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1.发明申请MIDDLE DISTILLATE HYDROCRACKING CATALYST CONTAINING ZEOLITE BETA WITH LOW OD ACIDITY AND LARGE DOMAIN SIZE 审中-公开含有低沸点和大尺寸的ZEOLITE BETA的中间蒸馏水解反应催化剂公开(公告)号：US20170043328A1
公开(公告)日：2017-02-16
申请号：US14823791
申请日：2015-08-11
申请人： Yihua Zhang , Theodorus Ludovicus Michael Maesen , Yalin Hao , Don Ramon Bushee , Thomas Michael Rea
发明人： Yihua Zhang , Theodorus Ludovicus Michael Maesen , Yalin Hao , Don Ramon Bushee , Thomas Michael Rea
CPC分类号： B01J29/80 , B01J23/88 , B01J23/888 , B01J29/084 , B01J29/166 , B01J29/7007 , B01J29/7815 , B01J35/0006 , B01J35/002 , B01J37/0018 , B01J37/0201 , B01J37/0207 , B01J37/0236 , B01J37/04 , B01J37/08 , C10G47/20
摘要： A hydrocracking catalyst is provided comprising:a. from 0.5 to 10 wt % zeolite beta having an OD acidity of 20 to 400 nmol/g and an average domain size from 800 to 1500 nm2;b. from 0 to 5 wt % zeolite USY having an ASDI between 0.05 and 0.12; wherein a wt % of the zeolite beta is greater than the wt % of the zeolite USY;c. a catalyst support; andd. at least one metal selected from the group consisting of elements from Group 6 and Groups 8 through 10 of the Periodic Table. A process for hydrocracking using the hydrocracking catalyst to produce middle distillates is provided. A method for making the hydrocracking catalyst is also provided.
摘要翻译： d。 选自元素周期表第6族和第8至10族元素中的至少一种金属。 提供了使用加氢裂化催化剂生产中间馏分的加氢裂化方法。 还提供了制备加氢裂化催化剂的方法。
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公开(公告)号：US20150307789A1
公开(公告)日：2015-10-29
申请号：US14261350
申请日：2014-04-24
申请人： Jifei JIA , Henry SATERNUS , Xianghua YU , Cecelia RADLOWSKI , Theodorus Ludovicus Michael MAESEN
发明人： Jifei JIA , Henry SATERNUS , Xianghua YU , Cecelia RADLOWSKI , Theodorus Ludovicus Michael MAESEN
IPC分类号： C10G45/12
CPC分类号： C10G45/08 , B01J21/12 , B01J23/883 , B01J27/19 , B01J35/1019 , B01J35/1042 , B01J37/0201 , B01J37/0203 , B01J37/20 , C10G45/04
摘要： This disclosure relates to supported multi-metallic catalysts for use in the hydrotreating of hydrocarbon feeds. The catalysts are prepared from a catalyst precursor comprised of at least one Group VIB metal, at least one Group VIII metal and an organic acid. The catalyst precursor is thermally treated to partially decompose the organic acid, then sulfided. The catalysts have a high carbon-as-carboxyl to total carbon ratio (Ccarboxy/Ctotal) as a result of a unique post-metal calcination method employed during the manufacture of the catalyst.
摘要翻译： 本公开涉及用于烃进料加氢处理的负载型多金属催化剂。 催化剂由包含至少一种VIB族金属，至少一种第Ⅷ族金属和有机酸的催化剂前体制备。 将催化剂前体进行热处理以部分分解有机酸，然后硫化。 作为催化剂制造过程中使用的独特的后金属煅烧方法，催化剂具有高碳 - 羧 - 总碳比（Ccarboxy / Ctotal）。
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公开(公告)号：US20150136646A1
公开(公告)日：2015-05-21
申请号：US14541684
申请日：2014-11-14
IPC分类号： C10M101/02 , C10G67/02
CPC分类号： C10M101/02 , C10G47/06 , C10G65/12 , C10G67/02
摘要： A process is provided for producing a heavy lubricating base oil by hydrocracking a lubricating oil feedstock at high yield. The lubricating oil feedstock contains a hydroprocessed stream that is difficult to process using a conventional catalyst system. The catalyst used in the process includes a mixed metal sulfide catalyst that comprises at least one Group VIB metal and at least one Group VIII metal. The process also provides for hydroisomerization and hydrofinishing process steps to prepare the lubricating base oil.
