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公开(公告)号：US08557014B2
公开(公告)日：2013-10-15
申请号：US12931277
申请日：2011-01-28
CPC分类号： C21B13/004 , C21B13/0026 , C21B13/0073 , C21B13/14 , C21C2100/02 , Y02P10/136
摘要： A carbonaceous-based metallizing method and apparatus wherein a metallic oxide is converted into a carbon-containing, metallized intermediate that is melted in an induction channel furnace to produce liquid metal from said metallic oxide. In the application of iron ore in the form of fines or concentrate, using low-cost coal will greatly reduce capital and operating costs by virtue of eliminating agglomeration of ore, cokemaking, and blast furnace operation. The liquid iron so produced is efficiently converted into steel in a steelmaking furnace such as a basic oxygen furnace (BOF), especially when it is physically integrated to the induction channel furnace wherein the liquid iron is directly poured into the integrated BOF by the induction channel furnace, producing low-cost steel, little heat loss, and minimum emissions.
摘要翻译： 一种碳质金属化方法和装置，其中将金属氧化物转化为在所述金属氧化物中在感应通道炉中熔化以产生液态金属的含碳金属化中间体。 在罚款或浓缩铁矿石的应用中，采用低成本煤炭，通过消除矿石团聚，高炉运行，大大降低资金和运营成本。 这样生产的液态铁在碱性氧气炉（BOF）等炼钢炉中有效地转化为钢，特别是当物理地与感应通道炉一体化时，通过感应通道将液态铁直接注入到集成BOF中 炉，生产低成本钢，热损失小，排放最少。
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2.发明申请Advanced method and apparatus for addressing the serious pollution from existing coal-burning power stations 审中-公开解决现有燃煤电厂严重污染的先进手段和方法公开(公告)号：US20130042615A1
公开(公告)日：2013-02-21
申请号：US13199034
申请日：2011-08-18
IPC分类号： F01K13/00 , B01D53/74 , B01D53/50 , B01D53/56 , C22C7/00 , C01B3/02 , B01J19/00 , B01J7/00 , C07C5/00 , C03C3/00 , B01D53/62 , C07C41/01
CPC分类号： C10K1/002 , B01D53/75 , B01D2251/208 , B01D2257/302 , B01D2257/404 , B01D2257/504 , B01D2257/602 , B01D2258/0283 , C01B3/24 , C01B2203/0266 , C01B2203/042 , C01B2203/0465 , C01B2203/06 , C01B2203/061 , C01B2203/062 , C01B2203/0872 , C01B2203/1258 , C05C11/00 , C05D9/00 , C07C231/00 , C07C233/00 , C10B49/02 , C10B53/06 , C10G2300/4043 , C10G2300/405 , C10J3/64 , C10J2300/094 , C10J2300/0956 , C10J2300/0969 , C10K1/004 , C10K1/005 , C10K1/20 , C10K1/32 , C10K3/008 , C10L1/026 , C10L1/04 , F02C3/28 , F23J15/02 , Y02E20/326 , Y02P20/152 , Y02P30/446 , C07C233/56
摘要： The present invention deals with the serious pollution problems from electric power plants that burn coal which may be forced to shut down by virtue of their being uneconomical to be retrofitted with expensive pollution controls. The pollutants from coal-burning power stations comprise SO2, NOx, Hg, Particulate Matter, Ash, and CO2. This invention offers a unique and comprehensive solution that makes possible the prevention of the ill-effects currently caused to health and environment while at the same time would also prevent the closure of these badly needed power generation facilities that provide some 50% of the electricity generated in this country. The herein comprehensive solution converts the six mentioned pollutants into valuable products and thus avoids the discharge of such pollutants into the atmosphere.
