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公开(公告)号:US06974852B2
公开(公告)日:2005-12-13
申请号:US10889018
申请日:2004-07-13
申请人: Bernd Stanger , Peter Keller , Eckehardt Wistuba , Andree Dragon
发明人: Bernd Stanger , Peter Keller , Eckehardt Wistuba , Andree Dragon
CPC分类号: C08F2/24 , B01F17/0057 , C04B24/26 , C09D5/027 , Y10S526/91 , Y10S526/911 , Y10S526/932
摘要: An emulsifier system comprising a) a salt of a sulfuric monoester of a C9-C15 alcohol or of an alkoxylated C9-C15 alcohol, and b) an alkoxylated C8-C16 alcohol, and the use of this emulsifier system for preparing aqueous polymer dispersions.
摘要翻译: 一种乳化剂体系,其包含a)C 9 -C 15醇的硫酸单酯或烷氧基化C 9 -C 15醇的盐, 并且b)烷氧基化的C 8 -C 16醇,以及使用该乳化剂体系来制备聚合物水分散体。
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公开(公告)号:US5348993A
公开(公告)日:1994-09-20
申请号:US15426
申请日:1993-02-09
申请人: Bernd Daeumer , Andree Dragon , Wilhelm F. Beckerle , Gernot Franzmann , Josef Neutzner , Eckehardt Wistuba , Joachim Pakusch , Maximilian Angel
发明人: Bernd Daeumer , Andree Dragon , Wilhelm F. Beckerle , Gernot Franzmann , Josef Neutzner , Eckehardt Wistuba , Joachim Pakusch , Maximilian Angel
摘要: Aqueous polymer dispersions contain, as a dispersant, a mixture of an ethylene oxide/propylene oxide copolymer, an ethoxylated alkylphenol and/or an ethoxylated fatty alcohol, an ethoxylated polysaccharide and, if required, as a further component, sulfuric acid half-esterified with an ethoxylated alkylphenol and/or an ethoxylated fatty alcohol.
摘要翻译: 聚合物水分散体含有作为分散剂的环氧乙烷/环氧丙烷共聚物,乙氧基化烷基酚和/或乙氧基化脂肪醇的混合物,乙氧基化多糖,如果需要,作为另外的组分含有硫酸,其与 乙氧基化烷基酚和/或乙氧基化脂肪醇。
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公开(公告)号:US4980411A
公开(公告)日:1990-12-25
申请号:US292311
申请日:1988-12-30
申请人: Wilhelm F. Beckerle , Andree Dragon , Gernot Franzmann , Lothar Matthaei , Eckehardt Wistuba , Helmut Teichmann
发明人: Wilhelm F. Beckerle , Andree Dragon , Gernot Franzmann , Lothar Matthaei , Eckehardt Wistuba , Helmut Teichmann
IPC分类号: C09D133/10 , C08L33/02 , C09D133/04 , C09D133/06
CPC分类号: C09D133/06 , C08L33/02
摘要: Binders for non-tacky, non-soiling, flexible coatings based on aqueous copolymer dispersions which contain zinc-amine complexes essentially consist of(A) from 99 to 90% by weight of a (meth)acrylate copolymer dispersion whose polymer has a glass transition temperature of from -40.degree. to -1.degree. C. and(B) from 1 to 10% by weight of a water-soluble zinc-amine complex salt of a polymeric carboxylic acid,the percentages by weight being based on the total amount of polymer.
摘要翻译: 基于含有锌 - 胺配合物的含水共聚物分散体的非粘性,不污染柔软涂层的粘合剂基本上由(A)99-90%重量的聚合物具有玻璃化转变的(甲基)丙烯酸酯共聚物分散体 温度为-40℃至-1℃,和(B)1至10重量%的聚合羧酸的水溶性锌 - 胺络合盐,其重量百分比基于 聚合物。
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公开(公告)号:US06258890B1
公开(公告)日:2001-07-10
申请号:US08745924
申请日:1996-11-08
IPC分类号: C08K506
CPC分类号: C08F212/06 , C08F236/10 , C09D125/10 , Y10T428/31884 , Y10T428/31891 , Y10T428/31906 , Y10T428/31935
摘要: An aqueous polymer dispersion whose polymer is composed of vinyl-aromatic structures and conjugated dienes, and which has a reduced content of alkali metal ions, is used for producing water-vapor barriers; the invention also relates to the aqueous, low alkali metal polymer dispersion itself.
