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    Titanium and zirconium compounds
    1.
    发明授权
    Titanium and zirconium compounds 失效
    钛和锆化合物

    公开(公告)号：US06870064B2

    公开(公告)日：2005-03-22

    申请号：US10173270

    申请日：2002-06-17

    申请人： Giorgio Agostini ,  Mario Corigliano ,  Uwe Ernst Frank

    发明人： Giorgio Agostini ,  Mario Corigliano ,  Uwe Ernst Frank

    IPC分类号： C07D303/22 ,  C07F7/00 ,  C08K5/56 ,  C07F7/28

    CPC分类号： C07D303/22 ,  C07F7/003 ,  C08K5/56 ,  C08L21/00

    摘要： The present invention relates to titanium and zirconium compounds of the formulae (R1—OyXO—R2—W)z  I wherein each R1 is independently selected from the group consisting of alkyl radicals having from 1 to 8 carbon atoms; R2 is a divalent radical selected from the group consisting of alkylenes having 1 to 15 carbon atoms, arylene and alkyl substituted arylene groups having 6 to 10 carbon atoms; W is an epoxy group; and y is an integer of from 1 to 3, z is an integer of from 1 to 3 and the sum of y and z equals 4; and X is titanium or zirconium.

    摘要翻译： 本发明涉及式中的钛和锆化合物，其中每个R 1独立地选自具有1至8个碳原子的烷基; R 2是选自具有1至15个碳原子的亚烷基，亚芳基和具有6至10个碳原子的烷基取代亚芳基的二价基团; W是环氧基; y为1〜3的整数，z为1〜3的整数，y与z的和为4。 X为钛或锆。

    Titanium and zirconium compounds
    2.
    发明授权
    Titanium and zirconium compounds 失效
    钛和锆化合物

    公开(公告)号：US06417286B1

    公开(公告)日：2002-07-09

    申请号：US09624733

    申请日：2000-07-25

    申请人： Giorgio Agostini ,  Mario Corigliano ,  Uwe Ernst Frank

    发明人： Giorgio Agostini ,  Mario Corigliano ,  Uwe Ernst Frank

    IPC分类号： C08C1900

    CPC分类号： C07D303/22 ,  C07F7/003 ,  C08K5/56 ,  C08L21/00

    摘要： The present invention relates to titanium and zirconium compounds of the formulae (R1—O&Parenclosest;yX&Parenopenst;O—R2—W)z  I wherein each R1 is independently selected from the group consisting of alkyl radicals having from 1 to 8 carbon atoms; R2 is a divalent radical selected from the group consisting of alkylenes having 1 to 15 carbon atoms, arylene and alkyl substituted arylene groups having 6 to 10 carbon atoms; W is an epoxy group; and y is an integer of from 1 to 3, z is an integer of from 1 to 3 and the sum of y and z equals 4; and X is titanium or zirconium.

    摘要翻译： 本发明涉及下式的钛和锆化合物，其中R 1独立地选自具有1至8个碳原子的烷基; R2是选自具有1至15个碳原子的亚烷基，亚芳基和具有6至10个碳原子的烷基取代亚芳基的二价基团; W是环氧基; y为1〜3的整数，z为1〜3的整数，y与z的和为4。 X为钛或锆。

    Asymmetrical siloxy compounds
    3.
    发明授权
    Asymmetrical siloxy compounds 失效
    不对称甲硅烷基化合物

    公开(公告)号：US06410625B1

    公开(公告)日：2002-06-25

    申请号：US09535484

    申请日：2000-03-24

    申请人： Thierry Florent Edme Materne ,  Rene Jean Zimmer ,  Friedrich Visel ,  Uwe Ernst Frank ,  Giorgio Agostini

    发明人： Thierry Florent Edme Materne ,  Rene Jean Zimmer ,  Friedrich Visel ,  Uwe Ernst Frank ,  Giorgio Agostini

    IPC分类号： C08J320

    CPC分类号： C08K5/548 ,  C07F7/1804 ,  C08L21/00

    摘要： The present invention relates to asymmetrical siloxy compounds of the formula wherein R1, R2 and R3 are independently selected from the group consisting of alkoxy radicals having from 1 to 8 carbon atoms; R4 is selected from the group consisting of alkylene groups having from 1 to 1.5 carbon atoms and arylene and alkyl-substituted arylene groups having from 6 to 10 carbon atoms; n is an integer of from 2 to 8 and X is selected from the group consisting of and R5 is selected from the group consisting of alkyl groups having from 1 to 15 carbon atoms, aryl and alkyl substituted aryl groups having 6 to 10 carbon atoms.

