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公开(公告)号：US10213772B2
公开(公告)日：2019-02-26
申请号：US14683435
申请日：2015-04-10
摘要： A hydrocracking catalyst is provided comprising: a) greater than 10 wt % of a zeolite USY having: i. a total OD acidity of 0.350 to 0.650 mmol/g; ii. an ASDI between 0.05 and 0.15; iii. a BET surface area greater than 600 m2/g; iv. a SAR greater than 10; v. less than 45 vol % of pores greater than 2 nm; b) a support; and c) at least one metal selected from the group consisting of elements from Group 6 and Groups 8 through 10 of the Periodic Table. A process for hydrocracking using a hydrocracking catalyst to produce middle distillates is provided. A method for making a hydrocracking catalyst is also provided.
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2.发明申请MIDDLE DISTILLATE HYDROCRACKING CATALYST CONTAINING ZEOLITE USY WITH ENHANCED ACID SITES 审中-公开含有增稠酸性网站的中等沸点水解催化剂公开(公告)号：US20160296922A1
公开(公告)日：2016-10-13
申请号：US14683435
申请日：2015-04-10
CPC分类号： B01J29/166 , B01J35/002 , B01J35/023 , B01J35/1023 , B01J35/1061 , B01J35/108 , B01J37/0009 , B01J37/0207 , B01J2229/20 , C10G47/20
摘要： A hydrocracking catalyst is provided comprising: a) greater than 10 wt % of a zeolite USY having: i. a total OD acidity of 0.350 to 0.650 mmol/g; ii. an ASDI between 0.05 and 0.15; iii. a BET surface area greater than 600 m2/g; iv. a SAR greater than 10; v. less than 45 vol % of pores greater than 2 nm; b) a support; and c) at least one metal selected from the group consisting of elements from Group 6 and Groups 8 through 10 of the Periodic Table. A process for hydrocracking using a hydrocracking catalyst to produce middle distillates is provided. A method for making a hydrocracking catalyst is also provided.
摘要翻译： 提供加氢裂化催化剂，其包含：a）大于10重量％的具有以下成分的沸石USY： 总OD酸度为0.350〜0.650mmol / g; ii。 0.05和0.15之间的ASDI; iii。 BET表面积大于600m2 / g; iv。 大于10的SAR; v。小于45体积％的孔大于2nm; b）支持; 和c）选自元素周期表第6族和第8至10族元素中的至少一种金属。 提供了使用加氢裂化催化剂生产中间馏分的加氢裂化方法。 还提供了制备加氢裂化催化剂的方法。
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公开(公告)号：US10183282B2
公开(公告)日：2019-01-22
申请号：US14602394
申请日：2015-01-22
IPC分类号： B01J29/06 , B01J29/12 , C10G47/18 , B01J37/02 , B01J37/04 , B01J35/10 , B01J35/00 , B01J37/30 , B01J37/00 , C10G47/16
摘要： A second-stage hydrocracking catalyst is provided comprising: a. from 40 wt % to 70 wt % of a zeolite USY having an ASDI from 0.05 to 0.18; b. an amorphous silica alumina; c. a second alumina; and d. 0.1 to 10 wt % noble metal; wherein the second-stage hydrocracking catalyst has a BET surface area from 450 to 650 m2/g. A second-stage hydrocracking process is provided comprising using the second-stage hydrocracking catalyst to produce middle distillate. A method for making the second-stage hydrocracking catalyst is also provided.
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公开(公告)号：US20160214094A1
公开(公告)日：2016-07-28
申请号：US14602394
申请日：2015-01-22
CPC分类号： B01J37/0201 , B01J21/04 , B01J21/12 , B01J29/126 , B01J35/0006 , B01J35/002 , B01J35/0026 , B01J35/1004 , B01J35/1023 , B01J37/0009 , B01J37/0207 , B01J37/30 , B01J2229/18 , B01J2229/186 , B01J2229/20 , B01J2229/40 , B01J2229/42 , C10G47/16 , C10G47/18
摘要： A second-stage hydrocracking catalyst is provided comprising: a. from 40 wt % to 70 wt % of a zeolite USY having an ASDI from 0.05 to 0.18; b. an amorphous silica alumina; c. a second alumina; and d. 0.1 to 10 wt % noble metal; wherein the second-stage hydrocracking catalyst has a BET surface area from 450 to 650 m2/g. A second-stage hydrocracking process is provided comprising using the second-stage hydrocracking catalyst to produce middle distillate. A method for making the second-stage hydrocracking catalyst is also provided.
