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公开(公告)号：US20060280677A1
公开(公告)日：2006-12-14
申请号：US11483164
申请日：2006-07-10
申请人： Alfred Hagemeyer , Raymond Carhart , Karin Yaccato , Michael Herrmann , Andreas Lesik , Christopher Brooks , Cory Phillips
发明人： Alfred Hagemeyer , Raymond Carhart , Karin Yaccato , Michael Herrmann , Andreas Lesik , Christopher Brooks , Cory Phillips
IPC分类号： C01B3/12
CPC分类号： C01B3/16 , B01J19/0046 , B01J23/6525 , B01J23/8913 , B01J23/894 , B01J23/8946 , B01J23/8993 , B01J2219/00387 , B01J2219/00536 , B01J2219/00596 , B01J2219/00605 , B01J2219/00612 , B01J2219/00637 , B01J2219/00641 , B01J2219/00659 , B01J2219/00691 , B01J2219/00745 , B01J2219/00747 , C01B2203/00 , C01B2203/0283 , C01B2203/1011 , C01B2203/1023 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1088 , C01B2203/1094 , C01B2203/1614 , C40B30/08 , C40B40/18 , C40B60/14 , Y02P20/52
摘要： A method and catalysts and fuel processing apparatus for producing a hydrogen-rich gas, such as a hydrogen-rich syngas are disclosed. According to the method, a CO-containing gas, such as a syngas, contacts a platinum-free ruthenium-cobalt water gas shift (“WGS”) catalyst, in the presence of water and preferably at a temperature of less than about 450° C., to produce a hydrogen-rich gas, such as a hydrogen-rich syngas. Also disclosed is a platinum-free ruthenium-cobalt water gas shift catalyst formulated from: a) Ru, its oxides or mixtures thereof, b) Co, Mo, their oxides or mixtures thereof, and c) at least one of Li, Na, K, Rb, Cs, Ti, Zr, Cr, Fe, La, Ce, Eu, their oxides and mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, zeolite, perovskite, silica clay, yttria and iron oxide. Fuel processors containing such water gas shift catalysts are also disclosed.
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2.发明申请公开(公告)号：US20060194694A1
公开(公告)日：2006-08-31
申请号：US11412918
申请日：2006-04-28
申请人： Alfred Hagemeyer , Raymond Carhart , Karin Yaccato , Peter Strasser , Robert Grasselli , Christopher Brooks , Cory Phillips
发明人： Alfred Hagemeyer , Raymond Carhart , Karin Yaccato , Peter Strasser , Robert Grasselli , Christopher Brooks , Cory Phillips
CPC分类号： C01B3/16 , B01J23/40 , B01J23/462 , B01J23/56 , B01J23/58 , B01J23/622 , B01J23/63 , B01J23/6482 , B01J23/6525 , B01J23/6562 , B01J23/89 , B01J23/8933 , B01J23/894 , B01J23/8946 , B01J23/8993 , B01J37/024 , B01J2219/00585 , B01J2219/00596 , B01J2219/00605 , B01J2219/00612 , B01J2219/00637 , B01J2219/00641 , B01J2219/00659 , B01J2219/00662 , B01J2219/00691 , B01J2219/00702 , B01J2219/00707 , B01J2219/00745 , B01J2219/00747 , C01B2203/00 , C01B2203/0283 , C01B2203/1011 , C01B2203/1023 , C01B2203/1041 , C01B2203/1052 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01B2203/1094 , C01B2203/1614 , C40B30/08 , C40B40/18 , H01M8/0618 , H01M8/0668 , Y02P20/52
摘要： A method and catalysts for producing a hydrogen-rich syngas are disclosed. According to the method a CO-containing gas contacts a water gas shift (WGS) catalyst, optionally in the presence of water, preferably at a temperature of less than about 450° C. to produce a hydrogen-rich gas, such as a hydrogen-rich syngas. Also disclosed is a water gas shift catalyst formulated from: a) Pt, its oxides or mixtures thereof; b) Ru, its oxides or mixtures thereof; and c) at least one of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Co, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu. Another disclosed catalyst formulation comprises Pt, its oxides or mixtures thereof; Ru, its oxides or mixtures thereof; Co, its oxides or mixtures thereof; and at least one of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu, their oxides and mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, zeolite, perovskite, silica clay, yttria and iron oxide. Fuel processors containing such water gas shift catalysts are also disclosed.
