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    .alpha.-Hydroxy thioethers
    1.
    发明授权
    .alpha.-Hydroxy thioethers 失效
    α-羟基硫醚

    公开(公告)号：US4808572A

    公开(公告)日：1989-02-28

    申请号：US936671

    申请日：1986-12-01

    申请人： Andreas Beck ,  Werner Breitenstein ,  Andreas von Sprecher ,  Robert W. Lang ,  Konrad Oertle

    发明人： Andreas Beck ,  Werner Breitenstein ,  Andreas von Sprecher ,  Robert W. Lang ,  Konrad Oertle

    IPC分类号： A61K31/16 ,  A61K31/165 ,  A61K31/19 ,  A61K31/195 ,  A61K31/215 ,  A61K31/22 ,  A61K31/23 ,  A61K38/00 ,  A61K45/00 ,  A61P11/00 ,  A61P29/00 ,  A61P37/08 ,  A61P43/00 ,  C07C67/00 ,  C07C313/00 ,  C07C321/18 ,  C07C323/00 ,  C07C323/52 ,  C07C323/58 ,  C07C323/59 ,  C07C323/60 ,  C07K1/113 ,  C07K5/02 ,  C07K5/06 ,  C07C149/243

    CPC分类号： C07K5/0606 ,  A61K31/19 ,  A61K31/215 ,  C07C323/00 ,  A61K38/00

    摘要： Novel asymmetric thioethers of the formula ##STR1## in which the general symbols have the following meanings: a is an integer of from 1 to 7,R.sup.o represents hydrogen or C.sub.1-7 -alkanoyl,R.sup.1 represents C.sub.1-3 -alkyl which may be substituted at the terminal carbon atom by a free or acylated hydroxy group, by a halogen atom having an atomic number of at most 17, or by methoxy, or represents C.sub.1-3 -perfluoroalkyl,R.sup.2 represents an optionally unsaturated aliphatic radical having from 5 to 15 carbon atoms,A represents ethylene or alternatively, if R.sup.1 represents a halogenated radical and/or B represents phenylene or ethylene, a single bond or vinylene,B represents a single bond, ethynylene or phenylene,R.sup.3 represents hydroxy, C.sub.1-7 -alkoxy or an optionally substituted amino group, and--X-- represents a single bond, a methylene group of an optionally N-acylated primary aminomethylene group,and their salts are active as leucotriene antagonists since they eliminate the contractions of smooth muscles brought about by leucotrienes, and are therefore suitable for the treatment of allergic, especially asthmatic, conditions.

    摘要翻译： 式（I）的新型不对称硫醚，其中通式具有以下含义：a为1至7的整数，R 4表示氢或C 1-7 - 烷酰基，R 1表示C 1-3 - 烷基， 可以在末端碳原子上被游离或酰化的羟基，原子数至多为17的卤素原子或甲氧基取代，或表示C1-3-全氟烷基，R2表示任选不饱和的脂肪族基，其具有 5至15个碳原子，A代表乙烯，或者，如果R1代表卤代基，和/或B代表亚苯基或亚乙基，则单键或亚乙烯基，B代表单键，亚乙炔基或亚苯基，R3代表羟基，C1-7 - 烷氧基或任选取代的氨基，-X-表示单键，任选N-酰化的伯氨基亚甲基的亚甲基，并且它们的盐作为白三烯拮抗剂是有活性的，因为它们消除平滑肌的收缩b 由白细胞三烯生成，因此适用于治疗过敏性疾病，特别是哮喘病症。

    Aromatic thioethers
    2.
    发明授权
    Aromatic thioethers 失效
    芳香硫醚

    公开(公告)号：US4785004A

    公开(公告)日：1988-11-15

    申请号：US941676

    申请日：1986-12-15

    申请人： Andreas Von Sprecher ,  Werner Breitenstein ,  Andreas Beck ,  Robert W. Lang ,  Konrad Oertle

    发明人： Andreas Von Sprecher ,  Werner Breitenstein ,  Andreas Beck ,  Robert W. Lang ,  Konrad Oertle

