利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

59 条记录 (耗时 0.025 秒)

    Highly selective n-olefin isomerization process using ZSM-35
    2.
    发明授权
    Highly selective n-olefin isomerization process using ZSM-35 失效
    使用ZSM-35的高选择性正烯烃异构化方法

    公开(公告)号：US5516959A

    公开(公告)日：1996-05-14

    申请号：US357841

    申请日：1994-12-09

    申请人： Iraj I. Rahmim ,  Albin Huss, Jr. ,  Daria N. Lissy ,  Donald J. Klocke ,  Werner O. Haag

    发明人： Iraj I. Rahmim ,  Albin Huss, Jr. ,  Daria N. Lissy ,  Donald J. Klocke ,  Werner O. Haag

    IPC分类号： B01J29/65 ,  B01J29/70 ,  C07C5/27 ,  C07C5/22

    CPC分类号： B01J29/7042 ,  B01J29/65 ,  B01J29/7046 ,  C07C5/2775 ,  B01J2229/26 ,  B01J2229/42

    摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds to iso-olefins at high levels of feed conversion wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-35 under skeletal isomerization conditions which can include temperatures of 100 to 750.degree. C. The process uses a catalyst composition comprising ZSM-35, e.g., microcrystalline ZSM-35 having a crystal size whose largest dimension is no greater than 0.5 micron and whose ratio of its second largest dimension to said largest dimension ranges from 0.5 to 1. The process exhibits enhanced catalyst cycle life where the ZSM-35 is composited with a silica-containing matrix to provide a catalyst composite having a total pore volume greater than 0.6 cc/g or 300.sup.+ angstroms pore volume of greater than 0.1 cc/g.

    摘要翻译： 公开了一种用于在高水平进料转化率下将含线性烯烃的有机原料高度选择性骨架异构化为异烯烃的方法，其中线性烯烃例如正丁烯在骨架异构化条件下与包含ZSM-35的催化剂接触， 可以包括100至750℃的温度。该方法使用包含ZSM-35的催化剂组合物，例如具有最大尺寸不大于0.5微米的晶体尺寸的微晶ZSM-35，其第二大尺寸与所述 最大尺寸范围为0.5至1.该方法表现出增强的催化剂循环寿命，其中ZSM-35与含二氧化硅的基质复合以提供总孔体积大于0.6cc / g或300多埃孔体积的催化剂复合材料 大于0.1cc / g。

    Highly selective N-olefin isomerization process using microcrystalline ZSM-22
    3.
    发明授权
    Highly selective N-olefin isomerization process using microcrystalline ZSM-22 失效
    使用微晶ZSM-22的高选择性N-烯烃异构化方法

    公开(公告)号：US5237121A

    公开(公告)日：1993-08-17

    申请号：US925442

    申请日：1992-08-11

    申请人： Iraj Rahmim ,  Albin Huss, Jr. ,  Daria N. Lissy ,  Donald J. Klocke ,  Ivy D. Johnson

    发明人： Iraj Rahmim ,  Albin Huss, Jr. ,  Daria N. Lissy ,  Donald J. Klocke ,  Ivy D. Johnson

    IPC分类号： C07C5/27

    CPC分类号： C07C5/2775

    摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds to iso-olefins at high levels of feed conversion wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-22 having a crystal size whose largest dimension is no greater than 0.5 micron. The process is carried out under isomerization conditions to produce iso-olefins of corresponding carbon number, e.g., isobutene. High overall iso-olefin yields thus can be obtained, even at relatively low temperatures.

    摘要翻译： 公开了一种用于在高水平进料转化率下将含线性烯烃的有机原料高度选择性骨架异构化成异烯烃的方法，其中线性烯烃例如正丁烯与包含ZSM-22的催化剂接触，ZSM-22的晶体尺寸 最大尺寸不大于0.5微米。 该方法在异构化条件下进行以产生相应碳数的异烯烃，例如异丁烯。 即使在相对较低的温度下也能获得高的全部异烯烃收率。

    Process for the production of alkylate gasoline from FCC light aliphatics
    7.
    发明授权
    Process for the production of alkylate gasoline from FCC light aliphatics 失效
    FCC轻脂肪酸生产烷基化汽油的方法

    公开(公告)号：US5475175A

    公开(公告)日：1995-12-12

    申请号：US228780

    申请日：1994-04-18

    申请人： Altaf Husain ,  Albin Huss, Jr. ,  Iraj I. Rahmim

    发明人： Altaf Husain ,  Albin Huss, Jr. ,  Iraj I. Rahmim

    IPC分类号： C07C2/12 ,  C07C2/58 ,  C07C2/56

    CPC分类号： B01J29/65 ,  B01J37/0009 ,  C07C2/58 ,  B01J2229/42 ,  B01J29/70 ,  C07C2521/04 ,  C07C2529/70

    摘要： This invention provides a process for upgrading hydrocarbon feedstock comprising the steps of:(i) recovering a C.sub.4 -rich aliphatic stream from a catalytic cracking process;(ii contacting said C.sub.4 -rich aliphatic stream with an isomerization catalyst comprising a zeolite sorbing 30 to 55 mg n-hexane at 90.degree. C., 83 torr, and 15 to 40 mg 3-methylpentane at 90.degree. C., 90 torr, per g dry zeolite in the hydrogen form in a first reaction stage to selectively isomerize C.sub.4 n-olefins to C.sub.4 isoolefins; and(iii) contacting the product stream from said first reaction stage with a solid acid alkylation catalyst selected from the group consisting of MCM-36 and MCM-49, as described herein and zeolites having a Constraint Index of less than or equal to about 2, to produce isoparaffinic alkylate gasoline.

