Cationic microcapsule particles
    1.
    发明授权
    Cationic microcapsule particles 有权
    阳离子微胶囊颗粒

    公开(公告)号:US08067089B2

    公开(公告)日:2011-11-29

    申请号:US12382946

    申请日:2009-03-27

    IPC分类号: B32B27/14

    摘要: The present invention teaches a cationically charged or neutral microcapsule particle comprising an oil soluble or dispersible core material and a wall material at least partially surrounding the core material, the microcapsule wall material comprising the reaction product of a first composition in the presence of a second composition comprising an emulsifier which is cationic or nonionic, the first composition comprising a reaction product of i) an oil soluble or dispersible amine with ii) a multifunctional acrylate or methacrylate monomer or oligomer, an oil soluble acid and an initiator. The cationic or nonionic emulsifier comprises a water soluble or water dispersible material and optionally a water phase initiator. The first composition initiator and the water phase initiator is an energy-activated initiator. The reaction product of the first composition and second composition results in the formation of a population of microcapsules having a microcapsule wall of low permeance to the core material and having a zeta potential of −5 millivolts or greater. The resulting microcapsules have adherence to anionic surfaces.

    摘要翻译: 本发明教导了一种阳离子电荷或中性微胶囊颗粒,其包含油溶性或可分散的芯材料和至少部分包围芯材料的壁材料,所述微胶囊壁材料包含第一组合物在第二组合物存在下的反应产物 包括阳离子或非离子的乳化剂,所述第一组合物包含i)油溶性或可分散胺与ii)多官能丙烯酸酯或甲基丙烯酸酯单体或低聚物,油溶性酸和引发剂的反应产物。 阳离子或非离子乳化剂包括水溶性或水分散性材料和任选的水相引发剂。 第一组合物引发剂和水相引发剂是能量活化引发剂。 第一组合物和第二组合物的反应产物导致形成具有低磁导率至核心材料并具有-5毫伏或更大的ζ电位的微胶囊壁的微胶囊群。 所得微胶囊具有与阴离子表面的粘附。

    Cationic microcapsule particles
    3.
    发明申请
    Cationic microcapsule particles 有权
    阳离子微胶囊颗粒

    公开(公告)号:US20090274905A1

    公开(公告)日:2009-11-05

    申请号:US12382946

    申请日:2009-03-27

    IPC分类号: B32B27/14

    摘要: The present invention teaches a cationically charged or neutral microcapsule particle comprising an oil soluble or dispersible core material and a wall material at least partially surrounding the core material, the microcapsule wall material comprising the reaction product of a first composition in the presence of a second composition comprising an emulsifier which is cationic or nonionic, the first composition comprising a reaction product of i) an oil soluble or dispersible amine with ii) a multifunctional acrylate or methacrylate monomer or oligomer, an oil soluble acid and an initiator. The cationic or nonionic emulsifier comprises a water soluble or water dispersible material and optionally a water phase initiator. The first composition initiator and the water phase initiator is an energy-activated initiator. The reaction product of the first composition and second composition results in the formation of a population of microcapsules having a microcapsule wall of low permeance to the core material and having a zeta potential of−5 millivolts or greater. The resulting microcapsules have adherence to anionic surfaces.

    摘要翻译: 本发明教导了一种阳离子电荷或中性微胶囊颗粒,其包含油溶性或可分散的芯材料和至少部分包围芯材料的壁材料,所述微胶囊壁材料包含第一组合物在第二组合物存在下的反应产物 包括阳离子或非离子的乳化剂,所述第一组合物包含i)油溶性或可分散胺与ii)多官能丙烯酸酯或甲基丙烯酸酯单体或低聚物,油溶性酸和引发剂的反应产物。 阳离子或非离子乳化剂包括水溶性或水分散性材料和任选的水相引发剂。 第一组合物引发剂和水相引发剂是能量活化引发剂。 第一组合物和第二组合物的反应产物导致形成一组微胶囊,其具有低渗透性至核心材料的微胶囊壁,并且具有-5毫伏或更大的ζ电位。 所得微胶囊具有与阴离子表面的粘附。

    Encapsulated solid hydrophilic particles
    6.
    发明授权
    Encapsulated solid hydrophilic particles 有权
    密封固体亲水性颗粒

    公开(公告)号:US09192908B2

    公开(公告)日:2015-11-24

    申请号:US13864667

    申请日:2013-04-17

    IPC分类号: B01J13/22 B01J13/14

    摘要: A process of forming microcapsules is described. The microcapsule population is formed by providing an anionic or cationic, solid hydrophilic core material; providing an oil continuous phase, the oil continuous phase comprising one or more esters with chain length up to about 18 carbons. Emulsification is achieved by subjecting the mixture to high shear agitation and heating the mixture for a time sufficient to enable acid or amine acrylate or methacrylate and multifunctional acrylate or methacrylate to form a prepolymer which migrates to the anionic or cationic solid hydrophilic material, thereby forming prepolymers adhered to the hydrophilic core materials. Temperature is held or heating continued for a time sufficient to enable the prepolymer to flow onto and coalesce into a continuous film surface coating on the hydrophilic core material. Heating is carried out or light exposure or both for a time and temperature sufficient to cross link the prepolymers.

