摘要:
The invention relates to a new process which allows the preparation of TS-1 zeolites in a pure phase and with a crystallinity higher than 95%, operating at reduced reaction volumes, and obtaining high productivities and extremely high crystallization yields. The particular crystalline form of the TS-1 zeolite thus prepared, is also described.
摘要:
The invention relates to a new process which allows the preparation of TS-1 zeolites in a pure phase and with a crystallinity higher than 95%, operating at reduced reaction volumes, and obtaining high productivities and extremely high crystallization yields. The particular crystalline form of the TS-1 zeolite thus prepared, is also described.
摘要:
The present invention relates to a new zeolite having a beta-type crystalline structure, characterized by a distribution of the Lewis acid sites and Brønsted acid sites corresponding to a molar ratio [Lewis sites] [Brønsted sites] equal to or higher than 1.5. This new zeolite is useful in preparation processes of alkylated aromatic hydrocarbons through the alkylation and/or transalkylation of aromatic compounds. The preparation method of the new zeolite is also object of the present invention.
摘要:
The present invention relates to a new zeolite having a beta-type crystalline structure, characterized by a distribution of the Lewis acid sites and Brønsted acid sites corresponding to a molar ratio [Lewis sites] [Brønsted sites] equal to or higher than 1.5. This new zeolite is useful in preparation processes of alkylated aromatic hydrocarbons through the alkylation and/or transalkylation of aromatic compounds. The preparation method of the new zeolite is also object of the present invention.
摘要:
The object of the present invention relates to a simple, rapid and inexpensive process for effecting solid-liquid separations in the case of zeolites, also having small crystals. This process, which is particularly useful for the recovery of zeolite crystals in suspension in the crystallization water, comprises treating this suspension of crystals with an acid or one of its precursors and subjecting the resulting mixture to filtration or decanting.According to a particular aspect of the invention, the crystalline phase is separated in a mixture with oxides which can be used as ligands. Said oxides can be generated by the reagents of the zeolite preparation reagent mixture, not transformed into crystalline phase during the synthesis hydrothermal treatment, or they can be added to the suspension of crystals before the separation treatment, or again they can be generated by precursors suitably added to the crystallization slurry.
摘要:
The invention relates to a multi-step chemical transformation process for the production of 2,6-dimethylnaphthalene starting from one or more naphthalene hydrocarbons or hydrocarbon blends containing the same, one or more benzene hydrocarbons and, optionally, a methylating agent reacted in the presence of a catalyst containing a zeolite belonging to the MTW structural group, where hydrogen is fed in at least one of the steps.
摘要:
The invention relates to a multi-step chemical transformation process for the production of 2,6-dimethylnaphthalene starting from one or more naphthalene hydrocarbons or hydrocarbon blends containing the same, one or more benzene hydrocarbons and, optionally, a methylating agent reacted in the presence of a catalyst containing a zeolite belonging to the MTW structural group, where hydrogen is fed in at least one of the steps.
摘要:
Process for preparing alkylated aromatic compounds which comprises reacting an aromatic compound with a ketone and hydrogen in the presence of a catalytic composition comprising a solid acid material and copper. A preferred aspect is to use a catalytic composition also containing one or more elements selected from elements of groups IIIA, IVA, IIIB, IVB, VB, VIB, VIIB, group VIII limited to Fe, Ru and Os, and of the series of lanthanides. A particularly preferred aspect is to use a catalytic composition containing one or more elements selected from elements of groups IIIA and VIB.
摘要:
Process for preparing alkylated aromatic compounds which comprises reacting an aromatic compound with a ketone and hydrogen in the presence of a catalytic composition comprising a solid acid material and copper. A preferred aspect is to use a catalytic composition also containing one or more elements selected from elements of groups IIIA, IVA, IIIB, IVB, VB, VIB, VIIB, group VIII limited to Fe, Ru and Os, and of the series of lanthanides. A particularly preferred aspect is to use a catalytic composition containing one or more elements selected from elements of groups IIIA and VIB.
摘要:
A catalytic composition for transalkylation of aromatic hydrocarbons which contains a zeolite and an inorganic binder and has an extra-zeolitic porosity higher than or equal to 0.7 cc/g for a fraction of pores of which at least 30% have a diameter greater than 100 nanometers. A catalytic composition having a crushing strength not lower than 1.7 kg/mm and an apparent density not higher than 0.5 g/cc. A process for transalkylating polyalkylated aromatic hydrocarbons using a catalytic composition.