摘要:
An object of the present invention is to provide a novel polysaccharide derivative used for a separating agent for optical isomers. The novel polysaccharide derivative contains a structure in which a hydrogen atom of a hydroxyl group or an amino group at the 2-position in a structural unit of the polysaccharide is substituted with a monovalent group represented by the following general formula (1), and a hydrogen atom of a hydroxyl group or an amino group at the 3-position in the structural unit is substituted with a monovalent group represented by the following general formula (2): R1—NH—CO— (1) R2—NH—CO— (2) where R1 and R2 represent substituted or unsubstituted aryl groups which are different from each other.
摘要:
A fuel injection valve includes: a swirl chamber having an inner peripheral wall formed to be gradually increased in curvature toward a downstream side from an upstream side; a swirl passage, through which a fuel is introduced into the swirl chamber; and a fuel injection port opened to the swirl chamber, wherein the swirl chamber and the swirl passage are formed so that a side wall of the swirl passage connected to a downstream end side of the swirl chamber, or an extension thereof is made not to intersect a downstream side portion of the inner peripheral wall of the swirl chamber, or an extension thereof.
摘要:
A fuel injector has a swirl generator located downstream from a valve seat. A fuel injection hole is connected to a downstream side of the swirl generator. The swirl generator includes a swirl chamber having an involute or a spiral shape and the fuel injection hole bored at a bottom or the swirl chamber and a swirl generation use passage connected to the upstream side of the swirl chamber for introducing fuel into the swirl chamber. The bottom of the swirl chamber is provided with a step height so as to make a level difference in which the bottom of the swirl chamber is lower than a bottom of the swirl generation use passage, and the step height is formed at a position where fuel flowing into the swirl chamber from the swirl generation use passage meets fuel turning in the swirl chamber.
摘要:
A fuel injection valve includes a valve element movably disposed to a valve seat member having a valve seat and formed with an opening located at a downstream side thereof. A swirl imparting chamber is formed to impart a swirl force to fuel within the swirl imparting chamber by turning fuel. An injection hole is opened to the bottom of swirl imparting chamber to inject fuel to outside. Additionally, a communication passage is formed to connect the swirl imparting chamber with the opening of the valve seat member. In this fuel injection valve, the swirl imparting chamber and the communication passage are formed to satisfy the following equation: 0.15≦W/D
摘要翻译:燃料喷射阀包括可移动地设置在阀座构件上的阀元件,该阀座构件具有阀座,并形成有位于其下游侧的开口。 涡旋赋予室形成为通过转动燃料而赋予漩涡赋予室内的燃料旋涡力。 喷射孔向涡流施加室的底部开口以将燃料喷射到外部。 此外,形成连通通道以将涡流施加室与阀座构件的开口连接。 在该燃料喷射阀中,形成涡旋赋予室和连通通路,满足下式:0.15&nlE; W / D <0.5其中W是连通通道的宽度; D是涡流赋予室的直径。
摘要:
A polymer compound derivative, obtained by modifying part of the hydroxy or amino groups of a polymer compound having the hydroxy or amino groups with molecules of a compound represented by the following general formula (I): A-X—Si(Y)nR3-n (I), where A represents a reactive group which reacts with a hydroxy or amino group, X represents an alkylene group which has 1 to 18 carbon atoms and which may have a branch, or an arylene group which may have a substituent, Y represents a reactive group which reacts with a silanol group to form a siloxane bond, R represents an alkyl group which has 1 to 18 carbon atoms and which may have a branch, or an aryl group which may have a substituent, and n represents an integer of 1 to 3.
摘要:
There is provided a process for producing beads for enantiomeric isomer resolution with a satisfactory separation efficiency. The beads for enantiomeric isomer resolution include a polysaccharide derivative, in which the polysaccharide derivative has a structure crosslinked at the 6-position hydroxy group of constituent units of the polysaccharide with a crosslinking agent. The process for producing the beads for enantiomeric isomer resolution includes: the step of adding dropwise an organic solvent solution of the polysaccharide derivative to a coagulation bath being stirred to thereby produce beads; the step of taking out the beads and then optionally drying the same after washing; and the step of reacting the beads with a crosslinking agent in an organic solvent to react at least part of the 6-position hydroxy groups in the constituent units of the polysaccharide with the crosslinking agent, thereby obtaining a reaction mixture containing beads having a crosslinked structure.
摘要:
The present invention provides a separating agent for enantiomeric isomers exhibiting high separation power. That is, the present invention provides a separating agent for enantiomeric isomers including, as an active ingredient, a polysaccharide derivative having at least part of hydrogen atoms of hydroxyl groups of a polysaccharide such as cellulose or amylose substituted by at least one of atomic groups represented by the following general formulae (I) and (II): (in the formulae, R represents a substituted or unsubstituted aromatic group, or a linear, branched, or cyclic aliphatic group).
摘要:
A polymer compound derivative, obtained by modifying part of the hydroxy or amino groups of a polymer compound having the hydroxy or amino groups with molecules of a compound represented by the following general formula (I): A-X—Si(Y)nR3-n (I), where A represents a reactive group which reacts with a hydroxy or amino group, X represents an alkylene group which has 1 to 18 carbon atoms and which may have a branch, or an arylene group which may have a substituent, Y represents a reactive group which reacts with a silanol group to form a siloxane bond, R represents an alkyl group which has 1 to 18 carbon atoms and which may have a branch, or an aryl group which may have a substituent, and n represents an integer of 1 to 3.
摘要:
The present invention provides a separating agent for optical isomers having a porous monolithic inorganic type carrier and polysaccharide or a derivative thereof supported on the monolithic inorganic type carrier, and a separation column for optical isomers in which the separating agent for optical isomers is held in a column tube. According to the invention, the separating agent for optical isomers and the separation column for optical isomers which have high asymmetry recognition ability and can be used particularly at a high flow rate when used for the separation of optical isomers is provided.
摘要:
A separating agent which combines a high optical resolving power inherent in polysaccharide derivatives with sufficient solvent resistance and a method with which the separating agent can be produced efficiently in short steps. The separating agent for enantiomeric isomers is characterized in that a polymerizable polysaccharide derivative of a polysaccharide derivative having polymerizable functional groups and a polymerizable monomer having polymerizable unsaturated groups are copolymerized with a carrier having polymerizable functional groups to be chemically bound mutually. The separating agent is preferably used for high performance liquid chromatography (HPLC) and has an excellent solvent resistance.