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    USE OF HYPERBRANCHED POLYCARBONATES AS A DISPERSING AGENT FOR PIGMENTS
    1.
    发明申请
    USE OF HYPERBRANCHED POLYCARBONATES AS A DISPERSING AGENT FOR PIGMENTS 审中-公开
    超级聚碳酸酯作为颜料分散剂的用途

    公开(公告)号：US20090093589A1

    公开(公告)日：2009-04-09

    申请号：US12299323

    申请日：2007-05-15

    申请人： Bernd Bruchmann ,  Andres Carlos Garcia Espino ,  Matthias Kluglein ,  Wolfgang Best ,  Joachim Jesse ,  Benno Sens

    发明人： Bernd Bruchmann ,  Andres Carlos Garcia Espino ,  Matthias Kluglein ,  Wolfgang Best ,  Joachim Jesse ,  Benno Sens

    IPC分类号： C08L69/00 ,  C08G64/02

    CPC分类号： C09B67/0063 ,  C08G64/0216 ,  C09B67/0066 ,  C09B67/009

    摘要： Use of high functionality hyperbranched polycarbonates obtainable bya) preparing one or more different condensation products (K) either bya1) reacting at least one organic carbonate (A) of the general formula RO[(CO)O]nR with at least one aliphatic, aliphatic/aromatic or aromatic alcohol (B) having at least 3 OH groups by elimination of alcohols ROH, where each R is independently a straight chain or branched aliphatic, aromatic-aliphatic or aromatic hydrocarbyl radical having 1 to 20 carbon atoms and the R radicals may also be bonded to each other to form a ring comprising the grouping —O[(CO)O]n—, where n is an integer from 1 to 5,ora2) reacting phosgene, diphosgene or triphosgene with the aliphatic, aliphatic/aromatic or aromatic alcohol (B) to liberate hydrogen chloride,the quantitative ratio of the alcohols (B) to the carbonates (A) or to the phosgenes in the reaction mixture being so chosen that the condensation products (K) comprise on average either one carbonate or carbamoyl chloride group and more than one OH group or one OH group and more than one carbonate or carbamoyl chloride group,andb) intermolecularly reacting the condensation products (K) from step a),as a dispersant for a pigment.

    摘要翻译： 通过a）制备一种或多种不同的缩合产物（K）的高官能度超支化聚碳酸酯的使用，通过a1）使通式RO [（CO）O] n R的至少一种有机碳酸酯（A）与至少一种脂族 ，通过消除醇ROH具有至少3个OH基团的脂族/芳族或芳族醇（B），其中每个R独立地是具有1至20个碳原子的直链或支链脂族，芳族 - 脂族或芳族烃基，R 自由基也可以彼此键合以形成包含分组-O [（CO）O] n - 的环，其中n是1至5的整数，或a2）使光气，双光气或三光气与脂族，脂族 /芳族或芳香族醇（B）以释放氯化氢，反应混合物中醇（B）与碳酸酯（A）或光气体的定量比被选择为使得缩合产物（K）平均包含 一个碳酸盐或卡巴莫 多于一个OH基团或一个OH基团和多于一个碳酸酯或氨基甲酰氯基团，和b）使来自步骤a）的缩合产物（K）与颜料分散反应。

    Highly functional polyetherols and the production and use thereof
    2.
    发明授权
    Highly functional polyetherols and the production and use thereof 有权
    高功能性聚醚类及其生产和使用

    公开(公告)号：US08946377B2

    公开(公告)日：2015-02-03

    申请号：US12866464

    申请日：2009-02-12

    申请人： Rolf Muelhaupt ,  Anne Fiedler ,  Fabian Schueler ,  Bernd Bruchmann ,  Markus Schuette ,  Daniel Schoenfelder

    发明人： Rolf Muelhaupt ,  Anne Fiedler ,  Fabian Schueler ,  Bernd Bruchmann ,  Markus Schuette ,  Daniel Schoenfelder

    IPC分类号： C08G63/668 ,  C08G63/688 ,  C08G63/695 ,  C08G63/82 ,  C08G65/28 ,  C08G65/34 ,  C08G65/26 ,  C08G65/30 ,  C08G65/46 ,  C08G65/48

