公开(公告)号：US20150240172A1

公开(公告)日：2015-08-27

申请号：US14427339

申请日：2013-09-13

申请人： BIG DUTCHMAN INTERNATIONAL GMBH

发明人： Armin Schwarz

IPC分类号： C10J3/72 ,  C10J3/82

CPC分类号： C10J3/723 ,  C10J3/06 ,  C10J3/26 ,  C10J3/64 ,  C10J3/725 ,  C10J3/82 ,  C10J2200/15 ,  C10J2200/152 ,  C10J2300/0916 ,  C10J2300/092 ,  C10J2300/0956 ,  C10J2300/1207 ,  C10J2300/1609 ,  C10J2300/1618 ,  C10J2300/1846

摘要： The invention relates to a method and an apparatus for generating fuel gas from a solid material in a shaft gasifier, and comprises a gasification zone, into which the solid material can be filled, and an oxidation zone designed to oxidize the generated gas connected to the gasifier zone so that the gases generated in the gasifier zone run to the oxidation zone. A first air supply device and a second air supply device downstream of the first air supply in the processing direction of the solid material supply air into the gasification zone. A measurement unit samples the raw gas that is generated in the oxidation zone or of the flammable product gas. A control unit, which is coupled with the measurement unit by means of signal technology, transmits a test signal and controls the air supplied by the second air supply device via the test signal.

摘要翻译： 本发明涉及一种用于从轴式气化炉中的固体材料产生燃料气体的方法和装置，并且包括可以填充固体材料的气化区和设计用于氧化连接到 气化器区域，使得在气化器区域中产生的气体运行到氧化区域。 第一空气供应装置和第二空气供应装置在固体材料的加工方向上的第一空气供应装置的下游供应空气进入气化区。 测量单元对在氧化区或易燃产物气体中产生的原始气体进行采样。 通过信号技术与测量单元耦合的控制单元经由测试信号发送测试信号并控制由第二供气装置供应的空气。

公开(公告)号：US20070163176A1

公开(公告)日：2007-07-19

申请号：US11460379

申请日：2006-07-27

申请人： Dietmar Ruger ,  Olaf Schulze ,  Jonas Kappeller ,  Burkhard Moller ,  Bodo Wolf

发明人： Dietmar Ruger ,  Olaf Schulze ,  Jonas Kappeller ,  Burkhard Moller ,  Bodo Wolf

IPC分类号： C10J3/00

CPC分类号： C10J3/487 ,  C10J3/526 ,  C10J3/64 ,  C10J3/84 ,  C10J2200/158 ,  C10J2300/1609

摘要： A process for the endothermic gasification of solid carbon in an entrained bed facility comprises partial oxidation of fuel(s) and endothermic gasification of solid carbon, preferably preceded by low temperature carbonization such that the carbonization gas is passed to the partial oxidation and the carbonization coke is passed to the endothermic gasification. The hot gas streaming downwardly from the combustion chamber is deflected to produce separation of the liquid slag and is then passed to the endothermic gasification that operates with a rising gas stream and with addition of solid carbon having a grain diameter of up to 20 mm. The speed of the gas at the carbon inlet is higher than, and the speed of the gas at the end of the endothermic gasification is lower than, the suspension rate of the reactive carbon particles, to produce an increase of the relative speed difference between the gas and the carbon particles. Apparatus is also disclosed for carrying out the process.

摘要翻译： 在夹带床设备中固体碳的吸热气化的方法包括燃料的部分氧化和固体碳的吸热气化，优选在低温碳化之前，使得碳化气体进入部分氧化和碳化焦炭 被传递到吸热气化。 从燃烧室向下流动的热气体被偏转以产生液体炉渣的分离，然后被传递到用升高的气流运行的吸热气化，并加入具有高达20mm的粒径的固体碳。 碳入口处的气体速度高于吸热气化结束时的气体速度低于反应性碳颗粒的悬浮速度，以产生相对速度差 气体和碳颗粒。 还公开了用于执行该过程的装置。