摘要翻译： 公开了一种用于生产富氢合成气的方法和催化剂。 根据该方法，含CO气体任选地在水存在下，优选在低于约450℃的温度下接触水煤气变换（WGS）催化剂，以产生富氢气体，例如氢气 富含合成气。 还公开了一种由以下物质配制的水煤气变换催化剂：a）Pt，其氧化物或其混合物; b）Ru，其氧化物或其混合物; 和c）Li，Na，K，Rb，Cs，Mg，Ca，Sr，Ba，Sc，Y，Ti，Zr，V，Mo，Mn，Fe，Co，Rh，Ir，Ge，Sn中的至少一种 ，Sb，La，Ce，Pr，Sm和Eu。 另一种公开的催化剂配方包括Pt，其氧化物或其混合物; Ru，其氧化物或其混合物; Co，其氧化物或其混合物; 以及Li，Na，K，Rb，Cs，Mg，Ca，Sr，Ba，Sc，Y，Ti，Zr，V，Mo，Mn，Fe，Rh，Ir，Ge，Sn，Sb，La中的至少一种 ，Ce，Pr，Sm和Eu，它们的氧化物及其混合物。 WGS催化剂可以负载在载体上，例如氧化铝，氧化锆，二氧化钛，二氧化铈，氧化镁，镧系，氧化铌，沸石，钙钛矿，硅土，氧化钇和氧化铁中的任一种或其组合。 还公开了含有这种水煤气变换催化剂的燃料加工机。
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3.发明申请Noble metal-free nickel containing catalyst formulations for hydrogen generation 有权贵金属无镍含氢催化剂配方用于氢气生成公开(公告)号：US20080051280A1
公开(公告)日：2008-02-28
申请号：US11898807
申请日：2007-09-17
IPC分类号： B01J23/76 , B01J21/08 , B01J21/16 , B01J23/889 , B01J29/00 , B01J27/057 , B01J23/83 , B01J23/755
CPC分类号： B01J23/835 , B01J23/80 , B01J23/825 , B01J23/8435 , B01J27/0576 , B01J2219/00364 , B01J2219/00378 , B01J2219/00536 , B01J2219/00605 , B01J2219/00612 , B01J2219/00637 , B01J2219/00641 , B01J2219/00659 , B01J2219/00691 , B01J2219/00702 , B01J2219/00745 , B01J2219/00747 , C01B3/16 , C01B2203/00 , C01B2203/0283 , C01B2203/1041 , C01B2203/1052 , C01B2203/1082 , C01B2203/1088 , C01B2203/1094 , C01B2203/1614 , C40B30/08 , C40B40/18 , C40B60/14 , Y02E60/324 , Y02P20/52
摘要： The invention relates to noble metal-free nickel catalysts that exhibit both high activity and selectivity to hydrogen generation and carbon monoxide oxidation. The noble metal-free water gas shift catalyst of the invention comprises Ni in either a supported or a bulk state and at least one of Ge, Cd, In, Sn, Sb, Te, Pb, their oxides and mixtures thereof.
摘要翻译： 本发明涉及对氢生成和一氧化碳氧化具有高活性和选择性的贵金属不含镍催化剂。 本发明的无贵金属水煤气变换催化剂包括负载或体态的Ni和Ge，Cd，In，Sn，Sb，Te，Pb中的至少一种，它们的氧化物及其混合物。
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