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    Thermoset coating compositions having improved hardness
    1.
    发明授权
    Thermoset coating compositions having improved hardness 失效
    具有改善硬度的热固性涂料组合物

    公开(公告)号：US5681906A

    公开(公告)日：1997-10-28

    申请号：US424205

    申请日：1995-04-19

    申请人： Albert Ilya Yezrielev ,  Vijay Swarup ,  Konstantinos R. Rigopoulos

    发明人： Albert Ilya Yezrielev ,  Vijay Swarup ,  Konstantinos R. Rigopoulos

    IPC分类号： C08G18/32 ,  C08G18/65 ,  C08G18/66 ,  C08G18/72 ,  C08G18/80 ,  C09D161/32 ,  C09D175/04 ,  C09D201/06 ,  C08L61/20 ,  C08L61/28 ,  C08L67/00

    CPC分类号： C09D175/04 ,  C08G18/3215 ,  C08G18/3221 ,  C08G18/6511 ,  C08G18/664 ,  C08G18/728 ,  C08G18/8067 ,  C09D201/06

    摘要： The present invention provides for amino-crosslinkable coating formulations based on a mixture of a di- or polyhydroxy functional polymeric component selected from the group consisting of diesters, polyesters, alkyd polymers, acrylic polymers and polycarbonate polymers, a crosslinking agent such as a methylol (alkoxymethyl) amino crosslinking agent, and a reactive additive which is the ester reaction product of a phenol carboxylic acid, preferably para-hydroxybenzoic acid, and an epoxy compound selected from glycidyl ethers, glycidyl esters, linear epoxies and aromatic epoxies. The crosslinkable compositions of this invention may be used to prepare curable coating and paint formulations, and also may contain other ingredients such as a crosslinking catalyst, fillers, pigments and the like. When cured, the coatings of this invention exhibit improved physical and chemical properties when compared with cured coatings which do not contain the ester reaction product additive.

    摘要翻译： 本发明提供了基于选自二酯，聚酯，醇酸聚合物，丙烯酸聚合物和聚碳酸酯聚合物的二元或多羟基官能聚合物组分的混合物的氨基可交联涂料配方，交联剂如羟甲基（ 烷氧基甲基）氨基交联剂，以及作为酚羧酸，优选对羟基苯甲酸和选自缩水甘油醚，缩水甘油酯，直链环氧化合物和芳族环氧化合物的环氧化合物的酯反应产物的反应性添加剂。 本发明的可交联组合物可用于制备可固化涂料和涂料制剂，并且还可以含有其它成分如交联催化剂，填料，颜料等。 当固化时，与不含酯反应产物添加剂的固化涂层相比，本发明的涂层表现出改善的物理和化学性质。

    Thermoset coating compositions having improved hardness and curing properties
    2.
    发明授权
    Thermoset coating compositions having improved hardness and curing properties 失效
    具有改善的硬度和固化性能的热固性涂料组合物

    公开(公告)号：US5780556A

    公开(公告)日：1998-07-14

    申请号：US480076

    申请日：1995-06-07

    申请人： Albert Ilya Yezrielev ,  Konstantinos R. Rigopoulos ,  Vijay Swarup

    发明人： Albert Ilya Yezrielev ,  Konstantinos R. Rigopoulos ,  Vijay Swarup

    IPC分类号： C07C69/84 ,  C07C69/44 ,  C08L67/00 ,  C09D133/00 ,  C09D163/00 ,  C09D167/00 ,  C09D169/00 ,  C09D171/00 ,  C09D201/00 ,  C08F20/00 ,  C08G63/68