公开(公告)号：US20030089038A1

公开(公告)日：2003-05-15

申请号：US10293815

申请日：2002-11-12

发明人： Lloyd Weaver

IPC分类号： C10J003/00

CPC分类号： C10J3/466 ,  C10J3/485 ,  C10J3/526 ,  C10J3/723 ,  C10J3/80 ,  C10J3/84 ,  C10J3/86 ,  C10J2300/0956 ,  C10J2300/0959 ,  C10J2300/0973 ,  C10J2300/0996 ,  C10J2300/1609 ,  C10J2300/1884 ,  C10J2300/1892 ,  C10K1/08 ,  C10K1/101 ,  Y02E20/16 ,  Y02E20/18

摘要： A gasifier system includes a gasifier chamber, a plurality of nozzles or burners injecting and combusting a mixture including coal and oxygen within the gasifier chamber, and an ash bed disposed proximate a bottom of the gasifier chamber. Concurrent flow is generated within the gasifier such that gas and bi-products generated by the combustion of the mixture flow through the ash bed. The ash bed serves as a filter and reducing volume for the trace carbon not gasified during the combustion process. The hot gases exit the gasifier and enter a gas cooler and then a hot gas filter. Ash is unloaded from the gasifier chamber and is transferred into a quench tank, where ash settles and is removed to atmospheric conditions by a progressive pitched dewatering screw press. The dewatering screw press also serves as a seal to prevent excessive water escaping from the high pressure of gasifier operation.

摘要翻译： 气化器系统包括气化器室，在气化器室内喷射和燃烧包括煤和氧的混合物的多个喷嘴或燃烧器，以及设置在气化器室的底部附近的灰床。 在气化器内产生并流，使得由混合物的燃烧产生的气体和双体产物流过灰床。 灰床用作过滤器，并减少在燃烧过程中未气化的痕量碳的体积。 热气体离开气化器并进入气体冷却器，然后进入热气体过滤器。 灰从气化器室中卸载并被转移到骤冷罐中，灰烬沉淀并通过渐进式倾斜脱水螺旋压榨机去除大气条件。 脱水螺旋压榨机还用作密封件，以防止过多的水从气化器操作的高压逸出。

公开(公告)号：US4987115A

公开(公告)日：1991-01-22

申请号：US248808

申请日：1988-09-23

申请人： Herwig Michel-Kim

发明人： Herwig Michel-Kim

IPC分类号： C01B31/08 ,  C01B31/10 ,  C10J3/02 ,  C10J3/54

CPC分类号： C10J3/721 ,  C01B31/088 ,  C01B31/10 ,  C10J3/02 ,  C10J3/34 ,  C10J3/54 ,  C10J2200/158 ,  C10J2300/1609 ,  Y02P20/129

摘要： A method and an apparatus for producing generator gas and activated carbon from solid fuels. A first gasification stage is supplied with fuel by an underfeed charging system and preheated air, the air and fuel being supplied in the same direction. In a second gasification stage and accompanied by the supply of secondary air, an intermediate gasification takes place. Finally, in a third gasification stage, the gas is reacted with glowing coke or charcoal, and the heat of the exiting gas is used for heating the air. The fuel centrally entering the first gasification stage is led from the inside to the outside and then upwards. Part of the entering fuel is precombusted in a precombustion chamber linked with the supply of the preheated air for reducing the oxygen content of the preheated air. In the intermediate gasification stage, the gas with the admixed air is passed through a Venturi nozzle or tube with a diffuser. The flue coal entrained from the first gasification stage is at least partly returned to the throat of the Venturi tube. The return is assisted both by vacuum in the Venturi tube and mechanically.

摘要翻译： 一种从固体燃料生产发电机气体和活性炭的方法和装置。 第一气化阶段由欠充电系统和预热空气供应燃料，空气和燃料沿相同方向供应。 在第二气化阶段并伴随着二次空气的供应，发生中间气化。 最后，在第三气化阶段，气体与发光的焦炭或木炭反应，排出气体的热量用于加热空气。 中心进入第一气化阶段的燃料从内部引导到外部然后向上。 进入燃料的一部分被预燃烧在与预热空气供应相连的预燃室中，以减少预热空气的氧含量。 在中间气化阶段，具有混合空气的气体通过文丘里管或喷管扩散管。 从第一气化阶段夹带的烟道煤至少部分地返回文丘里管的喉部。 返回由文丘里管中的真空和机械辅助。