    CPC分类号： C08G65/2609 ,  C08G65/30 ,  C08G65/34 ,  C08G65/46 ,  C08G65/48 ,  Y10S424/16

    摘要： The present invention relates to a process for preparing high-functionality polyetherols by reacting at least one trifunctional or higher-functionality alcohol and if appropriate further di- and/or monofunctional alcohols and/or modifying reagents, with the aid of acidic catalysts, where the trifunctional or higher-functionality alcohol is not glycerol. The present invention further relates to high-functionality polyetherols obtainable by such a process and to the use of these high-functionality polyetherols as adhesion promoters, thixotropic agents, rheology modifiers of polymers, phase transfer reagents, micro- or nanocontainers for biologically active compounds, for example for active medical ingredients, biocides, herbicides or fungicides, as pigment dispersants, an additive in printing inks or as structural units for preparing polyaddition or polycondensation polymers or for treatment of seed.

    摘要翻译： 本发明涉及通过在酸性催化剂的帮助下使至少一种三官能或更高官能度的醇与适当的其它二 - 和/或单官能醇和/或改性试剂反应制备高官能度聚醚的方法，其中 三官能或高官能醇不是甘油。 本发明还涉及通过这种方法获得的高官能度聚醚醚，以及这些高官能度聚醚类作为粘合促进剂，触变剂，聚合物的流变改性剂，相转移试剂，生物活性化合物的微型或纳米容器的用途， 例如用于活性医疗成分，杀生物剂，除草剂或杀真菌剂，作为颜料分散剂，印刷油墨中的添加剂或用于制备加聚或缩聚聚合物或用于种子处理的结构单元。

    Branched polyesters with sulfonate groups
    3.
    发明授权
    Branched polyesters with sulfonate groups 有权
    具有磺酸基团的支化聚酯

    公开(公告)号：US08901066B2

    公开(公告)日：2014-12-02

    申请号：US13495512

    申请日：2012-06-13

    申请人： Monika Haberecht ,  Juergen Detering ,  Bernd Bruchmann ,  Helmut Witteler ,  Heike Weber ,  Karl Kolter

    发明人： Monika Haberecht ,  Juergen Detering ,  Bernd Bruchmann ,  Helmut Witteler ,  Heike Weber ,  Karl Kolter

    IPC分类号： C11D3/37 ,  C11D1/00 ,  B08B3/04 ,  C08G63/91 ,  C02F5/10 ,  C08G63/688

    CPC分类号： C02F5/10 ,  C08G63/6884 ,  C08G63/918 ,  C11D3/378

    摘要： Branched polyesters with sulfonate groups can be obtained by reacting components A, B, optionally C, and optionally D to yield branched polyesters, then reacting these branched polyesters with hydrogen sulfite. Component A is at least one α,β-olefinically unsaturated dicarboxylic acid, component B is at least one di- or higher-functional alcohol, optional component C is at least one di- or higher-functional carboxylic acid or hydroxycarboxylic acid without an α,β-olefinically unsaturated bond, and optional component D is at least one compound of formula CH3(—O—CH2—CH2)n—OH. In reacting the branched polyesters with hydrogen sulfite, a molar amount of hydrogen sulfite is at most 95 mol %, based on an amount of α,β-olefinically unsaturated dicarboxylic acid.

    摘要翻译： 具有磺酸盐基团的支链聚酯可以通过使组分A，B，任选地C和任选的D反应得到支链聚酯，然后使这些支化聚酯与亚硫酸氢钠反应而获得。 组分A是至少一种α，β-烯属不饱和二羧酸，组分B是至少一种二官能或更高官能的醇，任选的组分C是至少一种二官能或更高官能的羧酸或羟基羧酸，没有 α，β-烯属不饱和键，任选的组分D是至少一种式CH3（-O-CH2-CH2）n-OH的化合物。 在使支化聚酯与亚硫酸氢钠反应时，基于α，α-烯属不饱和二羧酸的量，亚硫酸氢的摩尔量为至多95摩尔％。

    Hyperbranched polyesters and polycarbonates as demulsifiers for cracking crude oil emulsions
    6.
    发明授权
    Hyperbranched polyesters and polycarbonates as demulsifiers for cracking crude oil emulsions 失效
    超支化聚酯和聚碳酸酯作为用于裂化原油乳液的破乳剂