    CPC分类号： C09D167/00 ,  C09D201/00

    摘要： The present invention provides an amino curable polyester oligomer composition having low viscosity and a narrow molecular weight distribution comprising one or a mixture of oligomers (a) and (b): ##STR1## wherein R is the residue of at least one aliphatic, cycloaliphatic or mixed aliphatic/aromatic polycarboxylic-acid having from 2 to about 20 carbon atoms, R.sub.1 is the residue of at least one aliphatic, cycloaliphatic or mixed aliphatic/cycloaliphatic polyol having from 2 to about 20 carbon atoms, A is a radical of the formula: ##STR2## B is a radical of the formula: ##STR3## wherein R.sub.4 is H, OH, halogen or an organic radical containing 1 to 4 carbon atoms, R.sub.5 is a direct bond or an organic radical containing 1 to 20 carbon atoms and R.sub.6 is an organic radical containing 2 to 20 carbon atoms, n is a number averaging from greater than 0 up to less than 2 and p is a number averaging from about 0.5 up to less than 2, said composition further characterized by a number average molecular weight in the range of from about 250 to about 1,000 and a polydispersity of less than about 2.0. The invention also provides for curable blends of these polyester oligomers with other polymers such as polyesters, alkyds, acrylic polymers and the like, which may be further used to prepare curable coating and paint formulations, and also may contain other ingredients such as a crosslinking catalyst, fillers, pigments and the like. When cured, the coatings of this invention exhibit improved physical and chemical properties when compared with cured coatings which do not contain the polyester oligomer component.

    摘要翻译： 本发明提供一种具有低粘度和窄分子量分布的氨基可固化聚酯低聚物组合物，其包含一种或低聚物（a）和（b）的混合物：（a）其中R是 具有2至约20个碳原子的至少一种脂肪族，脂环族或混合脂族/芳族多元羧酸的残基，R 1是至少一个具有2-约20个碳原子的脂族，脂环族或混合脂族/脂环族多元醇的残基 A是具有下列基团的基团：B是具有下式的基团：含有1至4个碳原子的基团，R 5是直接键或含有1至20个碳原子的有机基团，R 6是有机基团 含有2至20个碳原子，n是大于0至小于2的平均值，p为约0.5至小于2的平均数，所述组合物的特征还在于数均分子量在 从约250到 约1,000，多分散性小于约2.0。 本发明还提供了这些聚酯低聚物与其它聚合物如聚酯，醇酸树脂，丙烯酸聚合物等的可固化共混物，其可以进一步用于制备可固化涂料和涂料配方，并且还可以含有其它成分例如交联催化剂 ，填料，颜料等。 当固化时，与不含聚酯低聚物组分的固化涂层相比，本发明的涂层表现出改善的物理和化学性质。

    Method for decomposition of ethers
    3.
    发明授权
    Method for decomposition of ethers 有权
    醚分解方法

    公开(公告)号：US07655826B2

    公开(公告)日：2010-02-02

    申请号：US11104315

    申请日：2005-04-12

    申请人： Charles M. Yarbrough ,  Vijay Swarup ,  Patrick Joseph Maher ,  Albert Y Hu ,  Michael Walter Bedell

    发明人： Charles M. Yarbrough ,  Vijay Swarup ,  Patrick Joseph Maher ,  Albert Y Hu ,  Michael Walter Bedell

    IPC分类号： C07C4/02 ,  C07C1/00 ,  C10G9/00 ,  C10G11/00

    CPC分类号： C07C1/24 ,  C07C1/213 ,  C10G3/40 ,  C10G3/49 ,  C10G3/57 ,  C10G3/62 ,  C10G2300/1037 ,  C10G2300/202 ,  C10G2300/4093 ,  C10G2400/20 ,  C10G2400/28

    摘要： This invention relates to a method of making an olefin from a dialkyl ether comprising (a) introducing an ether having a formula CxH2x+1CyH2y+1 into a thermal or catalytic cracking unit processing a hydrocarbon feedstock; and (b) decomposing at least a portion of the ether to form an olefin having a formula CxH2x and/or CyH2y and an alcohol having a formula CxH2x+1 and/or CyH2y+1OH, wherein x and y independently range from about 1 to about 30. This invention also relates to a method of reducing coking in a thermal or catalytic cracking unit comprising (a) introducing an ether, having a formula CxH2x+1OCyH2y+1, into the cracking unit processing a hydrocarbon feedstock in an amount effective to reduce coke formation relative to processing the hydrocarbon feedstock in the absence of the ether, wherein x and y independently range from about 1 to about 30.