公开(公告)号：US09234148B2

公开(公告)日：2016-01-12

申请号：US13138542

申请日：2010-02-26

申请人： Norbert Ullrich

发明人： Norbert Ullrich

IPC分类号： C10J3/48 ,  C10J3/46 ,  C10J3/50 ,  C10J3/72 ,  C10J3/84 ,  C10K1/04 ,  C10K1/10

CPC分类号： C10J3/487 ,  C10J3/506 ,  C10J3/721 ,  C10J3/84 ,  C10J2200/152 ,  C10J2300/0916 ,  C10J2300/1609 ,  C10K1/04 ,  C10K1/101 ,  Y02P20/145

摘要： A process for the generation of a syngas in an entrained-flow gasification process includes a solid, carbon-containing fuel which is introduced via burners into a reactor which also supplies the oxygen for gasification. The fuel is introduced on a burner level where the burners are arranged concentrically around the reaction chamber or in the head area. The syngas obtained is discharged from the reaction chamber via a discharge nozzle, so that the syngas is passed into a collecting chamber for cooling by addition of low-temperature gaseous, vaporous or liquid cooling agents. A quench chamber is provided between the reactor and the collecting chamber. Additional burner levels are in the quench chamber via which a fuel material of renewable fuels or biofuels is introduced into the syngas, so that the heat enthalpy of the syngas can be utilized for the endothermic gasification reaction of the biological raw material. An apparatus for this generation of synthesis gas includes several burner levels, the renewable fuel being supplied to the gasification chamber with or without water vapor or oxygen and the enthalpy of the hot syngas being utilized for the gasification of the renewable fuel.

摘要翻译： 在夹带气化过程中产生合成气的方法包括固体含碳燃料，其通过燃烧器引入反应器中，所述反应器也提供用于气化的氧气。 燃料被引入燃烧器水平，其中燃烧器围绕反应室或头部区域同心地排列。 获得的合成气经由排出喷嘴从反应室排出，使得合成气通过添加低温气态，蒸气或液体冷却剂而进入收集室进行冷却。 在反应器和收集室之间设有骤冷室。 另外的燃烧器水平位于骤冷室中，可再生燃料或生物燃料的燃料通过其被引入到合成气中，使得合成气的热焓可用于生物原料的吸热气化反应。 用于这种产生合成气的装置包括几个燃烧器水平，可再生燃料在有或者没有水蒸气或氧气的情况下供应到气化室，并且热合成气的焓用于可再生燃料的气化。

公开(公告)号：US20150144842A1

公开(公告)日：2015-05-28

申请号：US14551664

申请日：2014-11-24

申请人： SIEMENS AKTIENGESELLSCHAFT ,  CLARIANT INTERNATIONAL LTD.

发明人： Yeping CAI ,  William M. Faris ,  Christian GÖRSCH ,  Frank HANNEMANN ,  Doris KLOSTERMANN ,  Robert MARX ,  Manfred SCHINGNITZ ,  Justin WANG ,  Ling XU

IPC分类号： C01B3/58 ,  B01J8/02 ,  B01J8/18 ,  B01J8/00

CPC分类号： B01J8/18 ,  B01J8/0005 ,  B01J8/02 ,  B01J8/0285 ,  B01J8/0457 ,  B01J8/0492 ,  B01J8/0496 ,  B01J2208/00176 ,  B01J2208/0053 ,  B01J2208/025 ,  B01J2208/027 ,  C01B3/16 ,  C01B2203/0288 ,  C01B2203/0877 ,  C01B2203/0883 ,  C10J3/46 ,  C10J2300/1609 ,  C10K3/04 ,  Y02P20/129 ,  Y02P20/52

摘要： A technology for producing synthesis gas from crude gas from various gasification processes for solid or liquid fuels. To limit the temperatures in a subsequent strongly exothermic CO shift reaction to adjust the H2/CO ratio, the crude gas which has been freed of dust flows through two shift reactors arranged in series. The first reactor has a specific reaction-kinetically limited catalyst and the second reactor has a conventional sour gas catalyst. The specific catalyst used in the first reactor limits the exothermic shift reaction to such an extent that the reaction temperatures in the first and second reactors remain so low to avoid thermal damage to the catalysts even without introduction of external steam, and the desired gas composition is achieved.