摘要翻译: 聚合物由乙烯基 - 芳族结构和共轭二烯组成并且具有降低的碱金属离子含量的聚合物水分散体用于生产水蒸汽屏障; 本发明还涉及水性低碱金属聚合物分散体本身。
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公开(公告)号:US07112626B1
公开(公告)日:2006-09-26
申请号:US09582216
申请日:1998-12-18
申请人: Peter Fickeisen , Martin Meister , Bernd Reck , Dieter Urban , Eckehardt Wistuba , Thomas Koch , Georg Langhauser
发明人: Peter Fickeisen , Martin Meister , Bernd Reck , Dieter Urban , Eckehardt Wistuba , Thomas Koch , Georg Langhauser
IPC分类号: C08L33/08 , C08L33/10 , C08K3/26 , C08K3/34 , C09J133/08
CPC分类号: C09J11/00 , C08L2666/54 , C09J157/00 , Y10S524/914 , Y10S524/915
摘要: An aqueous composition comprises a mixture of from 10 to 50% by weight of a polymer A) having a gel content of less than 40% by weight and a number-average molecular weight Mn of the soluble fractions of less than 30,000 and from 50 to 90% by weight of a filler B), the amounts by weight being based on the weight sum of the polymer and of the filler.
摘要翻译: 水性组合物包含10至50重量%的聚合物A)的混合物,该聚合物A)的凝胶含量小于40重量%,数均分子量M n n可溶部分 小于30,000和50至90重量%的填料B),重量的量基于聚合物和填料的重量之和。
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6.
公开(公告)号:US06710118B2
公开(公告)日:2004-03-23
申请号:US10288528
申请日:2002-11-06
申请人: Markus Koppers , Marco Schmidt , Thomas Anselmann , Jürgen Schmidt-Thümmes , Mike Zott , Eckehardt Wistuba
发明人: Markus Koppers , Marco Schmidt , Thomas Anselmann , Jürgen Schmidt-Thümmes , Mike Zott , Eckehardt Wistuba
IPC分类号: C08F3606
CPC分类号: C09D125/08 , C08F212/04 , C08F236/10 , Y10T428/31891 , Y10T428/31906 , Y10T428/31931 , Y10T428/31935 , C08F2/22
摘要: An aqueous polymer dispersion whose polymer, present in disperse distribution, is composed in free-radically polymerized form of from 20 to 65% by weight of at least one vinylaromatic monomer (monomers A), from 30 to 75% by weight of at least one monomer having two conjugated, ethylenically unsaturated double bonds (monomers B), and from 0.5 to 10% by weight of at least one other monomer, C, selected from the group consisting of &agr;,&bgr;-monoethyienically unsaturated mono- and dicarboxylic acids and amide or ester derivatives thereof and whose alkali metal ion content GA, based on the mass of the dispersed polymer, is ≧0.5% by weight, the pH of the aqueous dispersion medium being adjusted to a value below 6.
