截面的通孔，使得单元具有低的空隙率，GV，几何表面积的高比，GSA， 没有通道的等效圆柱形单元的体积V和GSA与GV的乘积和不具有通道的等效圆柱形单元的表面积A的高比率。
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公开(公告)号：US4200592A
公开(公告)日：1980-04-29
申请号：US916535
申请日：1978-06-19
CPC分类号： C07C45/50
摘要： This invention relates to catalytic hydroformylation reactions, for example the hydroformylation of internal olefins. In particular the invention relates to a process for the production of a straight chain aldehyde from an olefin comprising reacting the said olefin in a liquid reaction medium with hydrogen and carbon monoxide at a total pressure of less than 500 psig in the presence of a complex of Rh(I) in solution in the said medium and a homogeneous co-catalyst dissolved in said reaction medium comprising a co-ordination complex of a transition metal other than rhodium selected from Group 6 or Group 8 of the Periodic Table.The transition metal is, preferably, selected from the group consisting of Cr, Mo, W, Fe, Co, Pd, Pt and Ru.
摘要翻译： 本发明涉及催化加氢甲酰化反应，例如内烯烃的加氢甲酰化。 特别地，本发明涉及从烯烃生产直链醛的方法，包括在液体反应介质中的所述烯烃与氢和一氧化碳的总压力小于500psig的条件下，在 在所述介质中的溶液中的Rh（I）和溶解在所述反应介质中的均相助催化剂，其包含选自元素周期表第6族或第8族的铑以外的过渡金属的配位络合物。 过渡金属优选选自Cr，Mo，W，Fe，Co，Pd，Pt和Ru。
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公开(公告)号：US5048284A
公开(公告)日：1991-09-17
申请号：US378070
申请日：1989-07-11
CPC分类号： C01B3/386 , B01J8/0453 , B01J8/0492 , B01J8/0496 , F02B43/10 , F02C3/20 , B01J2208/0007 , B01J2208/00088 , B01J2208/0015 , B01J2208/00212 , B01J2208/00256 , B01J2208/00371 , B01J2208/00495 , B01J2208/00504 , B01J2208/0053 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/06 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/0866 , C01B2203/1023 , C01B2203/1052 , C01B2203/107 , C01B2203/1241 , C01B2203/1276 , C01B2203/142 , C01B2203/143 , C01B2203/148 , C01B2203/1604 , C01B2203/80 , C01B2203/82 , Y02P20/128 , Y02T10/32
摘要： At least during some part-load operation of a gas turbine wherein a fuel gas is combusted with air with the formation of a flame and the combustion products are let down through a turbine, the fuel gas comprises the product of a stage of catalytic autothermal steam reforming of a light hydrocarbon feedstock gas and the amount of air fed to the gas turbine combuster, relative to the amount of hydrocarbon fed to the catalytic autothermal steam reforming stage, is greater than the maximum amount of air that enables a flame to be sustained in said combustor if that amount of hydrocarbon were to be fed directly to the combustor.
摘要翻译： 至少在燃气轮机的一些部分负载运行期间，其中燃料气体与形成火焰的空气一起燃烧并且燃烧产物通过涡轮机通入，燃料气体包括催化自热蒸汽阶段 轻烃原料气体的重整和供给到燃气轮机燃烧器的空气量相对于进料到催化自热蒸汽重整段的烃的量大于能够维持火焰的最大空气量 如果将该量的烃直接供给到燃烧器，则说明燃烧器。
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公开(公告)号：US4743578A
公开(公告)日：1988-05-10
申请号：US925911
申请日：1986-11-03
申请人： Peter J. Davidson
发明人： Peter J. Davidson
CPC分类号： C01B3/40 , B01J19/32 , B01J35/02 , B01J35/04 , B01J8/008 , B01J2208/00884 , B01J2219/32268 , B01J2219/32275 , B01J2219/32293 , B01J2219/32296 , B01J2219/32425 , B01J2219/32466 , C01B2203/1047 , Y02P20/142 , Y02P20/52 , Y10T428/24149
摘要： A self-supporting structure, particularly for use as a support for a catalyst, e.g. for secondary steam reforming of hydrocarbons, comprises an assembly of interlocking units, preferably of prismatic polygonal, e.g. hexagonal, configuration. Each unit is provided with projections in its upper part enabling the unit to be supported on a complementary projection in the lower part of an adjacent unit and/or on a supporting member of a vessel containing the assembly. As the structure heats or cools, expansion and contraction of the units relative to the containing vessel is accommodated by the structure bowing.
