公开(公告)号：US20100053511A1

公开(公告)日：2010-03-04

申请号：US12549735

申请日：2009-08-28

申请人： Katsufumi OHMURO ,  Ryuta Takegami ,  Zemin Shi ,  Kiyokazu Hashimoto

发明人： Katsufumi OHMURO ,  Ryuta Takegami ,  Zemin Shi ,  Kiyokazu Hashimoto

IPC分类号： G02F1/13363

CPC分类号： G02F1/13363 ,  G02F1/133371 ,  G02F2413/01 ,  G02F2413/02 ,  G02F2413/08

摘要： The invention relates to a liquid crystal display device comprising a retardation layer wherein an in-plane slow axis of the retardation layer is within the direction of 90±40 degrees relative to to an absorption axis of the polarizing layer disposed at a closer position to the retardation layer; Re(550) meets following relation, 25 nm≦Re(550)≦230 nm; R[40°] of the retardation layer which is measured for incident light in a direction tilted by 40 degrees toward the tilt direction of the retardation layer relative to the normal line of the retardation layer meets following relation, 0 nm≦R[40°]≦300 nm; and R[+40°] of the retardation layer and retardation R[−40°] of the retardation layer meet following relation, 1

摘要翻译： 本发明涉及一种液晶显示装置，包括相位差层，其中延迟层的平面内慢轴相对于位于更接近位置的偏振层的吸收轴在90±40度的方向内 延迟层 Re（550）满足以下关系：25nm＆nlE; Re（550）＆nlE; 230nm; 相对于延迟层的法线，向相对于相位差层的倾斜方向倾斜40度的方向的入射光测定的相位差层的R [40°]满足以下关系：0nm＆nlE; R [40° ]＆nlE; 300nm; 相位差层的R [+ 40°]和延迟层的相位差R [-40°]满足关系式，1

公开(公告)号：US20050057706A1

公开(公告)日：2005-03-17

申请号：US10497487

申请日：2002-12-24

申请人： Kaori Seki ,  Tadashi Akamatsu ,  Zemin Shi ,  Hiroyuki Torisu

发明人： Kaori Seki ,  Tadashi Akamatsu ,  Zemin Shi ,  Hiroyuki Torisu

IPC分类号： G02B1/10 ,  G02B5/30 ,  G02F1/1335

CPC分类号： G02B5/3033 ,  G02B1/105 ,  G02B1/14 ,  Y10T428/105 ,  Y10T428/1077

摘要： A polarizing plate has a polarizer and a protective film formed on at least one surface of the polarizer. The protective film is formed by curing an energy ray-curable composition that contains at least one of a first energy ray-polymerizing compound having a bisphenol residue, a second energy ray-polymerizing compound having a neopentylglycol group, a third energy ray-polymerizing compound having a trimethylolpropane group, and a fourth energy ray-polymerizing compound having a pentaerythritol group. In the polarizing plate, though the protective film is thin, the polarizer is protected from the influence of external moisture, etc., and therefore its polarizability is kept good even in high-temperature high-humidity environments.

摘要翻译： 偏振片具有偏振器和形成在偏振器的至少一个表面上的保护膜。 保护膜是通过固化含有具有双酚残基的第一能量射线聚合化合物，具有新戊二醇基的第二能量射线聚合化合物，第三能量射线聚合化合物中的至少一种而形成的能量射线固化性组合物 具有三羟甲基丙烷基和具有季戊四醇基的第四能量射线聚合化合物。 在偏光板中，虽然保护膜薄，但是防止偏振器受到外部湿度等的影响，因此即使在高温高湿环境下也能保持良好的极化性。

公开(公告)号：US08197726B2

公开(公告)日：2012-06-12

申请号：US11793014

申请日：2005-12-22

申请人： Kiyokazu Hashimoto ,  Zemin Shi

发明人： Kiyokazu Hashimoto ,  Zemin Shi

IPC分类号： B29D7/01 ,  B29C47/60

CPC分类号： C08J5/18 ,  B29C41/24 ,  B29C47/0004 ,  B29C47/0021 ,  B29C47/14 ,  B29C47/6018 ,  B29C55/045 ,  B29C55/06 ,  B29K2001/00 ,  B29K2001/12 ,  B29K2995/0034 ,  C08J2301/12 ,  C08J2301/14 ,  G02B5/30 ,  G02B5/3083 ,  G02F1/133528 ,  Y10T428/10 ,  Y10T428/1041 ,  Y10T428/1086