    公开(公告)号：US08618180B2

    公开(公告)日：2013-12-31

    申请号：US13142654

    申请日：2009-12-21

    申请人： Bernd Bruchmann ,  Andreas Eichhorn ,  Marcus Guzmann

    发明人： Bernd Bruchmann ,  Andreas Eichhorn ,  Marcus Guzmann

    IPC分类号： C10G33/04

    CPC分类号： C08G64/14 ,  B01D17/047 ,  C08G63/20 ,  C08G64/0216 ,  C08G64/1616 ,  C10G33/04 ,  C10G2300/1033

    摘要： The invention relates to the use of nondendrimeric, high-functionality hyperbranched polyesters and polycarbonates which are obtainable by reacting (i) at least one aliphatic, cycloaliphatic, araliphatic or aromatic dicarboxylic acid (A2) or derivatives thereof, or organic carbonates (A2′) with (ii) at least one x-hydric aliphatic, cycloaliphatic, araliphatic or aromatic alcohol (Cx) which has more than two OH groups, where x is a number greater than 2, preferably from 3 to 8, more preferably from 3 to 6, even more preferably from 3 to 4 and especially 3, and (iii) at least one fatty acid amide alkoxylate (D) of saturated or unsaturated C2-C30 fatty acid amides with an average of from 1 to 40 alkylene oxide units as demulsifiers for splitting crude oil emulsions.

    摘要翻译： 本发明涉及通过使（i）至少一种脂肪族，脂环族，芳脂族或芳族二羧酸（A2）或其衍生物或有机碳酸酯（A2'）的至少一种反应获得的非二烯丙基，高官能度超支化聚酯和聚碳酸酯的用途， 与（ii）具有多于两个OH基团的至少一种x-脂肪族，脂环族，芳脂族或芳族醇（C x），其中x是大于2，优选3至8，更优选3至6的数 ，甚至更优选3至4，特别是3，和（iii）至少一种饱和或不饱和C 2 -C 30脂肪酸酰胺的脂肪酸酰胺烷氧基化物（D），平均具有1至40个烯化氧单元作为破乳剂用于 分裂原油乳液。

    Impact-modified polyesters with hyperbranched polyesters/polycarbonates
    7.
    发明授权
    Impact-modified polyesters with hyperbranched polyesters/polycarbonates 有权
    具有超支化聚酯/聚碳酸酯的抗冲改性聚酯

    公开(公告)号：US08362146B2

    公开(公告)日：2013-01-29

    申请号：US11659506

    申请日：2005-08-02

    申请人： Andreas Eipper ,  Bernd Bruchmann ,  Carsten Weiβ ,  Jean-Francois Stumbe

    发明人： Andreas Eipper ,  Bernd Bruchmann ,  Carsten Weiβ ,  Jean-Francois Stumbe

    IPC分类号： C08G63/48

    CPC分类号： C08L67/02 ,  C08G63/20 ,  C08G64/0216 ,  C08L23/0884 ,  C08L23/16 ,  C08L51/04 ,  C08L67/00 ,  C08L69/00 ,  C08L101/005 ,  C08L2666/02 ,  C08L2666/18

    摘要： Thermoplastic molding compositions, comprising A) from 10 to 98% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, C) from 1 to 40% by weight of an impact-modifying polymer, D) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to D) is 100%.

    摘要翻译： 热塑性成型组合物，其包含A）10至98重量％的至少一种热塑性聚酯，B）0.01至50重量％的B1）至少一种高度支化或超支化聚碳酸酯，其OH数为1至600 mgKOH / g聚碳酸酯（根据DIN 53240，第2部分）或B2）至少一种AxBy类型的高度支化或超支化的聚酯，其中x为至少1.1且y为至少2.1，或其混合物，C ）1至40重量％的冲击改性聚合物，D）0至60重量％的其它添加剂，其中组分A）至D）的重量百分比的总和为100％。

    Flowable polyesters with carbodiimide stabilizers
    8.
    发明授权
    Flowable polyesters with carbodiimide stabilizers 失效
    具有碳二亚胺稳定剂的可流动聚酯

