公开(公告)号：US08961794B2

公开(公告)日：2015-02-24

申请号：US13177738

申请日：2011-07-07

Applicant: Kristi Fjare ,  Jianhua Yao ,  Edward L. Sughrue ,  Jaehoon Bae ,  TiePan Shi ,  Yun Bao ,  Edgar Lotero

Inventor： Kristi Fjare ,  Jianhua Yao ,  Edward L. Sughrue ,  Jaehoon Bae ,  TiePan Shi ,  Yun Bao ,  Edgar Lotero

IPC: B01D11/04 ,  B01D11/02 ,  C10G21/06 ,  C10G21/14 ,  C10G21/16 ,  C10G3/00 ,  C10G1/02 ,  C10G21/02 ,  C10L1/02 ,  C10L1/00

CPC classification number: C10G3/40 ,  B01D11/0288 ,  B01D11/0492 ,  C10G1/02 ,  C10G21/02 ,  C10G2300/1014 ,  C10G2300/205 ,  C10G2300/208 ,  C10G2300/44 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/02 ,  C10L1/023 ,  C10L1/026 ,  Y02P30/20

Abstract: This invention relates to a process for production of transportation fuels from biomass. More particularly, this invention relates to a process for using solvent to remove metal impurities and high molecular weight components from biomass derived biocrude to prevent potential catalyst poisoning and catalyst bed plugging in biocrude-to-transportation fuel upgrading process.

Abstract translation: 本发明涉及从生物质生产运输燃料的方法。 更具体地说，本发明涉及一种使用溶剂从生物质衍生的生物原料中除去金属杂质和高分子量组分的方法，以防止潜在的催化剂中毒和催化剂床堵塞在生物重运输燃料升级过程中。

公开(公告)号：US20130237728A1

公开(公告)日：2013-09-12

申请号：US13416533

申请日：2012-03-09

Applicant: Edgar LOTERO ,  Kristi FJARE ,  TiePan SHI ,  Sourabh PANSARE ,  Yun BAO

Inventor： Edgar LOTERO ,  Kristi FJARE ,  TiePan SHI ,  Sourabh PANSARE ,  Yun BAO

IPC: C10L1/04 ,  B01J8/00

CPC classification number: C10L1/06 ,  B01J21/14 ,  B01J21/18 ,  B01J23/10 ,  B01J23/462 ,  B01J23/755 ,  B01J23/78 ,  B01J23/83 ,  B01J23/8885 ,  B01J35/1014 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/0201 ,  B01J37/08 ,  B01J37/20 ,  C10G1/08 ,  C10G3/44 ,  C10G3/45 ,  C10G3/47 ,  C10G3/50 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G50/00 ,  C10G69/126 ,  C10G2300/1011 ,  C10G2300/304 ,  C10G2300/307 ,  C10G2300/308 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/04 ,  C10L1/08 ,  Y02P30/20

Abstract: Oxygenate feedstocks derived from biomass are converted to a variety of fuels including gas, jet, and diesel fuel range hydrocarbons. General methods are provided including hydrolysis, dehydration, hydrogenation, condensation, oligomerization, and/or a polishing hydrotreating.

Abstract translation: 衍生自生物质的氧化合物原料转化为各种燃料，包括气体，喷射和柴油燃料范围的烃。 提供了一般方法，包括水解，脱水，氢化，缩合，低聚和/或抛光加氢处理。

公开(公告)号：US20130219778A1

公开(公告)日：2013-08-29

申请号：US13771169

申请日：2013-02-20

Applicant: Jianhua Yao ,  Edward L. Sughrue, II ,  TiePan Shi ,  Brian Dunn

Inventor： Jianhua Yao ,  Edward L. Sughrue, II ,  TiePan Shi ,  Brian Dunn

IPC: C07C29/17

CPC classification number: C07C29/175 ,  C07C29/60 ,  C07C31/08

Abstract: The conversion of diols to mono-alcohols as fuel blendstocks. In one embodiment hydrotreating processes are described that selectively convert glycols to mono-alcohols that can be blended as biofuels. Both NiMo and CoMo catalysts are active for the reaction and reaction conditions can also impact the selectivity of mono-alcohols.

