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    Dehydroisomerisation catalyst and its use in the preparation of isobutene from N-butane
    6.
    发明授权
    Dehydroisomerisation catalyst and its use in the preparation of isobutene from N-butane 失效
    脱氢异构化催化剂及其在N-丁烷制备异丁烯中的应用

    公开(公告)号：US5336830A

    公开(公告)日：1994-08-09

    申请号：US140572

    申请日：1993-10-21

    申请人： Giuseppe Bellussi ,  Aldo Giusti ,  Laura Zanibelli

    发明人： Giuseppe Bellussi ,  Aldo Giusti ,  Laura Zanibelli

    IPC分类号： B01J23/62 ,  B01J21/12 ,  B01J23/42 ,  B01J37/02 ,  C07C5/373 ,  C07C11/09 ,  C07C5/333

    CPC分类号： B01J23/42 ,  C07C5/373

    摘要： A catalyst is described for the preparation of isobutene by dehydroisomerization of n-butane consisting of a solid, granular support of porous gamma-alumina on the surface of which catalytic quantities of platinum, silica and preferably also one or more promotors are deposited. In a preferred form of embodiment this catalyst is used with a second catalyst which may be formed of Boralite B or a solid granular support of gamma-alumina on the surface of which catalytic quantities of silica are deposited. The present invention relates also to the process of dehydroisomerization of n-butane to isobutene in which the catalyst is used and the relative operating conditions.

    摘要翻译： 描述了一种催化剂，用于通过由多孔γ-氧化铝的固体粒状载体组成的正丁烷的脱氢异构化来制备异丁烯，其表面上催化量的铂，二氧化硅，并且优选还含有一种或多种促进剂。 在一个优选形式的实施方案中，该催化剂与第二催化剂一起使用，该第二催化剂可由Boreite B或γ-氧化铝的固体颗粒载体形成，其表面上沉积有催化量的二氧化硅。 本发明还涉及正丁烷与使用催化剂的异丁烯的脱氢异构化方法和相对操作条件。

    Dehydroisomerization catalyst and its use in the preparation of isobutene from n-butane
    7.
    发明授权
    Dehydroisomerization catalyst and its use in the preparation of isobutene from n-butane 失效
    脱氢异构催化剂及其在正丁烷制备异丁烯中的应用

    公开(公告)号：US5275995A

    公开(公告)日：1994-01-04

    申请号：US737067

    申请日：1991-07-29

    申请人： Giuseppe Bellussi ,  Aldo Giusti ,  Laura Zanibelli

    发明人： Giuseppe Bellussi ,  Aldo Giusti ,  Laura Zanibelli

    IPC分类号： B01J23/62 ,  B01J21/12 ,  B01J23/42 ,  B01J37/02 ,  C07C5/373 ,  C07C11/09 ,  B01J21/02

    CPC分类号： B01J23/42 ,  C07C5/373

    摘要： A catalyst is described for the preparation of isobutene by dehydroisomerization of n-butane consisting of a solid, granular support of porous gamma-alumina on the surface of which catalytic quantities of platinum, silica and preferably also one or more promotors are deposited. In a preferred form of embodiment this catalyst is used with a second catalyst which may be formed of Boralite B or a solid granular support gamma-alumina on the surface of which catalytic quantities of silica are deposited.The present invention relates also to the process of dehydroisomerization of n-butane to isobutene in which the catalyst is used and the relative operating conditions.

    摘要翻译： 描述了一种催化剂，用于通过由多孔γ-氧化铝的固体粒状载体组成的正丁烷的脱氢异构化来制备异丁烯，其表面上催化量的铂，二氧化硅，并且优选还含有一种或多种促进剂。 在优选的实施方案中，该催化剂与第二催化剂一起使用，第二催化剂可以由Boreite B或其表面上沉积有催化量的二氧化硅的固体颗粒载体γ-氧化铝形成。 本发明还涉及使用催化剂的正丁烷与异丁烯的脱氢异构化方法和相对的操作条件。

    Catalytic system and process for the total hydroconversion of heavy oils
    8.
    发明授权
    Catalytic system and process for the total hydroconversion of heavy oils 有权

