公开(公告)号：US20240076523A1

公开(公告)日：2024-03-07

申请号：US18036227

申请日：2021-09-29

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Wayne S. Mahoney ,  Michael A. Kropp ,  Anthony J. Ostlund

IPC: C09J4/06 ,  C08G65/332 ,  C09J11/08 ,  C09J151/08

CPC classification number: C09J4/06 ,  C08G65/3322 ,  C09J11/08 ,  C09J151/08

Abstract: A free-radically polymerizable crosslinker comprising divalent segments Z represented by the formula (I). Each divalent segment Z is respectively directly bonded to i) two secondary N atoms, each further directly bonded to a divalent segment Z or an X group; ii) two tertiary N atoms, each further directly bonded to p additional divalent segments Z and (2-p) X groups, wherein p is 0, 1, or 2; or iii) a secondary N atom further directly bonded to one additional divalent segment Z or an X group, and a tertiary N atom further directly bonded to p additional divalent segments Z and (2-p) X groups. R1 represents an alkylene group having from 1 to 4 carbon atoms, n represents a positive integer. X is represented by the formula: (II) L represents a covalent bond, O, S, NR1, or a divalent linking group having from 2 to 8 carbon atoms and up to 3 oxygen atoms. R2 is a free-radically polymerizable group selected from vinyloxy, allyloxy, methacryloxy, vinylaryl having from 8 to 12 carbon atoms, and 2-propenylaryl having from 9 to 13 carbon atoms. No two of O, S, or N atoms in the X group are adjacent. A curable composition comprises a monofunctional free-radically polymerizable monomer, a free-radical initiator, and the free-radically polymerizable crosslinker. At least partially cured reaction products are also disclosed.

公开(公告)号：US20220325022A1

公开(公告)日：2022-10-13

申请号：US17619195

申请日：2020-06-10

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Wayne S. Mahoney ,  Michael A. Kropp ,  Anthony J. Ostlund ,  Nelson T. Rotto ,  Kristine Klimovica ,  Carol-Lynn Spawn ,  Allan Clemens

IPC: C08F220/28 ,  C08F220/20 ,  C08F222/10 ,  C09J4/06

Abstract: Provided are novel crosslinkers and curable compositions including such crosslinkers. Bonded constructions including the disclosed curable compositions display high adhesion, elongation, and impact resistance even if the bonded substrate receives no surface treatment prior to bonding. Provided are elastomeric products including the curable compositions, methods of making the same, and uses thereof.

公开(公告)号：US20240059940A1

公开(公告)日：2024-02-22

申请号：US18268042

申请日：2021-12-17

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Nelson T. Rotto ,  Wayne S. Mahoney ,  Michael A. Kropp ,  Anthony J. Ostlund ,  Kristine Klimovica ,  Carol-Lynn Spawn

IPC: C09J133/02 ,  B32B37/12 ,  C09J5/00 ,  C09J133/14

CPC classification number: C09J133/02 ,  B32B37/1284 ,  C09J5/00 ,  C09J133/14 ,  C09J2433/00

Abstract: The composition includes at least 16 percent by weight of an acrylic monomer comprising a cycloalkyl group having up to 12 carbon atoms, an acrylic monomer having a carboxylic acid group, an acrylic monomer having a hydroxyl group, and a compound composed of divalent segments L and at least two X groups. The divalent segments L are represented by formula L. Each segment L is respectively directly bonded to two secondary N atoms, two tertiary N atoms, or a secondary and a tertiary N atom. Each R1 represents an alkylene group having from 1 to 4 carbon atoms, and at least some of the R1 groups are —CH2—CH2—CH2—CH2—. Each X group is independently represented by the formula CH2═C(R)—C(O)—O—V—W—C(O)—. Articles and methods using the composition are also described.