摘要翻译： 本发明涉及燃煤的严重污染问题，燃煤可能由于不经济而被迫关闭而被加以昂贵的污染控制。 燃煤电厂的污染物包括SO2，NOx，Hg，颗粒物，灰分和二氧化碳。 本发明提供了一种独特而全面的解决方案，可以预防目前对健康和环境造成的不良影响，同时也可以防止关闭这些急需的发电设施，提供大约50％的电力 在这个国家。 本综合解决方案将六种上述污染物转化为有价值的产品，从而避免将这些污染物排放到大气中。
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3.发明授权公开(公告)号：US08002033B2
公开(公告)日：2011-08-23
申请号：US12380669
申请日：2009-03-03
IPC分类号： E21B43/24 , E21B43/243
CPC分类号： E21B43/164 , E21B43/24 , E21B43/295
摘要： This method deals in recovering energy in-situ from an underground resource and upgrading such resource above ground. It consists of injecting a hot gas to pyrolyze it to produce gases and liquids with high hydrogen content and a residual hot char. The gases and liquids together with the injected hot gas form a mixture of gases and liquids that is brought above ground and treated into a clean mixture of gases and liquids rich in hydrogen and then used as a chemical feedstock and/or transportation fuel. Following the pyrolyzation of the resource, carbon dioxide and air are injected into the residual hot char to convert the CO2 into 2CO+N2, which is brought above ground and treated into a clean lean gas. This lean gas is used to generate efficient electric power, heat the injected gas for pyrolysis, and convert the 2CO+N2 as a feedstock into fertilizer.
摘要翻译： 这种方法涉及从地下资源原位回收能源，并将这些资源升级到地面以上。 它包括注入热气体来热解它以产生具有高氢含量的气体和液体以及残留的热焦炭。 气体和液体与注入的热气体一起形成气体和液体的混合物，该混合气体和液体被置于地面之上，并被处理成清洁的富含氢气的气体和液体的混合物，然后用作化学原料和/或运输燃料。 在资源热解之后，将二氧化碳和空气注入剩余的热焦炭中以将CO 2转化为2CO + N 2，将其置于地上并处理成干净的贫气。 这种贫气用于产生有效的电力，加热注入的气体进行热解，并将作为原料的2CO + N2转化为肥料。
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公开(公告)号：US20120047975A1
公开(公告)日：2012-03-01
申请号：US12807265
申请日：2010-09-01
摘要： A method and apparatus for continuously carbonizing materials while co-producing gases in a coking chamber closed to the atmosphere, having a charger at one end comprising a pushing ram surrounding a mandrel that surrounds an air or oxygen injection lance. The other end of the coking chamber collects and separates coke from gases, with coke directed to a closed quenching chamber and gases directed to a cleanup. Thermal energy for converting coal into coke derives from combusting some metallurgical coal by said lance. In the case of producing coke from metallurgical coal, which is expensive because of limited supply, the herein method and apparatus are configured to separately charge a low-cost, abundant, carbonizing material and expensive metallurgical coal so that metallurgical coal surrounds the low-cost carbonizing material, and a lance combusts the low-cost carbonizing material, releasing thermal energy that heats metallurgical coal under reducing conditions, producing specification coke and gases more economically. After cleanup, gases are used as chemical feedstock or fuel. The word “coke” herein used may also be referred to as “charcoal” or “char.”