    IPC分类号： C07D215/54 ,  C07D311/24 ,  C07C149/40 ,  A61K31/235

    CPC分类号： C07D311/24 ,  C07D215/54

    摘要： Novel asymmetric thioethers of the formula ##STR1## in which the general symbols have the following meanings: R.sup.0 represents hydrogen or C.sub.1-7 -alkanoyl,R.sup.1 represents C.sub.1-3 -alkyl which may be substituted by one or more halogen atoms having an atomic number of at most 17,R.sup.2 represents an aliphatic radical having from 5 to 15 carbon atoms,A represents ethylene, a single bond or vinylene,B.sup.1 represents C.sub.1-7 -alkylene or phenylene,B.sup.2 represents a single bond, ethylene or phenylene, andM represents an aromatic radical of the partial formula ##STR2## in which the symbols have the following meanings: R.sup.3 represents hydrogen or C.sub.1-4 -alkyl,X represents NH, O, S or if R.sup.4 represents hydrogen, a single bond,one of the symbols R.sup.4 and R.sup.5 represents hydrogen and the other represents the group --CO--R.sup.6, orR.sup.4 and R.sup.5 together represent the radical --CO--C(R.sup.6).dbd.C(R.sup.7)--or--CO--C(R.sup.7).dbd.C(R.sup.6)--orR.sup.4 R.sup.5, together with X, represent the radical --N.dbd.C(R.sup.8)--C(R.sup.6).dbd.CH--,in whichR.sup.6 represents --(CH.sub.2).sub.b --COOR.sup.3 (in which b=0 to 2)R.sup.7 represents hydrogen or C.sub.1-4 -alkyl andR.sup.8 represents hydrogen, methyl, mythoxy or halogen,and their salts are active as leucotriene antagonists since they eliminate the contractions of smooth muscles brought about by leucotrienes, and are therefore suitable for the treatment of allergic, especially asthmatic, conditions.

    摘要翻译： 式（I）的新颖的不对称硫醚，其中通式符号具有以下含义：R 0表示氢或C 1-7 - 烷酰基，R 1表示可以被一个或多个具有 原子数最多为17，R 2表示具有5至15个碳原子的脂族基团，A表示乙烯，单键或亚乙烯基，B1表示C1-7 - 亚烷基或亚苯基，B2表示单键，乙烯或亚苯基 ，M表示部分结构式（M）的芳族基团，其中符号具有以下含义：R 3表示氢或C 1-4 - 烷基，X表示NH，O，S或如果R 4表示氢，则 单键，R4和R5之一表示氢，另一个表示-CO-R6基团，或R4和R5一起代表基团-CO-C（R6）= C（R7）-OR-CO-C（ R7）= C（R6） - 或R4R5与X一起代表基团-N = C（R8）-C（R6）= CH-，其中R6表示 - （CH2）b-COOR3（其中b = 0至2）R7表示氢或C1-4烷基，R8表示氢，甲基，乙氧基或卤素，并且它们的盐作为白三烯拮抗剂是有活性的，因为它们消除了由白三烯引起的平滑肌的收缩，因此适用于 治疗过敏，特别是哮喘，病情。

    3-Fluoropyridyl-2-oxy-phenoxy derivatives having herbicidal activity
    5.
    发明授权
    3-Fluoropyridyl-2-oxy-phenoxy derivatives having herbicidal activity 失效
    具有除草活性的3-氟吡啶基-2-氧 - 苯氧基衍生物

    公开(公告)号：US4832736A

    公开(公告)日：1989-05-23

    申请号：US130487

    申请日：1987-12-09

    申请人： Rolf Schurter ,  Konrad Oertle

    发明人： Rolf Schurter ,  Konrad Oertle

    IPC分类号： A01N53/06 ,  A01N43/40 ,  A01N55/00 ,  A01N57/18 ,  A01N57/24 ,  C07D213/64 ,  C07D213/643 ,  C07F7/08 ,  C07F9/58

    CPC分类号： C07D213/643 ,  A01N43/40 ,  A01N55/00 ,  A01N57/24 ,  C07F7/0812 ,  C07F9/582

    摘要： New 3-fluoropyridyl-2-oxy-phenoxy derivatives are disclosed which have a herbicidal and plant growth inhibiting action. They correspond to the formula ##STR1## wherein X is halogen or trifluoromethyl,G is a C.sub.1 -C.sub.3 -alkylene chain which can be mono- or disubstituted by methyl or phenyl,m is zero or one,R.sup.12 and K.sup.13 are each C.sub.1 -C.sub.6 -alkyl andR.sup.17 is hydrogen, C.sub.1 -C.sub.2 -alkyl or methoxymethyl.These compounds are suitable for the selective control of weeds in crops of cultivated plants, or for the reduction of the growth of grasses.