    摘要翻译： 本发明涉及一种由二烷基醚制备烯烃的方法，包括（a）将具有式CxH2x + 1CyH2y + 1的醚导入加工烃原料的热催化裂解装置; 和（b）分解至少一部分醚以形成具有式CxH2x和/或CyH2y的烯烃和具有式CxH2x + 1和/或CyH2y + 1OH的醇，其中x和y独立地为约1至 本发明还涉及一种在热或催化裂化装置中减少焦化的方法，其包括（a）将具有式C x H 2 x + 1 O yy yy + 1的式C 4 H 8 O x + 1 O yy H y + 1的醚引入到裂化装置中， 在不存在醚的情况下相对于处理烃原料减少焦炭形成，其中x和y独立地为约1至约30。

    Process for alcohol production by selective ether decomposition
    4.
    发明申请
    Process for alcohol production by selective ether decomposition 失效
    通过选择性醚分解生产酒精的方法

    公开(公告)号：US20060281954A1

    公开(公告)日：2006-12-14

    申请号：US11147919

    申请日：2005-06-08

    申请人： Charles Yarbrough ,  Brian Roberts ,  Dennis Davoren ,  Kenneth Buturla ,  Carl Katzenstein ,  Doron Levin ,  Hans Korsten ,  Vijay Swarup

    发明人： Charles Yarbrough ,  Brian Roberts ,  Dennis Davoren ,  Kenneth Buturla ,  Carl Katzenstein ,  Doron Levin ,  Hans Korsten ,  Vijay Swarup

    IPC分类号： C07C29/03

    CPC分类号： B01J23/24 ,  B01J21/06 ,  B01J21/066 ,  B01J23/10 ,  C07C29/04 ,  C07C29/10 ,  C07C31/10 ,  C07C31/12

    摘要： This invention relates to a process for the production of an alcohol, the process comprising (a) reacting an olefin and water in the presence of a catalyst under conditions sufficient to form a crude alcohol stream comprising alcohol, and a dialkyl ether; (b) separating at least a portion of the crude alcohol stream into an alcohol-containing stream and a dialkyl ether stream; (c) contacting at least a portion of the dialkyl ether stream with an ether decomposition catalyst, the ether decomposition catalyst comprising a mixed metal oxide having the following composition XmYnZpOq where X is at least one metal selected from Group 4 of the Periodic Table of Elements, Y is at least one metal selected from Group 3 (including the Lanthanides and Actinides) and Group 6 of the Periodic Table of Elements and Z is at least one metal selected from Groups 7, 8, and 11 of the Periodic Table of Elements; m, n, p, and q are the atomic ratios of their respective components and, when m is 1, n is from about 0.01 to about 0.75, p is from 0 to about 0.1, and q is the number of oxygen atoms necessary to satisfy the valence of the other components, to form a crude dialkyl ether decomposition stream comprising alcohol and olefin; (d) recovering at least a portion of the olefin from the crude dialkyl ether decomposition stream; and (e) recycling at least a portion of the olefin recovered in step (d) to step (a).

    摘要翻译： 本发明涉及一种生产醇的方法，该方法包括（a）在足以形成包含醇和二烷基醚的粗醇物流的条件下，在催化剂存在下使烯烃和水反应; （b）将至少一部分粗醇流分离成含醇流和二烷基醚流; （c）使至少一部分二烷基醚料流与醚分解催化剂接触，所述醚分解催化剂包含具有以下组成的混合金属氧化物： 其中X是选自元素周期表第4族的至少一种金属，Y是选自第3族（包括镧系元素）中的至少一种金属 和锕系元素）和元素周期表第6族，Z是选自元素周期表第7,8和11族中的至少一种金属; m，n，p和q是它们各自成分的原子比，当m为1时，n为约0.01至约0.75，p为0至约0.1，q为必需的氧原子数 满足其他组分的化合价，形成包含醇和烯烃的粗二烷基醚分解物流; （d）从粗二烷基醚分解流中回收至少一部分烯烃; 和（e）将步骤（d）中回收的烯烃的至少一部分再循环到步骤（a）。