摘要翻译： 一种用于连续碳化材料的方法和装置，同时在大气中的焦化室中共同生产气体，其一端具有充电器，包括围绕围绕空气或氧气注入喷枪的心轴的推动压头。 焦化室的另一端收集和分离焦炭与气体，焦炭被引导到封闭的淬火室，并将气体导向清洁。 将煤炭转化为焦炭的热能源是由所述喷枪燃烧一些冶金煤。 在由于供应有限而昂贵的冶金煤生产焦炭的情况下，本发明的方法和装置构造成分别对低成本，丰富的碳化材料和昂贵的冶金煤进行充电，使得冶金煤围绕低成本 碳化材料和喷枪燃烧低成本碳化材料，释放在还原条件下加热冶金煤的热能，更经济地制造规格的焦炭和气体。 清理后，使用气体作为化学原料或燃料。 这里使用的“焦炭”一词也可以称为“炭”或“炭”。
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公开(公告)号：US07967881B2
公开(公告)日：2011-06-28
申请号：US11880708
申请日：2007-07-24
CPC分类号： C10J3/00 , C01C3/003 , C05C9/00 , C05C11/00 , C10J3/26 , C10J3/34 , C10J3/62 , C10J2200/154 , C10J2300/093 , C10J2300/094 , C10J2300/0956 , C10J2300/0959 , C10J2300/0973 , C10J2300/16 , C10J2300/1634 , C10J2300/165 , C10J2300/1659 , C10J2300/1665 , C10J2300/1671 , C10J2300/1675 , C10J2300/1846 , C10J2300/1861 , C10J2300/1892 , F02C1/007 , F02C3/28 , Y02E20/16
摘要： A method and apparatus for gasifying a solid fuel within a pressurized gasifier without a lockhopper, a slurry or pulverization comprising the feeding of said fuel into a charging chamber having a first section equipped with a ram through which a mandrel is disposed, and a second section within which an impervious seal is formed from the solid fuel by the compressive forces generated by said ram and a third section into which the seal is advanced while said ram forms a successive seal in said second section. The seal from said third section is reduced in size and charged into the pressurized gasifier where it is gasified without loss of pressure. The gases produced are utilized to polygenerate products such as transport fuels and electric power, and a fertilizer from waste gas resulting from the combustion of one of the produced gases.
摘要翻译： 一种用于在加压气化器内气化固体燃料的方法和装置，其中没有锁匙，浆料或粉碎，其包括将所述燃料进料到带有第一部分的充电室中，所述第一部分装备有设置有心轴的冲头，第二部分 其中由固体燃料通过所述压头产生的压缩力和密封件前进的第三部分形成不透气密封件，同时所述冲头在所述第二部分中形成连续的密封。 来自所述第三部分的密封件的尺寸减小并且被装入加压气化器中，在气化器中气化而不会失去压力。 所生产的气体用于多种产品，如运输燃料和电力，以及来自由所生产的气体之一的燃烧产生的废气的肥料。
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6.发明申请公开(公告)号：US20100224369A1
公开(公告)日：2010-09-09
申请号：US12380669
申请日：2009-03-03
CPC分类号： E21B43/164 , E21B43/24 , E21B43/295
摘要： A method for recovering energy in-situ from underground resources such as coal and upgrading such energy above ground, comprising a first step consisting of injecting a hot recycling gas through said resource to devolatilize it to produce a raw hydrogen rich gas and an in-situ residual hot char wherein said hydrogen rich gas is brought above ground and is treated to become a cleaned, upgraded hydrogen rich gas serving as a feedstock to make a chemical and/or transportation fuel, and a second step consisting of injecting a waste greenhouse gas like carbon dioxide (CO2) plus an oxidant such as air into said hot char to convert said CO2 into CO+N2 which is brought above ground and treated to form a clean lean gas which can be beneficially used to: (i) generate efficient electric power, (ii) heat the hydrogen rich recycle gas, and (iii) make a needed by-product such as fertilizer.
摘要翻译： 一种从诸如煤等地下资源中原位回收能源的方法，其特征在于包括将热回收气体通过所述资源注入脱挥发分以产生富含原氢的气体和原位的第一步骤 残余热焦炭，其中所述富氢气体被置于地面以上并被处理成为清洁的，升级的富氢气体，用作原料以制备化学和/或运输燃料，以及第二步骤，其包括将诸如 二氧化碳（CO 2）和氧化剂如空气进入所述热焦炭以将所述CO 2转化成CO + N 2，所述CO + N 2被置于地面并进行处理以形成干净的贫气，其可有利地用于：（i）产生有效的电力 ，（ii）加热富氢循环气体，和（iii）制备所需的副产物如肥料。
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公开(公告)号：US20150061200A1
公开(公告)日：2015-03-05
申请号：US13987805
申请日：2013-09-05
IPC分类号： F27B19/00 , C21B11/10 , F27D3/00 , F27B7/12 , F27D7/00 , F27D11/06 , C21C7/00 , F27D15/00 , C21B11/06 , F27D3/04
CPC分类号： F27B7/12 , C21B13/004 , C21B13/143 , C21B2100/282 , C21B2100/42 , F27B19/04 , F27D3/0024 , F27D3/0025 , F27D7/00 , Y02P10/136
摘要： A metallizing apparatus which is carbonaceous-based wherein a metallic oxide is converted into a carbon-containing, metallized intermediate that is melted in an induction channel furnace to produce liquid metal from said metallic oxide. In the application of iron ore in the form of fines or concentrate, using low-cost coal will greatly reduce capital and operating costs by virtue of eliminating agglomeration of ore, cokemaking, and blast furnace operation. The liquid iron so produced is efficiently converted into steel in a steelmaking furnace such as a basic oxygen furnace (BOF), especially when it is physically integrated to the induction channel furnace wherein the liquid iron is directly poured into the integrated BOF by the induction channel furnace, producing low-cost steel, little heat loss, and minimum emissions.