    摘要翻译： 公开了具有除草和植物生长抑制作用的新的3-氟吡啶基-2-氧基 - 苯氧基衍生物。 它们对应于式（I）其中X是卤素或三氟甲基，G是可被甲基或苯基单或双取代的C1-C3-亚烷基链，m是0或1，R12和 K13各自为C1-C6-烷基，R17为氢，C1-C2-烷基或甲氧基甲基。 这些化合物适合于选择性地控制栽培植物作物中的杂草，或者减少草的生长。

    Phosphorous-containing phenylsulfonamides
    6.
    发明授权
    Phosphorous-containing phenylsulfonamides 失效
    含磷苯基磺酰胺

    公开(公告)号：US4677217A

    公开(公告)日：1987-06-30

    申请号：US784274

    申请日：1985-10-04

    申请人： Ludwig Maier ,  Willy Meyer ,  Konrad Oertle ,  Achim Roloff ,  Werner Topfl

    发明人： Ludwig Maier ,  Willy Meyer ,  Konrad Oertle ,  Achim Roloff ,  Werner Topfl

    IPC分类号： A01N57/16 ,  A01N57/08 ,  A01N57/24 ,  C07D521/00 ,  C07F9/30 ,  C07F9/32 ,  C07F9/38 ,  C07F9/40 ,  C07F9/53 ,  C07F9/6512 ,  C07F9/6521

    CPC分类号： C07D521/00 ,  A01N57/08 ,  C07F9/304 ,  C07F9/3229 ,  C07F9/3808 ,  C07F9/3834 ,  C07F9/4006 ,  C07F9/4015 ,  C07F9/4021 ,  C07F9/4056 ,  C07F9/5325 ,  C07F9/65127 ,  C07F9/65217

    摘要： Phenylsulfonamides of the formula ##STR1## in which X is a group ##STR2## Y is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, trifluoromethyl, C.sub.2 -C.sub.5 -alkenyl, C.sub.2 -C.sub.5 -alkynyl, nitro, --COOR.sup.6 or --Q--R.sup.6, A is oxygen, sulfur, a direct bond, C.sub.1 -C.sub.5 -alkylene, C.sub.2 -C.sub.5 -alkenylene, C.sub.1 -C.sub.5 -halogenoalkylene or --NR.sup.7 --(CH.sub.2).sub.m --; --CH.sub.2 --NH--(CH.sub.2).sub.m ; --(CH.sub.2).sub.m --NR.sup.7 -- or --O--(CH.sub.2).sub.p --, --S--(CH.sub.2).sub.p --, --(CH.sub.2).sub.p --O-- or --(CH.sub.2).sub.p --S--, n is zero or one, G is oxygen or sulfur, R.sup.4 is C.sub.1 -C.sub.5 -alkoxy, C.sub.1 -C.sub.5 -halogenoalkoxy, C.sub.1 -C.sub.5 -alkylthio, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -halogenoalkyl, phenyl or hydroxyl, R.sup.5 is hydrogen, C.sub.1 -C.sub.5 -alkoxy, C.sub.1 -C.sub.5 -halogenoalkoxy, C.sub.1 -C.sub.5 -alkylthio, C.sub.1 -C.sub. 5 -alkyl or hydroxyl, R.sup.6 is hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -halogenoalkyl or C.sub.2 -C.sub.6 -alkoxyalkyl, Q is oxygen, sulfur, --SO-- or --SO.sub.2 --, R.sup.7 is hydrogen, C.sub.1 -C.sub.5 -alkyl, phenyl, benzyl or phenyl which is substituted by C.sub.1 -C.sub.5 -alkyl, halogen, or nitro, m is a number from zero to three, p is a number from zero to two and r is one or two are useful as intermediates for phosphorous-containing N-phenylsulfonyl-N'-pyrimdinylurea and N-phenylsulfonyl-N'-triazinylurea herbicides.