摘要翻译： 提供了第二级加氢裂化催化剂，其包括：a。 40重量％至70重量％的具有0.05至0.18的ASDI的沸石USY; b。 无定形二氧化硅氧化铝; C。 第二氧化铝; 和d。 贵金属0.1〜10重量％ 其中第二级加氢裂化催化剂的BET表面积为450〜650m2 / g。 提供第二阶段加氢裂化方法，包括使用第二级加氢裂化催化剂生产中间馏分。 还提供了制备第二级加氢裂化催化剂的方法。
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5.发明授权Hydroconversion processes employing multi-metallic catalysts and method for making thereof 有权采用多金属催化剂的加氢转化方法及其制备方法公开(公告)号：US08173570B2
公开(公告)日：2012-05-08
申请号：US12259467
申请日：2008-10-28
申请人： Theodorus Ludovicus Michael Maesen , Alexander E. Kuperman , Bi-Zeng Zhang , Andrew Rainis , Christopher J. Dillon
发明人： Theodorus Ludovicus Michael Maesen , Alexander E. Kuperman , Bi-Zeng Zhang , Andrew Rainis , Christopher J. Dillon
CPC分类号： C10G45/08 , B01J23/002 , B01J23/8885 , B01J31/2239 , B01J37/0018 , B01J37/036 , B01J37/20 , B01J2523/00 , B01J2531/26 , B01J2531/66 , B01J2531/847 , C10G45/06 , C10G45/10 , C10G45/12 , C10G45/48 , C10G45/50 , C10G45/52 , C10G45/54 , C10G47/06 , C10G47/18 , C10G47/20 , C10G49/04 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/27 , B01J2523/22 , B01J2523/31 , B01J2523/41 , B01J2523/43 , B01J2523/845
摘要： A catalyst precursor composition and methods for making such catalyst precursor are disclosed. The catalyst precursor comprises at least a Promoter metal selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, at least one Group VIB metal, at least one organic, oxygen-containing ligand, and a cellulose-containing material. Catalysts prepared from the sulfidation of such catalyst precursors are used in the hydroprocessing of hydrocarbon feeds. In one embodiment, the sulfidation is carried out by contacting the catalyst precursor with hydrogen and a sulfur containing compound, wherein the contacting is carried out ex-situ. Catalysts prepared from such catalyst precursors have a fouling rate of less than 8° F. (4.4° C.) per 1000 hour.
摘要翻译： 公开了催化剂前体组合物和制备这种催化剂前体的方法。 催化剂前体至少包含选自VIII族，IIB族，IIA族，IVA族及其组合的至少一种促进剂金属，至少一种VIB族金属，至少一种有机，含氧配体和含纤维素材料。 由这些催化剂前体的硫化制备的催化剂用于烃进料的加氢处理。 在一个实施方案中，硫化是通过使催化剂前体与氢和含硫化合物接触进行的，其中接触是非原位进行的。 由这种催化剂前体制备的催化剂每1000小时的结垢率小于8°F（4.4℃）。
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6.发明授权Hydroconversion processes employing multi-metallic catalysts and method for making thereof 有权采用多金属催化剂的加氢转化方法及其制备方法公开(公告)号：US08163169B2
公开(公告)日：2012-04-24
申请号：US12259495
申请日：2008-10-28
CPC分类号： C10G45/08 , B01J23/002 , B01J23/8885 , B01J31/2239 , B01J37/0018 , B01J37/036 , B01J37/20 , B01J2523/00 , B01J2531/26 , B01J2531/66 , B01J2531/847 , C10G45/06 , C10G45/10 , C10G45/12 , C10G45/48 , C10G45/50 , C10G45/52 , C10G45/54 , C10G47/06 , C10G47/18 , C10G47/20 , C10G49/04 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/27 , B01J2523/22 , B01J2523/31 , B01J2523/41 , B01J2523/43 , B01J2523/845
摘要： A catalyst precursor composition and methods for making such a catalyst precursor are disclosed. The catalyst precursor comprises at least a promoter metal selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, having an oxidation state of +2 or +4, at least one Group VIB metal, at least one organic, oxygen-containing ligand, and a cellulose-containing material. In one embodiment, the catalyst precursor is of the formula Av[(MP) (OH)x (L)ny]z (MVIBO4), wherein A is one or more monovalent cationic species, MP is selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof, L is one or more oxygen-containing ligands, MVIB is at least a Group VIB metal, MP:MVIB has an atomic ratio between 100:1 and 1:100. In one embodiment, catalysts prepared from the sulfidation of such catalyst precursors are used in the hydroprocessing of hydrocarbon feeds. In a hydroconversion process at a hydrogen partial pressure of ˜450 psig, the catalyst a 700° F.+ conversion rate of at least 50% of the 700° F.+ conversion results gives obtained under comparable conditions and with a hydrogen partial pressure of 600 psig.