摘要： A cellulose acylate film in which the number of V-shaped thickness-uneven portions having a variation width in the thickness direction of 0.1 to 10% of a film thickness and a width in the in-plane direction of 1 to 20 mm is in the range of 0 to 10 per 100 m in the length direction of the film. A display unevenness is solved in a liquid crystal display device having the cellulose acylate film.

摘要翻译： 在纤维素酰化物膜中，其厚度方向上的变化宽度为薄膜厚度的0.1〜10％，面内方向的宽度为1〜20mm的V字形厚度不均匀部分的数量为 在膜的长度方向上为100〜100μm的范围。 在具有纤维素酰化物膜的液晶显示装置中解决了显示不均匀性。

公开(公告)号：US20120070615A1

公开(公告)日：2012-03-22

申请号：US13220588

申请日：2011-08-29

申请人： Zemin SHI ,  Akihide FUJITA ,  Akira YAMADA

发明人： Zemin SHI ,  Akihide FUJITA ,  Akira YAMADA

IPC分类号： B32B3/00 ,  C08G63/183 ,  B29C55/02 ,  H01L31/0216 ,  B29C47/00

CPC分类号： C08J5/18 ,  B29B7/483 ,  B29B7/489 ,  B29B7/72 ,  B29B7/826 ,  B29B7/845 ,  B29B7/86 ,  B29C48/08 ,  B29C48/37 ,  B29C48/402 ,  B29C48/54 ,  B29C48/55 ,  B29C48/57 ,  B29C48/693 ,  B29C48/767 ,  B29C48/91 ,  B29C48/914 ,  B29C48/917 ,  B29C55/143 ,  B29C2948/92152 ,  B29C2948/92447 ,  B29C2948/92514 ,  B29C2948/92704 ,  B29C2948/92895 ,  B29C2948/92923 ,  B29K2067/00 ,  B29K2067/003 ,  C08G63/85 ,  C08J2367/02 ,  H01L31/0481 ,  H01L31/049 ,  Y02E10/50 ,  Y10T428/24372

摘要： Provided is a method for producing a polyester film, including: subjecting a polyester raw material resin, which contains a titanium compound and has an intrinsic viscosity of from 0.71 to 1.00, to melt extrusion using a twin-screw extruder which includes a cylinder; two screws disposed inside the cylinder; and a kneading disk unit disposed in at least a portion of a region extending from a 10%-position to a 65%-position of screw length with respect to an upstream end of the screws in a resin extrusion direction as a starting point, at a maximum shear rate generated inside the twin-screw extruder of from 10 sec−1 to 2000 sec−1; forming an unstretched film by cooling and solidifying the melt extruded polyester resin on a cast roll; subjecting the unstretched film to biaxial stretching in a longitudinal direction and a lateral direction; and heat fixing the stretched film formed by biaxial stretching.

摘要翻译： 本发明提供一种聚酯薄膜的制造方法，其特征在于，使用包含圆筒的双螺杆挤出机对含有钛化合物的特性粘度为0.71〜1.00的聚酯原料树脂进行熔融挤出， 设置在气缸内的两个螺钉; 以及捏合盘单元，其设置在相对于所述螺钉的上游端以螺旋长度的10％位置至65％位置的区域的至少一部分中，以树脂挤出方向为起点，在 在双螺杆挤出机内产生的最大剪切速率为10秒-1至2000秒-1; 通过在挤压辊上冷却和固化熔融挤出的聚酯树脂来形成未拉伸的薄膜; 对未拉伸膜进行纵向和横向的双轴拉伸; 并且通过双轴拉伸热固化拉伸的膜。

