公开(公告)号：US20150259270A1

公开(公告)日：2015-09-17

申请号：US14434981

申请日：2013-10-09

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Steven J. Martin ,  Luke T. Dressel ,  Aaron E. Hutt ,  Eric A. Schotz ,  Terence D. Spawn ,  Miguel A. Guerra ,  Tatsuo Fukushi ,  Jeremy A. Miller ,  Christopher M. Geise ,  James A. McDonell

IPC: C07C45/58 ,  C07C17/26

CPC classification number: C07C45/58 ,  C07C17/00 ,  C07C17/093 ,  C07C17/26 ,  C07C19/16

Abstract: A method of making α,ω-diiodoperfluoroalkanes includes combining: diatomic iodine, at least one perfluoroalkylene oxide represented by the formula wherein Rf represents a perfluoroalkyl group; and at least one of: a) a first metallic compound comprising nickel, and a second metallic compound comprising molybdenum that is compositionally different from the first metallic compound; or b) a metallic alloy comprising from 50 to 70 percent by weight of nickel and from 20 to 40 percent by weight of molybdenum, based on the total weight of the metallic alloy, thereby producing at least one product represented by the formula I(CF2)nI, wherein n independently represents an integer in the range of from 1 to 11. The total weight of the at least one product wherein n is 3 or greater exceeds the total weight of the at least one product wherein n is 1 or 2 by a factor of at least 4.

Abstract translation: 制备α，ω-二碘全氟烷烃的方法包括组合：双原子碘，至少一种由下式表示的全氟氧化烯，其中Rf表示全氟烷基; 和至少一种：a）包含镍的第一金属化合物和包含与第一金属化合物成分不同的钼的第二金属化合物; 或b）金属合金，其包含基于金属合金的总重量的50-70重量％的镍和20至40重量％的钼，由此产生至少一种由式I表示的产物（CF 2 ）nI，其中n独立地表示1至11范围内的整数。其中n为3或更大的至少一种产物的总重量超过至少一种产物的总重量，其中n为1或2，其中n为1或2， 至少4的因素。

公开(公告)号：US20150147579A1

公开(公告)日：2015-05-28

申请号：US14610727

申请日：2015-01-30

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Chetan P. Jariwala ,  Gregory D. Clark ,  Jason T. Petrin ,  Rudolf J. Dams ,  Steven J. Martin ,  Mark J. Pellerite

IPC: C08F14/18 ,  C09D127/12

CPC classification number: C08F14/185 ,  C08F8/40 ,  C08F220/10 ,  C08F220/18 ,  C08F220/22 ,  C08F220/36 ,  C08J3/09 ,  C08J2333/16 ,  C09D127/12 ,  C09D133/06 ,  C09D133/14 ,  C09D133/16 ,  C09D143/02 ,  Y10T428/3154 ,  Y10T428/31678 ,  C08F20/22 ,  C08F230/02

Abstract: A composition comprising at least one first divalent unit represented by formula: and at least one of a second divalent unit comprising a pendant Z group or a monovalent unit comprising a thioether linkage and a terminal Z group, wherein each Z group is independently selected from the group consisting of —P(O)(OY)2 and —O—P(O)(OY)2. R″ and R′″ are each independently selected from the group consisting of hydrogen and alkyl having from 1 to 4 carbon atoms. Y is selected from the group consisting of hydrogen, alkyl, trialkylsilyl, and a counter cation. Methods of treating a surface using these compositions and articles with a surface in contact with these compositions are provided. Methods of making these compositions are also provided.

Abstract translation: 一种组合物，其包含至少一种由式表示的第一二价单元和至少一种包含侧基Z基团的第二二价单元或包含硫醚键和末端Z基团的一价单元，其中每个Z基团独立地选自 由-P（O）（OY）2和-O-P（O）（OY）2组成的组。 R“和R”“各自独立地选自氢和具有1至4个碳原子的烷基。 Y选自氢，烷基，三烷基甲硅烷基和抗衡阳离子。 提供了使用这些组合物和具有与这些组合物接触的表面的制品处理表面的方法。 还提供制备这些组合物的方法。

公开(公告)号：US20130269932A1

公开(公告)日：2013-10-17

申请号：US13996143

申请日：2011-12-20

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Rudolf J. Dams ,  Yong K. Wu ,  Steven J. Martin

IPC: C09K8/60 ,  E21B43/25

CPC classification number: C09K8/60 ,  C09K8/035 ,  C09K8/506 ,  C09K8/5751 ,  C09K8/584 ,  C09K8/604 ,  C09K8/68 ,  C09K8/80 ,  C09K8/88 ,  E21B43/25

Abstract: A method of treating a carbonate hydrocarbon-bearing formation is disclosed. The method includes contacting the hydrocarbon-bearing formation with a composition comprising solvent and a fluorinated amine oxide. Carbonate hydrocarbon-bearing formations treated according to the method are also disclosed.