摘要翻译： 一种基于碳质的金属化装置，其中将金属氧化物转化为含碳的金属化中间体，其在诱导通道炉中熔化以从所述金属氧化物生产液态金属。 在罚款或浓缩铁矿石的应用中，采用低成本煤炭，通过消除矿石团聚，高炉运行，大大降低资金和运营成本。 这样生产的液态铁在碱性氧气炉（BOF）等炼钢炉中有效地转化为钢，特别是当物理地与感应通道炉一体化时，通过感应通道直接将液态铁倒入集成BOF 炉，生产低成本钢，热损失小，排放最少。
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公开(公告)号：US20120192677A1
公开(公告)日：2012-08-02
申请号：US12931277
申请日：2011-01-28
CPC分类号： C21B13/004 , C21B13/0026 , C21B13/0073 , C21B13/14 , C21C2100/02 , Y02P10/136
摘要： A carbonaceous-based metallizing method and apparatus wherein a metallic oxide is converted into a carbon-containing, metallized intermediate that is melted in an induction channel furnace to produce liquid metal from said metallic oxide. In the application of iron ore in the form of fines or concentrate, using low-cost coal will greatly reduce capital and operating costs by virtue of eliminating agglomeration of ore, cokemaking, and blast furnace operation. The liquid iron so produced is efficiently converted into steel in a steelmaking furnace such as a basic oxygen furnace (BOF), especially when it is physically integrated to the induction channel furnace wherein the liquid iron is directly poured into the integrated BOF by the induction channel furnace, producing low-cost steel, little heat loss, and minimum emissions.
摘要翻译： 一种碳质金属化方法和装置，其中将金属氧化物转化为在所述金属氧化物中在感应通道炉中熔化以产生液态金属的含碳金属化中间体。 在罚款或浓缩铁矿石的应用中，采用低成本煤炭，通过消除矿石团聚，高炉运行，大大降低资金和运营成本。 这样生产的液态铁在碱性氧气炉（BOF）等炼钢炉中有效地转化为钢，特别是当物理地与感应通道炉一体化时，通过感应通道将液态铁直接注入到集成BOF中 炉，生产低成本钢，热损失小，排放最少。
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公开(公告)号：US20100234640A1
公开(公告)日：2010-09-16
申请号：US12653675
申请日：2009-03-13
IPC分类号： C07C231/08 , B01D53/62 , B01D53/50 , B01D53/56
CPC分类号： B01D53/75 , B01D53/565 , B01D53/62 , B01D2251/21 , B01D2253/102 , B01D2257/504 , B01D2257/60 , B01D2257/602 , C01B17/0482 , C10B49/04 , C10B53/04 , C10J3/00 , C10J3/62 , C10J2300/0943 , C10J2300/0969 , C10J2300/1609 , C10J2300/1659 , C10J2300/1665 , C10K1/004 , C10K3/008 , Y02C10/04 , Y02P20/152
摘要： This invention provides a comprehensive solution which comprises the production of a bed of ash-containing hot char via the pyrolysis of coal which generates a hydrogen rich gas that, subsequent to its cleanup, can be synthesized into chemicals and/or transportation fuels, while the hot char is used to: (i) reduce SO2 and NOX to elemental sulfur and to elemental nitrogen, respectively; (ii) react hot char with CO2 to reduce it to CO, a valuable chemical that can be converted into fertilizer or into a fuel gas that can be used for electric or thermal power generation; (iii) trap particulate matter in the bed of char to join the ash in the char to form a combined ash which is eventually converted to inert slag; and (iv) filter the mercury through a portion of the char to prevent it from being emitted into the atmosphere.
