公开(公告)号：US06262214B1

公开(公告)日：2001-07-17

申请号：US09297062

申请日：1999-04-29

申请人： Akira Yanagase ,  Seiji Tone ,  Toru Tokimitsu

发明人： Akira Yanagase ,  Seiji Tone ,  Toru Tokimitsu

IPC分类号： C08F22012

CPC分类号： G11B7/2542 ,  C08F220/28 ,  C08F222/20 ,  G02B1/04 ,  G02B5/3083 ,  G02B6/02033 ,  G11B7/1372 ,  G11B7/2533 ,  G11B7/2534 ,  G11B7/2578 ,  G11B7/2585 ,  G11B7/259 ,  G11B7/2595 ,  C08L33/14

摘要： A copolymer having low birefringence substantially consisting of a repeating unit represented by the following general formula (1) and a repeating unit of a (meth)acrylate: wherein, R1 represents a hydrogen atom or a hydrocarbon group having 1 to 25 carbon atoms, an alicyclic hydrocarbon group or a substituted hydrocarbon group.). This copolymer has low birefringence and low hydrophilia, is excellent in transparency, heat-resistance and mechanical strength, and can be applied to lenses, optical disks, optical fibers and the like.

摘要翻译： 一种基本上由下述通式（1）表示的重复单元和（甲基）丙烯酸酯的重复单元组成的双折射率低的共聚物，其中，R 1表示氢原子或碳原子数1〜25的烃基， 脂环族烃基或取代烃基）。 该共聚物的双折射率低，亲水性低，透明性，耐热性和机械强度优异，可以应用于透镜，光盘，光纤等。

公开(公告)号：US20100243458A1

公开(公告)日：2010-09-30

申请号：US12739083

申请日：2008-10-24

申请人： Katsuhiro Kojima ,  Eiko Okamoto ,  Yoshihiro Uozu ,  Seiji Tone ,  Hideki Masuda ,  Takashi Yanagishita ,  Hiroaki Kita ,  Hisakazu Ito ,  Kota Shirai ,  Masayuki Saeki

发明人： Katsuhiro Kojima ,  Eiko Okamoto ,  Yoshihiro Uozu ,  Seiji Tone ,  Hideki Masuda ,  Takashi Yanagishita ,  Hiroaki Kita ,  Hisakazu Ito ,  Kota Shirai ,  Masayuki Saeki

IPC分类号： C25D11/18 ,  C25D11/12 ,  C25D11/16 ,  B28B3/02

CPC分类号： B29C33/3814 ,  B29C33/38 ,  B29C35/0888 ,  B29C35/10 ,  B29C39/148 ,  B29C43/222 ,  B29C59/046 ,  B29C2035/0827 ,  B29C2059/023 ,  B29K2905/02 ,  C25D5/02 ,  C25D9/06 ,  C25D11/04 ,  C25D11/12 ,  C25D11/18 ,  G02B1/118

摘要： Disclosed herein are a stamper which has anodized alumina formed on the surface thereof and which will not cause macroscopic unevenness or color unevenness on the transcribed surface; a method for producing the same; and a method for producing a molded material without macroscopic unevenness or color unevenness on the transcribed surface thereof by using such a stamper. The stamper includes alumina which has a microasperity structure and which is formed by anodization on the surface of a prototype aluminum mold having an aluminum purity of 99.5% or more, an average crystal-grain diameter of 1 mm or less, and an arithmetic mean surface roughness Ra of 0.05 μm or less. The use of this stamper enables the production of a molded material which does not have macroscopic unevenness or color unevenness on the transcribed surface thereof and which is suitable for use as an antireflection article and the like.