    摘要翻译： 本发明涉及式R 1，R 2和R 3的不对称甲硅烷氧基化合物独立地选自具有1至8个碳原子的烷氧基; R 4选自具有1至1.5个碳原子的亚烷基和具有6至10个碳原子的亚芳基和烷基取代的亚芳基; n为2〜8的整数，X选自由以下组成的组，R 5选自碳原子数为1〜15的烷基，碳原子数为6〜10的芳基和烷基取代芳基。

    Rubber composition which contains irregular-shaped hollow inorganic particles and article having component thereof
    4.
    发明授权
    Rubber composition which contains irregular-shaped hollow inorganic particles and article having component thereof 有权
    包含不规则形状的中空无机颗粒的橡胶组合物和其组分的制品

    公开(公告)号：US06245860B1

    公开(公告)日：2001-06-12

    申请号：US09334409

    申请日：1999-06-16

    申请人： Thierry Florent Edmé Materne ,  Christian Kaes ,  Giorgio Agostini ,  Uwe Ernst Frank ,  Friedrich Visel

    发明人： Thierry Florent Edmé Materne ,  Christian Kaes ,  Giorgio Agostini ,  Uwe Ernst Frank ,  Friedrich Visel

    IPC分类号： C08F21012

    CPC分类号： C08K7/24 ,  C08K9/00 ,  C08L21/00

    摘要： A rubber composition which contains substantially hollow, irregularly-shaped particles, and/or fragments thereof derived from a surface-modified carbon black aggregate from the which the carbon black core has been removed. For example, an irregularly-shaped carbon black aggregate may be surface-modified to have interconnecting domains of at least one inorganic material on its surface and the carbon black core removed by an oxidation process leaving an irregularly-shaped, substantially hollow particle and/or fragments thereof of said inorganic materials. An article having a component of such rubber composition is also provided such as, for example, a tire or an industrial product.

    摘要翻译： 一种橡胶组合物，其含有基本上中空的不规则形状的颗粒，和/或其衍生自表面改性的炭黑聚集体的碎片，从其中去除了炭黑芯。 例如，不规则形状的炭黑聚集体可以被表面改性以在其表面上具有至少一种无机材料的互连结构域，并且通过氧化工艺除去碳黑芯，留下不规则形状的基本上中空的颗粒和/或 所述无机材料的片段。 还提供了具有这种橡胶组合物成分的制品，例如轮胎或工业产品。

    Process for the preparation of a particular reinforced rubber composition
    6.
    发明授权
    Process for the preparation of a particular reinforced rubber composition 失效
    制备特定增强橡胶组合物的方法

    公开(公告)号：US5760110A

    公开(公告)日：1998-06-02

    申请号：US801426

    申请日：1997-02-18

    申请人： Rene Jean Zimmer ,  Uwe Ernst Frank ,  Friedrich Visel ,  Thierry Florent Edme Materne ,  Giorgio Agostini

    发明人： Rene Jean Zimmer ,  Uwe Ernst Frank ,  Friedrich Visel ,  Thierry Florent Edme Materne ,  Giorgio Agostini

    IPC分类号： B60C1/00 ,  C08K3/04 ,  C08K3/06 ,  C08K3/22 ,  C08K3/36 ,  C08K5/44 ,  C08K5/548 ,  C08K9/04 ,  C08L9/00 ,  C09C1/28 ,  C09C1/40 ,  C09C1/56 ,  C08K5/46 ,  C08K3/08 ,  C08K3/34

    CPC分类号： C08K5/548

    摘要： The invention relates to a process for the preparation of a rubber composition involving thermomechanically mixing in a preparatory mixing step at least one sulfur vulcanizable elastomer, a particulate filler and an unsymmetrical organosilicon disulfide compound of the formula ##STR1## wherein Z is selected from the group consisting of: ##STR2## wherein R.sup.2 may be the same or different and is independently selected from the group consisting of an alkyl group having 1 to 4 carbons and phenyl; R.sup.3 may be the same of different and is independently selected from the group consisting of alkoxy groups having 1 to 8 carbon atoms and cycloalkoxy groups with 5 to 8 carbon atoms; and R.sup.1 is selected from the group consisting of a substituted or unsubstituted alkylene group having a total of 1 to 18 carbon atoms and a substituted or unsubstituted arylene group having a total of 6 to 12 carbon atoms.