摘要翻译： 用于从用于固体或液体燃料的各种气化过程的原油生产合成气的技术。 为了在随后的强放热CO转化反应中限制温度以调节H 2 / CO比，已经没有灰尘的粗气体流过串联排列的两个变换反应器。 第一反应器具有特定的反应动力学有限的催化剂，第二反应器具有常规的酸性气体催化剂。 在第一反应器中使用的特定催化剂将放热转变反应限制到使得第一和第二反应器中的反应温度保持如此低的程度，以避免即使不引入外部蒸汽对催化剂的热损伤，并且所需的气体组成为 实现了

公开(公告)号：US08323366B2

公开(公告)日：2012-12-04

申请号：US12519210

申请日：2007-12-11

申请人： Rolf Ljunggren

发明人： Rolf Ljunggren

IPC分类号： C01B3/36 ,  C01B6/24 ,  B01J7/00 ,  B01D53/22 ,  B01D53/02

CPC分类号： B01J7/00 ,  B01D53/22 ,  C10B49/02 ,  C10B53/02 ,  C10J3/00 ,  C10J3/62 ,  C10J3/66 ,  C10J2300/0909 ,  C10J2300/0916 ,  C10J2300/092 ,  C10J2300/0943 ,  C10J2300/0956 ,  C10J2300/1253 ,  C10J2300/1606 ,  C10J2300/1609 ,  C10J2300/1693 ,  C10J2300/1861 ,  C10J2300/1884 ,  C10K1/004 ,  C10K1/12 ,  C10K1/143 ,  C10K1/32 ,  Y02E50/14 ,  Y02P20/145

摘要： A process for producing synthesis gas (S) from biomass, includes drying the biomass and gasifying the biomass. An equipment to carry out the process is also disclosed. The process further includes: subjecting the outgoing gases (CO2, N2 and H2O) from the gasifying step to a first heat exchange, where the outgoing gases (CO2, N2 and H2O) are cooled, purifying the outgoing gases (CO2, N2 and H2O) to achieve a process gas (P), the purification being effected by eliminating nitrogen (N2) from the outgoing gases (CO2, N2 and H2O), subjecting the process gas (P) to heat exchange, where the process gas (P) is heated, reducing the process gas (P) to synthesis gas (S), subjecting the synthesis gas (S) to heat exchange, where the synthesis gas (S) is cooled and supply air to the gasification is heated.

摘要翻译： 从生物质生产合成气（S）的方法包括干燥生物质并使生物质气化。 还披露了执行该过程的设备。 该方法还包括：对来自气化步骤的排出气体（CO 2，N 2和H 2 O）进行第一次热交换，其中排出的气体（CO 2，N 2和H 2 O）被冷却，净化排出的气体（CO 2，N 2和H 2 O ）以实现工艺气体（P），通过从输出气体（CO 2，N 2和H 2 O）中除去氮气（N 2），对工艺气体（P）进行热交换进行净化，其中工艺气体（P） 被加热，将工艺气体（P）还原为合成气（S），使合成气（S）进行热交换，合成气（S）被冷却并供给空气进行气化。

公开(公告)号：US07678164B2

公开(公告)日：2010-03-16

申请号：US10451616

申请日：2002-01-09

申请人： Paul D Williams

发明人： Paul D Williams

IPC分类号： C10J3/72

CPC分类号： C10J3/40 ,  C10J3/002 ,  C10J3/32 ,  C10J3/48 ,  C10J3/50 ,  C10J3/52 ,  C10J3/72 ,  C10J3/84 ,  C10J2300/1223 ,  C10J2300/1609 ,  C10J2300/1628 ,  F27D7/02 ,  F27D2099/0093 ,  Y02P20/133

摘要： A solid fuel gasifier includes first wall structure (12) defining a gasification chamber (14) and means (50, 52) to collect particulate solid residue from gasification in the gasification chamber. Second wall structure (16) defines a gas combustion chamber (17) and means (19) is arranged for admitting a flow of hot gases from the gasification chamber to the gas combustion chamber as combustion takes place. Also provided is means (178, 170) to conduct hot gases from the gasification chamber and/or gas combustion chamber into thermal contact with said collected particulate solid residue, for facilitating post-combustion and/or post-reduction of the solid residue. Also disclosed are an agitator bed (52, 182) for fine particulate material, and a method of gasification of solid fuel.