公开(公告)号：US20230303898A1

公开(公告)日：2023-09-28

申请号：US18020599

申请日：2021-08-11

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Anthony J. Ostlund ,  Wayne S. Mahoney ,  Michael A. Kropp ,  Kristine Klimovica ,  Carol-Lynn Spawn

IPC: C09J133/10 ,  C09J4/06 ,  C09J11/06 ,  C09J11/04 ,  C09J7/30

CPC classification number: C09J133/10 ,  C09J4/06 ,  C09J11/06 ,  C09J11/04 ,  C09J7/30 ,  C09J2433/00

Abstract: Provided are curable (meth)acrylate structural adhesive compositions comprising a cyclic imide-containing (meth)acrylate monomer and a crosslinker, and methods, particularly methods of use.

公开(公告)号：US11739172B2

公开(公告)日：2023-08-29

申请号：US17553473

申请日：2021-12-16

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Nelson T. Rotto ,  Wayne S. Mahoney ,  Michael A. Kropp ,  Anthony J. Ostlund ,  Kristine Klimovica ,  Carol-Lynn Spawn

IPC: C08F220/06 ,  C08F220/36 ,  C08F220/20 ,  C08F220/18 ,  C08F220/14 ,  C08K5/13 ,  C08K5/19 ,  C09J4/00 ,  C08L9/06 ,  C08L9/02

CPC classification number: C08F220/36 ,  C08F220/06 ,  C08F220/14 ,  C08F220/1811 ,  C08F220/1812 ,  C08F220/20 ,  C08K5/13 ,  C08K5/19 ,  C09J4/00 ,  C08F2800/20 ,  C08L9/02 ,  C08L9/06 ,  C08L2207/53 ,  C09J2477/006

Abstract: The composition includes an acrylic monomer having a carboxylic acid group, an acrylic monomer having a hydroxyl group, and a compound composed of divalent segments L and at least two X groups. The divalent segments L are represented by the formula




Each divalent segment L is respectively directly bonded to two secondary N atoms, two tertiary N atoms, or a secondary and a tertiary N atom. Each R1 represents an alkylene group having from 1 to 4 carbon atoms, and at least some of the R1 groups are —CH2—CH2—CH2—CH2—. Each X group is independently represented by the formula CH2═C(R)—C(O)—O—V-W—C(O)—. The acrylic monomer having a carboxylic acid group is present in an amount of at least 20 percent by weight, based on the total weight of acrylic-functional compounds. Articles and a method of using the composition are also described.

公开(公告)号：US20220195093A1

公开(公告)日：2022-06-23

申请号：US17553473

申请日：2021-12-16

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Nelson T. Rotto ,  Wayne S. Mahoney ,  Michael A. Kropp ,  Anthony J. Ostlund ,  Kristine Klimovica ,  Carol-Lynn Spawn

IPC: C08F220/36 ,  C08F220/20 ,  C08F220/18 ,  C08F220/14 ,  C08F220/06 ,  C09J4/00 ,  C08K5/13 ,  C08K5/19

Abstract: The composition includes an acrylic monomer having a carboxylic acid group, an acrylic monomer having a hydroxyl group, and a compound composed of divalent segments L and at least two X groups. The divalent segments L are represented by the formula Each divalent segment L is respectively directly bonded to two secondary N atoms, two tertiary N atoms, or a secondary and a tertiary N atom. Each R1 represents an alkylene group having from 1 to 4 carbon atoms, and at least some of the R1 groups are —CH2—CH2—CH2—CH2—. Each X group is independently represented by the formula CH2═C(R)—C(O)—O—V—W—C(O)—. The acrylic monomer having a carboxylic acid group is present in an amount of at least 20 percent by weight, based on the total weight of acrylic-functional compounds. Articles and methods using the composition are also described.