    摘要翻译： 本发明涉及一种制备橡胶组合物的方法，所述橡胶组合物在制备混合步骤中热机械混合至少一种硫可硫化弹性体，颗粒填料和式“IMAGE”的不对称有机硅二硫化物化合物，其中Z选自 其组成为：其中R 2可以相同或不同，并且独立地选自具有1至4个碳原子的烷基和苯基; R3可以相同，不同，独立地选自碳原子数为1〜8的烷氧基和碳原子数为5〜8的环烷氧基。 并且R 1选自具有总共1至18个碳原子的取代或未取代的亚烷基和具有总共6至12个碳原子的取代或未取代的亚芳基。

    Rubber composition containing two silicas
    7.
    发明授权
    Rubber composition containing two silicas 有权
    含有二氧化硅的橡胶组合物

    公开(公告)号：US06506829B1

    公开(公告)日：2003-01-14

    申请号：US09625109

    申请日：2000-07-25

    申请人： Thierry Florent Edme Materne ,  Giorgio Agostini ,  Friedrich Visel ,  Uwe Ernst Frank ,  René Jean Zimmer

    发明人： Thierry Florent Edme Materne ,  Giorgio Agostini ,  Friedrich Visel ,  Uwe Ernst Frank ,  René Jean Zimmer

    IPC分类号： C08K336

    CPC分类号： B60C1/0016 ,  C08K3/36 ,  C08K2201/014 ,  C08L21/00

    摘要： The present invention relates to a rubber composition comprising (A) an elastomer containing olefinic unsaturation and (B) 35 to 110 phr of silica filler, wherein said silica filler is comprised of (i) 10 to 100 phr of a first silica having a pore size distribution maximum of the aggregates in the first silica ranging from greater than 55 to 400 nm as determined by mercury porosimetry and an average specific surface area ranging from 60 to 135 m2/g as determined by N2 adsorption; and (ii) 10 to 100 phr of a second silica having a pore size distribution maximum of the aggregates in the second silica ranging from 5 to 50 nm as determined by mercury porosimetry and an average specific surface area ranging from 140 to 250 m2/g as determined by N2 adsorption.

    摘要翻译： 本发明涉及一种橡胶组合物，其包含（A）含有烯属不饱和的弹性体和（B）35至110phr的二氧化硅填料，其中所述二氧化硅填料由（i）10至100phr的具有孔 通过汞孔率法测定的第一硅石中的聚集体的尺寸分布最大值为大于55至400nm，通过N 2吸附测定的平均比表面积为60至135m 2 / g; 和（ii）通过水银孔率法测定的10至100phr的第二二氧化硅，其第二硅石中的聚集体的孔径分布最大值为5至50nm，平均比表面积为140-250m 2 / g 由N 2吸附测定。

    Rubber composition and tire having tread thereof
    8.
    发明授权
    Rubber composition and tire having tread thereof 失效
    橡胶组合物和具有胎面的轮胎

    公开(公告)号：US6136919A

    公开(公告)日：2000-10-24

    申请号：US85203

    申请日：1998-05-27

    申请人： Rene Jean Zimmer ,  Friedrich Visel ,  Uwe Ernst Frank ,  Thierry Florent Edme Materne ,  Giorgio Agostini

    发明人： Rene Jean Zimmer ,  Friedrich Visel ,  Uwe Ernst Frank ,  Thierry Florent Edme Materne ,  Giorgio Agostini

    IPC分类号： B60C1/00 ,  C08F2/44 ,  C08F4/602 ,  C08F4/6192 ,  C08F36/04 ,  C08K3/04 ,  C08K3/36 ,  C08K9/04 ,  C08L9/06 ,  C08L51/10

    CPC分类号： C08F36/04 ,  Y10T152/10495

    摘要： A method of preparing a pre-formed elastomer/filler composite of a diene-based elastomer and particulate filler dispersed therein by polymerizing monomers in the presence of said filler with a polymerization promoting catalyst in which at least a portion of said catalyst is pre-deposited on said filler. Such pre-formed elastomer composite is also contemplated as well as a rubber composition comprised of a blend of such pre-formed composite and at least one additional elastomer. Such filler may be, for example, precipitated silica, carbon black and/or a modified carbon black. A tire having a component of such composite or rubber composition such as, for example a tread, is also provided.

    摘要翻译： 一种通过在所述填料存在下通过聚合单体在聚合促进催化剂中聚合单体的方法来制备二烯基弹性体和颗粒填料的预成形弹性体/填料复合材料，其中至少部分所述催化剂预沉积 在所述填料上。 还预期了这种预成型的弹性体复合材料以及由这种预成型复合材料和至少一种另外的弹性体的共混物组成的橡胶组合物。 这种填料可以是例如沉淀二氧化硅，炭黑和/或改性炭黑。 还提供了具有这种复合材料或橡胶组合物成分例如胎面的轮胎。