摘要翻译： 本文公开了在其表面上形成有阳极化氧化铝的压模，并且不会在转录表面上造成宏观的不均匀或颜色不均匀; 其制造方法; 以及通过使用这样的压模在其转录表面上制造没有宏观不均匀或颜色不均匀的模塑材料的方法。 压模包括氧化铝，其具有微细结构，并且通过在铝纯度为99.5％以上，平均晶粒直径为1mm以下的原型铝模具的表面上阳极氧化而形成的氧化铝，以及算术平均表面 粗糙度Ra为0.05μm以下。 使用该压模能够制造在其转录表面上不具有宏观不均匀性或颜色不均匀性并适合用作抗反射制品等的模塑材料。

公开(公告)号：US5177167A

公开(公告)日：1993-01-05

申请号：US465180

申请日：1990-02-22

申请人： Seiji Tone ,  Hiroshi Mori ,  Naoki Yamamoto ,  Haruko Takeda ,  Masahiro Sugimori

发明人： Seiji Tone ,  Hiroshi Mori ,  Naoki Yamamoto ,  Haruko Takeda ,  Masahiro Sugimori

IPC分类号： A61L27/18 ,  C08F293/00 ,  C08L53/00 ,  C08L55/00 ,  C09D153/00 ,  G02B1/04

CPC分类号： G02B1/043 ,  A61L27/18 ,  C08F293/005 ,  C08L53/00 ,  C08L55/005 ,  C09D153/00 ,  Y10T428/2913

摘要： The present invention provides shaped articles having good transparency and high oxygen permeability in a specific direction thereof, which have been made from a block copolymer (a) composed of a polyalkyl methacrylate segment and a silicone-based polymethacrylate segment, or a block copolymer (b) or graft copolymer (c) containing a polyorganosiloxane as one component, according to a process permitting the creation of a specific higher-order structure. These shaped articles have high oxygen permeability at relatively low silicone contents and, therefore, can provide oxygen-permeable products having high tear strength and surface hardness.

公开(公告)号：US5164452A

公开(公告)日：1992-11-17

申请号：US359704

申请日：1989-05-31

申请人： Seiji Tone ,  Haruko Takeda ,  Masahiro Sugimori

发明人： Seiji Tone ,  Haruko Takeda ,  Masahiro Sugimori

IPC分类号： C09K3/16 ,  C08F8/44 ,  C08F287/00 ,  C08F297/02 ,  C08F297/06 ,  C08F297/08

CPC分类号： C08F287/00 ,  C08F297/026

摘要： An antistatic agent capable of imparting a permanent antistatic property to a methacrylic resin is prepared as follows. First, an alkyl methacrylate is subjected to living polymerization in an atmosphere substantially free of water in the pressure of at least one compound acting as a source for supplying an anion selected from HF.sub.2.sup.-, (CH.sub.3).sub.3 SiF.sub.2.sup.- and F.sup.- by using as an initiator a compound represented by the formula (I) or (II): ##STR1## wherein R is H or CH.sub.3 and R.sup.1 is H or alkyl; second, a methacrylic acid ester comprising at least 80 mole % of a methacrylic acid ester represented by the formula (III): ##STR2## wherein R.sup.2 is alkyl and m is from 1 to 6, is subjected to living polymerization in the presence of the polymer obtained in the first step, to prepare a di-block or tri-block copolymer; and then, amino groups of segments derived from the methacrylic acid ester of the formula (III) in the block copolymer are quaternized.

公开(公告)号：US5116910A

公开(公告)日：1992-05-26

申请号：US711950

申请日：1991-06-07

申请人： Seiji Tone ,  Haruko Takeda ,  Masahiro Sugimori

发明人： Seiji Tone ,  Haruko Takeda ,  Masahiro Sugimori

IPC分类号： C08F265/06 ,  C08F290/04 ,  C08L33/12 ,  C08L51/00

CPC分类号： C08L33/12 ,  C08F265/06 ,  C08F290/046 ,  C08L51/00

摘要： A comb copolymer consisting of a methacrylic macromonomer as a branch ingredient and acrylic ester as a backbone ingredient and being suitable for an acrylic elastomer material which is excellent in transparency, weatherability and mechanical strength; an impact resistant acrylic resin composition obtained by blending the above comb copolymer with a PMMA (co)polymer; and a comb copolymer similarly consisting of a methacrylic macromonomer as a branch component and acrylic ester as a backbone component and being an acrylic resin which is excellent in transparency, weatherability, gloss and light resistance, are disclosed in this invention.Preparation methods of the high molecular weight comb copolymers useful for molding materials comprising the above mentioned comb copolymers are disclosed. The disclosed preparation methods comprise, in the copolymerization of the macromonomer having a vinyl group at one end of the main chain with a vinyl monomer, conducting aqueous suspension polymerization of the monomer mixture in the presence of an initiator in a solvent which is a good solvent for the macromonomer and has a solubility of 10% by weight or more in water at 30.degree. C., or conducting aqueous suspension polymerization of the monomer mixture in the presence of an initiator in a halogenated hydrocarbon solvent which is a good solvent for the macromonomer and has an azeotropic point with water ranging from 30.degree. to 90.degree. C. at a temperature above said azeotropic point.