摘要翻译： 固体燃料气化器包括限定气化室（14）的第一壁结构（12）和用于从气化室中气化收集颗粒固体残余物的装置（50,52）。 第二壁结构（16）限定气体燃烧室（17），并且设置装置（19），用于在发生燃烧时将气体流从气化室引入气体燃烧室。 还提供了用于将来自气化室和/或气体燃烧室的热气体与所述收集的颗粒固体残余物热接触的装置（178,170），以便于固体残余物的后燃烧和/或后还原。 还公开了一种用于细颗粒材料的搅拌床（52,182）和固体燃料的气化方法。

公开(公告)号：US07238222B2

公开(公告)日：2007-07-03

申请号：US11070527

申请日：2005-03-01

申请人： Oren V. Peterson

发明人： Oren V. Peterson

IPC分类号： C21B15/00

CPC分类号： C10J3/00 ,  C10J3/005 ,  C10J3/725 ,  C10J2200/09 ,  C10J2300/093 ,  C10J2300/0946 ,  C10J2300/16 ,  C10J2300/1606 ,  C10J2300/1609 ,  C21B13/0073 ,  C21B13/143 ,  C21B2100/22 ,  C21C1/02 ,  C21C5/562 ,  C21C5/567 ,  Y02P10/136 ,  Y02P10/216

摘要： A process for producing liquid steel is disclosed. Carbon monoxide and oxygen may be combusted in a high temperature reactor. Iron and iron oxide materials, along with scrap steel if desired, may be placed in the high temperature reactor. Carbon dioxide produced in the high temperature reactor may be circulated through a back reactor vessel. Coke masses may be placed in the back reactor vessel. The coke may be formed by circulating heated carbon monoxide counter current to crushed coal in a rotary kiln. The carbon dioxide circulated through the back reactor vessel reacts with the coke to form carbon monoxide. The carbon monoxide may be conveyed to the high temperature reactor to be combusted with oxygen to produce the heat for forming the liquid steel.

公开(公告)号：US07220293B2

公开(公告)日：2007-05-22

申请号：US11086630

申请日：2005-03-21

申请人： Oren V. Peterson

发明人： Oren V. Peterson

IPC分类号： C21B15/00

CPC分类号： C10J3/00 ,  C10J3/005 ,  C10J3/725 ,  C10J2200/09 ,  C10J2300/093 ,  C10J2300/0946 ,  C10J2300/16 ,  C10J2300/1606 ,  C10J2300/1609 ,  C21B13/0073 ,  C21B13/143 ,  C21B2100/22 ,  C21C1/02 ,  C21C5/562 ,  C21C5/567 ,  Y02P10/136 ,  Y02P10/216

摘要： A process for producing liquid steel is disclosed. Carbon monoxide and oxygen may be combusted in a high temperature reactor. Iron and iron oxide materials, along with scrap steel if desired, may be placed in the high temperature reactor. Carbon dioxide produced in the high temperature reactor may be circulated through a back reactor vessel. Coke masses may be placed in the back reactor vessel. The coke may be formed by circulating heated carbon monoxide counter current to crushed coal in a rotary kiln. The carbon dioxide circulated through the back reactor vessel reacts with the coke to form carbon monoxide. The carbon monoxide may be conveyed to the high temperature reactor to be combusted with oxygen to produce the heat for forming the liquid steel.

摘要翻译： 公开了一种生产液态钢的方法。 一氧化碳和氧气可能在高温反应器中燃烧。 如果需要，铁和氧化铁材料以及废钢可以放置在高温反应器中。 在高温反应器中产生的二氧化碳可以通过反向反应器容器循环。 焦炭质量可以放置在后反应器容器中。 可以通过在回转窑中将加热的一氧化碳逆流循环到粉碎煤上形成焦炭。 通过后反应器容器循环的二氧化碳与焦炭反应形成一氧化碳。 一氧化碳可以被输送到高温反应器中以与氧气一起燃烧以产生用于形成液态钢的热量。