Abstract translation: 公开了一种处理含碳酸盐烃的地层的方法。 该方法包括使含烃地层与包含溶剂和氟化氧化胺的组合物接触。 还公开了根据该方法处理的含碳酸盐的地层。

公开(公告)号：US09688785B2

公开(公告)日：2017-06-27

申请号：US14610727

申请日：2015-01-30

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Chetan P. Jariwala ,  Gregory D. Clark ,  Jason T. Petrin ,  Rudolf J. Dams ,  Steven J. Martin ,  Mark J. Pellerite

IPC: C08F14/18 ,  C08F8/40 ,  C09D127/12 ,  C08F220/22 ,  C08F220/36 ,  C08J3/09 ,  C09D133/06 ,  C09D133/14 ,  C09D133/16 ,  C09D143/02 ,  C08F220/10 ,  C08F220/18

CPC classification number: C08F14/185 ,  C08F8/40 ,  C08F220/10 ,  C08F220/18 ,  C08F220/22 ,  C08F220/36 ,  C08J3/09 ,  C08J2333/16 ,  C09D127/12 ,  C09D133/06 ,  C09D133/14 ,  C09D133/16 ,  C09D143/02 ,  Y10T428/3154 ,  Y10T428/31678 ,  C08F20/22 ,  C08F230/02

Abstract: A composition comprising at least one first divalent unit represented by formula: and at least one of a second divalent unit comprising a pendant Z group or a monovalent unit comprising a thioether linkage and a terminal Z group, wherein each Z group is independently selected from the group consisting of —P(O)(OY)2 and —O—P(O)(OY)2. R″ and R″′ are each independently selected from the group consisting of hydrogen and alkyl having from 1 to 4 carbon atoms. Y is selected from the group consisting of hydrogen, alkyl, trialkylsilyl, and a counter cation. Methods of treating a surface using these compositions and articles with a surface in contact with these compositions are provided. Methods of making these compositions are also provided.

公开(公告)号：US09212119B2

公开(公告)日：2015-12-15

申请号：US14434981

申请日：2013-10-09

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Steven J. Martin ,  Luke T. Dressel ,  Aaron E. Hutt ,  Eric A. Schotz ,  Terence D. Spawn ,  Miguel A. Guerra ,  Tatsuo Fukushi ,  Jeremy A. Miller ,  Christopher M. Geise ,  James A. McDonell

IPC: C07C21/18 ,  C07C45/58 ,  C07C17/26 ,  C07C17/093

CPC classification number: C07C45/58 ,  C07C17/00 ,  C07C17/093 ,  C07C17/26 ,  C07C19/16

Abstract: A method of making α,ω-diiodoperfluoroalkanes includes combining: diatomic iodine, at least one perfluoroalkylene oxide represented by the formula wherein Rf represents a perfluoroalkyl group; and at least one of: a) a first metallic compound comprising nickel, and a second metallic compound comprising molybdenum that is compositionally different from the first metallic compound; or b) a metallic alloy comprising from 50 to 70 percent by weight of nickel and from 20 to 40 percent by weight of molybdenum, based on the total weight of the metallic alloy, thereby producing at least one product represented by the formula I(CF2)nI, wherein n independently represents an integer in the range of from 1 to 11. The total weight of the at least one product wherein n is 3 or greater exceeds the total weight of the at least one product wherein n is 1 or 2 by a factor of at least 4.

Abstract translation: 制备α，ω-二碘全氟烷烃的方法包括组合：双原子碘，至少一种由下式表示的全氟氧化烯，其中Rf表示全氟烷基; 和至少一种：a）包含镍的第一金属化合物和包含与第一金属化合物成分不同的钼的第二金属化合物; 或b）金属合金，其包含基于金属合金的总重量的50-70重量％的镍和20至40重量％的钼，由此产生至少一种由式I表示的产物（CF 2 ）nI，其中n独立地表示1至11范围内的整数。其中n为3或更大的至少一种产物的总重量超过至少一种产物的总重量，其中n为1或2，其中n为1或2， 至少4的因素。