摘要翻译： 提供了一种通过以高产率加氢裂化润滑油原料来生产重质润滑基础油的方法。 润滑油原料含有使用常规催化剂体系难以加工的加氢处理流。 在该方法中使用的催化剂包括含有至少一种VIB族金属和至少一种第Ⅷ族金属的混合金属硫化物催化剂。 该方法还提供加氢异构化和加氢处理步骤以制备润滑基础油。
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公开(公告)号：US08702970B2
公开(公告)日：2014-04-22
申请号：US13676256
申请日：2012-11-14
CPC分类号： C10G45/08 , B01J23/002 , B01J23/8885 , B01J31/2239 , B01J37/0018 , B01J37/036 , B01J37/20 , B01J2523/00 , B01J2531/26 , B01J2531/66 , B01J2531/847 , C10G45/06 , C10G45/10 , C10G45/12 , C10G45/48 , C10G45/50 , C10G45/52 , C10G45/54 , C10G47/06 , C10G47/18 , C10G47/20 , C10G49/04 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/27 , B01J2523/22 , B01J2523/31 , B01J2523/41 , B01J2523/43 , B01J2523/845
摘要： A method for hydroprocessing a hydrocarbon feedstock is provided. The method comprises contacting the feedstock with a catalyst under hydroprocessing conditions, wherein the catalyst is formed by sulfiding an unsupported catalyst precursor of the general formula Av[(MP) (OH)x (L)ny]z (MVIBO4), wherein MP is selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof; L is one or more oxygen-containing ligands, and L has a neutral or negative charge n
摘要翻译： 提供了一种用于加氢处理烃原料的方法。 该方法包括在加氢处理条件下使原料与催化剂接触，其中催化剂是通过硫化通式Av [（MP）（OH）x（L）ny] z（MVIBO4）的无载体催化剂前体形成的，其中MP为 选自第VIII组，IIB组，IIA组，IVA组及其组合; L是一个或多个含氧配体，L具有中性或负电荷n <= 0，MVIB至少为具有+6的氧化态的VIB族金属; MP：MVIB的原子比在100：1和1：100之间; v-2 + P * z-x * z + n * y * z = 0; 和0＆nlE; y＆nlE; -P / n; 0＆nlE; x＆nlE; P; 0＆nlE; v＆nlE; 2; 0＆nlE; z。 在一个实施方案中，催化剂前体还包含含纤维素的材料。 在另一个实施方案中，催化剂前体还包含至少一种稀释剂（粘合剂）。 在一个实施方案中，稀释剂是硅铝酸镁粘土。
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5.发明授权Hydroconversion processes employing multi-metallic catalysts and method for making thereof 有权采用多金属催化剂的加氢转化方法及其制备方法公开(公告)号：US08206575B2
公开(公告)日：2012-06-26
申请号：US12259435
申请日：2008-10-28
CPC分类号： C10G45/08 , B01J23/002 , B01J23/8885 , B01J31/2239 , B01J37/0018 , B01J37/036 , B01J37/20 , B01J2523/00 , B01J2531/26 , B01J2531/66 , B01J2531/847 , C10G45/06 , C10G45/10 , C10G45/12 , C10G45/48 , C10G45/50 , C10G45/52 , C10G45/54 , C10G47/06 , C10G47/18 , C10G47/20 , C10G49/04 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/27 , B01J2523/22 , B01J2523/31 , B01J2523/41 , B01J2523/43 , B01J2523/845
摘要： A process for upgrading a hydrocarbon feedstock by hydroprocessing using multi-metallic catalysts is disclosed. In one aspect, the invention relates to hydroprocessing of a hydrocarbon feedstock using a catalyst derived from a catalyst precursor of the formula Av[(MP)(OH)x(L)ny]z(MVIBO4), wherein A comprises an alkali metal cation, an ammonium, an organic ammonium or a phosphonium cation, MP is selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, L is an organic, oxygen-containing ligand, MVIB is at least one of Group VIB metals, and the atomic ratio of MVIII:MVIB is between 100:1 and 1:100.
