公开(公告)号：US11845836B2

公开(公告)日：2023-12-19

申请号：US17276724

申请日：2019-09-30

申请人： BOREALIS AG

发明人： Jari-Jussi Ruskeeniemi ,  Jeroen Oderkerk ,  Oscar Prieto ,  Stefan Hellström ,  Tanja Piel ,  Daniela Mileva ,  Floran Prades

IPC分类号： C08G77/442 ,  C08J3/24

CPC分类号： C08G77/442 ,  C08J3/24 ,  C08J2383/10

摘要： Articles comprising a polymer composition, wherein the polymer composition is obtainable by grafting an ethylene copolymer with comonomer units comprising hydrolysable silane groups, wherein the polymer composition shows high gel content and low compression set at −25° C. These articles have applications in automotive weather-stripping, such as sealing systems for doors, trunks and hoods.

公开(公告)号：US20200308324A1

公开(公告)日：2020-10-01

申请号：US16644537

申请日：2018-10-11

申请人： Borealis AG

发明人： Jeroen Oderkerk ,  Jari-Jussi Ruskeeniemi ,  Oscar Prieto ,  Stefan Hellström ,  Tanja Piel ,  Daniela Mileva

IPC分类号： C08F210/02 ,  C08F220/14 ,  C08F4/16 ,  E04D1/20 ,  A43B13/04

摘要： The present invention provides a polyolefin composition, said composition comprising a terpolymer comprising a cross-linkable polyolefin comprising hydrolysable silane groups and a polar comonomer, the polyolefin composition further comprising a cross-linking catalyst and a silicon containing compound. The polar comonomer Is present in an amount of 5-35 wt %.

公开(公告)号：US20230130603A1

公开(公告)日：2023-04-27

申请号：US17914675

申请日：2021-03-08

申请人： BOREALIS AG

发明人： Stefan Hellström ,  Francis Costa ,  Bert Broeders ,  Jeroen Oderkerk

IPC分类号： C09D123/08 ,  C08F210/02 ,  C08K5/3492 ,  C09D7/63 ,  H01L31/048 ,  H01L31/049

摘要： The present invention relates a photovoltaic module comprising a protective front layer element, an encapsulation layer element, a photovoltaic cell element and a protective back layer element, whereby at least one of the protective elements comprises glass; wherein the encapsulation layer element comprises a polymer composition (I) comprising at least the following components: (A) 97.00 to 99.99 wt.-% based on the overall weight of the polymer composition (I) of a polymer selected from an ethylene-vinylacetate copolymer, a polyolefin elastomer or a polymer of ethylene (a) selected from (a1) a copolymer of ethylene which bears functional groups containing units; (a2) a copolymer of ethylene comprising one or more polar comonomer unit(s) selected from (C1-C6)-alkyl acrylate or (C1-C6)-alkyl (C1-C6)-alkyl acrylate comonomer units, and optionally bears functional groups containing units different from said polar comonomer unit(s); (a3) a copolymer of ethylene comprising one or more alpha-olefin comonomer unit(s); and optionally bears functional groups containing units different from said polar comonomer unit(s) of polymer (a2); or mixtures thereof; and (b) silane group(s) containing units; (B) 0.01 to 3.00 wt.-% based on the overall weight of the polymer composition (I) of a compound according to Formula (I); wherein; R1, R1′, R2 and R2′ are each independently selected from the group consisting of hydrogen, n-alkyl, iso-alkyl, alkoxy, cycloalkyl, alkenyl, halogen and mixtures thereof; X is selected from the group consisting of primary amines, secondary amines, tertiary amines, hydrogen, alkyl, alkenyl and mixtures thereof. Furthermore, the present invention refers to the use of an encapsulation layer element comprising polymer composition (I) according to the invention for increasing the Pmax determined after 96 h according to IEC 60904, by applying the foil method with a temperature of 85° C. and relative humidity of 60% and a potential difference of 1500 V, of a photovoltaic module comprising besides the encapsulation layer element a protective front layer element, a photovoltaic cell element and a protective back element, whereby at least one of the protective elements comprises glass.

公开(公告)号：US20210363319A1

公开(公告)日：2021-11-25

申请号：US17286670

申请日：2019-11-05

申请人： BOREALIS AG

发明人： Tanja Piel ,  Antti Tynys ,  Stefan Hellström ,  Jeroen Oderkerk ,  Oscar Prieto ,  Jari-Jussi Ruskeeniemi ,  Daniela Mileva ,  Johan Defoer

IPC分类号： C08J9/12 ,  C08L23/08 ,  C08J9/00 ,  C08K3/34 ,  C08K5/42

摘要： The present invention is directed to a foamable polyolefin composition which is crosslinkable by silane groups, to a crosslinked foam obtained from such a foamable polyolefin composition, and to a process for producing a crosslinked foam based on the foamable polyolefin composition. The foamable polyolefin composition comprises a polyethylene bearing hydrolysable silane groups and comonomer units comprising a polar group selected from the group consisting of acrylic acid, methacrylic acid, acrylates, methacrylates, vinyl esters, and mixtures thereof, a silanol condensation catalyst, a physical blowing agent, and a cell nucleating agent.