    摘要翻译： 其中X是基团Y的式“IMAGE”的苯磺酰胺是氢，卤素，C 1 -C 5 - 烷基，三氟甲基，C 2 -C 5 - 烯基，C 2 -C 5炔基，硝基，-COOR 6或-Q- R6，A是氧，硫，直接键，C1-C5-亚烷基，C2-C5-亚烯基，C1-C5-卤代亚烷基或-NR7-（CH2）m-; -CH 2 -NH-（CH 2）m; - （CH 2）m -NR 7 - 或-O-（CH 2）p - ， - S-（CH 2）p - ， - （CH 2）p O-或 - （CH 2）p -S-，n为0或1，G为氧 或硫，R4是C1-C5-烷氧基，C1-C5-卤代烷氧基，C1-C5-烷硫基，C1-C5-烷基，C1-C5-卤代烷基，苯基或羟基，R5是氢，C1-C5-烷氧基，C1 -C5-卤代烷氧基，C1-C5-烷硫基，C1-C5-烷基或羟基，R6是氢，C1-C5-烷基，C1-C5-卤代烷基或C2-C6-烷氧基烷基，Q是氧，硫，-SO - 或-SO 2 - ，R 7是氢，C 1 -C 5 - 烷基，苯基，苄基或被C 1 -C 5 - 烷基，卤素或硝基取代的苯基，m是0至3的数，p是 0至2，r是1或2个可用作含磷的N-苯基磺酰基-N'-嘧啶基脲和N-苯基磺酰基-N'-三嗪基脲除草剂的中间体。

    Phenylsulfonyl isocyanates and thioisocyanates
    7.
    发明授权
    Phenylsulfonyl isocyanates and thioisocyanates 失效
    苯磺酰基异氰酸酯和硫代异氰酸酯

    公开(公告)号：US4952726A

    公开(公告)日：1990-08-28

    申请号：US440004

    申请日：1989-11-21

    申请人： Willy Meyer ,  Konrad Oertle

    发明人： Willy Meyer ,  Konrad Oertle

    IPC分类号： C07D249/16 ,  A01N43/70 ,  A01N47/36 ,  C07C20060101 ,  C07C67/00 ,  C07C301/00 ,  C07C309/86 ,  C07C311/15 ,  C07C311/16 ,  C07C311/17 ,  C07C311/29 ,  C07C311/39 ,  C07C311/53 ,  C07C311/65 ,  C07C325/00 ,  C07C331/16 ,  C07C331/32 ,  C07D239/42 ,  C07D239/46 ,  C07D239/47 ,  C07D239/48 ,  C07D239/52 ,  C07D239/56 ,  C07D239/69 ,  C07D251/16 ,  C07D251/18 ,  C07D251/22 ,  C07D251/46 ,  C07D251/52 ,  C07D521/00

    CPC分类号： C07C309/86 ,  A01N47/36 ,  C07C311/65 ,  C07D521/00

    摘要： N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the formula I ##STR1## wherein A is 3,3,3-trifluoropropyl or 3,3-difluorobutyl,R.sup.1 is hydrogen, halogen, nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfonyl, C.sub.1 -C.sub.4 -alkylsulfonyl, --CO--R.sup.6, --NR.sup.7 R.sup.8, --CO--NR.sup.9 R.sup.10 or --SO.sub.2 --NR.sup.11 R.sup.12,R.sup.2 is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkysulfonyl or C.sub.1 -C.sub.4 -alkylsulfonyl,R.sup.3 and R.sup.4 independently of one another are each hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.2 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkylthio, C.sub.2 -C.sub.4 -alkoxyalkyl, C.sub.1 -C.sub.4 -alkoxy or --NR.sup.13 R.sup.13,R.sup.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy,R.sup.6 is C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.2 -C.sub.6 -alkoxyalkoxy, hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -haloalkyl,R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12 and R.sup.13 independently of one another are each hydrogen or C.sub.1 -C.sub.4 -alkyl,E is nitrogen or the methine bridge, andZ is oxygen or sulfur;and also the salts of these compounds.