摘要翻译： 公开了一种通过使用多金属催化剂的加氢处理来升级烃原料的方法。 一方面，本发明涉及使用衍生自式Av [（MP）（OH）x（L）ny] z（MVIBO4）的催化剂前体的催化剂加氢处理烃原料，其中A包含碱金属阳离子 ，铵，有机铵或鏻阳离子，MP选自VIII族，IIB族，IIA族，IVA族及其组合，L为有机含氧配体，MVIB为VIB族金属中的至少一种 ，MVIII：MVIB的原子比在100:1和1:100之间。
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6.发明申请Hydroconversion Processes Employing Multi-Metallic Catalysts and Method for Making Thereof 有权采用多金属催化剂的加氢转化方法及其制备方法公开(公告)号：US20090107889A1
公开(公告)日：2009-04-30
申请号：US12259435
申请日：2008-10-28
IPC分类号： C10G45/00
CPC分类号： C10G45/08 , B01J23/002 , B01J23/8885 , B01J31/2239 , B01J37/0018 , B01J37/036 , B01J37/20 , B01J2523/00 , B01J2531/26 , B01J2531/66 , B01J2531/847 , C10G45/06 , C10G45/10 , C10G45/12 , C10G45/48 , C10G45/50 , C10G45/52 , C10G45/54 , C10G47/06 , C10G47/18 , C10G47/20 , C10G49/04 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/27 , B01J2523/22 , B01J2523/31 , B01J2523/41 , B01J2523/43 , B01J2523/845
摘要： A process for upgrading a hydrocarbon feedstock by hydroprocessing using multi-metallic catalysts is disclosed. In one aspect, the invention relates to hydroprocessing of a hydrocarbon feedstock using a catalyst derived from a catalyst precursor of the formula Av[(MP)(OH)x(L)ny]z(MVIBO4), wherein A comprises an alkali metal cation, an ammonium, an organic ammonium or a phosphonium cation, MP is selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, L is an organic, oxygen-containing ligand, MVIB is at least one of Group VIB metals, and the atomic ratio of MVIII:MVIB is between 100:1 and 1:100.
摘要翻译： 公开了一种通过使用多金属催化剂的加氢处理来升级烃原料的方法。 一方面，本发明涉及使用衍生自式Av [（MP）（OH）x（L）ny] z（MVIBO4）的催化剂前体的催化剂加氢处理烃原料，其中A包含碱金属阳离子 ，铵，有机铵或鏻阳离子，MP选自VIII族，IIB族，IIA族，IVA族及其组合，L为有机含氧配体，MVIB为VIB族金属中的至少一种 ，MVIII：MVIB的原子比在100:1和1:100之间。
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公开(公告)号：US10213772B2
公开(公告)日：2019-02-26
申请号：US14683435
申请日：2015-04-10
摘要： A hydrocracking catalyst is provided comprising: a) greater than 10 wt % of a zeolite USY having: i. a total OD acidity of 0.350 to 0.650 mmol/g; ii. an ASDI between 0.05 and 0.15; iii. a BET surface area greater than 600 m2/g; iv. a SAR greater than 10; v. less than 45 vol % of pores greater than 2 nm; b) a support; and c) at least one metal selected from the group consisting of elements from Group 6 and Groups 8 through 10 of the Periodic Table. A process for hydrocracking using a hydrocracking catalyst to produce middle distillates is provided. A method for making a hydrocracking catalyst is also provided.
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8.发明申请MIDDLE DISTILLATE HYDROCRACKING CATALYST CONTAINING HIGHLY A STABILIZED Y ZEOLITE WITH ENHANCED ACID SITE DISTRIBUTION 审中-公开含有高稳定性Y沸石的中间蒸馏水解催化剂具有增强酸性位点分布公开(公告)号：US20160121313A1
公开(公告)日：2016-05-05
申请号：US14529794
申请日：2014-10-31
CPC分类号： B01J29/166 , B01J29/106 , B01J35/002 , B01J35/026 , B01J35/1023 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J35/109 , B01J37/20 , B01J2229/12 , B01J2229/20 , B01J2229/37 , B01J2229/40 , B01J2229/42 , C01B39/24 , C10G47/16 , C10G47/20
摘要： Described herein is an improved hydrocracking catalyst containing a stabilized Y zeolite (SY) having an enhanced acid site distribution as compared to conventional SY zeolites. The SY zeolite is also characterized as having a high nanopore volume (HNPV).