摘要翻译： 公开了催化剂前体组合物和制备这种催化剂前体的方法。 催化剂前体至少包含选自氧化态为+2或+4的至少一种选自VIII族，IIB族，IIA族，IVA族及其组合的助催化剂金属，至少一种VIB族金属，至少一种有机氧 的含配体，和含纤维素的材料。 在一个实施方案中，催化剂前体具有式Av [（MP）（OH）x（L）ny] z（MVIBO4），其中A是一个或多个一价阳离子物质，MP选自VIII族，IIB族， IIA族，IVA族及其组合，L为一个或多个含氧配位体，MVIB为至少VIB族金属，MP：MVIB的原子比为100:1至1:100。 在一个实施方案中，由烃催化剂前体的硫化制备的催化剂用于烃进料的加氢处理。 在约450psig的氢分压下的加氢转化过程中，催化剂在700°F +转化结果的至少50％的转化率为700°F +，在相当的条件下得到，并且在氢分压 600 psig
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7.发明申请NOBLE METAL ZEOLITE CATALYST FOR SECOND-STAGE HYDROCRACKING TO MAKE MIDDLE DISTILLATE 审中-公开NOBLE金属沸石催化剂用于第二阶段加氢裂化中间馏分公开(公告)号：US20170043330A1
公开(公告)日：2017-02-16
申请号：US14823839
申请日：2015-08-11
申请人： Jifei Jia , Andrew Rainis , Theodorus Luvidocus Michael Maesen , Richard Joseph Coser , Yihua Zhang , Thomas Michael Rea
发明人： Jifei Jia , Andrew Rainis , Theodorus Luvidocus Michael Maesen , Richard Joseph Coser , Yihua Zhang , Thomas Michael Rea
CPC分类号： B01J29/80 , B01J23/88 , B01J23/888 , B01J29/084 , B01J29/126 , B01J29/7007 , B01J29/7415 , B01J35/0006 , B01J35/002 , B01J35/0026 , B01J37/0009 , B01J37/0018 , B01J37/0201 , B01J37/0207 , B01J37/0236 , B01J37/04 , B01J37/08 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C10G47/18
摘要： A second-stage hydrocracking catalyst is provided, comprising: a) a zeolite beta having an OD acidity of 20 to 400 nmol/g and an average domain size from 800 to 1500 nm2; b) a zeolite USY having an ASDI between 0.05 and 0.12; c) a catalyst support; and d) 0.1 to 10 wt % noble metal; wherein the second-stage hydrocracking catalyst provides a hydrogen consumption less than 350 SCFB across a range of synthetic conversions up to 37 wt % when used to hydrocrack hydrocarbonaceous feeds having an initial boiling point greater than 380° F. (193° C.). A second-stage hydrocracking process using the second-stage hydrocracking process is provided. A method to make the second-stage hydrocracking catalyst is also provided.