Abstract translation: 二醇转化为单醇作为燃料混合料。 在一个实施方案中，描述了加氢处理方法，其选择性地将二醇转化为可以作为生物燃料混合的单醇。 NiMo和CoMo催化剂对于反应都是有活性的，反应条件也会影响单醇的选择性。

公开(公告)号：US08809605B2

公开(公告)日：2014-08-19

申请号：US13089458

申请日：2011-04-19

Applicant: Yun Bao ,  Edward L. Sughrue, II ,  Jianhua Yao ,  TiePan Shi ,  Kristi A. Fjare ,  Lisa L. Myers ,  Ronald E. Brown

Inventor： Yun Bao ,  Edward L. Sughrue, II ,  Jianhua Yao ,  TiePan Shi ,  Kristi A. Fjare ,  Lisa L. Myers ,  Ronald E. Brown

IPC: C07C1/20 ,  C10G45/30 ,  C01B3/38 ,  C10G3/00 ,  C10G45/02 ,  C10G45/46 ,  C10G45/44

CPC classification number: C10G3/50 ,  C01B3/38 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/062 ,  C01B2203/1058 ,  C01B2203/107 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1247 ,  C10G3/49 ,  C10G45/02 ,  C10G45/30 ,  C10G45/44 ,  C10G45/46 ,  C10G2300/1014 ,  C10G2300/202 ,  C10G2300/4081 ,  C10G2300/42 ,  C10G2400/02 ,  Y02P30/42

Abstract: Technologies to convert biomass to liquid hydrocarbon fuels are currently being developed to decrease our carbon footprint and increase use of renewable fuels. Since sugars/sugar derivatives from biomass have high oxygen content and low hydrogen content, coke becomes an issue during zeolite upgrading to liquid hydrocarbon fuels. A process was designed to reduce the coke by co-feeding sugars/sugar derivatives with a saturated recycle stream containing hydrogenated products.

Abstract translation: 目前正在开发将生物质转化为液态碳氢化合物燃料的技术，以减少我们的碳足迹和增加可再生燃料的使用。 由于来自生物质的糖/糖衍生物具有高氧含量和低氢含量，因此在沸石升级成液态烃燃料时，焦炭成为问题。 设计了一种方法，通过将糖/糖衍生物与含有氢化产物的饱和循环流共同进料来减少焦炭。

公开(公告)号：US20120023810A1

公开(公告)日：2012-02-02

申请号：US13177738

申请日：2011-07-07

Applicant: Kristi FJARE ,  Jianhua YAO ,  Edward L. SUGHRUE ,  Jaehoon BAE ,  TiePan SHI ,  Yun BAO ,  Edgar LOTERO

Inventor： Kristi FJARE ,  Jianhua YAO ,  Edward L. SUGHRUE ,  Jaehoon BAE ,  TiePan SHI ,  Yun BAO ,  Edgar LOTERO

IPC: C10L1/00

CPC classification number: C10G3/40 ,  B01D11/0288 ,  B01D11/0492 ,  C10G1/02 ,  C10G21/02 ,  C10G2300/1014 ,  C10G2300/205 ,  C10G2300/208 ,  C10G2300/44 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/02 ,  C10L1/023 ,  C10L1/026 ,  Y02P30/20

Abstract: This invention relates to a process for production of transportation fuels from biomass. More particularly, this invention relates to a process for using solvent to remove metal impurities and high molecular weight components from biomass derived biocrude to prevent potential catalyst poisoning and catalyst bed plugging in biocrude-to-transportation fuel upgrading process.

Abstract translation: 本发明涉及从生物质生产运输燃料的方法。 更具体地说，本发明涉及一种使用溶剂从生物质衍生的生物原料中除去金属杂质和高分子量组分的方法，以防止潜在的催化剂中毒和催化剂床堵塞在生物重运输燃料升级过程中。

公开(公告)号：US08993818B2

公开(公告)日：2015-03-31

申请号：US13214508

申请日：2011-08-22

Applicant: Yun Bao ,  Edward L. Sughrue, II ,  Jianhua Yao ,  TiePan Shi ,  Kristi A. Fjare ,  Lisa L. Myers

Inventor： Yun Bao ,  Edward L. Sughrue, II ,  Jianhua Yao ,  TiePan Shi ,  Kristi A. Fjare ,  Lisa L. Myers

