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公开(公告)号：US09371256B2
公开(公告)日：2016-06-21
申请号：US14230835
申请日：2014-03-31
IPC分类号： C07C1/20 , C07C1/22 , C07C5/02 , C10L1/08 , C10G3/00 , C10G45/02 , C10G69/06 , C10G9/00 , C07C1/00 , C07C1/06 , C07C1/213
CPC分类号： C07C1/22 , C07C5/02 , C10G3/42 , C10G3/46 , C10G3/50 , C10G9/00 , C10G45/02 , C10G69/06 , C10G2300/1014 , C10G2300/1018 , C10G2300/1037 , C10G2300/1055 , C10G2300/107 , C10G2300/1074 , C10G2300/301 , C10G2400/04 , C10L1/08 , Y02E50/13 , Y02P30/20
摘要： A heated petroleum-derived hydrocarbon is contacted with a triglyceride feed in a thermal cracking zone to decompose and remove impurities prior to hydrotreating the mixture to fuel range hydrocarbon. This process allows the use of a variety of low cost triglyceride feeds while reducing fouling of process equipment and catalyst. The process also reduces the use of chemicals required for conventional degumming of triglyceride feeds.
摘要翻译： 将加热的石油衍生的烃与热裂解区中的甘油三酯进料接触以在将混合物加氢处理至燃料范围的烃之前分解和除去杂质。 该方法允许使用各种低成本甘油三酯饲料，同时减少工艺设备和催化剂的结垢。 该方法还减少了甘油三酯饲料常规脱胶所需的化学品的使用。
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2.发明授权Metal impurity and high molecular weight components removal of biomass derived biocrude 有权金属杂质和高分子量成分除去生物质衍生生物公开(公告)号：US08961794B2
公开(公告)日：2015-02-24
申请号：US13177738
申请日：2011-07-07
申请人： Kristi Fjare , Jianhua Yao , Edward L. Sughrue , Jaehoon Bae , TiePan Shi , Yun Bao , Edgar Lotero
发明人： Kristi Fjare , Jianhua Yao , Edward L. Sughrue , Jaehoon Bae , TiePan Shi , Yun Bao , Edgar Lotero
IPC分类号： B01D11/04 , B01D11/02 , C10G21/06 , C10G21/14 , C10G21/16 , C10G3/00 , C10G1/02 , C10G21/02 , C10L1/02 , C10L1/00
CPC分类号： C10G3/40 , B01D11/0288 , B01D11/0492 , C10G1/02 , C10G21/02 , C10G2300/1014 , C10G2300/205 , C10G2300/208 , C10G2300/44 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/02 , C10L1/023 , C10L1/026 , Y02P30/20
摘要： This invention relates to a process for production of transportation fuels from biomass. More particularly, this invention relates to a process for using solvent to remove metal impurities and high molecular weight components from biomass derived biocrude to prevent potential catalyst poisoning and catalyst bed plugging in biocrude-to-transportation fuel upgrading process.
摘要翻译： 本发明涉及从生物质生产运输燃料的方法。 更具体地说，本发明涉及一种使用溶剂从生物质衍生的生物原料中除去金属杂质和高分子量组分的方法，以防止潜在的催化剂中毒和催化剂床堵塞在生物重运输燃料升级过程中。
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公开(公告)号：US20110046423A1
公开(公告)日：2011-02-24
申请号：US12849109
申请日：2010-08-03
申请人： Edward L. SUGHRUE , Jianhua YAO
发明人： Edward L. SUGHRUE , Jianhua YAO
IPC分类号： C07C1/00
CPC分类号： C10G3/45 , C01B3/34 , C01B2203/0205 , C10G3/46 , C10G3/47 , C10G3/50 , C10G45/08 , C10G2300/1011 , C10G2300/1014 , C10G2300/104 , C10G2300/1044 , C10G2300/1051 , C10G2300/1055 , C10G2300/305 , C10G2400/02 , Y02P20/133 , Y02P20/145 , Y02P30/20
摘要： Conversion of renewable hydrocarbons to transportation fuels is required to reduce carbon emission, limit the use of fossil fuels, and develop renewable energy sources. Sorbitol, xylitol and trehelose are polyalcohols generated from the liquefaction of various sugars and carbohydrates in biomass from algae, corn, sugarcane, switchgrasses, and biological wastes. Mixtures of aqueous polyols and fuel feedstocks are catalyzed over metal catalysts to produce hexanes, pentanes, and lighter hydrocarbons. By managing the catalyst, reaction conditions and sulfur content, the octane value of the product fuel is dramatically increased.