摘要翻译： 提供了第二级加氢裂化催化剂，其包括：a）具有20至400nmol / g的OD酸度和800至1500nm 2的平均结晶域尺寸的沸石β; b）具有0.05至0.12的ASDI的沸石USY; c）催化剂载体; 和d）0.1〜10重量％的贵金属; 其中第二级加氢裂化催化剂在用于加氢裂化沸点高于380°F（193℃）的烃类进料加氢裂化的情况下，在高达37wt％的合成转化率范围内提供小于350SCFB的氢消耗。 提供了使用第二级加氢裂化方法的第二级加氢裂化方法。 还提供了制备二级加氢裂化催化剂的方法。
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公开(公告)号：US10183286B2
公开(公告)日：2019-01-22
申请号：US14823839
申请日：2015-08-11
申请人： Jifei Jia , Andrew Rainis , Theodorus Luvidocus Michael Maesen , Richard Joseph Coser , Yihua Zhang , Thomas Michael Rea
发明人： Jifei Jia , Andrew Rainis , Theodorus Luvidocus Michael Maesen , Richard Joseph Coser , Yihua Zhang , Thomas Michael Rea
IPC分类号： B01J29/06 , B01J29/80 , B01J35/00 , B01J37/00 , B01J37/04 , B01J23/88 , B01J23/888 , B01J29/08 , B01J29/70 , B01J37/02 , B01J37/08 , C10G47/18 , B01J29/12 , B01J29/74
摘要： A second-stage hydrocracking catalyst is provided, comprising: a) a zeolite beta having an OD acidity of 20 to 400 μmol/g and an average domain size from 800 to 1500 nm2; b) a zeolite USY having an ASDI between 0.05 and 0.12; c) a catalyst support; and d) 0.1 to 10 wt % noble metal; wherein the second-stage hydrocracking catalyst provides a hydrogen consumption less than 350 SCFB across a range of synthetic conversions up to 37 wt % when used to hydrocrack hydrocarbonaceous feeds having an initial boiling point greater than 380° F. (193° C.). A second-stage hydrocracking process using the second-stage hydrocracking process is provided. A method to make the second-stage hydrocracking catalyst is also provided.
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公开(公告)号：US5685973A
公开(公告)日：1997-11-11
申请号：US653094
申请日：1996-05-24
申请人： Stacey I. Zones , Andrew Rainis
发明人： Stacey I. Zones , Andrew Rainis
IPC分类号： B01J29/04 , C01B39/08 , C01B39/12 , C01B39/48 , C07C2/66 , C07C5/22 , C07C5/27 , C07C5/41 , C07C6/12 , C10G3/00 , C10G11/05 , C10G35/095 , C10G45/64 , C10G47/16 , C10G50/00
CPC分类号： C10G50/00 , B01J29/04 , C01B39/082 , C01B39/12 , C01B39/48 , C07C2/66 , C07C5/226 , C07C5/2724 , C07C5/41 , C07C5/415 , C07C6/126 , C10G11/05 , C10G3/44 , C10G3/45 , C10G3/49 , C10G35/095 , C10G45/64 , C10G47/16 , C07C2529/064 , C10G2300/1037 , C10G2300/1088 , C10G2300/1096 , C10G2300/301 , C10G2400/02 , C10G2400/30 , Y02P30/20
摘要： The present invention relates to new crystalline zeolite SSZ-42 prepared by processes for preparing crystalline molecular sieves, particularly large pore zeolites, using an organic templating agent selected from the group consisting of N-benzyl-1,4-diazabicyclo�2.2.2!octane cations and N-benzyl-1-azabicyclo�2.2.2!octane cations.
摘要翻译： 本发明涉及通过使用选自N-苄基-1,4-二氮杂双环[2.2.2]二氧杂环己烷的有机模板剂制备结晶分子筛，特别是大孔沸石的方法制备的新的结晶沸石SSZ-42， 辛烷阳离子和N-苄基-1-氮杂双环[2.2.2]辛烷阳离子。
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公开(公告)号：US4388180A
公开(公告)日：1983-06-14
申请号：US330300
申请日：1981-12-14
申请人： Andrew Rainis
发明人： Andrew Rainis
摘要： A process is disclosed which removes gangue minerals from phosphate rock by forming an aqueous slurry of phosphate rock and its impurities, then using a low boiling, nonpolar, water insoluble, bridging hydrocarbon to selectively agglomerate the phosphates.
摘要翻译： 公开了一种方法，其通过形成磷酸盐岩及其杂质的含水浆料，然后使用低沸点，非极性的水不溶性桥联烃选择性地聚集磷酸盐，从磷酸盐岩中除去脉石矿物。
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