IPC: C07C1/20 ,  B01J23/882 ,  B01J23/883 ,  B01J23/887 ,  B01J29/40 ,  C10G3/00

CPC classification number: C07C1/20 ,  B01J23/882 ,  B01J23/883 ,  B01J23/8877 ,  B01J29/40 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/06 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/72 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2523/80 ,  C07C2523/86 ,  C07C2523/882 ,  C07C2523/883 ,  C07C2525/02 ,  C07C2527/10 ,  C07C2531/20 ,  C07C2531/22 ,  C07C2531/24 ,  C10G3/00 ,  C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/49 ,  C10G3/50 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2400/02 ,  Y02P30/20 ,  C07C9/00

Abstract: Technologies to convert biomass to liquid hydrocarbon fuels are currently being developed to decrease our carbon footprint and increase use of renewable fuels. Since sugars/sugar derivatives from biomass have high oxygen content and low hydrogen content, coke becomes an issue during zeolite upgrading to liquid hydrocarbon fuels. A self-sustainable process was designed to reduce the coke by co-feeding sugars/sugar derivatives with the paraffin products from hydrogenation of sugars/sugar derivatives. Paraffins without complete conversion result in products with less aromatics and relatively low density compared with the products directly from zeolite upgrading. Thus, the process is more economically favorable.

Abstract translation: 目前正在开发将生物质转化为液态碳氢化合物燃料的技术，以减少我们的碳足迹和增加可再生燃料的使用。 由于来自生物质的糖/糖衍生物具有高氧含量和低氢含量，因此在沸石升级成液态烃燃料时，焦炭成为问题。 旨在通过将糖/糖衍生物与糖/糖衍生物氢化的石蜡产品共同进料来减少焦炭的自我维持过程。 没有完全转化的石蜡与直接来自沸石升级的产品相比，产生的芳族化合物和密度相对较低的产物。 因此，这个过程在经济上更有利。

公开(公告)号：US20120095274A1

公开(公告)日：2012-04-19

申请号：US13214508

申请日：2011-08-22

Applicant: Yun BAO ,  Edward L. SUGHRUE, II ,  Jianhua YAO ,  TiePan SHI ,  Kristi A. FJARE ,  Lisa L. MYERS

Inventor： Yun BAO ,  Edward L. SUGHRUE, II ,  Jianhua YAO ,  TiePan SHI ,  Kristi A. FJARE ,  Lisa L. MYERS

IPC: C07C1/20 ,  C07C1/00 ,  B01J10/00

CPC classification number: C07C1/20 ,  B01J23/882 ,  B01J23/883 ,  B01J23/8877 ,  B01J29/40 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/06 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/72 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2523/80 ,  C07C2523/86 ,  C07C2523/882 ,  C07C2523/883 ,  C07C2525/02 ,  C07C2527/10 ,  C07C2531/20 ,  C07C2531/22 ,  C07C2531/24 ,  C10G3/00 ,  C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/49 ,  C10G3/50 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2400/02 ,  Y02P30/20 ,  C07C9/00

Abstract: Technologies to convert biomass to liquid hydrocarbon fuels are currently being developed to decrease our carbon footprint and increase use of renewable fuels. Since sugars/sugar derivatives from biomass have high oxygen content and low hydrogen content, coke becomes an issue during zeolite upgrading to liquid hydrocarbon fuels. A self-sustainable process was designed to reduce the coke by co-feeding sugars/sugar derivatives with the paraffin products from hydrogenation of sugars/sugar derivatives. Paraffins without complete conversion result in products with less aromatics and relatively low density compared with the products directly from zeolite upgrading. Thus, the process is more economically favorable.

Abstract translation: 目前正在开发将生物质转化为液态碳氢化合物燃料的技术，以减少我们的碳足迹和增加可再生燃料的使用。 由于来自生物质的糖/糖衍生物具有高氧含量和低氢含量，因此在沸石升级成液态烃燃料时，焦炭成为问题。 旨在通过将糖/糖衍生物与糖/糖衍生物氢化的石蜡产品共同进料来减少焦炭的自我维持过程。 没有完全转化的石蜡与直接来自沸石升级的产品相比，产生的芳族化合物和密度相对较低的产品。 因此，这个过程在经济上更有利。

公开(公告)号：US08629310B2

公开(公告)日：2014-01-14

申请号：US13416533

申请日：2012-03-09

Applicant: Edgar Lotero ,  Kristi Fjare ,  TiePan Shi ,  Sourabh Pansare ,  Yun Bao

Inventor： Edgar Lotero ,  Kristi Fjare ,  TiePan Shi ,  Sourabh Pansare ,  Yun Bao

