摘要:
The present invention relates generally to a novel process for making a solid solventless MQ resin comprising the steps of (1)(A) feeding at least one MQ resin dispersed in a volatile solvent into an extrusion device, (2) removing the volatile solvent to form a solid solventless MQ resin; and (3) recovering the solid solventless MQ resin, provided steps (1) to (3) are completed without the addition of a linear silicone fluid.
摘要:
This invention relates to a flame retardant composition comprising: (a) 81 to 99.99 weight percent of a thermoplastic resin, thermoset resin, thermoplastic resin blend, or thermoset resin blend which upon burning forms a char and (b) 0.01-19 weight percent of a silsesquioxane resin having a weight average molecular weight of greater than 300.
摘要:
Thermal curable compositions contains a glycidyl ether epoxide resin, a carbinol functional silicone resin or an anhydride functional silicone resin, and a thermal catalyst. An organic polyol, an organic anhydride, and filler, are optional components that may also be included in the composition. The glycidyl ether epoxide resin adds toughness and adhesion to the composition, whereas the carbinol functional silicone resin and the anhydride functional silicone resin provide water resistance, weatherability, thermal stability, and flexibility.
摘要:
A silicone composition comprising (A) 100 parts by weight of a polydiorganosiloxane containing an average of at least two silicon-bonded alkenyl groups per molecule; (B) 75 to 150 parts by weight of an organopolysiloxane resin having a number-average molecular weight of from 2,000 to 5,000 and consisting essentially of R.sup.3.sub.2 R.sup.4 SiO.sub.1/2 units and SiO.sub.4/2 units wherein each R.sup.3 is independently selected from the group consisting of monovalent hydrocarbon and monovalent halogenated hydrocarbon groups free of aliphatic unsaturation, R.sup.4 is selected from the group consisting of R.sup.3 and alkenyl, the mole ratio of R.sup.3.sub.2 R.sup.4 SiO.sub.1/2 units to SiO.sub.4/2 units is from 0.6:1 to 1.1:1, and the resin contains an average of from 2.5 to 7.5 mole percent of alkenyl groups; (C) an organohydrogenpolysiloxane having an average of at least three silicon-bonded hydrogen atoms per molecule in an amount sufficient to provide from one to three silicon-bonded hydrogen atoms per alkenyl group in components (A) and (B) combined; (D) an adhesion promoter in an amount sufficient to effect adhesion of the composition to a substrate; and (E) a hydrosilylation catalyst in an amount sufficient to cure the composition.
摘要:
A moisture-curable silicone hot melt pressure-sensitive adhesive composition is disclosed, said composition comprising(i) a solid hydroxyl-functional organopolysiloxane resin comprising R.sub.3 SiO.sub.1/2 siloxane units and SiO.sub.4/2 siloxane units in a molar ratio of 0.5/1 to 1.2/1, respectively, wherein R is selected from hydrocarbon and halogenated hydrocarbon radicals and said hydroxyl content is 1.2 to 6 percent by weight;(ii) an alkoxy-functional diorganopolysiloxane polymer having a viscosity at 25.degree. C. of 20 to
摘要:
Solventless silicone resins, which exhibit a high degree of reconstitution, are produced in forms such as powders and flakes. The degree of reconstitution is judged by the fact that silicone resin/fluid alloys produced therefrom exhibit only a minor shift in T.sub.g, the glass transition temperature, in comparison to analogous alloys produced from solvent dispersed (virgin) resin. Resin, and preferably virgin resin, is dispersed in a volatile liquid dispersant and blended with a nonvolatile silicone fluid. Thereafter, the volatile liquid dispersant is removed by means such as spray-drying or evaporation, resulting in the solventless resin forms of the invention.
摘要:
A coating composition contains a carbamate-functional film-forming material, a carbinol-functional, nonlinear siloxane resin, and an aminoplast crosslinking agent. The composition provides excellent high-bake repair adhesion of a repair-coating layer over the initial coating.
摘要:
A radiation or thermal curable coating composition contains a cycloaliphatic epoxide resin, a carbinol functional silicone resin or an anhydride functional silicone resin, and a thermal or photoactivated acid catalyst. An organic polyol may also be included in the composition as an optional component. The composition is useful as a radiation curable coating, as an adhesive, a photodefinable coating, or as a thermal cure coating. The cycloaliphatic epoxide resin adds toughness and adhesion to the composition, whereas either of the carbinol functional silicone resin or the anhydride functional silicone resin provides the composition with water resistance, weatherability, thermal stability, and flexibility.
摘要:
A planar optical waveguide assembly prepared by a method comprising the steps of (i) applying a curable polymer composition to a surface of a substrate to form a polymer film; (ii) curing the polymer film to form a lower clad layer; (iii) applying a silicone composition to the lower clad layer to form a silicone film; (iv) exposing at least one selected region of the silicone film to radiation having a wavelength of from 150 to 800 nm to produce a partially exposed film having at least one exposed region and at least one non-exposed region; (v) removing the non-exposed region of the partially exposed film with a developing solvent to form a patterned film; and (vi) heating the patterned film for an amount of time sufficient to form at least one silicone core having a refractive index of from 1.3 to 1.7 at 23° C. for light having a wavelength of 589 nm; wherein the lower clad layer has a refractive index less than the refractive index of the silicone core.
摘要:
This invention relates to methods for preparing polyheterosiloxane materials having at least two different non-Si metal elements. The polyheterosiloxane materials prepared by these methods are solid materials which can be easily dispersed in a solvent of choice.