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公开(公告)号：US4745216A
公开(公告)日：1988-05-17
申请号：US715716
申请日：1985-03-25
IPC分类号： C07C265/00 , C07C67/00 , C07C71/00 , C07C241/00 , C07C263/10 , C07C265/14
CPC分类号： C07C263/10 , C07C263/20
摘要： Polyisocyanates are produced by reacting a polyamide solution with a phosgene solution. After the product polyisocyanate has been recovered, the solvent or a portion of the solvent employed is treated with crosslinked polymers insoluble in the solvent which polymers contain primary and/or secondary alcoholic hydroxyl groups and/or primary and/or secondary amino groups. After treatment, the polymer and any reaction products are removed. The solvent may then be reused. Preferred solvents are chlorobenzene and o-dichlorobenzene. The preferred polymers are bead polymers or bead copolymers of (meth)acrylic acid or styrene/divinyl benzene copolymer.
摘要翻译： 聚异氰酸酯通过聚酰胺溶液与光气溶液反应制备。 在产物多异氰酸酯已被回收之后，溶剂或所用溶剂的一部分用不溶于溶剂的交联聚合物处理，该聚合物含有伯和/或仲醇羟基和/或伯和/或仲氨基。 处理后，除去聚合物和任何反应产物。 然后可以重新使用溶剂。 优选的溶剂是氯苯和邻二氯苯。 优选的聚合物是（甲基）丙烯酸或苯乙烯/二乙烯基苯共聚物的珠粒聚合物或珠粒共聚物。
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公开(公告)号：US4563371A
公开(公告)日：1986-01-07
申请号：US565081
申请日：1983-12-23
IPC分类号： C22C1/08 , B01J20/02 , B01J23/44 , B01J37/30 , C23C18/20 , C23C18/28 , C23C20/04 , B05D3/04 , B01J31/08 , B05D1/18 , B05D3/10
CPC分类号： C23C18/28 , C23C18/1644 , C23C18/208 , C23C18/30
摘要： The metallization of porous solid bodies, such as, for example, ion exchange materials, by loading the surfaces of the metal-free substrates with transition metal ions and subsequently treating them with reducing agents can be improved by activating the substrates, before or after the loading with metal ions, with elements of group 1 or 8 of the periodic table or compounds thereof and sensitizing any activating ions still present. The metallization products are useful hydrogenation catalysts.
摘要翻译： 通过用过渡金属离子加载无金属底物的表面并随后用还原剂处理它们的多孔固体物质例如离子交换材料的金属化可以通过在底物之前或之后激活而改善 用金属离子负载周期表中第1或8族的元素或其化合物，并使任何仍然存在的活化离子敏化。 金属化产物是有用的氢化催化剂。
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公开(公告)号：US5012031A
公开(公告)日：1991-04-30
申请号：US320262
申请日：1989-03-07
申请人： Bernhard Schleppinghoff , Hans-Ludwig Niederberger , Christian Gabel , Peter M. Lange , Alfred Mitschker
发明人： Bernhard Schleppinghoff , Hans-Ludwig Niederberger , Christian Gabel , Peter M. Lange , Alfred Mitschker
IPC分类号： C07C1/20
CPC分类号： C07C1/20 , C07C2531/10
摘要： Tert.-olefins are obtained in high purity by cleavage of their alkyl ethers, when the catalysts used for this purpose are styrene/divinylbenzene resins which contain sulphonic acid groups and have a macroporous structure and the polymer matrix of which has an internal surface area of at least 400 m.sup.2 /g, a pore volume (porosity) of 0.6-2.5 ml/g and a mean pore diameter of 40-1000 .ANG.. These catalysts show long service lives.
摘要翻译： 当用于此目的的催化剂是含有磺酸基团并且具有大孔结构并且其聚合物基质的内表面积为的苯乙烯/二乙烯基苯树脂时，通过其烷基醚的裂解获得高纯度的烯烃 至少400m 2 / g，孔体积（孔隙率）为0.6-2.5ml / g，平均孔径为40-1000安培。 这些催化剂使用寿命长。
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公开(公告)号：US4695556A
公开(公告)日：1987-09-22
申请号：US909995
申请日：1986-09-22
摘要： The invention relates to a new process for the preparation of strongly acid cation exchangers loaded with catalytically active metals by loading the cation exchangers with a solution of a salt of the catalytically active metal and reducing the cation exchangers loaded with metal ions, according to which the loading of the cation exchangers is carried out at temperatures from 50.degree. to 120.degree. C. and formic acid is used as the reducing agent; the invention also relates to the catalyst resins which can be obtained by the process.