公开(公告)号：US07981994B2

公开(公告)日：2011-07-19

申请号：US11916620

申请日：2006-06-06

申请人： Shinichi Nakai ,  Kiyokazu Hashimoto ,  Zemin Shi

发明人： Shinichi Nakai ,  Kiyokazu Hashimoto ,  Zemin Shi

IPC分类号： C08F251/02

CPC分类号： B29C71/0072 ,  B29C71/02 ,  B29C2071/022 ,  B29K2995/0034 ,  B29L2007/002 ,  C08J5/18 ,  C08J2301/10 ,  G02B5/3033

摘要： A cellulose acylate resin film which can suppress generation of color nonuniformity even after exposure to high temperature and high humidity when incorporated in a liquid crystal display element can be produced. The cellulose acylate resin film is heat-treated at a temperature of Tg−30° C. to Tg+20° C., Tg representing the glass transition temperature of the cellulose acylate resin, for 10 seconds to 600 seconds while conveying the cellulose acylate resin film at a tension of 2 N/cm2 to 120 N/cm2.

摘要翻译： 可以制造即使在掺入到液晶显示元件中时也可以在暴露于高温高湿度之后抑制颜色不均匀的产生的纤维素酰化物树脂膜。 将纤维素酰化物树脂膜在Tg-30℃至Tg + 20℃的温度下热处理，Tg代表纤维素酰化物树脂的玻璃化转变温度，持续10秒至600秒，同时输送纤维素酰化物 树脂膜以2N / cm 2至120N / cm 2的张力。

公开(公告)号：US07662446B2

公开(公告)日：2010-02-16

申请号：US10497487

申请日：2002-12-24

申请人： Kaori Seki ,  Tadashi Akamatsu ,  Zemin Shi ,  Hiroyuki Torisu

发明人： Kaori Seki ,  Tadashi Akamatsu ,  Zemin Shi ,  Hiroyuki Torisu

IPC分类号： G02F1/1335

CPC分类号： G02B5/3033 ,  G02B1/105 ,  G02B1/14 ,  Y10T428/105 ,  Y10T428/1077

摘要： A polarizing plate has a polarizer and a protective film formed on at least one surface of the polarizer. The protective film is formed by curing an energy ray-curable composition that contains at least one of a first energy ray-polymerizing compound having a bisphenol residue, a second energy ray-polymerizing compound having a neopentylglycol group, a third energy ray-polymerizing compound having a trimethylolpropane group, and a fourth energy ray-polymerizing compound having a pentaerythritol group. In the polarizing plate, though the protective film is thin, the polarizer is protected from the influence of external moisture, etc., and therefore its polarizability is kept good even in high-temperature high-humidity environments.

摘要翻译： 偏振片具有偏振器和形成在偏振器的至少一个表面上的保护膜。 保护膜是通过固化含有具有双酚残基的第一能量射线聚合化合物，具有新戊二醇基的第二能量射线聚合化合物，第三能量射线聚合化合物中的至少一种而形成的能量射线固化性组合物 具有三羟甲基丙烷基和具有季戊四醇基的第四能量射线聚合化合物。 在偏光板中，虽然保护膜薄，但是防止偏振器受到外部湿度等的影响，因此即使在高温高湿环境下也能保持良好的极化性。

公开(公告)号：US20090269514A1

公开(公告)日：2009-10-29

申请号：US11887725

申请日：2005-04-14

申请人： Kaori Seki ,  Tadashi Akamatsu ,  Zemin Shi

发明人： Kaori Seki ,  Tadashi Akamatsu ,  Zemin Shi

IPC分类号： C09K19/52

CPC分类号： G02B5/3025 ,  G02B1/105 ,  G02B1/14 ,  G02F1/133528 ,  G02F2201/50 ,  Y10T428/1041

摘要： A polarizing plate is provided in which adhesion properties between a polarizer and a protection film are improved and in which the optical properties of the polarizer are stable under the influence of moisture and the like. Specifically, in polarizing plates 4 and 12, protection films 3 and 11 are formed on at least one side of polarizers 2 and 10, respectively, by curing an energy ray-curable composition. The energy ray-curable composition contains (1) an energy ray-polymerizable compound having a bridged hydrocarbon group, a bisphenol group, a neopentyl glycol group, a trimethylolpropane group, or a pentaerythritol group and (2) a hydrolysate of a silane-based coupling agent. At least one of the polarizing plates 4 and 12 is provided on at least one side of a liquid crystal panel 1, whereby a liquid crystal device 9 is constituted.

