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    Thermoplastic molding compositions based on polyesters and polycarbonate
    2.
    发明授权
    Thermoplastic molding compositions based on polyesters and polycarbonate 失效
    基于聚酯和聚碳酸酯的热塑性模塑组合物

    公开(公告)号：US6031031A

    公开(公告)日：2000-02-29

    申请号：US146197

    申请日：1998-09-03

    申请人： Martin Weber ,  Rolf Mulhaupt

    发明人： Martin Weber ,  Rolf Mulhaupt

    IPC分类号： C08L23/02 ,  C08L67/02 ,  C08L69/00 ,  C08F20/00

    CPC分类号： C08L67/02 ,  C08L69/00 ,  C08L23/025

    摘要： A thermoplastic molding composition comprisesA) from 1 to 97% by weight of a thermoplastic polyesterB) from 1 to 97% by weight of a polycarbonateC) from 1 to 40% by weight of an elastomer containing oxazoline groups and having a glass transition temperature (T.sub.g).ltoreq.0.degree. C.D) from 0.05 to 5% by weight of a bisoxazolineE) from 0 to 70% by weight of other additives and processing aids,where the total of the percentages by weight of components A) to E) is 100%.

    摘要翻译： 热塑性模塑组合物包含A）1至97重量％的热塑性聚酯B）1至97重量％的聚碳酸酯C）1至40重量％的含有恶唑啉基并具有玻璃化转变的弹性体 温度（Tg）

    Moisture curable polyurethane resin having a compound or an oxazolidine containing silane group
    3.
    发明授权
    Moisture curable polyurethane resin having a compound or an oxazolidine containing silane group 失效
    具有化合物或含恶唑烷的硅烷基的水溶性聚氨酯树脂

    公开(公告)号：US5128423A

    公开(公告)日：1992-07-07

    申请号：US716713

    申请日：1991-06-17

    申请人： Giovanni Parrinello ,  Rolf Mulhaupt ,  Hubert Simon

    发明人： Giovanni Parrinello ,  Rolf Mulhaupt ,  Hubert Simon

    IPC分类号： C07F7/18 ,  C08G18/10 ,  C08G18/83 ,  C08K5/544 ,  C08L75/00 ,  C08L75/04 ,  C09J175/00 ,  C09J175/04

    CPC分类号： C08G18/10 ,  C07F7/1836 ,  C08K5/5442 ,  Y10T442/2803

    摘要： Compounds of the general formula I ##STR1## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.7 cycloalkyl, phenyl or benzyl,R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl, orR.sub.1 and R.sub.2, together with the linking carbon atom, form a 5- or 6-membered ring, andR.sub.3, R.sub.4, R.sub.5 and R.sub.6 are identical or different and are hydrogen, C.sub.1 -C.sub.12 alkyl, phenyl or phenyl substituted by 1 to 3 members selected from the group consisting of C.sub.1 -C.sub.4 alkyl, halogen or C.sub.1 -C.sub.4 alkoxy or are a group of formula --CH.sub.2 OR.sub.11, where R.sub.11, where R.sub.11 is C.sub.1 -C.sub.12 alkyl, phenyl or phenyl substituted by 1 to 3 members selected from the group consisting of C.sub.1 -C.sub.4 alkyl, halogen or C.sub.1 -C.sub.4 alkoxy, or are --C(O)--R.sub.12, and R.sub.12, and R.sub.12 is C.sub.1 -C.sub.12 alkyl,R.sub.7 is C.sub.1 -C.sub.4 alkylene, R.sub.8 is C.sub.1 -C.sub.8 alkylene, R.sub.9 is C.sub.1 -C.sub.4 alkyl, or two radicals R.sub.9 together are C.sub.1 -C.sub.4 alkylene, and R.sub.10 is C.sub.1 -C.sub.4 alkyl or phenyl,q is a value from 0 to 2,X is --S--or --NH--,Y is O or S, andZ is an organic radical which is derived from a polyisocyanate or a polyisothiocyanate containing at least three three NCO or NCS groups respectively,n is a value.gtoreq.1 and m is a value .gtoreq.1, with the proviso that n+m.gtoreq.3, are suitable for use as couplers, especially for moisture-curable polyurethane resins.