    摘要翻译： 式I的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲其中A是3,3,3-三氟丙基或3,3-二氟丁基，R 1是氢，卤素，硝基，氰基，C 1 C 1-4烷基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4 - 烷基亚磺酰基，C 1 -C 4烷基磺酰基，-CO-R 6，-NR 7 R 8，-CO-NR 9 R 10或-SO 2 -NR 11 R 12，R 2是氢，卤素，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4烷基亚磺酰基或C 1 -C 4烷基磺酰基，R 3和R 4彼此独立地各自为氢， 卤素，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 2 -C 4卤代烷氧基，C 1 -C 4烷硫基，C 1 -C 4卤代烷硫基，C 2 -C 4烷氧基烷基，C 1 -C 4烷氧基或-NR 12 R 13， ，C 1 -C 4烷基或C 1 -C 4 - 烷氧基，R 6是C 1 -C 4 - 烷氧基，C 1 -C 4卤代烷氧基，C 1 -C 4烷硫基，C 2 -C 6烷氧基烷氧基，氢，C 1 -C 4烷基或C 1 -C 4 卤代烷基，R 7，R 8，R 9，R 10，R 11，R 12和R 13各自独立地为氢或C 1 -C 4烷基，E为氮或次甲基桥，Z为氧或硫; 以及这些化合物的盐。

    Certain fluoroalkylphenylsulfonamides
    8.
    发明授权
    Certain fluoroalkylphenylsulfonamides 失效
    某些氟代烷基苯基磺酰胺

    公开(公告)号：US4908467A

    公开(公告)日：1990-03-13

    申请号：US179339

    申请日：1988-04-08

    申请人： Willy Meyer ,  Konrad Oertle

    发明人： Willy Meyer ,  Konrad Oertle

    IPC分类号： C07D249/16 ,  A01N43/70 ,  A01N47/36 ,  C07C20060101 ,  C07C67/00 ,  C07C301/00 ,  C07C309/86 ,  C07C311/15 ,  C07C311/16 ,  C07C311/17 ,  C07C311/29 ,  C07C311/39 ,  C07C311/53 ,  C07C311/65 ,  C07C325/00 ,  C07C331/16 ,  C07C331/32 ,  C07D239/42 ,  C07D239/46 ,  C07D239/47 ,  C07D239/48 ,  C07D239/52 ,  C07D239/56 ,  C07D239/69 ,  C07D251/16 ,  C07D251/18 ,  C07D251/22 ,  C07D251/46 ,  C07D251/52 ,  C07D521/00

    CPC分类号： C07C309/86 ,  A01N47/36 ,  C07C311/65 ,  C07D521/00

    摘要： N-Phenylsulfonyl-B'-pyrimidinyl- and -triazinylureas of the formula I ##STR1## wherein A is 3,3,3-trifluoropropyl or 3,3-difluorobutyl,R.sup.1 is hydrogen, halogen, nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, --CO--R.sup.6, --NR.sup.7 R.sup.8, --CO--NR.sup.9 R.sup.10 or --SO.sub.2 --NR.sup.11 R.sup.12,R.sup.2 is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl or C.sub.1 -C.sub.4 -alkylsulfonyl,R.sup.3 and R.sup.4 independently of one another are each hydrogen, halogen C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.2 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkylthio, C.sub.2 -C.sub.4 -alkoxyalkyl, C.sub.1 -C.sub.4 -alkoxy or --NR.sup.12 R.sup.13,R.sup.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy,R.sup.6 is C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.2 -C.sub.6 -alkoxyalkoxy, hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -haloalkyl,R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12 and R.sup.13 independently of one another are each hydrogen or C.sub.1 -C.sub.4 -alkyl,E is nitrogen or the methine bridge, andZ is oxygen or sulfur;and also the salts of these compounds.