摘要翻译： 提供了一种偏振片，其中偏振片和保护膜之间的粘合性能得到改善，并且偏振片的光学特性在水分等的影响下是稳定的。 具体地说，在偏光板4和12中，通过固化能量射线固化性组合物，分别在偏振片2和10的至少一侧上形成保护膜3和11。 能量射线固化性组合物含有（1）具有桥连烃基的能量射线聚合性化合物，双酚基，新戊二醇基，三羟甲基丙烷基或季戊四醇基，和（2）硅烷系 偶联剂。 至少一个偏振片4和12设置在液晶面板1的至少一侧上，由此构成液晶装置9。

公开(公告)号：US20090187000A1

公开(公告)日：2009-07-23

申请号：US11916620

申请日：2006-06-06

申请人： Shinichi Nakai ,  Kiyokazu Hashimoto ,  Zemin Shi

发明人： Shinichi Nakai ,  Kiyokazu Hashimoto ,  Zemin Shi

IPC分类号： C08F251/02

CPC分类号： B29C71/0072 ,  B29C71/02 ,  B29C2071/022 ,  B29K2995/0034 ,  B29L2007/002 ,  C08J5/18 ,  C08J2301/10 ,  G02B5/3033

摘要： A cellulose acylate resin film which can suppress generation of color nonuniformity even after exposure to high temperature and high humidity when incorporated in a liquid crystal display element can be produced. The cellulose acylate resin film is heat-treated at a temperature of Tg−30° C. to Tg+20° C., Tg representing the glass transition temperature of the cellulose acylate resin, for 10 seconds to 600 seconds while conveying the cellulose acylate resin film at a tension of 2 N/cm2 to 120 N/cm2.

摘要翻译： 可以制造即使在掺入到液晶显示元件中时也可以在暴露于高温高湿度之后抑制颜色不均匀的产生的纤维素酰化物树脂膜。 将纤维素酰化物树脂膜在Tg-30℃至Tg + 20℃的温度下热处理，Tg代表纤维素酰化物树脂的玻璃化转变温度，持续10秒至600秒，同时输送纤维素酰化物 树脂膜以2N / cm 2至120N / cm 2的张力。

公开(公告)号：US20070281112A1

公开(公告)日：2007-12-06

申请号：US11808101

申请日：2007-06-06

申请人： Zemin Shi ,  Kazuhiro Ono

发明人： Zemin Shi ,  Kazuhiro Ono

IPC分类号： C09K19/00

CPC分类号： C08J5/18 ,  B29C47/0021 ,  B29C47/8805 ,  B29C47/8845 ,  B29C47/8855 ,  B29C47/886 ,  B29C55/06 ,  B29C55/12 ,  B29C55/16 ,  B29K2001/00 ,  B29K2001/12 ,  B29K2023/38 ,  B29K2995/0034 ,  C08J2301/02 ,  C08L1/10 ,  G02B5/30 ,  Y02P20/582 ,  Y10T428/1041

摘要： A method for producing a thermoplastic film, comprising cooling and solidifying a filmy thermoplastic melt resin, by holding it between a metallic presser and a metallic casting roll for cooling; wherein the temperature of the filmy thermoplastic resin just before being held between the metallic presser and the casting roll for cooling is from Tg+20° C. to Tg+90° C. and a difference between a surface temperature (Tt) of the metallic presser and a surface temperature (T1) of the casting roll for cooling satisfies the formula (1) and a contact length Q satisfies the following formula (2) 0.5° C.≦T1−Tt≦20° C.   (1) 0.1 cm≦Q≦8 cm   (2) The method provides a thermoplastic film having high thickness accuracy and surface smoothness.