摘要翻译： 本发明提供了一种全面的解决方案，其包括通过煤的热解生产含灰分的热炭床，其产生富氢气体，其在其清洁之后可以合成为化学品和/或运输燃料，而 热焦炭用于：（i）分别将SO 2和NO x还原成元素硫和元素氮; （ii）将热焦炭与二氧化碳反应，以将其还原成CO，这是一种有价值的化学物质，可以转化为可用于电力或火力发电的肥料或燃料气体; （iii）将焦炭中的颗粒物质收集在焦炭中以将灰分加入到焦炭中以形成最终转化为惰性矿渣的组合灰分; 和（iv）通过焦炭的一部分过滤汞，以防止其被排放到大气中。
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公开(公告)号：US07413647B2
公开(公告)日：2008-08-19
申请号：US11078949
申请日：2005-03-07
CPC分类号： C10G11/14 , B01J4/002 , B01J8/125 , B01J19/26 , B01J2208/00495 , B01J2208/00504 , B01J2208/00557 , B01J2219/0004 , B01J2219/185 , B01J2219/187 , B01J2219/1943 , B01J2219/1946 , C10G11/18
摘要： The present invention consists of an improved method and apparatus to upgrade bitumen in various forms which comprises four main components; namely, a fractionator equipped with a condenser, a heavy gas oil catalytic treater, a catalyst regenerator/gasifier and a gas cleanup assembly. In operation, the bitumen in liquid form is fed to the fractionator for initial separation of fractions with the bulk of the bitumen leaving the bottom of the fractionator in the form of a heavy gas oil which is pumped to the catalytic treater and sprayed on a hot catalyst to crack the heavy gas oil (an endothermic reaction) to release lighter hydrocarbons in the form of H2 rich volatile matter while depositing carbon on the catalyst. The volatile matter from the treater is directed to the fractionator where the condensable fractions are separated from the non-condensable H2 rich gas, a valuable primary gas. The carbon containing catalyst from the treater is recycled to the regenerator/gasifier, and the catalyst after being regenerated (an exothermic reaction) is fed hot to the treater. Various fractions are removed from the fractionator as intermediates in the form of light napthas and light oils. The off-gas from the regenerator/gasifier is directed to a gas cleanup system to produce a valuable secondary gas. Both the primary gas and the secondary gas may be further utilized in the processing of the intermediates produced by the method, the primary gas being a source of H2 and the secondary gas being a source of thermal energy.
摘要翻译： 本发明包括一种以各种形式升级沥青的改进方法和装置，其包括四个主要组分; 即配备有冷凝器，重质瓦斯油催化处理器，催化剂再生器/气化器和气体净化组件的分馏器。 在操作中，将液体形式的沥青进料到分馏器中，用于初始分离馏分，其中大部分沥青离开分馏器的底部，形式为重质瓦斯油，其被泵送到催化处理器并喷涂在热的 催化剂裂解重质瓦斯油（吸热反应）以释放富含H 2 O 3挥发物质的较轻质烃，同时在催化剂上沉积碳。 来自处理器的挥发性物质被引导至分馏器，其中可冷凝馏分与不可冷凝的H 2富含气体（有价值的一次气体）分离。 来自处理器的含碳催化剂被再循环到再生器/气化器中，再生后的催化剂（放热反应）被热加热到处理器。 从分馏器中除去各种馏分，作为浅萘和轻油形式的中间体。 来自再生器/气化器的废气被引导到气体净化系统以产生有价值的二次气体。 初级气体和次级气体都可以进一步用于通过该方法生产的中间体的处理，主气体是H 2 2源，二次气体是热能源。
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