摘要翻译： 本发明涉及一种用于制备负载催化活性金属的强酸阳离子交换剂的新方法，其通过用催化活性金属的盐的溶液负载阳离子交换剂并还原负载有金属离子的阳离子交换剂，根据该方法， 阳离子交换剂的负载在50〜120℃的温度下进行，甲酸用作还原剂; 本发明还涉及可以通过该方法获得的催化剂树脂。
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5.发明授权Preparation and use of ion exchange resins loaded with quinolonecarboxylic acid derivatives 失效离子交换树脂与喹啉羧酸衍生物的制备和使用
公开(公告)号：US5152986A
公开(公告)日：1992-10-06
申请号：US426123
申请日：1989-10-24
申请人： Peter M. Lange , Alfred Mitschker , Arundev H. Naik , Hubert Rast , Martin Scheer , Herbert Voege
发明人： Peter M. Lange , Alfred Mitschker , Arundev H. Naik , Hubert Rast , Martin Scheer , Herbert Voege
IPC分类号： C08J5/20 , A23K1/00 , A23K1/16 , A61K9/00 , A61K9/18 , A61K31/44 , A61K31/47 , A61K31/495 , A61K31/535 , A61K47/30 , A61K47/48 , B01J39/18 , B01J41/12
CPC分类号： A61K47/48184 , A61K31/44 , A61K31/47 , A61K31/535
摘要： Known antibacterial quinolonecarboxylic acid derivatives such as ciprofloxacin are administered to animals in their food in the form of weak cation exchangers loaded therewith. The taste is much improved and the animals accept the material more readily.
摘要翻译： 将已知的抗菌喹诺酮羧酸衍生物如环丙沙星以其负载的弱阳离子交换剂的形式施用于其食物中的动物。 味道大大改善，动物更容易接受材料。
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公开(公告)号：US5059306A
公开(公告)日：1991-10-22
申请号：US541555
申请日：1990-06-21
CPC分类号： C07C7/14875
摘要： In the removal of pure aromatics from aromatic-containing hydrocarbon mixtures by liquid-phase extraction or extractive distillation using a selective solvent, the specific cost of separation can be reduced at the same yield of aromatics or the yield of aromatics can be increased at the same specific cost of separation if the liquid-phase extraction or the extractive distillation is carried out in the presence of a reactive solid. At the same time, substantially aromatic-free raffinates are obtained.
摘要翻译： 在通过使用选择性溶剂的液相萃取或萃取蒸馏从含芳烃的烃混合物中除去纯芳烃时，可以以相同的芳族化合物产率降低分离的具体成本，或者相同的芳族化合物的产率可以提高 如果在反应性固体的存在下进行液相萃取或萃取蒸馏，则具体的分离成本。 同时，获得基本上无芳香族的残余物。
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7.发明授权Process for the preparation of bifunctional anion exchange resins, new bifunctional anion exchange resins and use thereof 失效双功能阴离子交换树脂的制备方法，新型双功能阴离子交换树脂及其用途
公开(公告)号：US4988738A
公开(公告)日：1991-01-29
申请号：US373836
申请日：1989-06-30
申请人： Alfred Mitschker , Peter M. Lange , Harold Heller , Friedrich Werner , Hans-Karl Soest , Gunter Siegers
发明人： Alfred Mitschker , Peter M. Lange , Harold Heller , Friedrich Werner , Hans-Karl Soest , Gunter Siegers
CPC分类号： B01J41/14 , B01J41/043
摘要： A process for the preparation of a bifunctional anion exchange resin by partial quaternization of a weakly basic anion exchanger containing tertiary amino groups which process comprises (a) partially loading the weakly basic anion exchanger with a strong acid and (b) quaternizing the partially loaded anion exchanger by means of a customary alkylating agent.
摘要翻译： 通过含有叔氨基的弱碱性阴离子交换剂的部分季铵化制备双功能阴离子交换树脂的方法，该方法包括（a）用强酸部分负载弱碱性阴离子交换剂和（b）将部分负载的阴离子季铵化 交换器通过常规的烷基化剂。
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公开(公告)号：US4943420A
公开(公告)日：1990-07-24
申请号：US337585
申请日：1989-04-13
申请人： Alfred Mitschker , Peter M. Lange , Heiko Hoffmann , Gunter Lossmann , Andries P. van der Meer , Cornelius J. Smit
发明人： Alfred Mitschker , Peter M. Lange , Heiko Hoffmann , Gunter Lossmann , Andries P. van der Meer , Cornelius J. Smit
CPC分类号： C01G15/003 , C22B3/24 , Y02P10/234 , Y10S423/14
摘要： In the process for recovering gallium from aqueous, alkaline solutions by adsorption of the gallium on to bead-polymerized synthetic resins impregnated with 8-hydroxyquinolines and elution thereof with aqueous acids, the synthetic resins employed according to the invention are macroporous polydivinylbenzene or macroporous divinylbenzene copolymers which have been obtained by bead polymerization of divinylbenzene or mixtures of aromatic mono-, di- and/or trivinylbenzenes containing at least 50% by weight of divinylbenzene, in the presence of methyl isobutyl ketone, and which have been loaded with 160-190 g of Kelex 100 per liter of resin; in addition the resin is washed with sodium hydroxide solution after the elution step and before the commencement of each individual service cycle.