    摘要翻译： 式I的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲其中A是3,3,3-三氟丙基或3,3-二氟丁基，R 1是氢，卤素，硝基，氰基，C 1 C 1-4烷基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4 - 烷基亚磺酰基，C 1 -C 4烷基磺酰基，-CO-R 6，-NR 7 R 8，-CO-NR 9 R 10或-SO 2 -NR 11 R 12，R 2是氢，卤素，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4烷基亚磺酰基或C 1 -C 4烷基磺酰基，R 3和R 4彼此独立地各自为氢， 卤素，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 2 -C 4卤代烷氧基，C 1 -C 4烷硫基，C 1 -C 4卤代烷硫基，C 2 -C 4烷氧基烷基，C 1 -C 4烷氧基或-NR 12 R 13， ，C 1 -C 4烷基或C 1 -C 4 - 烷氧基，R 6是C 1 -C 4 - 烷氧基，C 1 -C 4卤代烷氧基，C 1 -C 4 - 烷硫基，C 2 -C 6 - 烷氧基烷氧基，氢，C 1 -C 4烷基或C 1 -C 4 卤代烷基，R 7，R 8，R 9，R 10，R 11，R 12和R 13各自独立地为氢或C 1 -C 4烷基，E为氮或次甲基桥，Z为氧或硫; 以及这些化合物的盐。

    N-phenylsulfonyl-N'-triazinylureas
    9.
    发明授权
    N-phenylsulfonyl-N'-triazinylureas 失效
    N-苯基磺酰基-N'-三嗪基脲

    公开(公告)号：US4780125A

    公开(公告)日：1988-10-25

    申请号：US525366

    申请日：1983-08-22

    申请人： Willy Meyer ,  Dieter Reinehr ,  Konrad Oertle ,  Rolf Schurter

    发明人： Willy Meyer ,  Dieter Reinehr ,  Konrad Oertle ,  Rolf Schurter

    IPC分类号： B01J31/24 ,  A01N47/36 ,  A01P13/00 ,  C07B61/00 ,  C07C303/22 ,  C07C309/29 ,  C07C309/30 ,  C07C309/44 ,  C07C309/86 ,  C07C309/87 ,  C07C311/15 ,  C07C311/16 ,  C07C311/29 ,  C07C311/53 ,  C07C311/54 ,  C07C311/58 ,  C07C311/65 ,  C07C317/10 ,  C07D239/42 ,  C07D239/46 ,  C07D239/47 ,  C07D239/52 ,  C07D239/69 ,  C07D251/16 ,  C07D251/42 ,  C07D251/46 ,  C07D251/52 ,  C07D521/00 ,  A01N43/66

    CPC分类号： C07C311/65 ,  A01N47/36 ,  C07C309/00 ,  C07D239/47 ,  C07D521/00

    摘要： The invention relates to N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N-triazinylureas of the general formula ##STR1## wherein R.sub.1 is hydrogen, halogen, nitro, amino, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.4 haloalkyl or a --Q--R.sub.7, --CO--OR.sub.8 or --(CO).sub.n --NR.sub.9 R.sub.10 radical,R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, halogen or alkoxyalkyl containing not more than 4 carbon atoms,R.sub.3 is C.sub.2 -C.sub.10 alkenyl which is substituted by one or more fluorine or bromine atoms or by one or more hydroxyl, cyano, nitro, --(Y).sub.m --CO--(Z).sub.n --R.sub.8, --SO.sub.2 --NR.sub.11 R.sub.12, --S(O).sub.p --C.sub.1 --C.sub.3 haloalkyl or --S(O).sub.n --C.sub.1 -C.sub.3 alkyl groups and which may additionally be substituted by one or more chlorine atoms,R.sub.4 is C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkoxy, R.sub.5 is hydrogen, halogen, --NR.sub.13 R.sub.14, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.2 haloalkoxy,R.sub.6 is hydrogen, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy,X is oxygen or sulfur, andE is nitrogen or the methine group, andR.sub.7 is C.sub.1 -C.sub.4 alkyl which is substituted by halogen or C.sub.1 -C.sub.3 alkoxy or is C.sub.3 -C.sub.5 alkenyl,R.sub.8 is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl or C.sub.2 -C.sub.6 alkoxyalkyl,R.sub.9, R.sub.10, R.sub.11, R.sub.12, R.sub.13 and R.sub.14, each independently of the other, are hydrogen or C.sub.1 -C.sub.3 alkyl,Q is oxygen, sulfur, the sulfinyl or sulfonyl bridge,Y is oxygen, sulfur or --NR.sub.16 --, wherein R.sub.16 is hydrogen or C.sub.1 -C.sub.3 alkyl,Z is oxygen, sulfur or --NR.sub.17 --, wherein R.sub.17 is hydrogen or C.sub.1 -C.sub.3 alkyl,m and n are each 0 to 1, andp is 0, 1 or 2, and to the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases.These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.

