Melamine-polyethers as dispersants in non-aqueous, liquid pigment compositions

    公开(公告)号:US11242467B2

    公开(公告)日:2022-02-08

    申请号:US16071120

    申请日:2017-01-20

    申请人: BASF SE

    摘要: The present invention relates to novel mono- or polynuclear melamine compounds and their use as dispersants for pigments and fillers in coating compositions, in particular in solvent-borne coating compositions. The mono- or polynuclear melamine compounds of the invention have at least one 2,4,6-triamino-1,3,5-triazine ring, wherein at least one amino groups of at least one of the 2,4,6-triamino-1,3,5-triazine rings of the mono- or polynuclear melamine compounds is of the formula A:NR1R2 (A) where R1 is H, CH(R3)OR4 or R2, R2 is CH(R3)O(A-O)x—R5, where R3 is H, C1-C10-alkyl or aryl; R4 is H, C1-C4-alkyl or C1-C4-alkoxy-C1-C4-alkyl; R5 is a hydrocarbon radical having from 1 to 40 carbon atoms; x is an integer from 2 to 500, having on average a value in the range from 2.5 to 400; A is an C2-C4-alkan-1,2-diyl radical.

    Polymer dispersants
    8.
    发明授权
    Polymer dispersants 有权
    聚合物分散剂

    公开(公告)号:US09404009B2

    公开(公告)日:2016-08-02

    申请号:US14380557

    申请日:2013-02-22

    申请人: BASF SE

    摘要: The present invention relates to novel polymer dispersants and to a liquid compositions containing solid fine particles, such as organic or inorganic pigments and fillers, and the polymer dispersants. The polymer dispersants have at least one functional moiety of the formula I, which is bound to one of the termini or to the backbone of the polymer: (I) where # indicates the point of attachment to the terminus and/or to the polymer backbone; k is 0, 1, 2, 3 or 4, m is 0, 1, 2, 3, 4, 5, 6, 7, 8 or 9, A is a chemical bond or a divalent moiety selected from the group consisting of C1-C6 alkylene, —O—(C2-C6 alkylene), —C(═O—O—(C2-C6 alkylene), —NR3—(C2-C6 alkylene) and C(═O)—NR3—(C2-C6 alkylene), where the C2-C6 alkylene part is attached to Q; Q is a divalent moiety selected from the group consisting of —O—, —NH— and —S—; R1 is independently selected from the group consisting of —OH, —COOH, —COOCH3, —NH2, —NH(C1-C6 alkyl), —N(C1-C6 alkyl)2, —NO2, —S(═O)2R4, C1-C20 alkyl, C1-C4 alkoxy, halogen, aryloxy, aryl, heteroaryl; R2 is selected from the group consisting of hydrogen, —S(═O)2R4, C1-C20 alkyl, C3-C10 cycloalkyl, aryl, heteroaryl, aryl-C1-C4-alkyl and heteroaryl-C1-C4-alkyl; R3 is selected from the group consisting of hydrogen, —S(═O)2R4, C1-C20 alkyl, C3-C10 cycloalkyl, aryl and heteroaryl; R4 is selected from the group consisting of OH, —NH2, —NH(C1-C6 alkyl), —N(C1-C6 alkyl)2, C1-C4 alkyl, C1-C4 alkoxy, aryl and heteroaryl.

    摘要翻译: 本发明涉及新型聚合物分散剂和含有固体微粒例如有机或无机颜料和填料以及聚合物分散剂的液体组合物。 聚合物分散剂具有至少一个式I的功能部分,其结合到聚合物的末端或主链之一:(I)其中#表示与末端和/或与聚合物骨架的连接点 ; k为0,1,2,3或4,m为0,1,2,3,4,5,6,7,8或9,A为化学键或选自C1 -C(C 2 -C 6亚烷基),-C(= O-O-(C 2 -C 6亚烷基),-NR 3 - (C 2 -C 6亚烷基)和C(= O) C6亚烷基),其中C2-C6亚烷基部分连接到Q; Q是选自-O - , - NH-和-S-的二价部分; R 1独立地选自-OH ,-COOH,-COOCH 3,-NH 2,-NH(C 1 -C 6烷基),-N(C 1 -C 6烷基)2,-NO 2,-S(= O)2 R 4,C 1 -C 20烷基,C 1 -C 4烷氧基, 卤素,芳氧基,芳基,杂芳基; R 2选自氢,-S(= O)2 R 4,C 1 -C 20烷基,C 3 -C 10环烷基,芳基,杂芳基,芳基-C 1 -C 4烷基和杂芳基 - C 1 -C 4烷基; R 3选自氢,-S(= O)2 R 4,C 1 -C 20烷基,C 3 -C 10环烷基,芳基和杂芳基; R 4选自OH,-NH 2 ,-NH(C 1 -C 6烷基) ,-N(C 1 -C 6烷基)2,C 1 -C 4烷基,C 1 -C 4烷氧基,芳基和杂芳基。

    Block copolymers having a polydimethylsiloxane block

    公开(公告)号:US10301434B2

    公开(公告)日:2019-05-28

    申请号:US14759821

    申请日:2014-01-17

    申请人: BASF SE

    摘要: The present invention relates to novel block copolymers of general formula (I). The invention further relates to a method for producing such block copolymers and to the use of such block copolymers, particularly as additives in liquid coating-agent compositions. A{X—[O—C(O)NH—Y—NH—C(O)—O-M-B]k}n (I). In formula (I), the variables have the following meanings: n is a number in the range from 1 to 40 or 2 to 40, particularly 1 to 10 or 2 to 10 and especially 2 to 5; k is 1 or 2; A is a poly(dimethylsiloxane) block; B is a polymer block constructed of ethylenically unsaturated monomers, which optionally comprises a terminal group different from hydrogen; X is a bivalent or trivalent group having 2 to 20 C atoms, which is saturated or unsaturated and which optionally bears 1, 2, 3, or 4 substituents selected from among OH, COOH, CONH2, C1-C4 alkoxy, C1-C4 alkoxycarbonyl, and halogen; Y is a bivalent hydrocarbon group having 2 to 20 C atoms, which is saturated or unsaturated, and M is a chemical bond or C2-C10 alkylene, which can be interrupted by one or two groups not directly adjacent, selected from among O, C(═O)O, and (C═O)NH and which optionally bears 1, 2, 3, or 4 substituents selected from among OH, COOH, CONH2, C1-C4 alkoxy, C1-C4 alkoxycarbonyl, and phenyl.