摘要翻译： 将可再生碳氢化合物转化为运输燃料需要减少碳排放，限制化石燃料的使用和开发可再生能源。 山梨糖醇，木糖醇和古洛糖是来自藻类，玉米，甘蔗，柳枝稷和生物废物的生物质中各种糖和碳水化合物的液化所产生的多元醇。 含水多元醇和燃料原料的混合物在金属催化剂上催化产生己烷，戊烷和轻质烃。 通过管理催化剂，反应条件和硫含量，产品燃料的辛烷值显着增加。
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4.发明授权Process for the removal of heavy metals from gases, and compositions therefor and therewith 有权用于从气体中除去重金属的方法及其组合物公开(公告)号：US07625837B2
公开(公告)日：2009-12-01
申请号：US11158231
申请日：2005-06-21
IPC分类号： B01J23/00 , B01J23/20 , B01J21/00 , B01J29/06 , C01G29/00 , C01G30/00 , C01D1/02 , B01D53/04
CPC分类号： B01D53/64 , B01D53/8665 , B01D2257/60 , B01D2257/602 , B01J20/0214 , B01J20/04 , B01J20/06 , B01J20/08 , B01J20/106 , B01J20/18 , B01J20/3007 , B01J20/3078 , B01J20/3204 , B01J20/3236 , B01J2220/42 , Y10S502/516
摘要： A composition, containing vanadium, potassium and a support is disclosed. A method of preparing such composition is also disclosed. The composition is employed in a process to remove a heavy metal from a gaseous feed stream which can optionally include a separate heavy metal adsorption stage.
摘要翻译： 公开了含有钒，钾和载体的组合物。 还公开了制备这种组合物的方法。 该组合物用于从气态进料流中除去重金属的方法，其可以任选地包括单独的重金属吸附级。
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5.发明申请HYDROTREATING AND CATALYTIC DEWAXING PROCESS FOR MAKING DIESEL FROM OILS AND/OR FATS 有权用于从油和/或脂肪制造柴油的加氢和催化脱蜡方法公开(公告)号：US20090019763A1
公开(公告)日：2009-01-22
申请号：US11778295
申请日：2007-07-16
IPC分类号： C10L1/16
CPC分类号： C10G45/64 , C10G3/46 , C10G3/49 , C10G2300/1014 , C10G2300/1018 , C10G2300/1048 , C10G2300/107 , C10G2300/304 , C10G2300/4018 , C10G2300/802 , C10G2400/04 , Y02P30/20
摘要： Methods for producing C10-C30 hydrocarbons from fatty materials, such as triglyceride compounds, are provided. Hydrocarbon compounds, particularly those boiling in the temperature range of between about 80° F. to about 1000° F., are produced by contacting a fatty material with at least one catalyst comprising cobalt and molybdenum on a zeolite support under hydrotreating conditions. Additional hydrotreating catalysts may also be used to further improve the properties of the hydrocarbon product.
摘要翻译： 提供了从脂肪材料如甘油三酯化合物制备C10-C30烃的方法。 通过在加氢处理条件下使脂肪材料与至少一种包含钴和钼的催化剂在沸石载体上接触来制备烃化合物，特别是在约80°F至约1000°F温度范围内沸腾的烃化合物。 另外的加氢处理催化剂也可用于进一步改进烃产物的性质。
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公开(公告)号：US20080305949A1
公开(公告)日：2008-12-11
申请号：US12190177
申请日：2008-08-12
IPC分类号： B01J20/06
CPC分类号： B01J20/20 , B01D53/64 , B01D53/8665 , B01D2255/20715 , B01D2255/20723 , B01D2257/602 , Y10S210/914
摘要： A sorbent composition comprising a vanadium compound and a ZrO2 support material is disclosed. Methods of making and using the composition to remove heavy metals or heavy metal containing compounds from a fluid stream are also provided. Such methods are particularly useful in the removal of mercury and mercury compounds from flue gas streams produced from the combustion of hydrocarbon-containing materials such as coal and petroleum fuels.