公开(公告)号：US20240271021A1

公开(公告)日：2024-08-15

申请号：US18564661

申请日：2022-06-02

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Anthony J. Ostlund ,  Vivek Krishnan

IPC: C09J133/14 ,  B32B7/12 ,  B32B15/085 ,  B32B15/18 ,  B32B27/18 ,  B32B27/32 ,  B32B37/12 ,  C08F220/28 ,  C09J4/06 ,  C09J5/00

CPC classification number: C09J133/14 ,  B32B7/12 ,  B32B15/085 ,  B32B15/18 ,  B32B27/18 ,  B32B27/32 ,  B32B37/12 ,  C08F220/281 ,  C09J4/06 ,  C09J5/00 ,  B32B2250/02 ,  B32B2264/101 ,  C08F2800/20 ,  C09J2400/166 ,  C09J2423/108 ,  C09J2433/00

Abstract: The composition includes a blend of monomers containing at least one of a cyclic imide-containing acrylate or a cyclic amide-containing methacrylate and an organoborane complex. The composition may be packaged as a two-part composition, wherein a first part comprises the blend of monomers, and wherein a second part comprises the organoborane complex. Articles are bonded with the composition, which is at least partially cured. Methods of making a bonded article are also disclosed. Bonded articles can include at least one low-surface-energy plastic.

公开(公告)号：US20240084060A1

公开(公告)日：2024-03-14

申请号：US18268173

申请日：2021-12-17

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Nelson T. Rotto ,  Wayne S. Mahoney ,  Michael A. Kropp ,  Anthony J. Ostlund ,  Kristine Klimovica ,  Carol-Lynn Spawn

IPC: C08F220/06 ,  C08F220/14 ,  C08F220/20 ,  C08F220/36 ,  C09J4/00

CPC classification number: C08F220/06 ,  C08F220/14 ,  C08F220/20 ,  C08F220/36 ,  C09J4/00 ,  C09J2427/006 ,  C09J2433/006 ,  C09J2455/006 ,  C09J2477/006

Abstract: The composition includes an acrylic monomer having a carboxylic acid group, an acrylic monomer having a hydroxyl group, at least one of an alkyl acrylate or alkyl methacrylate, and from 20 to 35 percent by weight of a compound composed of divalent segments L and at least two X groups. The divalent segments L are represented by formula L. Each segment L is respectively directly bonded to two secondary N atoms, two tertiary N atoms, or a secondary and a tertiary N atom. Each R1 represents an alkylene group having from 1 to 4 carbon atoms, and at least some of the R1 groups are —CH2—CH2—CH2—CH2—. Each X group is independently represented by the formula CH2═C(R)—C(O)—O—V—W—C(O)—. The acrylic monomer having a carboxylic acid group is present in an amount of at least one percent and less than 20 percent by weight. Articles and methods using the composition are also described.

公开(公告)号：US20230399463A1

公开(公告)日：2023-12-14

申请号：US18036230

申请日：2021-09-29

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Wayne S. Mahoney ,  Michael A. Kropp ,  Anthony J. Ostlund

IPC: C08G65/26 ,  C08F220/30 ,  C09J4/06

CPC classification number: C08G65/2615 ,  C08F220/30 ,  C09J4/06

Abstract: A free-radically polymerizable crosslinker comprising divalent segments Z represented by the formula (I). Each divalent segment Z is respectively directly bonded to i) two secondary N atoms, each further directly bonded to a divalent segment Z or an X group; ii) two tertiary N atoms, each further directly bonded to p additional divalent segments Z and (2−p) X groups, wherein p is 0, 1, or 2; or iii) a secondary N atom further directly bonded to one additional divalent segment Z or an X group, and a tertiary N atom further directly bonded to p additional divalent segments Z and (2−p) X groups. R1 represents an alkylene group having from 1 to 4 carbon atoms, n represents a positive integer. X is represented by the formula: (II) L represents a covalent bond, O, S, NR1, or a divalent linking group having from 2 to 8 carbon atoms and up to 3 oxygen atoms. R2 is a free-radically polymerizable group selected from vinyloxy, allyloxy, methacryloxy, vinylaryl having from 8 to 12 carbon atoms, and 2-propenylaryl having from 9 to 13 carbon atoms. No two of O, S, or N atoms in the X group are adjacent. A curable composition comprises a monofunctional free-radically polymerizable monomer, a free-radical initiator, and the free-radically polymerizable crosslinker. At least partially cured reaction products are also disclosed.