摘要翻译: 一种聚合物水分散体,其分散分布中的聚合物以自由基聚合的形式由20至65重量%的至少一种乙烯基芳族单体(单体A),30至75重量%的至少一种单体 具有两个共轭的烯属不饱和双键(单体B)和0.5至10重量%的至少一种其它单体C,选自α,β-单异乙烯基不饱和单羧酸和二羧酸以及酰胺或酯 其衍生物,其碱金属离子含量GA基于分散聚合物的质量为≥0.5重量%,将水性分散介质的pH调节至小于6的值。
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公开(公告)号:US06593421B2
公开(公告)日:2003-07-15
申请号:US09982939
申请日:2001-10-22
IPC分类号: C08L2510
CPC分类号: C08F236/10 , C08K3/26 , C08L93/04 , C08L2666/26 , C09J113/00
摘要: An aqueous composition containing from 1 to 60% by weight of a polymer A) built up from a) from 10 to 50% by weight of a vinylaromatic having up to 20 carbon atoms, b) from 45 to 75% by weight of a nonaromatic hydrocarbon having two conjugated double bonds, c) from 0 to 20% by weight of a water-soluble monomer having a water solubility of at least 100 g per liter of water under standard conditions (21° C. and 1 bar), the water-soluble monomer containing no acid group or acid anhydride group, d) from 0.1 to 4.5% by weight of a monomer containing at least one acid group or acid anhydride group, e) from 0 to 30% by weight of a monomer other than a) to d), and from 40 to 99% by weight of a filler B), the weight data for A) and B) being based on the sum of A) and B).
摘要翻译: 含有1至60重量%的聚合物A)的水性组合物,其由a)10至50重量%的至多20个碳原子的乙烯基芳族化合物组成,b)45至75重量%的非芳族烃 具有两个共轭双键,c)在标准条件(21℃和1巴)下,0至20重量%的水溶性单体的水溶解度至少为100g /升水, 不含酸性基团或酸酐基团的可溶性单体,d)0.1〜4.5重量%的含有至少一个酸基或酸酐基团的单体,e)0〜30重量%的除a) 至d),和40至99重量%的填料B),A)和B)的重量数据基于A)和B)的总和。
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公开(公告)号:US06291573B1
公开(公告)日:2001-09-18
申请号:US09210765
申请日:1998-12-14
申请人: Joachim Pakusch , Bernd Reck , Peter Claassen , Hans-Jürgen Denu , Eckehardt Wistuba , Claudia Heibel
发明人: Joachim Pakusch , Bernd Reck , Peter Claassen , Hans-Jürgen Denu , Eckehardt Wistuba , Claudia Heibel
IPC分类号: C08L2904
CPC分类号: C08J3/16 , C04B24/2676 , C04B24/2688 , C04B26/04 , C04B2103/0057 , C08J2325/08
摘要: The present invention relates to a process for preparing polymer powders from aqueous polymer dispersions in which the dispersed polymer P comprises in copolymerized form: i) at least one vinylaromatic monomer (a), ii) 1,3-butadiene as monomer (b), and iii) one or more monomers (c) different than the monomers (a) and (b), which comprises drying the aqueous polymer dispersion in the presence of polyvinyl alcohol as drying agent. The present invention also relates to the polymer powders obtainable by this process and to the use of these polymer powders as binders in paints, varnishes and coating compositions generally, in adhesives, and for modifying mineral construction materials. The present invention also relates to mineral construction materials in the form of dry formulations comprising the polymer powders of the invention.
摘要翻译: 本发明涉及一种由聚合物水分散体制备聚合物粉末的方法,其中分散的聚合物P以共聚形式包含:i)至少一种乙烯基芳族单体(a),ii)1,3-丁二烯作为单体(b), 和ii)与单体(a)和(b)不同的一种或多种单体(c),其包括在聚乙烯醇存在下干燥聚合物水分散体作为干燥剂。 本发明还涉及通过该方法获得的聚合物粉末以及这些聚合物粉末作为粘合剂在粘合剂中的用途,通常用于粘合剂和用于改性矿物建筑材料中的粘合剂。 本发明还涉及包含本发明的聚合物粉末的干制剂形式的矿物构造材料。
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公开(公告)号:US06169132A
公开(公告)日:2001-01-02
申请号:US09325044
申请日:1999-06-03
申请人: Peter Fickeisen , Eckehardt Wistuba
发明人: Peter Fickeisen , Eckehardt Wistuba
IPC分类号: C08L9304
CPC分类号: C09J193/00 , C08L25/00 , C08L27/00 , C08L33/00 , C08L2666/04 , C08L2666/08 , Y10S524/915
摘要: Aqueous composition comprising from 10 to 35% by weight of a water-dispersed polymer A) having a glass transition temperature Tg of below −10° C. from 5 to 22% by weight of a resin B) which is liquid at 23° C. and 1 bar, has a glass transition temperature of below −10° C. and in which abietic acid is soluble at 23° C. and 1 bar such that it is possible to obtain solutions of resin B and abietic acid having a weight content of up to 50% by weight of abietic acid from 5 to 22% by weight of a resin C) which is based on abietic acid or on modified abietic acid and has a glass transition temperature of from 0 to 90° C. and from 21 to 80% by weight of a filler D), the percentages by weight being based on the sum of the constituents of the aqueous composition with the exception of water.
