-
公开(公告)号:US20230377879A1
公开(公告)日:2023-11-23
申请号:US17747978
申请日:2022-05-18
Applicant: Applied Materials, Inc.
Inventor: Srinivas Gandikota , Elizabeth Mao , Tianyi Huang , Tengzhou Ma , Chi-Chou Lin , Yixiong Yang
IPC: H01L21/02
CPC classification number: H01L21/02362 , H01L21/02153 , H01L21/02181
Abstract: Embodiments of the present disclosure are related to methods of preventing aluminum diffusion in a metal gate stack (e.g., high-κ metal gate (HKMG) stacks and nMOS FET metal gate stacks). Some embodiments relate to a barrier layer for preventing aluminum diffusion into high-κ metal oxide layers. The barrier layer described herein is configured to reduce threshold voltage (Vt) shift and reduce leakage in the metal gate stacks. Additional embodiments relate to methods of forming a metal gate stack having the barrier layer described herein. The barrier layer may include one or more of amorphous silicon (a-Si), titanium silicon nitride (TiSiN), tantalum nitride (TaN), or titanium tantalum nitride (TiTaN).
-
公开(公告)号:US20210384035A1
公开(公告)日:2021-12-09
申请号:US17225667
申请日:2021-04-08
Applicant: Applied Materials, Inc.
Inventor: Ilanit Fisher , Shih Chung Chen , Kedi Wu , Ashley Lin , Chi-Chou Lin , Yi Xu , Yu Lei , Mandyam Sriram , Wen Ting Chen , Srinivas Gandikota , Chenfei Shen , Naomi Yoshida , He Ren
IPC: H01L21/285 , H01L21/02 , C23C16/14 , C23C16/02
Abstract: Methods of forming metallic tungsten films selectively on a conductive surface relative to a dielectric surface are described. A substrate is exposed to a first process condition to deposit a fluorine-free metallic tungsten film. The fluorine-free metallic tungsten film is exposed to a second process condition to deposit a tungsten film on the fluorine-free metallic tungsten film.
-
公开(公告)号:US10665450B2
公开(公告)日:2020-05-26
申请号:US16104352
申请日:2018-08-17
Applicant: APPLIED MATERIALS, INC.
Inventor: Yixiong Yang , Paul F. Ma , Wei V. Tang , Wenyu Zhang , Shih Chung Chen , Chen Han Lin , Chi-Chou Lin , Yi Xu , Yu Lei , Naomi Yoshida , Lin Dong , Siddarth Krishnan
Abstract: Methods and apparatus for forming a semiconductor structure, including depositing a doping stack having a first surface atop a high-k dielectric layer, wherein the doping stack includes at least one first metal layer having a first surface, at least one second metal layer comprising a first aluminum dopant and a first surface, wherein the second metal layer is atop the first surface of the first metal layer, and at least one third metal layer atop the first surface of the second metal layer; depositing an anneal layer atop the first surface of the doping stack; annealing the structure to diffuse at least the first aluminum dopant into the high-k dielectric layer; removing the anneal layer; and depositing at least one work function layer atop the first surface of the doping stack.
-
公开(公告)号:US20240332008A1
公开(公告)日:2024-10-03
申请号:US18126583
申请日:2023-03-27
Applicant: Applied Materials, Inc.
Inventor: Geetika Bajaj , Tianyi Huang , Hsin-Jung Yu , Yixiong Yang , Srinivas Gandikota , Chi-Chou Lin , Pei Hsuan Lin
CPC classification number: H01L21/02321 , H01L21/02178 , H01L21/02181 , H01L21/02189 , H01L21/02194 , H01L21/28229
Abstract: Methods of manufacturing and processing semiconductor devices (i.e., electronic devices) are described. Embodiments of the disclosure advantageously provide electronic devices which meet reduced thickness, lower thermal budget, and Vt requirements, and have improved device performance and reliability. The electronic devices described herein comprise a source region, a drain region, and a channel separating the source region and the drain region, an interfacial layer on a top surface of the channel, a high-κ dielectric layer on the interfacial layer, a dipole layer on the high-κ dielectric layer, and a capping layer on the dipole layer. In some embodiments, the dipole layer comprises a metal oxynitride (MON), such as aluminum oxynitride (AlON). In some embodiments, the methods comprise annealing the substrate to drive atoms from the dipole layer into one or more of the interfacial layer or the high-κ dielectric layer.
-
公开(公告)号:US20240183033A1
公开(公告)日:2024-06-06
申请号:US18074197
申请日:2022-12-02
Applicant: Applied Materials, Inc.
Inventor: Tianyi Huang , Srinivas Gandikota , Yixiong Yang , Elizabeth Mao , Chi-Chou Lin
IPC: C23C16/455 , C23C16/34 , H01L21/3205 , H01L21/768
CPC classification number: C23C16/45527 , C23C16/34 , H01L21/32051 , H01L21/76843
Abstract: Embodiments of the present disclosure advantageously provide improved control over precursor/reactant pulse/purge time, greater growth per cycle, and higher throughput during formation of a metal-containing film on a substrate surface (including substrate surfaces having at least one feature) compared to traditional atomic layer deposition (ALD) processes. In some embodiments, forming the metal-containing film comprises exposing a substrate to a constant flow of an inert carrier gas and a co-flow of a pulse of a metal-containing precursor and a pulse of a reactant. The pulse of the metal-containing precursor and the pulse of the reactant may be interrupted by a mini purge. The metal-containing precursor and/or the reactant may be charged during the mini purge to avoid precursor/reactant depletion.