摘要翻译： 自支撑结构，特别是用作催化剂的载体，例如， 用于烃的二次蒸汽重整，包括互锁单元的组件，优选为棱柱形多边形，例如， 六角形，配置。 每个单元在其上部设置有突起，使得单元能够支撑在相邻单元的下部中的互补突起和/或在容纳组件的容器的支撑构件上。 当结构加热或冷却时，单元相对于容纳容器的膨胀和收缩由结构弯曲来容纳。
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8.发明授权
公开(公告)号：US5355275A
公开(公告)日：1994-10-11
申请号：US809908
申请日：1991-12-20
CPC分类号： H01F6/06 , H02H9/023 , H01F2006/001 , Y02E40/69 , Y10S336/01
摘要： A variable impedance device comprises a coil (10) and an associated magnetic circuit (16) having a gap receiving a plate (20) of superconducting material which acts as a shield or barrier so that, while the plate (20) is in its superconducting state, magnetic flux is caused to traverse the gap via pathways substantially greater in length than the width of the gap. If a large current is passed through the coil (10), the plate (20) becomes resistive thereby presenting a substantially increased impedance to the current. The device may be used in current limiting applications, or other applications where a variable impedance is required.
摘要翻译： 可变阻抗装置包括线圈（10）和相关联的磁路（16），该磁路具有接纳超导材料的板（20）的间隙，其作为屏蔽或屏障，使得当板（20）处于超导 状态下，使磁通量通过比间隙的宽度大得多的路径穿过间隙。 如果大电流通过线圈（10），则板（20）变得电阻性，从而对电流呈现显着增加的阻抗。 该器件可用于限流应用或需要可变阻抗的其他应用中。
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公开(公告)号：US4772579A
公开(公告)日：1988-09-20
申请号：US924038
申请日：1986-10-28
IPC分类号： B01J8/02 , B01D53/18 , B01J19/30 , B01J23/745 , B01J23/78 , B01J35/02 , B01J35/04 , C01C1/04 , C07C67/00 , C07C209/00 , C07C209/48 , C07C211/09 , B01J23/70 , B01J21/04 , B01J21/08 , B01J23/00
CPC分类号： B01J35/026 , B01J19/30 , B01J23/745 , B01J2219/30223 , B01J2219/30296 , B01J2219/30416 , B01J2219/30475 , B01J2219/3085
摘要： Catalyst precursor units, e.g. for ammonia synthesis catalysts, comprise an iron oxide composition in the form of sintered shaped units of substantially uniform cross section having a plurality, e.g. 13 to 50 or more, through passages of substantially uniform cross section. The passages preferably have a diameter of less than 1.5, particularly less than 0.7, mm.
摘要翻译： 催化剂前体单元，例如 对于氨合成催化剂，包含具有基本上均匀横截面的烧结成形单元形式的氧化铁组合物，其具有多个例如 13至50或更多，通过基本上均匀横截面的通道。 通道优选具有小于1.5，特别是小于0.7mm的直径。
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公开(公告)号：US4340501A
公开(公告)日：1982-07-20
申请号：US183414
申请日：1980-09-02
申请人： Peter J. Davidson
发明人： Peter J. Davidson
IPC分类号： C10G35/04 , B01J12/00 , B01J15/00 , B01J19/24 , B01J19/32 , B01J35/04 , C01B3/38 , F28F1/40 , F28F13/06 , C01B3/34
CPC分类号： F28F13/06 , B01J12/007 , B01J15/005 , B01J19/2415 , B01J19/32 , B01J35/04 , C01B3/384 , B01J2219/00085 , B01J2219/185 , B01J2219/32206 , B01J2219/3221 , B01J2219/32213 , B01J2219/32227 , B01J2219/32296 , B01J2219/32466 , C01B2203/0233 , C01B2203/0811 , C01B2203/0816 , C01B2203/0866 , C01B2203/1023 , C01B2203/1035 , C01B2203/1052 , C01B2203/1064 , C01B2203/1082 , C01B2203/1235 , F01N2330/34 , Y02P20/52 , Y10T428/24149
摘要： A process and apparatus for contacting a fluid with the walls of a vessel are characterized by flow of the fluid alternatingly (a) through a structure within the vessel and having passages angled to the general direction of flow in the vessel and (b) through a space between the structure and the vessel walls. The structure can be for example a cross flow ceramic or metal honeycomb or a stack of profiled plates or of apertured plates such as expanded metal. The structure can carry a catalytic coating and then affords high activity and low pressure drop. The process and apparatus are especially suitable for endothermic tubular steam hydrocarbon reforming.
摘要翻译： 用于使流体与容器的壁接触的方法和装置的特征在于，流体交替地（a）流过容器内的结构，并具有与容器中的大体流动方向成一定角度的通道，（b）通过 结构和血管壁之间的空间。 该结构可以是例如交叉流动陶瓷或金属蜂窝体或成型板或多孔板如多孔金属的堆叠。 该结构可以进行催化涂层，然后提供高活性和低压降。 该方法和装置特别适用于吸热管式蒸汽烃重整。
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