    摘要翻译: 描述形成微胶囊的方法。 通过提供阴离子或阳离子固体亲水芯材料形成微胶囊群; 提供油连续相,所述油连续相包含一种或多种链长至多约18个碳的酯。 通过使混合物进行高剪切搅拌并加热混合物足以使酸或胺丙烯酸酯或甲基丙烯酸酯和多官能丙烯酸酯或甲基丙烯酸酯形成预聚物以迁移至阴离子或阳离子固体亲水材料,从而形成预聚物来实现乳化 粘附在亲水芯材上。 温度保持或加热持续一段时间,足以使预聚物流动并聚结成亲水芯材上的连续膜表面涂层。 进行加热或曝光或两者都足以使预聚物交联的时间和温度。

    Particle with selected permeance wall
    7.
    发明授权
    Particle with selected permeance wall 有权
    颗粒与选定的渗透壁

    公开(公告)号:US08071214B2

    公开(公告)日:2011-12-06

    申请号:US12221781

    申请日:2008-08-06

    IPC分类号: B32B5/16

    摘要: The invention discloses a population of selected permeability microcapsule particles comprising an oil soluble or dispersible core material and a wall material at least partially surrounding the core material. The microcapsule wall material comprises the reaction product of a first composition in the presence of a second composition comprising an anionic emulsifier. The first composition comprises a reaction product of i) an oil soluble or dispersible amine with ii) a multifunctional acrylate or methacrylate monomer or oligomer, an oil soluble acid and an initiator. The anionic emulsifier comprises a water soluble or water dispersible acrylic acid alkyl acid copolymer, an optional initiator and an alkali or alkali salt. The reaction product of the first composition and second composition can result in the formation of a low permeability microcapsule wall. Optionally, one or both of the first composition initiator or water phase initiator is an energy-activated initiator, such as a UV initiator. The reaction can proceed by exposing the respective compositions to actinic radiation. Microcapsules of selected permeability can be produced by the process of the invention.

    摘要翻译: 本发明公开了一组选择的渗透性微胶囊颗粒,其包含油溶性或可分散的芯材料和至少部分地围绕芯材料的壁材料。 微胶囊壁材料包含第一组合物在包含阴离子乳化剂的第二组合物存在下的反应产物。 第一组合物包含i)油溶性或可分散胺与ii)多官能丙烯酸酯或甲基丙烯酸酯单体或低聚物,油溶性酸和引发剂的反应产物。 阴离子乳化剂包括水溶性或水分散性丙烯酸烷基酸共聚物,任选的引发剂和碱金属或碱金属盐。 第一组合物和第二组合物的反应产物可导致低渗透性​​微胶囊壁的形成。 任选地,第一组合物引发剂或水相引发剂中的一种或两种是能量活化引发剂,例如UV引发剂。 反应可以通过将各组合物暴露于光化辐射来进行。 选择的渗透性的微胶囊可以通过本发明的方法生产。

    Oil-in-water capsule manufacture process and microcapsules produced by such process
    9.
    发明授权
    Oil-in-water capsule manufacture process and microcapsules produced by such process 有权
    油包水胶囊制造工艺和通过这种方法生产的微胶囊

    公开(公告)号:US07736695B2

    公开(公告)日:2010-06-15

    申请号:US11436317

    申请日:2006-05-18

    IPC分类号: B01J13/02

    摘要: A novel method of forming oil in water process is disclosed. According to the invention process are obtained by steps comprising dispersing an oil soluble amine modified polyfunctional polyvinyl monomer and an oil soluble bi- or polyfunctional vinyl monomer along with a thermal or UV free radical initiator (optionally included in one or both of the oil or water phases) and an organic acid into an internal phase oil; heating or UV exposing for a time (and temperature) sufficient to oligomerize the amine modified polyfunctional polyvinyl monomer and oil soluble bi- or polyfunctional vinyl monomer forming a pre-polymer. Thereafter the process involves adding to the oil phase oil a water phase comprising a dispersion in water of an anionic emulsifier (and optionally initiator), and adding an emulsifying agent. Emulsification of the oil phase into the water phase (O/W) is controlled through the quantity of water employed. The emulsion is then UV exposed or heated for a time (and temperature) sufficient to decompose the free radical initiators in the oil and/or water phases; thereby forming microcapsule wall material at the interface of the water and oil phases.

    摘要翻译: 公开了一种在水中形成油的新方法。 根据本发明方法,通过以下步骤获得方法:包括将油溶性胺改性的多官能聚乙烯基单体和油溶性双官能或多官能乙烯基单体与热或UV自由基引发剂(任选地包括在一种或两种油或水中) 相)和有机酸转化为内相油; 加热或UV曝光足以使胺改性的多官能聚乙烯基单体和油溶性双官能或多官能乙烯基单体低聚的时间(和温度),形成预聚物。 此后,该方法包括向油相油中加入包含阴离子乳化剂(和任选的引发剂)的水分散体的水相,并加入乳化剂。 通过所用的水量控制油相进入水相(O / W)的乳化。 然后将乳液UV暴露或加热足以分解油和/或水相中的自由基引发剂的时间(和温度); 从而在水相和油相的界面处形成微胶囊壁材料。