    公开(公告)号：US09700880B2

    公开(公告)日：2017-07-11

    申请号：US14343007

    申请日：2012-09-06

    申请人： Daniele Molinari ,  Giuseppe Bellussi ,  Alberto Landoni ,  Paolo Pollesel

    发明人： Daniele Molinari ,  Giuseppe Bellussi ,  Alberto Landoni ,  Paolo Pollesel

    IPC分类号： C10G47/02 ,  C10G47/16 ,  C10G65/12 ,  B01J29/89 ,  B01J27/051 ,  B01J29/78 ,  C10G45/12 ,  C10G65/00

    CPC分类号： B01J29/89 ,  B01J27/051 ,  B01J29/7876 ,  C10G45/12 ,  C10G47/16 ,  C10G65/12

    摘要： A catalytic system characterized in that it comprises: a first catalyst, having a hydrogenating function, consisting of solid particles of which at least 95% by volume having an equivalent diameter smaller than 20 μm, containing one or more sulfides of metals of group VI and/or VIII B, possibly prepared starting from an oil-soluble precursor of the same; and a second catalyst, having a cracking function, consisting of solid particles of which at least 90% by volume having an equivalent diameter larger than 5 μm and smaller than 5 mm, containing an amorphous silico-aluminate and/or a crystalline silico-aluminate and/or an alumina, the equivalent average diameter of the solid particles of the second catalyst being greater than the equivalent average diameter of the solid particles of the first catalyst. Said catalytic system can be used in a process for the hydroconversion of heavy oils which comprises sending the heavy oil to a hydroprocessing step carried out in one or more slurry reactors, in the presence of hydrogen or a mixture of hydrogen and H2S, obtaining a stream of products in vapor or liquid-vapor phase, and extracting at the bottom, in continuous or discontinuous, a liquid stream containing non-converted products together with the two catalysts of said catalytic system, said liquid stream extracted then being separated into a clarified primary stream containing the first catalyst, which is at least partially recycled to the hydroprocessing step, and a stream rich in the second catalyst, which is regenerated in a regeneration step and at least partially recycled to the hydroprocessing step.

    ORGANIC-INORGANIC HYBRID SILICATES AND METAL-SILICATES HAVING AN ORDERED STRUCTURE
    10.
    发明申请
    ORGANIC-INORGANIC HYBRID SILICATES AND METAL-SILICATES HAVING AN ORDERED STRUCTURE 有权
    有机无机混合硅酸盐和具有订购结构的金属硅酸盐

    公开(公告)号：US20100191009A1

    公开(公告)日：2010-07-29

    申请号：US12376704

    申请日：2007-08-03

    申请人： Giuseppe Bellussi ,  Angela Carati ,  Caterina Rizzo ,  Urbano Diaz Morales ,  Stefano Zanardi ,  Wallace O'Neil Parker ,  Roberto Millini

    发明人： Giuseppe Bellussi ,  Angela Carati ,  Caterina Rizzo ,  Urbano Diaz Morales ,  Stefano Zanardi ,  Wallace O'Neil Parker ,  Roberto Millini

    IPC分类号： C07F7/08

    CPC分类号： C09C1/3081 ,  C01B33/44 ,  C01B37/00 ,  C01B39/00 ,  C01B39/02 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/86 ,  C01P2006/17 ,  C07F7/1804

    摘要： The present invention relates to new organic-inorganic hybrid silicates and metal-silicates called ECS, characterized by an X-ray powder diffraction pattern with reflections exclusively at angular values higher than 4.0° of 2Θ, preferably at angular values higher than 4.7°, and an ordered structure containing structural units having formula (a) wherein R is an organic group: Formula (a) and possibly containing one or more elements T selected from groups III B, IV B, V B and transition metals, with a Si/(Si+T) molar ratio in said structure higher than 0.3 and lower than or equal to 1, wherein Si is the silicon contained in the structural unit (a). A process is also described, starting from disilanes, for the preparation of these materials, which does not include the use of templates or surfactants. These materials can be used as molecular sieves, adsorbents, in the field of catalysis, in the field of electronics, in the field of sensors, in the field of nanotechnologies.

    摘要翻译： 本发明涉及称为ECS的新的有机 - 无机杂化硅酸盐和金属硅酸盐，其特征在于具有专门在高于4.0°的角度值为2θ，优选高于4.7°的角度值的反射的X射线粉末衍射图，以及 含有具有式（a）的结构单元的有序结构，其中R是有机基团：式（a）并且可能含有选自IIIB，IVB，VB族和过渡金属的一种或多种元素T，其中Si /（Si + T）的摩尔比高于0.3且小于或等于1，其中Si是结构单元（a）中所含的硅。 还描述了从二硅烷开始制备这些材料的方法，其不包括使用模板或表面活性剂。 这些材料可用作纳米技术领域的电子领域，传感器领域的催化剂领域的分子筛，吸附剂。