    摘要翻译： 本发明提供了一种用于升级烃原料的方法，包括以下步骤：（i）从催化裂化过程中回收富含C4的脂族物流; （ii）使所述富C4脂族物流与异构化催化剂接触，所述异构化催化剂包括在90℃下吸附30至55mg正己烷的沸石，83托和15至40mg 3-甲基戊烷，90℃，90托， 在氢气形式的每g干沸石中，在第一反应阶段中选择性地将C 4正构烯烃异构化为C 4异烯烃;和（iii）使来自所述第一反应阶段的产物流与固体酸烷基化催化剂接触，所述固体酸烷基化催化剂选自MCM -36和MCM-49，以及具有小于或等于约2的约束指数的沸石以产生异链烷烃烷基化汽油。

    Isoparaffin:olefin alkylation in the presence of synthetic porous MCM-49
    8.
    发明授权
    Isoparaffin:olefin alkylation in the presence of synthetic porous MCM-49 失效
    异构烷烃：在合成多孔MCM-49存在下进行烯烃烷基化

    公开(公告)号：US5254792A

    公开(公告)日：1993-10-19

    申请号：US774482

    申请日：1991-10-10

    申请人： Altaf Husain ,  Albin Huss, Jr. ,  Donald J. Klocke ,  Hye K. C. Timken

    发明人： Altaf Husain ,  Albin Huss, Jr. ,  Donald J. Klocke ,  Hye K. C. Timken

    IPC分类号： C07C2/58 ,  C07C2/56

    CPC分类号： C07C2/58 ,  C07C2529/70

    摘要： The invention provides an isoparaffin: olefin alkylation process comprising contacting isoparaffin and olefin with a synthetic porous crystalline material which is characterized, in its uncalcined form, by an X-ray diffraction pattern including values substantially as set forth in Table I of the specification and having a composition comprising the molar relationshipX.sub.2 O.sub.3 :(n)YO.sub.2,wherein n is less than about 20, X is a trivalent element and Y is a tetravalent element.

    摘要翻译： 本发明提供了异链烷烃：烯烃烷基化方法，其包括使异链烷烃和烯烃与合成的多孔结晶材料接触，所述合成多孔结晶材料的特征在于其未煅烧形式，其X射线衍射图包括基本上如本说明书的表I所述的值，并且具有 包含摩尔关系X 2 O 3：（n）YO 2的组合物，其中n小于约20，X是三价元素，Y是四价元素。

    Combined paraffin isomerization/ring opening process for c5+naphtha
    9.
    发明授权
    Combined paraffin isomerization/ring opening process for c5+naphtha 失效
    c5 +石脑油组合石蜡异构化/开环方法

    公开(公告)号：US5334792A

    公开(公告)日：1994-08-02

    申请号：US958826

    申请日：1992-10-09

    申请人： Kenneth J. Del Rossi ,  David J. Dovedytis ,  David J. Esteves ,  Mohsen N. Harandi ,  Albin Huss, Jr.

    发明人： Kenneth J. Del Rossi ,  David J. Dovedytis ,  David J. Esteves ,  Mohsen N. Harandi ,  Albin Huss, Jr.

    IPC分类号： C10G59/02 ,  C07C5/02 ,  C07C5/13 ,  C07C5/23

    CPC分类号： C10G59/02 ,  Y10S585/94

    摘要： There is provided a process for ring opening of aromatics and cycloaliphatics, as well as isomerization of aliphatics. The feedstream to this process comprises hydrocarbons having 6 carbon atoms. The process involves the use of at least two reactors connected in series. The first reactor contains a zeolite catalyst and is operated under conditions which particularly promote ring opening. The catalyst in this first reactor may comprise zeolite Beta and platinum. A downstream reactor is operated under conditions to promote isomerization of aliphatics. The catalyst in the second reactor may comprise alumina, platinum and a chloride component.

    摘要翻译： 提供了芳烃和环烯烃开环方法以及脂肪族异构化方法。 该方法的进料流包含具有6个碳原子的烃。 该方法涉及使用串联连接的至少两个反应器。 第一反应器含有沸石催化剂，并在特别促进开环的条件下操作。 该第一反应器中的催化剂可以包括沸石β和铂。 下游反应器在促进脂肪族异构化的条件下运行。 第二反应器中的催化剂可以包括氧化铝，铂和氯化物组分。

    Hydrogen transfer process
    10.
    发明授权
    Hydrogen transfer process 失效
    氢转移过程

    公开(公告)号：US5326922A

    公开(公告)日：1994-07-05

    申请号：US929547

    申请日：1992-08-13

    申请人： Albin Huss, Jr. ,  Quang N. Le ,  Robert T. Thomson

    发明人： Albin Huss, Jr. ,  Quang N. Le ,  Robert T. Thomson

    IPC分类号： C07C2/58 ,  C07C5/52

    CPC分类号： C07C5/52 ,  C07C2/58 ,  C07C2529/70

    摘要： The transfer of hydrogen from a paraffin to an olefin is carried out in the presence of, as catalyst, MCM-36. Especially when the paraffin reactant is an isoparaffin, the olefin produced from the reacted isoparaffin may react with unreacted isoparaffin to also produce an alkylate product.

    摘要翻译： 氢气从烷烃转化为烯烃在作为催化剂的MCM-36存在下进行。 特别是当链烷烃反应物是异链烷烃时，由反应的异链烷烃产生的烯烃可与未反应的异链烷烃反应，产生烷基化产物。