公开(公告)号：US20220325067A1

公开(公告)日：2022-10-13

申请号：US17634690

申请日：2020-08-12

申请人： Borealis AG

发明人： Stefan Hellström ,  Tina Gschneidtner ,  Susanne Nilsson ,  Bernt-Åke Sultan ,  Emma Hermansson

IPC分类号： C08K5/098 ,  C08K5/132 ,  C08K5/3492

摘要： The present invention relates to a polyolefin composition comprising a cross-linkable polyolefin with hydrolysable silane groups, an acidic silanol condensation catalyst, wherein the acidic silanol condensation catalyst is present in an amount of 0.0001 to 3 wt. % of the polyolefin composition, at least one UV stabilizer selected from the group consisting of phenols, benzophenones and/or combinations thereof, wherein component (C) is present in an amount of 0.0001 to 0.35 wt. % of the polyolefin composition, and/or at least one UV stabilizer selected from triazines, wherein component (D) is present in an amount of 0.0001 to 2.0 wt. % of the polyolefin composition. The present invention also relates to an article comprising such a composition, and to the use of such a composition for the production of an article.

公开(公告)号：US11299617B2

公开(公告)日：2022-04-12

申请号：US17276322

申请日：2019-09-26

申请人： BOREALIS AG

发明人： Oscar Prieto ,  Jeroen Oderkerk ,  Jari-Jussi Ruskeeniemi ,  Stefan Hellström ,  Tanja Piel ,  Daniela Mileva

IPC分类号： C08L51/06 ,  C08L23/08 ,  C08J3/24

摘要： The present invention relates to silane crosslinking catalyst comprising: —75 to 85 wt.-% of an olefin acrylate interpolymer and—15 to 25 wt.-% of a hindered amine light stabilizer (HALS) having a number average molecular weight Mn of 1500 to 4000 g/mol; and—optionally up to 5 wt.-% wax, wherein the silane crosslinking catalyst is free of tin, carboxylic acid(s) and sulphonic acid(s), all weight percentages with respect to the total weight of the silane crosslinking catalyst.

公开(公告)号：US12071558B2

公开(公告)日：2024-08-27

申请号：US17914675

申请日：2021-03-08

申请人： BOREALIS AG

发明人： Stefan Hellström ,  Francis Costa ,  Bert Broeders ,  Jeroen Oderkerk

IPC分类号： C09D123/08 ,  C08F210/02 ,  C08K5/3492 ,  C09D7/63 ,  H01L31/048 ,  H01L31/049

CPC分类号： C09D123/0892 ,  C08F210/02 ,  C08K5/34926 ,  C09D7/63 ,  H01L31/0481 ,  H01L31/049 ,  C08F2800/10 ,  C08F2800/20

摘要： The present invention relates a photovoltaic module comprising a protective front layer element, an encapsulation layer element, a photovoltaic cell element and a protective back layer element, whereby at least one of the protective elements comprises glass; wherein the encapsulation layer element comprises a polymer composition (I) comprising at least the following components: (A) 97.00 to 99.99 wt.-% based on the overall weight of the polymer composition (I) of a polymer selected from an ethylene-vinylacetate copolymer, a polyolefin elastomer or a polymer of ethylene (a) selected from (a1) a copolymer of ethylene which bears functional groups containing units; (a2) a copolymer of ethylene comprising one or more polar comonomer unit(s) selected from (C1-C6)-alkyl acrylate or (C1-C6)-alkyl (C1-C6)-alkyl acrylate comonomer units, and optionally bears functional groups containing units different from said polar comonomer unit(s); (a3) a copolymer of ethylene comprising one or more alpha-olefin comonomer unit(s); and optionally bears functional groups containing units different from said polar comonomer unit(s) of polymer (a2); or mixtures thereof; and (b) silane group(s) containing units; (B) 0.01 to 3.00 wt.-% based on the overall weight of the polymer composition (I) of a compound according to Formula (I); wherein; R1, R1′, R2 and R2′ are each independently selected from the group consisting of hydrogen, n-alkyl, iso-alkyl, alkoxy, cycloalkyl, alkenyl, halogen and mixtures thereof; X is selected from the group consisting of primary amines, secondary amines, tertiary amines, hydrogen, alkyl, alkenyl and mixtures thereof. Furthermore, the present invention refers to the use of an encapsulation layer element comprising polymer composition (I) according to the invention for increasing the Pmax determined after 96 h according to IEC 60904, by applying the foil method with a temperature of 85° C. and relative humidity of 60% and a potential difference of 1500 V, of a photovoltaic module comprising besides the encapsulation layer element a protective front layer element, a photovoltaic cell element and a protective back element, whereby at least one of the protective elements comprises glass.