    摘要翻译： 通式I的化合物其中R 1是氢，C 1 -C 12烷基，C 5 -C 7环烷基，苯基或苄基，R 2是氢或C 1 -C 4烷基，或者R 1和R 2与连接碳 原子形成5-或6-元环，并且R 3，R 4，R 5和R 6相同或不同，为氢，C 1 -C 12烷基，苯基或被1至3个选自C 1 -C 4烷基 ，卤素或C 1 -C 4烷氧基，或者是式-CH 2 OR 11的基团，其中R 11，其中R 11是C 1 -C 12烷基，苯基或被1至3个选自C 1 -C 4烷基，卤素或C 1 -C 4烷氧基的苯基取代的苯基， 或者是-C（O）-R 12，R 12和R 12是C 1 -C 12烷基，R 7是C 1 -C 4亚烷基，R 8是C 1 -C 8亚烷基，R 9是C 1 -C 4烷基或两个基团R 9一起是C 1 -C 4亚烷基，R 10 是C 1 -C 4烷基或苯基，q是0至2的值，X是-S-或-NH-，Y是O或S，Z是衍生自至少含有多异氰酸酯或多异硫氰酸酯的有机基团 第三个 ree NCO或NCS基团，n是值> / = 1，m是值> / = 1，条件是n + m> / = 3，适合用作成色剂，特别是用于湿固化聚氨酯 树脂。

    Novel oxazolidines
    5.
    发明授权
    Novel oxazolidines 失效
    新型恶唑烷

    公开(公告)号：US4874805A

    公开(公告)日：1989-10-17

    申请号：US212853

    申请日：1988-06-29

    申请人： Rolf Mulhaupt ,  Hubert Simon

    发明人： Rolf Mulhaupt ,  Hubert Simon

    IPC分类号： C07F7/18 ,  C08G18/10 ,  C08G18/61 ,  C08G59/40 ,  C08K5/54

    CPC分类号： C08G18/10 ,  C07F7/1836 ,  C08K5/54

    摘要： Compounds of the general formula I ##STR1## in which R.sup.1 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, phenyl or benzyl and R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl, or R.sup.1 and R.sup.2, together with the C atom to which they are attached, form a 5-membered or 6-membered ring, and R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are identical or different and are hydrogen, C.sub.1 -C.sub.12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy, or is a group of the formula --CH.sub.2 OR.sup.7 (II) in which R.sup.7 is C.sub.1- C.sub.12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy, or is --C(O)--R.sup.8, and R.sup.8 is C.sub.1 -C.sub.12 -alkyl, and also not more than two of the radicals R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are one or two groups of the formula --CH.sub.2 CH.sub.2 Si(OR.sup.9).sub.3 (III), --CH.sub.2 OC(O)CH.sub.2 Si(OR.sup.9).sub.3 (IV), --Ch.sub.2 O(C.sub.m H.sub.2m)Si(OR.sup.9).sub.3 (V) or ##STR2## in which R.sup.9 is C.sub.1 -C.sub.4 -alkyl or phenyl and m is a number from 1 to 8 and r is a number 1 or 2 and t is 0, 1, or 2 and R.sup.1 is as defined above, and, in addition, compounds of the formula I in which R.sup.4 and R.sup.5 together from a group of the formula ##STR3## in which R.sup.9 is as defined above and R.sup.3 and R.sup.6 in this case are hydrogen and n is 1 or 2 and, if n is 1, Z is an organic radical which is derived from a primary amine ZNH.sub.2 and can contain one or two --Si(OR.sup.9).sub.3 groups and, if n is 2, Z is a divalent organic radical derived from a diprimary diamine H.sub.2 NZNH.sub.2 ; subject to the proviso that the compounds of the formula I contain one to three --Si(OR.sup.9).sub.3 groups, are suitable for use as adhesion promoters, particularly for moisture-curing epoxide and polyurethane resins.

    摘要翻译： 其中R 1是氢，C 1 -C 12 - 烷基，C 5 -C 7 - 环烷基，苯基或苄基和R 2是通式I（I）的化合物是氢或C 1 -C 4烷基，或者R 1和R 2一起 与其连接的C原子形成5元或6元环，并且R 3，R 4，R 5和R 6相同或不同，为氢，C 1 -C 12 - 烷基，未取代或单取代至 或被C1-C4烷基，卤素或C1-C4-烷氧基三取代，或者是其中R 7为C 1 -C 12 - 烷基的式-CH 2 OR 7（II）基团，未取代或单取代至被C1-C4三取代的苯基 - 烷基，卤素或C 1 -C 4 - 烷氧基，或者是-C（O）-R 8，并且R 8是C 1 -C 12烷基，并且不多于两个基团R 3，R 4，R 5和R 6是一个或两个 （OR9）3（III），-CH2OC（O）CH2Si（OR9）3（IV），-Ch2O（CmH2m）Si（OR9）3（V）或（VI））的基团，其中 R 9为C 1 -C 4烷基或苯基，m为1至8的数，r为数1或2，t为0,1或2，R 1如上定义， d，此外，其中R 4和R 5一起来自其中R 9如上所定义的式Ⅶ（Ⅶ）基团和R 3和R 6在这种情况下的式I化合物是氢，n是1或2 并且如果n是1，Z是衍生自伯胺ZNH 2的有机基团，并且可以含有一个或两个-Si（OR 9）3基团，并且如果n是2，Z是衍生自二原子​​的二价有机基团 二胺H 2 NZNH 2; 条件是式I化合物含有一至三个-Si（OR9）3基团，适用于粘合促进剂，特别是用于湿固化环氧化物和聚氨酯树脂。