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公开(公告)号：US20080300132A1
公开(公告)日：2008-12-04
申请号：US12190155
申请日：2008-08-12
IPC分类号： B01J20/06
CPC分类号： B01J20/20 , B01D53/64 , B01D53/8665 , B01D2255/20715 , B01D2255/20723 , B01D2257/602 , Y10S210/914
摘要： A sorbent composition comprising a vanadium compound and a ZrO2 support material is disclosed. Methods of making and using the composition to remove heavy metals or heavy metal containing compounds from a fluid stream are also provided. Such methods are particularly useful in the removal of mercury and mercury compounds from flue gas streams produced from the combustion of hydrocarbon-containing materials such as coal and petroleum fuels.
摘要翻译： 公开了一种包含钒化合物和ZrO 2载体材料的吸附剂组合物。 还提供了制备和使用该组合物以从流体流中除去重金属或含重金属的化合物的方法。 这种方法特别适用于从含烃材料如煤和石油燃料的燃烧产生的烟道气流中除去汞和汞化合物。
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公开(公告)号：US07449104B2
公开(公告)日：2008-11-11
申请号：US10190457
申请日：2002-07-05
CPC分类号： B01J20/06 , B01J20/0225 , B01J20/08 , B01J20/106 , B01J20/28004 , B01J20/28011 , B01J20/3433 , B01J20/3458 , C10G11/05 , C10G11/18 , C10G25/09
摘要： An integrated fluid catalytic cracking (FCC) and desulfurization system for processing hydrocarbon-containing fluids. The integrated system employs a cracking/desulfurization unit having a reactor, a regenerator, and a reducer. A mixture of solid FCC catalyst particulates and solid sulfur sorbent particulates are circulated through the reactor, regenerator, and reducer to provide for substantially continuous cracking and desulfurization of the hydrocarbon-containing fluid, as well as substantially continuous regeneration of both the FCC catalyst and the sulfur sorbent.
摘要翻译： 用于处理含烃流体的综合流化催化裂化（FCC）和脱硫系统。 集成系统采用具有反应器，再生器和还原剂的裂化/脱硫装置。 固体FCC催化剂颗粒和固体硫吸附剂颗粒的混合物循环通过反应器，再生器和还原剂，以提供含烃流体的基本上连续的裂化和脱硫，以及FCC催化剂和 硫吸附剂。
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公开(公告)号：US5024750A
公开(公告)日：1991-06-18
申请号：US457411
申请日：1989-12-26
CPC分类号： C10G69/04 , C10G67/0463
摘要： Heavy hydrocarbon oil, containing asphaltene, sulfur and metal contaminants, is hydrotreated in the presence of a hydrotreating catalyst having a small pore diameter in an initial process step to remove sulfur and metal contaminants. Removal of additional metal and sulfur contaminants is then accomplished in a second process step by solvent deasphalting, wherein the size of the pore diameter of the hydrotreating catalyst utilized in the initial hydrotreating step affects the metals rejection in the subsequent solvent deasphalting step. In a third process step the deasphalted oil is catalytically cracked substantially in the absence of added hydrogen to provide lower boiling hydrocarbon products.
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公开(公告)号：US08673805B2
公开(公告)日：2014-03-18
申请号：US13233256
申请日：2011-09-15
申请人： Madhu Anand , Jianhua Yao , Edward L. Sughrue, II
发明人： Madhu Anand , Jianhua Yao , Edward L. Sughrue, II
IPC分类号： B01J27/051 , B01J27/02
CPC分类号： C10L3/08 , B01J21/06 , B01J27/051 , B01J37/033 , C07C1/22 , C10G3/44 , C10G3/50 , C10G2300/1014 , C10L1/04 , Y02P30/20
摘要： Cellulose and hemicellulose from biomass can be broken down to C6 and C5 sugars and further converted to corresponding sugar alcohols. It is now found that a new catalyst, MoS2, is active for the hydrogenation of sugar alcohols to hydrocarbons. Combining the technologies listed above allows us to convert the cellulose/hemicellulose to liquid hydrocarbons.
摘要翻译： 来自生物质的纤维素和半纤维素可以分解成C6和C5糖，并进一步转化为相应的糖醇。 现在发现，新的催化剂MoS2对于将醇氢化成烃类是有活性的。 结合上述技术，可以将纤维素/半纤维素转化为液体烃。
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