摘要翻译: 水性组合物,其包含10至35重量%的玻璃化转变温度Tg低于-10℃的水分散聚合物A),其重量比为5至22重量%的在23℃下为液体的树脂B) 和1巴,玻璃化转变温度低于-10℃,其中松香酸在23℃和1巴下溶解,使得可以获得重量含量为的树脂B和松香酸的溶液 至多50重量%的松香酸,其为5至22重量%的基于松香酸或改性松香酸的树脂C),并且具有0至90℃的玻璃化转变温度和21至80% 的填料D),重量百分比是基于除了水以外的水性组合物的组分的总和。
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公开(公告)号:US5486586A
公开(公告)日:1996-01-23
申请号:US440119
申请日:1995-05-12
申请人: Hubertus Kroener , Eberhard Schupp , Eckehardt Wistuba , Oral Aydin , Elmar Schwarzenbach , Klaus Schnell
发明人: Hubertus Kroener , Eberhard Schupp , Eckehardt Wistuba , Oral Aydin , Elmar Schwarzenbach , Klaus Schnell
IPC分类号: C08F16/26 , C08F16/14 , C08F16/16 , C08F16/28 , C08F16/30 , C08F216/18 , C09J129/00 , C09J129/10 , C08F16/12
CPC分类号: C09J129/10
摘要: Adhesives containing polyvinyl ether copolymers having a weight average molecular weight of >10,000, comprisea) from 0 to 95% by weight of vinyl ethers of the formula IH.sub.2 C.dbd.CH--O--Rb) from 5 to 100% by weight of hydrophilic vinyl ethers of the formula IIH.sub.2 C.dbd.CH--O--R.sup.1andc) from 0 to 30% by weight of further monomers,where R is C.sub.1 -C.sub.20 -alkyl and R.sup.1 is an aliphatic or cycloaliphatic radical which may be substituted by hydroxyl groups or interrupted by nonadjacent groups --Y--, Y is oxygen, sulfur or a group NR.sup.2 or N.sup.+ R.sup.2 R.sup.3 X.sup.-, R.sup.2 and R.sup.3 independently of one another are each hydrogen or C.sub.1 -C.sub.4 -alkyl and X.sup.- is a counter-anion, and the molar ratio of carbon atoms to the sum of groups Y and hydroxyl groups in the aliphatic or cycloaliphatic radical is from 1.01:1 to 6.5:1.
摘要翻译: 包含重均分子量> 10,000的聚乙烯醚共聚物的粘合剂包含a)0至95重量%的式I的乙烯基醚H 2 C = CH-OR b)5至100重量%的亲水乙烯基醚 的式IIH 2 C = CH-O-R 1和c)0至30重量%的另外的单体,其中R是C 1 -C 20 - 烷基,R 1是可以被羟基取代或被中断的脂族或脂环族基团 通过不相邻的基团-Y-,Y是氧,硫或基团NR2或N + R2R3X-,R2和R3彼此独立地各自是氢或C1-C4-烷基,X是抗衡阴离子, 脂肪族或脂环族基团中碳原子与基团Y和羟基之和的比例为1.01:1至6.5:1。
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