    Oxazolidines containing silane groups
    6.
    发明授权
    Oxazolidines containing silane groups 失效
    含有硅烷基的恶唑烷

    公开(公告)号：US4772716A

    公开(公告)日：1988-09-20

    申请号：US70741

    申请日：1987-07-06

    申请人： Rolf Mulhaupt ,  Hubert Simon

    发明人： Rolf Mulhaupt ,  Hubert Simon

    IPC分类号： C07F7/18 ,  C08G18/10 ,  C08G18/61 ,  C08G59/40 ,  C08K5/54

    CPC分类号： C08G18/10 ,  C07F7/1836 ,  C08K5/54

    摘要： Compounds of the general formula I ##STR1## in which R.sup.1 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, phenyl or benzyl and R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl, or R.sup.1 and R.sup.2, together with the C atom to which they are attached, form a 5-membered or 6-membered ring, and R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are identical or different and are hydrogen, C.sub.1 -C.sub.12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy, or is a group of the formula --CH.sub.2 OR.sup.7 (II) in which R.sup.7 is C.sub.1 -C.sub.12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy, or is --C(O)--R.sup.8, and R.sup.8 is C.sub.1 -C.sub.12 -alkyl, and also not more than two of the radicals R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are one or two groups of the formula --CH.sub.2 CH.sub.2 Si(OR.sup.9).sub.3 (III), --CH.sub.2 OC(O)CH.sub.2 CH.sub.2 Si(OR.sup.9).sub.3 (IV), --CH.sub.2 O(C.sub.m H.sub.2m)Si(OR.sup.9).sub.3 (V) or ##STR2## in which R.sup.9 is C.sub.1 -C.sub.4 -alkyl or phenyl and m is a number from 1 to 8 and r is a number 1 or 2 and t is 0, 1 or 2 and R.sup.1 is as defined above, and, in addition, compounds of the formula I in which R.sup.4 and R.sup.5 together form a group of the formula ##STR3## in which R.sup.9 is as defined above and R.sup.3 and R.sup.6 in this case are hydrogen and n is 1 or 2 and, if n is 1, Z is an organic radical which is derived from a primary amine ZnH.sub.2 and can contain one or two --Si(OR.sup.9).sub.3 groups and, if n is 2, Z is a divalent organic radical derived from a diprimary diamine H.sub.2 NZNH.sub.2 ; subject to the proviso that the compounds of the formula I contain one to three --Si(OR.sup.9).sub.3 groups, are suitable for use as adhesion promoters, particularly for moisture-curing epoxide and polyurethane resins.

    摘要翻译： 其中R 1是氢，C 1 -C 12 - 烷基，C 5 -C 7 - 环烷基，苯基或苄基和R 2是通式I（I）的化合物是氢或C 1 -C 4烷基，或者R 1和R 2一起 与其连接的C原子形成5元或6元环，并且R 3，R 4，R 5和R 6相同或不同，为氢，C 1 -C 12 - 烷基，未取代或单取代至 或被C1-C4烷基，卤素或C1-C4-烷氧基三取代，或者是其中R 7为C 1 -C 12 - 烷基的式-CH 2 OR 7（II）基团，未取代或单取代至被C1-C4三取代的苯基 - 烷基，卤素或C 1 -C 4 - 烷氧基，或者是-C（O）-R 8，并且R 8是C 1 -C 12烷基，并且不多于两个基团R 3，R 4，R 5和R 6是一个或两个 （OR9）3（III），-CH2OC（O）CH2CH2Si（OR9）3（IV），-CH2O（CmH2m）Si（OR9）3（V）或（VI））的基团，其中 R 9为C 1 -C 4烷基或苯基，m为1〜8的数，r为数1或2，t为0,1或2，R 1如上所述， 另外，其中R 4和R 5一起形成其中R 9如上所定义并且R 3和R 6在这种情况下为氢且n为1或2的式Ⅶ（Ⅶ）的基团的式I化合物 并且如果n是1，Z是衍生自伯胺ZnH 2的有机基团，并且可以含有一个或两个-Si（OR 9）3基团，并且如果n是2，Z是衍生自二原子​​的二价有机基团 二胺H 2 NZNH 2; 条件是式I化合物含有一至三个-Si（OR9）3基团，适用于粘合促进剂，特别是用于湿固化环氧化物和聚氨酯树脂。