摘要翻译： 在通过将镓吸附到用8-羟基喹啉浸渍的珠光聚合的合成树脂上并用含水酸洗脱的水性碱性溶液中回收镓的方法中，根据本发明使用的合成树脂是大孔聚二乙烯基苯或大孔二乙烯基苯共聚物 其通过二甲基苯的珠聚合或含有至少50重量％的二乙烯基苯的芳族单，二和/或三乙烯苯的混合物在甲基异丁基酮的存在下获得，并且已经装载了160-190g 的Kelex 100每升树脂; 此外，在洗脱步骤之后和在每个单独的使用周期开始之前，用氢氧化钠溶液洗涤树脂。
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9.发明授权Bead-shaped crosslinked copolymers containing epoxide groups and basic amino groups, a process for their preparation and their use 失效包含环氧基团和碱性氨基的珠状交联共聚物，其制备方法及其应用
公开(公告)号：US4772635A
公开(公告)日：1988-09-20
申请号：US934877
申请日：1986-11-25
IPC分类号： B01J20/281 , B01J20/26 , B01J20/285 , B01J41/14 , C07K1/16 , C07K16/00 , C08F2/16 , C08F2/22 , C08F2/44 , C08F16/14 , C08F16/26 , C08F20/32 , C08F20/34 , C08F20/36 , C08F216/14 , C08F220/32 , C08F220/36 , C08G59/50 , C08L101/00 , C08L101/06 , C12N11/08 , G01N30/88 , C08C19/22 , C08F24/00
CPC分类号： B01J20/261 , B01J20/26 , B01J20/267 , B01J41/14 , C08F216/1416 , C08F220/32 , C12N11/08
摘要： The invention relates to new bead-shaped crosslinked macroporous copolymers containing epoxide groups and basic amino groups, which are obtainable by reacting polymerizable glycidyl compounds, before or during free radical bead polymerization, which is carried out in the presence of agents which impart porosity and, if appropriate, with the addition of polyvinyl compounds which can be polymerized by free radical polymerization, with amines which are capable of reacting with at least two epoxide groups, a process for their preparation and their use, for example, for binding biologically active substances, for the preparation of strongly basic anion exchangers and hydrophilic chromatography resins for biomaterials.
摘要翻译： 本发明涉及包含环氧基团和碱性氨基的新的珠状交联的大孔共聚物，其可通过可聚合的缩水甘油基化合物在自由基珠子聚合之前或期间获得，其在赋予孔隙率的试剂存在下进行， 如果合适，加入可以通过自由基聚合聚合的聚乙烯基化合物与能够与至少两个环氧基团反应的胺，其制备方法及其用途，例如结合生物活性物质， 用于制备用于生物材料的强碱性阴离子交换剂和亲水层析树脂。
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公开(公告)号：US4511722A
公开(公告)日：1985-04-16
申请号：US466807
申请日：1983-02-16
IPC分类号： B01J41/08 , B01J41/09 , C07D207/26 , C07D207/267 , C07D207/27 , C07D209/48 , C07D233/32 , C07D233/74 , C07D263/22 , C08F26/00 , C08F26/06 , C07D263/20 , C07D209/40 , C07D207/12
CPC分类号： C07D207/267 , B01J41/085 , C07D207/27 , C07D209/48 , C07D233/32 , C07D263/22 , C08F26/06
摘要： Cyclic N-vinylacylamines are prepared by heating carbonic acid esters of cyclic N-2-hydroxyethylacylamines in the presence of a catalytic amount of alkali or alkaline earth metal compound having an alkaline reaction and subsequently distilling the reaction mixture.Cyclic N-vinylacylamines are valuable precursors for preparing plant protection agents and medicaments and serve as polymerization and copolymerization components for preparing plastics, surface coatings, paints and ion exchange materials.
摘要翻译： 在催化量的具有碱性反应的碱金属或碱土金属化合物的存在下，加热环状N-2-羟乙基酰胺的碳酸酯，然后蒸馏反应混合物，制备环状N-乙烯基酰胺。 环状N-乙烯基酰胺是制备植物保护剂和药物的有价值的前体，并且用作制备塑料，表面涂料，油漆和离子交换材料的聚合和共聚组分。
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