公开(公告)号：US11981781B2

公开(公告)日：2024-05-14

申请号：US17276275

申请日：2019-09-26

申请人： BOREALIS AG

发明人： Oscar Prieto ,  Jeroen Oderkerk ,  Jari-Jussi Ruskeeniemi ,  Stefan Hellström ,  Tanja Piel ,  Daniela Mileva

IPC分类号： C08J3/24 ,  B29B9/12 ,  C08L23/08 ,  C08L51/06 ,  B29K23/00

CPC分类号： C08J3/248 ,  B29B9/12 ,  C08L23/0815 ,  C08L51/06 ,  B29K2023/16 ,  C08J2323/08 ,  C08L2310/00 ,  C08L2312/08

摘要： The present invention discloses a process for providing a cross-linked composition, the process comprising the steps of (a) providing an ethylene-α-olefin plastomer having—a density of from 850 kg/m3 to 900 kg/m3; and—an melt flow rate (ISO 1133, 2.16 kg, 190° C.) of 0.3 to 50 g/10 min; (b) grafting the ethylene-α-olefin plastomer with silane crosslinker such that the content of silane crosslinker is in the range of 0.1 to 10.0 wt. % with respect to the grafted ethylene-α-olefin plastomer; (c) contacting said grafted ethylene-α-olefin plastomer with 2 to 8 wt. % of a tin-free silane crosslinking catalyst with respect to the resulting mixture of grafted ethylene-α-olefin plastomer and tin-freesilane crosslinking catalyst, wherein said tin-free catalyst comprises a Brönsted acid at 23° C. and 50% relative humidity for at least 15 minutes thus forming a cross-linked composition, wherein gel content of said cross-linked composition after 15 min is at least 60%.

公开(公告)号：US11685840B2

公开(公告)日：2023-06-27

申请号：US16644537

申请日：2018-10-11

申请人： Borealis AG

发明人： Jeroen Oderkerk ,  Jari-Jussi Ruskeeniemi ,  Oscar Prieto ,  Stefan Hellström ,  Tanja Piel ,  Daniela Mileva

IPC分类号： C08F210/02 ,  C08F220/14 ,  C08F4/16 ,  E04D1/20 ,  A43B13/04 ,  C09D123/08 ,  B29C48/00 ,  B29K23/00 ,  C08K5/00

CPC分类号： C09D123/0892 ,  A43B13/04 ,  C08F4/16 ,  C08F210/02 ,  C08F220/14 ,  E04D1/20 ,  B29C48/022 ,  B29K2023/08 ,  C08K5/005 ,  C08K5/0025 ,  C08F210/02 ,  C08F220/14 ,  C08F230/085

摘要： The present invention provides a polyolefin composition, said composition comprising a terpolymer comprising a cross-linkable polyolefin comprising hydrolysable silane groups and a polar comonomer, the polyolefin composition further comprising a cross-linking catalyst and a silicon containing compound. The polar comonomer Is present in an amount of 5-35 wt %.

公开(公告)号：US20220275172A1

公开(公告)日：2022-09-01

申请号：US17632053

申请日：2020-08-12

申请人： Borealis AG

发明人： Stefan Hellström ,  Tina Gschneidtner ,  Susanne Nilsson ,  Bernt-Ake Sultan ,  Emma Hermansson

IPC分类号： C08K5/42 ,  C08K5/3492 ,  C08K5/3435 ,  C08K5/132

摘要： The present invention relates to a polyolefin composition comprising a cross-linkable polyolefin with hydrolysable silane groups; an acidic silanol condensation catalyst, wherein the acidic silanol condensation catalyst (B) is present in an amount of 0.0001 to 3 wt. % of the polyolefin composition; at least one UV stabilizer selected from the group consisting of phenols, triazines, benzophenones, triazoles and/or combinations thereof; and at least one UV stabilizer of the hindered amine type (HALS) which is present in an amount of 0.0001 to 0.1 wt. % of the polyolefin composition. The present invention also relates to an article comprising such a composition, and to the use of such a composition for the production of an article.