    摘要翻译： 本发明涉及通式为（I）的N-苯基磺酰基-N'-嘧啶基脲和N-苯基磺酰基-N-三嗪基脲，其中R 1是氢，卤素，硝基，氨基，C 1 -C 5烷基，C 1 -C 4卤代烷基或 -Q-R7，-CO-OR8或 - （CO）n-NR9R10基，R2是氢，C1-C4烷基，C1-C4烷氧基，C1-C4烷硫基，C1-C4卤代烷基，C1-C4卤代烷氧基，卤素或不大于 4个碳原子，R 3是被一个或多个氟或溴原子或一个或多个羟基，氰基，硝基， - （Y）m -CO-（Z）n -R 8，-SO 2 -NR 11 R 12取代的C 2 -C 10链烯基 ，-S（O）p-C 1 -C 3卤代烷基或-S（O）n -C 1 -C 3烷基，并且其可以另外被一个或多个氯原子取代，R 4是C 1 -C 3烷基，C 1 -C 3卤代烷基，C 1 -C 3烷氧基或 C1-C3卤代烷氧基，R5是氢，卤素，-NR13R14，C1-C3烷基，C1-C3卤代烷基，C1-C3烷氧基或C1-C2卤代烷氧基，R6是氢，C1-C3烷基或C1-C3烷氧基，X是氧或硫，E是 氮或次甲基，并且R 7为被所取代的C 1 -C 4烷基 卤素或C 1 -C 3烷氧基或C 3 -C 5链烯基，R 8为C 1 -C 4烷基，C 1 -C 4卤代烷基或C 2 -C 6烷氧基烷基，R 9，R 10，R 11，R 12，R 13和R 14各自独立地为氢或C 1 -C 3烷基， Q是氧，硫，亚磺酰基或磺酰基桥，Y是氧，硫或-NR 16 - ，其中R 16是氢或C 1 -C 3烷基，Z是氧，硫或-NR 17 - ，其中R 17是氢或C 1 -C 3烷基， m和n各自为0至1，p为0,1或2，以及这些化合物与胺，碱金属碱或碱土金属碱的盐。 这些化合物具有良好的芽前和芽后选择性除草和生长调节性质。

    Silanes, process for their preparation, and their use
    10.
    发明授权
    Silanes, process for their preparation, and their use 失效
    硅烷，其制备过程及其用途

    公开(公告)号：US4695643A

    公开(公告)日：1987-09-22

    申请号：US782349

    申请日：1985-10-01

    申请人： Konrad Oertle ,  Hansjurg Wetter

    发明人： Konrad Oertle ,  Hansjurg Wetter

    IPC分类号： C07B51/00 ,  C07B31/00 ,  C07C67/00 ,  C07F7/02 ,  C07F7/08 ,  C07F7/10 ,  C07F7/12 ,  C07F7/18

    CPC分类号： C07F7/1896 ,  C07F7/0834 ,  C07F7/0898 ,  C07F7/10 ,  C07F7/12 ,  C07F7/188 ,  Y02P20/55

    摘要： Compounds of the formula Ia ##STR1## in which X and R.sup.1 to R.sup.6 are as defined in the claims, are obtainable by reacting monochlorosilanes of the formula II ##STR2## with tetrasubstituted ethylenes of the formula III ##STR3## X as Cl and Br can be replaced by ester groups of inorganic and organic acids. The compounds of the formula I and those with other ester groups are suitable especially as a protective-group reagent for hydroxyl, mercapto, carboxyl, amino and amide groups.

    摘要翻译： 其中X和R 1至R 6如权利要求中所定义的式Ia（Ia）化合物可通过使式II（II）的一氯代硅烷与式III的四取代乙烯反应获得。 （III）X为Cl和Br可以被无机酸和有机酸的酯基代替。 式I化合物和其它酯基的化合物特别适用作羟基，巯基，羧基，氨基和酰胺基团的保护基试剂。