IPC: C07C1/207

CPC classification number: C10L1/06 ,  B01J21/14 ,  B01J21/18 ,  B01J23/10 ,  B01J23/462 ,  B01J23/755 ,  B01J23/78 ,  B01J23/83 ,  B01J23/8885 ,  B01J35/1014 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/0201 ,  B01J37/08 ,  B01J37/20 ,  C10G1/08 ,  C10G3/44 ,  C10G3/45 ,  C10G3/47 ,  C10G3/50 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G50/00 ,  C10G69/126 ,  C10G2300/1011 ,  C10G2300/304 ,  C10G2300/307 ,  C10G2300/308 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/04 ,  C10L1/08 ,  Y02P30/20

Abstract: Oxygenate feedstocks derived from biomass are converted to a variety of fuels including gas, jet, and diesel fuel range hydrocarbons. General methods are provided including hydrolysis, dehydration, hydrogenation, condensation, oligomerization, and/or a polishing hydrotreating.

Abstract translation: 衍生自生物质的氧化合物原料转化为各种燃料，包括气体，喷射和柴油燃料范围的烃。 提供了一般方法，包括水解，脱水，氢化，缩合，低聚和/或抛光加氢处理。

公开(公告)号：US08552230B2

公开(公告)日：2013-10-08

申请号：US12912164

申请日：2010-10-26

Applicant: Jianhua Yao ,  Edward L. Sughrue, II ,  Yun Bao ,  Kristi Fjare ,  TiePan Shi

Inventor： Jianhua Yao ,  Edward L. Sughrue, II ,  Yun Bao ,  Kristi Fjare ,  TiePan Shi

IPC: C07C31/27

CPC classification number: C10G3/47 ,  C10G3/46 ,  C10G3/49 ,  C10G3/50 ,  C10G2300/1011 ,  C10G2300/301 ,  C10G2400/02 ,  Y02P30/20

Abstract: Materials and processes for the conversion of carbohydrates and polyols to gasoline boiling range hydrocarbons. Carbohydrates and polyols are reacted in the presence of modified zeolite catalysts to form a reaction product containing non-aromatic and aromatic gasoline boiling range hydrocarbons.

Abstract translation: 将碳水化合物和多元醇转化为汽油沸程烃的材料和方法。 碳水化合物和多元醇在改性沸石催化剂的存在下反应形成含有非芳族和芳族汽油沸程烃的反应产物。

公开(公告)号：US20110263916A1

公开(公告)日：2011-10-27

申请号：US13089458

申请日：2011-04-19

Applicant: Yun BAO ,  Edward L. SUGHRUE, II ,  Jianhua YAO ,  TiePan SHI ,  Kristi A. FJARE ,  Lisa L. MYERS ,  Ronald E. BROWN

Inventor： Yun BAO ,  Edward L. SUGHRUE, II ,  Jianhua YAO ,  TiePan SHI ,  Kristi A. FJARE ,  Lisa L. MYERS ,  Ronald E. BROWN

IPC: C07C1/20 ,  B01J8/00

CPC classification number: C10G3/50 ,  C01B3/38 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/062 ,  C01B2203/1058 ,  C01B2203/107 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1247 ,  C10G3/49 ,  C10G45/02 ,  C10G45/30 ,  C10G45/44 ,  C10G45/46 ,  C10G2300/1014 ,  C10G2300/202 ,  C10G2300/4081 ,  C10G2300/42 ,  C10G2400/02 ,  Y02P30/42

Abstract: Technologies to convert biomass to liquid hydrocarbon fuels are currently being developed to decrease our carbon footprint and increase use of renewable fuels. Since sugars/sugar derivatives from biomass have high oxygen content and low hydrogen content, coke becomes an issue during zeolite upgrading to liquid hydrocarbon fuels. A process was designed to reduce the coke by co-feeding sugars/sugar derivatives with a saturated recycle stream containing hydrogenated products.

Abstract translation: 目前正在开发将生物质转化为液态碳氢化合物燃料的技术，以减少我们的碳足迹和增加可再生燃料的使用。 由于来自生物质的糖/糖衍生物具有高氧含量和低氢含量，因此在沸石升级成液态烃燃料时，焦炭成为问题。 设计了一种方法，通过将糖/糖衍生物与含有氢化产物的饱和循环流共同进料来减少焦炭。