Abstract:
Waterborne base coat compositions and processes for preparing base coat/clear top coat multi-layer coatings are provided. In an embodiment, a waterborne base coat composition includes water, pigment(s) and resin solids consisting of about 60 to 100 wt. % of binder solids and 0 to about 40 wt. % of crosslinker solids, the binder solids consisting of about 1 to about 40 wt. % of a urethanized polyester/(meth)acryl copolymer hybrid binder having a hydroxyl number of about 30 to about 200 mg KOH/g and a carboxyl number of about 8 to 50 mg KOH/g, and about 60 to about 99 wt. % of one or more further binders, the sum of the respective wt. % in each case equaling 100 wt. %.
Abstract:
A method of preparing a coated article is disclosed. The method includes providing a substrate bearing a partially-dehydrated aqueous coating layer. The method further includes providing a coating composition to a high transfer efficiency applicator, the high transfer efficiency applicator comprising a plurality of nozzles each being configured to apply a stream of the coating composition to a substrate substantially without atomization. The coating composition is a waterborne fluid that exhibits a near-Newtonian viscosity profile, and comprises a binder, a crosslinker, and a thickener. The method further includes applying the coating composition to the substrate with the high transfer efficiency applicator via disposing a plurality of lines of the coating composition onto the partially-dehydrated aqueous coating layer of the substrate via the plurality of nozzles, thereby forming an overspray free coating layer thereon.
Abstract:
A method includes applying a coating composition to a substrate through a high transfer efficiency applicator to form the coating layer on the substrate wherein a loss of volatiles is less than about 0.5 weight, and wherein the coating composition comprises: A. a resin comprising an acrylic, a polyester, or combinations thereof; B. a melamine cross-linker; C. an optional pigment; D. an organic solvent; and E. at least one polyurea crystal sag control agent that is the reaction product of an amine and an isocyanate, that has a melting point of from about 50° C. to about 150° C., and that is present in an amount of from about 0.1 to about 4 weight percent based on a total weight of the coating composition; and wherein the coating composition has a wet film thickness of at least about 30 microns measured at about 45 degrees without visible sag.
Abstract:
A process for the production of an OEM base coat/clear top coat multi-layer coating wherein a waterborne base coat composition is spray-applied by electrostatically-assisted high speed rotary atomization is provided. The waterborne base coat composition comprises binder solids comprising about 20 to about 100 wt. % of an aqueously dispersed polyurethane urea resin with a carboxyl number of 10 to 50 mg KOH/g.
Abstract:
A process for the production of an OEM base coat/clear top coat multi-layer coating wherein a waterborne base coat composition is spray-applied by electrostatically-assisted high speed rotary atomization, wherein the waterborne base coat composition comprises binder solids comprising about 20 to about 100 wt. % of an aqueously dispersed polyurethane urea resin with a carboxyl number of about 10 to 50 mg KOH/g.
Abstract:
A non-aqueous solvent composition comprising 0 to 10 wt. % of N-alkyl pyrrolidone, 0 to 5 wt. % of dimethyl sulfoxide, 10 to 50 wt. % of γ-butyrolactone, 10 to 50 wt. % of at least one monoalcohol, 10 to 60 wt. % of at least one organic solvent inert towards isocyanate groups, other than γ-butyrolactone, other than N-alkyl pyrrolidone, and consisting of carbon, hydrogen, oxygen and, optionally, nitrogen, and 0 to 10 wt. % of at least one additive. The non-aqueous solvent composition can be used as barrier liquid within a coating installation of an industrial mass production coating line for the application of water-borne two-component polyurethane coatings.
Abstract:
A process for the production of an automotive OEM multi-layer coating, includes, but is not limited to applying a base coat layer onto an automotive substrate, applying a clear top coat layer onto the base coat layer, and jointly curing the base coat and clear top coat layers. The base coat layer is applied from a modified water-borne base coat produced by mixing an unmodified water-borne base coat with a polyisocyanate crosslinker component making use of a static mixer, and wherein the polyisocyanate crosslinker component comprises at least one polyisocyanate crosslinker and γ-butyrolactone as water-miscible solvent.
Abstract:
Coating installations are provided that include storage tanks for an aqueous base component and a non-aqueous hardener component, circulation lines for the components from the respective storage tanks, a mixer and an entrance to the mixer with a connection between each circulating line and the entrance to the mixer, and a release valve for the non-aqueous hardener component. The coating installation downstream of the non-aqueous hardener release valve is filled with a non-aqueous solvent composition comprising 0 to 10 wt. % of N-alkyl pyrrolidone, 0 to 5 wt. % of dimethyl sulfoxide, 10 to 50 wt. % of γ-butyrolactone, 10 to 50 wt. % of at least one monoalcohol, 10 to 60 wt. % of at least one organic solvent inert towards isocyanate groups, other than γ-butyrolactone, other than N-alkyl pyrrolidone, and consisting of carbon, hydrogen, oxygen and, optionally, nitrogen, and 0 to 10 wt. % of at least one additive.
Abstract:
A method includes applying a coating composition to a substrate through a high transfer efficiency applicator wherein the coating composition has a pH of greater than about 7 and comprises: A. a resin dispersion comprising a latex, a polyurethane, or combinations thereof; B. an optional cross-linker; C. an optional pigment; D. water; E. a water-soluble solvent; and F. at least one rheology control agent chosen from an alkali swellable emulsion, a layered silicate, and combinations thereof; wherein the coating composition has a viscosity of about 20 to about 100 cps as determined using ASTM 7867-13 with cone-and-plate or parallel plates at a shear rate of 1000 sec-1, and wherein the coating composition has a wet film thickness of at least 20 microns measured at about 45 degrees without visible sag.
Abstract:
A non-aqueous solvent composition comprising 0 to 10 wt. % of N-alkyl pyrrolidone, 0 to 5 wt. % of dimethyl sulfoxide, 10 to 50 wt. % of γ-butyrolactone, 10 to 50 wt. % of at least one monoalcohol, 10 to 60 wt. % of at least one organic solvent inert towards isocyanate groups, other than γ-butyrolactone, other than N-alkyl pyrrolidone, and consisting of carbon, hydrogen, oxygen and, optionally, nitrogen, and 0 to 10 wt. % of at least one additive. The non-aqueous solvent composition can be used as barrier liquid within a coating installation of an industrial mass production coating line for the application of water-borne two-component polyurethane coatings.