-
公开(公告)号:US20220098731A1
公开(公告)日:2022-03-31
申请号:US17036209
申请日:2020-09-29
Applicant: Applied Materials, Inc.
Inventor: Kedi Wu , Chenfei Shen , Chi-Chou Lin , Ilanit Fisher , Shih Chung Chen , Mandyam Sriram , Srinivas Gandikota
IPC: C23C16/455 , C23C16/34 , C23C16/06
Abstract: Methods of forming electronic devices comprising tungsten film stacks are provided. Methods include forming a tungsten nucleation layer on the barrier layer using an atomic layer deposition (ALD) process including a tungsten precursor that is free of fluorine. Forming the nucleation layer comprises controlling process parameters and/or forming WSi pre-nucleation layer.
-
公开(公告)号:US20210384036A1
公开(公告)日:2021-12-09
申请号:US17339454
申请日:2021-06-04
Applicant: Applied Materials, Inc.
Inventor: Ilanit Fisher , Chi-Chou Lin , Kedi Wu , Wen Ting Chen , Shih Chung Chen , Srinivas Gandikota , Mandyam Sriram , Chenfei Shen , Naomi Yoshida , He Ren
IPC: H01L21/285 , C23C16/455 , C23C16/14 , C23C16/04
Abstract: Methods of forming metallic tungsten films selectively on a conductive surface relative to a dielectric surface are described. A substrate is exposed to a first process condition to deposit a tungsten-containing film that is substrate free of tungsten metal. The tungsten-containing film is then converted to a metallic tungsten film by exposure to a second process condition.
-
公开(公告)号:US11018009B2
公开(公告)日:2021-05-25
申请号:US16381776
申请日:2019-04-11
Applicant: APPLIED MATERIALS, INC.
Inventor: Guoqiang Jian , Wei Tang , Chi-Chou Lin , Paul Ma , Yixiong Yang , Mei Chang , Wenyi Liu
IPC: H01L21/28 , H01L21/285 , H01L29/49 , H01L21/02 , H01L21/324 , H01L29/78 , H01L21/67 , H01L29/66
Abstract: The present disclosure relates to a method for forming a p-metal work function nitride film having a desired p-work function on a substrate, including: adjusting one or more of a temperature of a substrate, a duration of one or more temporally separated vapor phase pulses, a ratio of a tungsten precursor to a titanium precursor, or a pressure of a reaction to tune a work function of a p-metal work function nitride film to a desired p-work function, and contacting the substrate with temporally separated vapor phase pulses of the tungsten precursor, the titanium precursor, and a reactive gas to form a p-metal work function nitride film thereon having the desired p-work function.
-
公开(公告)号:US11355391B2
公开(公告)日:2022-06-07
申请号:US16803842
申请日:2020-02-27
Applicant: Applied Materials, Inc.
Inventor: Xi Cen , Feiyue Ma , Kai Wu , Yu Lei , Kazuya Daito , Yi Xu , Vikash Banthia , Mei Chang , He Ren , Raymond Hoiman Hung , Yakuan Yao , Avgerinos V. Gelatos , David T. Or , Jing Zhou , Guoqiang Jian , Chi-Chou Lin , Yiming Lai , Jia Ye , Jenn-Yue Wang
IPC: H01L21/768 , H01L21/02 , H01L21/3213
Abstract: The present disclosure generally relates to methods for processing of substrates, and more particularly relates to methods for forming a metal gapfill. In one implementation, the method includes forming a metal gapfill in an opening using a multi-step process. The multi-step process includes forming a first portion of the metal gapfill, performing a sputter process to form one or more layers on one or more side walls, and growing a second portion of the metal gapfill to fill the opening with the metal gapfill. The metal gapfill formed by the multi-step process is seamless, and the one or more layers formed on the one or more side walls seal any gaps or defects between the metal gapfill and the side walls. As a result, fluids utilized in subsequent processes do not diffuse through the metal gapfill.
-
公开(公告)号:US20210134972A1
公开(公告)日:2021-05-06
申请号:US17089047
申请日:2020-11-04
Applicant: Applied Materials, Inc.
Inventor: Yixiong Yang , Jacqueline S. Wrench , Srinivas Gandikota , Yongjing Lin , Steven C.H. Hung , Shih Chung Chen , Haoyan Sha , Chi-Chou Lin
Abstract: Metal gate stacks and integrated methods of forming metal gate stacks are disclosed. Some embodiment comprise MoN as a PMOS work function material. Some embodiments comprise TiSiN as a high-κ capping layer. Some embodiments provide improved PMOS bandedge performance. Some embodiments provide improved PMOS bandedge performance with reduced EOT penalty.
-
-
-
-
-
-
-
-
-