    Process for preparing biocompatible polyurea
    8.
    发明申请
    Process for preparing biocompatible polyurea 审中-公开
    制备生物相容性聚脲的方法

    公开(公告)号：US20060122367A1

    公开(公告)日：2006-06-08

    申请号：US10525953

    申请日：2003-08-07

    申请人： Rolf Mulhaupt ,  Jacobus Loontjens ,  Steffen Maier ,  Jorg Zimmermann

    发明人： Rolf Mulhaupt ,  Jacobus Loontjens ,  Steffen Maier ,  Jorg Zimmermann

    IPC分类号： C08G73/00

    CPC分类号： C08G71/02

    摘要： A process is provided for preparing urea-containing polymers by contacting a hydroxy-functional organic compound having a functionality of two or more, with a coupling agent in the presence of a strong base, wherein the coupling agent is a carbonylbislactam compound having the general formula (I): wherein n is an integer from 3 to 15, and that the contacting is conducted at a temperature between 0° C. and 80° C. The polymers thus obtained are believed to be new and are useful e.g. in tissue engineering and coatings applications.

    摘要翻译： 提供了一种制备含尿素聚合物的方法，其通过使具有两个或多个官能度的羟基官能的有机化合物与强碱的存在下与偶联剂接触，其中偶联剂是具有通式的羰基双内酰胺化合物 （I）：其中n为3至15的整数，并且接触在0℃至80℃之间的温度下进行。由此获得的聚合物被认为是新的，可用于例如 在组织工程和涂料应用中。

    Phenol-terminated polyurethane or polyurea(urethane) with epoxy resin
    9.
    发明授权
    Phenol-terminated polyurethane or polyurea(urethane) with epoxy resin 失效
    苯酚封端的聚氨酯或聚脲（聚氨酯）与环氧树脂

    公开(公告)号：US5278257A

    公开(公告)日：1994-01-11

    申请号：US823513

    申请日：1992-01-21

    申请人： Rolf Mulhaupt ,  Jeremy H. Powell ,  Christopher S. Adderley ,  Werner Rufenacht

    发明人： Rolf Mulhaupt ,  Jeremy H. Powell ,  Christopher S. Adderley ,  Werner Rufenacht

    IPC分类号： C08L9/00 ,  C08L63/00 ,  C08L75/00 ,  C09J175/00 ,  C08L9/02 ,  C08L63/02 ,  C08L75/02 ,  C08L75/08

    CPC分类号： C09J175/00 ,  C08L63/00 ,  C08L75/00 ,  C08L9/00

    摘要： Compositions containing A) a copolymer based on at least one 1,3-diene and at least one polar, ethylenically unsaturated comonomer and B) a phenol-terminated polyurethane, polyurea or polyurea-urethane of the formula I ##STR1## in which m is 1 or 2, n is 2 to 6, R.sup.1 is the n-valent radical of an elastomeric prepolymer which is soluble or dispersible in epoxide resins, X and Y independently of one another are --O-- or --NR.sup.3 --, it being necessary for one of these groups to be --NR.sup.3 --, R.sup.2 is an m+1-valent radical of a polyphenol or aminophenol after the removal of the phenolic hydroxy group(s) or the amino group or both the amino group and the phenolic hydroxyl group, respectively, and R.sup.3 is hydrogen, C.sub.1 -C.sub.6 alkyl or phenyl, are described.Compounds containing the components A) and B) as well as an epoxide resin C) are also described.The cured products are distinguished by a high peel strength and high resistance to crack propagation. The curable compositions can be employed, for example, as structural adhesives.

    摘要翻译： 含有A）基于至少一种1,3-二烯和至少一种极性烯属不饱和共聚单体的共聚物和B）式I的苯酚封端的聚氨酯，聚脲或聚脲 - 氨基甲酸酯（*化学结构*）（ I），其中m为1或2，n为2至6，R 1为在环氧树脂中可溶或可分散的弹性体预聚物的n价基团，X和Y彼此独立地为-O-或-NR 3 - ，这些基团中的一个为-NR 3 - ，除去酚羟基或氨基或氨基后，多酚或氨基苯酚的m + 1价基团是必需的 和酚羟基，R 3为氢，C 1 -C 6烷基或苯基。 还描述了含有组分A）和B）以及环氧树脂C）的化合物。 固化产物的特征在于高剥离强度和高抗裂纹扩展性。 可固化组合物可以用作例如结构粘合剂。