    公开(公告)号：US08362122B2

    公开(公告)日：2013-01-29

    申请号：US11815238

    申请日：2006-02-01

    申请人： Dietrich Scherzer ,  Bernd Bruchmann ,  Andreas Eipper ,  Karl Häberle ,  Carsten Weiss ,  Michaela Liese ,  Mark Völkel

    发明人： Dietrich Scherzer ,  Bernd Bruchmann ,  Andreas Eipper ,  Karl Häberle ,  Carsten Weiss ,  Michaela Liese ,  Mark Völkel

    IPC分类号： C08G18/28

    CPC分类号： C08L67/02 ,  C08K5/29 ,  C08L67/00 ,  C08L69/00 ,  C08L101/00 ,  C08L2666/02 ,  C08L2666/18

    摘要： Thermoplastic molding compositions comprising A) from 10 to 98.9% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, part 2), or B2) at least one highly branched or hyperbranched polyester of the AxBy type where x is at least 1.1 and y is at least 2.1 or mixtures thereof C) from 0.1 to 10% by weight of at least one carbodiimide, D) from 0 to 60% by weight of further additives, the sum of the percentages by weight of components A) to D) adding up to 100%.

    摘要翻译： 热塑性成型组合物，其包含A）10至98.9重量％的至少一种热塑性聚酯，B）0.01至50重量％的B1）至少一种高度支化或超支化聚碳酸酯，其OH数为1至600mg KOH / g聚碳酸酯（根据DIN 53240，第2部分）或B2）至少一种AxBy型的高支化或超支化聚酯，其中x为至少1.1，y为至少2.1或其混合物。C）0.1至10 至少一种碳化二亚胺的重量％，D）0至60重量％的其它添加剂，组分A）至D）的重量百分数之和为D）加起来至100％。

    Alkoxylated Hyperbranched Polycarbonates for Solubilizing Poorly Soluble Active Ingredients
    9.
    发明申请
    Alkoxylated Hyperbranched Polycarbonates for Solubilizing Poorly Soluble Active Ingredients 有权
    用于溶解不良溶解活性成分的烷氧基化超支化聚碳酸酯

    公开(公告)号：US20120309629A1

    公开(公告)日：2012-12-06

    申请号：US13514332

    申请日：2010-12-03

    申请人： Holger Türk ,  Monika Haberecht ,  Bernd Bruchmann ,  Andreas Kunst ,  Daniel Schönfelder ,  Michael Ishaque

    发明人： Holger Türk ,  Monika Haberecht ,  Bernd Bruchmann ,  Andreas Kunst ,  Daniel Schönfelder ,  Michael Ishaque

    IPC分类号： A01N25/02 ,  A61K8/85 ,  A01P13/00 ,  C07C69/96 ,  A01P3/00 ,  A01P7/04 ,  A01P7/02 ,  A61K47/34 ,  A01P21/00

    CPC分类号： A01N25/30 ,  C08G64/0216 ,  A01N47/24

    摘要： The present invention provides a composition comprising an active ingredient whose solubility in water at 20° C. is not more than 10 g/L, and an amphiphile comprising an alkoxylated hyperbranched polycarbonate, wherein the polycarbonate comprises an alcohol which is a trifunctional or higher polyfunctional polyetherol based on a C3-C12 alkylene oxide and an alcohol which has at least three OH groups. Likewise provided is an amphiphile comprising the polycarbonate, and a process for preparing the amphiphile. The invention further relates to the use of the amphiphile for solubilizing an active ingredient whose solubility in water at 20° C. is not more than 10 g/L, in aqueous solutions, and a method of controlling phytopathogenic fungi and/or unwanted plant growth and/or unwanted insect or mite infestation and/or of regulating the growth of plants.

    摘要翻译： 本发明提供一种组合物，其包含其在20℃下在水中的溶解度不超过10g / L的活性成分和包含烷氧基化超支化聚碳酸酯的两亲物，其中所述聚碳酸酯包含三官能或更高官能度的醇 基于C3-C12环氧烷的聚醚类和具有至少三个OH基的醇。 同样提供包含聚碳酸酯的两亲物和制备两亲物的方法。 本发明还涉及两亲物在水溶液中溶解在20℃下在水中的溶解度不超过10g / L的活性成分的用途，以及控制植物病原真菌和/或不需要的植物生长的方法 和/或不期望的昆虫或螨虫侵袭和/或调节植物的生长。