公开(公告)号：US6160070A

公开(公告)日：2000-12-12

申请号：US230359

申请日：1999-01-25

申请人： Akira Yanagase ,  Seiji Tone ,  Toru Tokimitsu ,  Mitsufumi Nodono

发明人： Akira Yanagase ,  Seiji Tone ,  Toru Tokimitsu ,  Mitsufumi Nodono

IPC分类号： C08F2/38 ,  C08F20/12 ,  C08F120/18

CPC分类号： C08F20/12 ,  C08F2/38

摘要： Disclosed is a process for the preparation of a poly-(meth)acrylate ester, which comprises, upon polymerization of a (meth)acrylate ester by using an organometallic compound ((C.sub.5 Me.sub.5).sub.2 SmMe(thf) or the like) having at least one polymerization initiating site, carrying out the polymerization in the presence of a compound (acetophenone, 4-methyl-2-pentanone or the like), which contains in the molecule thereof a reactive hydrogen atom, as a chain transfer agent. The above-described process makes it possible to control the molecular weight easily, reduce the using amount of the organometallic compound, prevent the coloring of the poly(meth)acrylate ester and improve thermal decomposition resistance.

摘要翻译： PCT No.PCT / JP97 / 02574 Sec。 371日期1999年1月25日 102（e）日期1999年1月25日PCT提交1997年7月24日PCT公布。 第WO98 / 04595号公报 日期1998年2月5日公开是制备聚（甲基）丙烯酸酯的方法，其包括在使用有机金属化合物（（C5Me5）2SmMe（thf）等聚合（甲基）丙烯酸酯时） ）具有至少一个聚合引发位点，在其分子中含有反应性氢原子的化合物（苯乙酮，4-甲基-2-戊酮等）存在下进行聚合作为链转移剂 。 上述方法可以容易地控制分子量，减少有机金属化合物的使用量，防止聚（甲基）丙烯酸酯的着色，提高耐热分解性。

公开(公告)号：US5919867A

公开(公告)日：1999-07-06

申请号：US860326

申请日：1997-06-23

申请人： Hajime Yasuda ,  Eiji Ihara ,  Akira Yanagase ,  Hitoshi Ige ,  Seiji Tone ,  Toru Tokimitsu

发明人： Hajime Yasuda ,  Eiji Ihara ,  Akira Yanagase ,  Hitoshi Ige ,  Seiji Tone ,  Toru Tokimitsu

IPC分类号： C08F297/00 ,  C08F297/02 ,  C08F297/06

CPC分类号： C08F297/026 ,  C08F297/00 ,  C08F297/06

摘要： An A-B-A type of block copolymer consisting of polymer block A of (meth)acrylate and polymer block B of olefin, having a Mw/Mn of 1.0 to 2.5, is disclosed. This block copolymer can be produced by polymerizing an olefin using a particular rare earth compound as an initiator, and then polymerizing the formed polymer with a (meth)acrylate.

摘要翻译： PCT No.PCT / JP95 / 02630 Sec。 371日期：1997年6月23日 102（e）日期1997年6月23日PCT 1995年12月22日PCT PCT。 出版物WO96 / 日期：1996年6月27日公开了一种由（甲基）丙烯酸聚合物嵌段A和烯烃的聚合物嵌段B（Mw / Mn为1.0〜2.5）组成的A-B-A型嵌段共聚物。 该嵌段共聚物可以通过使用特定的稀土类化合物作为引发剂使烯烃聚合，然后与（甲基）丙烯酸酯聚合所形成的聚合物来制备。