摘要翻译： 本文描述了与常规SY沸石相比，含有稳定的Y沸石（SY）的改进的加氢裂化催化剂具有增强的酸性位点分布。 SY沸石的特征还在于具有高纳米孔体积（HNPV）。
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公开(公告)号：US20150306591A1
公开(公告)日：2015-10-29
申请号：US14261346
申请日：2014-04-24
申请人： Jifei JIA , Henry SATERNUS , Xianghua YU , Cecelia RADLOWSKI , Theodorus Ludovicus Michael MAESEN
发明人： Jifei JIA , Henry SATERNUS , Xianghua YU , Cecelia RADLOWSKI , Theodorus Ludovicus Michael MAESEN
CPC分类号： B01J31/28 , B01J21/12 , B01J23/883 , B01J31/0209 , B01J31/04 , B01J35/1019 , B01J35/1042 , B01J37/0203 , B01J37/20 , B01J37/28 , B01J2231/005 , B01J2231/645 , B01J2531/002
摘要： This disclosure relates to supported multi-metallic catalysts for use in the hydrotreating of hydrocarbon feeds, as well as a method for preparing such catalysts. The catalysts are prepared from a catalyst precursor comprised of at least one Group VIB metal, at least one Group VIII metal and an organic acid. The catalyst precursor is thermally treated to partially decompose the organic acid, then sulfided. The catalysts have a high carbon-as-carboxyl to total carbon ratio (Ccarboxy/Ctotal) as a result of a unique post-metal calcination method employed during the manufacture of the catalyst. As a result, the hydrotreating catalysts have lower percent weight loss-on-ignition, higher activity and longer catalyst life.
摘要翻译： 本公开涉及用于烃进料加氢处理的负载型多金属催化剂，以及制备这种催化剂的方法。 催化剂由包含至少一种VIB族金属，至少一种第Ⅷ族金属和有机酸的催化剂前体制备。 将催化剂前体进行热处理以部分分解有机酸，然后硫化。 作为催化剂制造过程中使用的独特的后金属煅烧方法，催化剂具有高碳 - 羧 - 总碳比（Ccarboxy / Ctotal）。 因此，加氢处理催化剂具有较低的失重重量百分比，更高的活性和更长的催化剂寿命。
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公开(公告)号：US20140066296A1
公开(公告)日：2014-03-06
申请号：US14019397
申请日：2013-09-05
IPC分类号： B01J27/051 , B01J27/049
CPC分类号： B01J27/0515 , B01J27/043 , B01J27/047 , B01J27/049 , B01J27/051 , B01J35/002 , B01J35/1014 , B01J35/1038 , C10G45/08
摘要： The invention relates to a self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock and to a method for preparing the catalyst. The MMS catalyst has molar ratios of metal components Ni:Mo:W in a region defined by five points ABCDE of a ternary phase diagram, and wherein the five points ABCDE are defined as: A (Ni=0.72, Mo=0.00, W=0.25), B (Ni=0.25, Mo=0.00, W=0.75), C (Ni=0.25, Mo=0.25, W=0.50), D (Ni=0.60, Mo=0.25, W=0.15), E (Ni=0.72, Mo=0.13, W=0.15).
摘要翻译： 本发明涉及一种用于加氢处理烃原料的自支撑混合金属硫化物（MMS）催化剂及其制备方法。 MMS催化剂在由三元相图的五点ABCDE定义的区域中具有金属成分Ni:Mo:W的摩尔比，其中五点ABCDE定义为：A（Ni = 0.72，Mo = 0.00，W = 0.25），B（Ni = 0.25，Mo = 0.00，W = 0.75），C（Ni = 0.25，Mo = 0.25，W = 0.50），D（Ni = 0.60，Mo = 0.25，W = 0.15） Ni = 0.72，Mo = 0.13，W = 0.15）。
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