摘要翻译： 一种热塑性薄膜的制造方法，其特征在于，通过将薄膜状热塑性熔融树脂保持在金属压片和金属铸造辊之间进行冷却而固化， 其中刚好保持在金属压片机和用于冷却的铸辊之间的膜状热塑性树脂的温度为Tg + 20℃至Tg + 90℃，并且金属压制成型件的表面温度（Tt） 压力机和用于冷却的铸辊的表面温度（T1）满足式（1），接触长度Q满足下式（2）<？in-line-formula description =“In-line Formulas”end =“ 导线“>> 0.5℃<= T 1 -Tt <= 20℃（1）<？在线公式描述=”在线公式“end =”tail“？> <？in-line -formulae description =“In-line Formulas”end =“lead”？> 0.1 cm <= Q <= 8 cm（2）<？in-line-formula description =“In-line Formulas”end =“tail”？ >该方法提供了具有高厚度精度和表面平滑度的热塑性薄膜。

公开(公告)号：US20070114491A1

公开(公告)日：2007-05-24

申请号：US10581747

申请日：2004-08-31

申请人： Zemin Shi ,  Tadashi Akamatsu ,  Michio Sato ,  Tsuneo Hanada

发明人： Zemin Shi ,  Tadashi Akamatsu ,  Michio Sato ,  Tsuneo Hanada

IPC分类号： C09K19/52 ,  C09K19/54 ,  C09K19/38

CPC分类号： C09K19/3852 ,  C09K19/406 ,  C09K19/408 ,  C09K2019/328 ,  C09K2219/03 ,  Y10T428/10

摘要： A simple technique for introducing a hybrid alignment or a homeotropic (vertical) alignment into liquid crystal films, which, by their nature, tend to have a horizontal alignment of liquid crystal molecules. The technique does not require special alignment films. A liquid crystal composition for forming a liquid crystal film contains a polymerizable liquid crystal compound and a hydrolysate of an alkoxysilane compound. The hydrolysate of the alkoxysilane compound contains a siloxane oligomer of which degree of polymerization is from 2 to 25. Furthermore, the alkoxysilane compound is a trialkoxysilane compound having a functional group. This liquid crystal film composition can be produced by hydrolyzing an alkoxysilane compound to obtain a hydrolysate and then uniformly mixing the hydrolysate with a polymerizable liquid crystal compound. Alternatively, it can be obtained by uniformly mixing the alkoxysilane compound with the polymerizable liquid crystal compound and subsequently hydrolyzing the alkoxysilane compound in the mixture. One mole of the alkoxysilane compound is preferably hydrolyzed with 0.1d to 2.0d mol of water, given that the number of alkoxyl groups in a molecule of the alkoxysilane compound is d. An optically anisotropic film can be obtained by applying the liquid crystal film composition to a base film, causing the liquid crystal molecules in the composition to align in a nematic alignment, and curing the composition. The alignment of the liquid crystal molecules in the film is preferably a nematic hybrid or nematic homeotropic (vertical) alignment.

摘要翻译： 用于将混合取向或垂直（垂直）取向引入液晶膜的简单技术，其本质上倾向于具有液晶分子的水平取向。 该技术不需要特殊的取向膜。 用于形成液晶膜的液晶组合物含有可聚合液晶化合物和烷氧基硅烷化合物的水解产物。 烷氧基硅烷化合物的水解物含有聚合度为2〜25的硅氧烷低聚物。此外，烷氧基硅烷化合物为具有官能团的三烷氧基硅烷化合物。 该液晶膜组合物可以通过水解烷氧基硅烷化合物得到水解产物，然后将水解产物与可聚合液晶化合物均匀混合来制备。 或者，可以通过将烷氧基硅烷化合物与可聚合液晶化合物均匀混合，然后水解该混合物中的烷氧基硅烷化合物而获得。 考虑到烷氧基硅烷化合物的分子中的烷氧基数为d，一摩尔烷氧基硅烷化合物优选用0.1d至2.0dmol的水进行水解。 可以通过将液晶膜组合物施加到基膜上，使组合物中的液晶分子以向列取向取向并固化该组合物来获得光学各向异性膜。 膜中液晶分子的取向优选为向列混合或向列垂面（垂直）取向。