公开(公告)号：US5336725A

公开(公告)日：1994-08-09

申请号：US901210

申请日：1992-06-19

申请人： Seiji Tone ,  Akira Nakata ,  Naoki Yamamoto

发明人： Seiji Tone ,  Akira Nakata ,  Naoki Yamamoto

IPC分类号： C08F265/06 ,  C08F220/18

CPC分类号： C08F265/06

摘要： A method for preparing a graft copolymer is here disclosed which is characterized by comprising the step of carrying out a living polymerization of at least one (meth)acrylic ester by the use of a polymeric compound as an initiator having one or more units represented by the following formula (I) in a molecular chain substantially in the absence of water in the presence of a Lewis acid or a donor compound of an anion selected from the group consisting of HF.sub.2.sup.-, (CH.sub.3).sub.3 SiF.sub.2.sup.- and F.sup.- : ##STR1## wherein R is hydrogen or an alkyl group having 1 to 6 carbon atoms, and R' is an alkyl group having 1 to 12 carbon atoms.

摘要翻译： 这里公开了制备接枝共聚物的方法，其特征在于包括通过使用聚合化合物作为引发剂进行至少一种（甲基）丙烯酸酯的活性聚合的步骤，所述聚合化合物是具有一个或多个由 在路易斯酸或选自HF 2 - ，（CH 3）3 SiF 2 - 和F - 的阴离子的供体化合物的存在下，基本上不存在水的分子链中的下式（I） （I）其中R是氢或具有1至6个碳原子的烷基，R'是具有1至12个碳原子的烷基。

公开(公告)号：US5187244A

公开(公告)日：1993-02-16

申请号：US381864

申请日：1989-07-19

申请人： Masahiro Sugimori ,  Haruko Takeda ,  Seiji Tone

发明人： Masahiro Sugimori ,  Haruko Takeda ,  Seiji Tone

IPC分类号： C08F279/02 ,  C08F290/06 ,  C08F293/00 ,  C08F297/02 ,  C08G77/42 ,  C08G77/442

CPC分类号： C08G77/442 ,  C08F290/068 ,  C08F293/00

摘要： A preparation process of block copolymers which comprises conducting living polymerization of a (meth)acrylic ester substantially in the absence of water, by using a macromolecular compound having a functional end group represented by the formula (1): ##STR1## Wherein R is H or an n-alkyl group having from 1 to 3 carbon atoms and R' is H or an alkyl group having from 1 to 6 carbon atoms, as a polymerization initiator and in the presence of a Lewis acid or in the presence of a donor compound of an anion selected from HF.sub.2.sup.-, (CH.sub.3).sub.3 SiF.sub.2.sup.- or F.sup.-, as well as novel block copolymers prepared therefrom are disclosed.

公开(公告)号：US5053461A

公开(公告)日：1991-10-01

申请号：US399992

申请日：1989-08-29

申请人： Seiji Tone ,  Haruko Takeda ,  Masahiro Sugimori

发明人： Seiji Tone ,  Haruko Takeda ,  Masahiro Sugimori

IPC分类号： C08F265/06 ,  C08F290/04 ,  C08L33/12 ,  C08L51/00

CPC分类号： C08L33/12 ,  C08F265/06 ,  C08F290/046 ,  C08L51/00

摘要： A comb copolymer consisting of a methacrylic macromonomer as a branch ingredient and acrylic ester as a backbone ingredient and being suitable for an acrylic elastomer material which is excellent in transparency, weatherability and mechanical strength; an impact resistant acrylic resin composition obtained by blending the above comb copolymer with a PMMA (co)polymer; and a comb copolymer similarly consisting of a methacrylic macromonomer as a branch component and acrylic ester as a backbone component and being an acrylic resin which is excellent in transparency, weatherability, gloss and light resistance, are disclosed in this invention.Preparation methods of the high molecular weight comb compolymers useful for molding materials comprising the above mentioned comb copolymers are disclosed. The disclosed preparation methods comprise, in the copolymerization of the macromonomer having a vinyl group at one end of the main chain with a vinyl monomer, conducting aqueous suspension polymerization of the monomer mixture in the presence of an initiator in a solvent which is a good solvent for the macromonomer and has a solubility of 10% by weight or more in water at 30.degree. C., or conducting aqueous suspension polymerization of the monomer mixture in the presence of an initiator in a halogenated hydrocarbon solvent which is a good solvent for the macromonomer and has an azeotropic point with water raning from 30.degree. to 90.degree. C. at a temperature above said azeotropic point.